Content deleted Content added
m fix capitalization, fix formatting, mark ref link broken, add MSDS link |
|||
Line 1:
[[File:DEF_CanTire.jpg|thumb|right|upright|Diesel exhaust fluid for sale in small quantities]]
'''Diesel Exhaust Fluid''' (
The [[German Association of the Automotive Industry]] (VDA) ensures quality standards are maintained in accordance with ISO 22241 specifications.
== Chemistry ==
Diesel engines run with a [[lean burn]] air-to-fuel ratio ([[Stoichiometry#Stoichiometry of combustion|overstoichiometric]] ratio) to ensure the full combustion of soot and prevent unburnt fuel from being exhausted. The excess of oxygen necessarily leads to generation of [[NOx|nitrogen oxides]] (NO<sub>x</sub>), which are harmful [[pollutant]]s, from the nitrogen in the air. Selective catalytic reduction is used to reduce the amount of NO<sub>x</sub> released into the atmosphere. Diesel exhaust fluid (from a separate DEF tank) is injected into the exhaust pipeline, the aqueous urea vaporizes and decomposes to form [[ammonia]] and [[carbon dioxide]].
== Storage ==
SCR systems are sensitive to potential chemical impurities in the urea solution, therefore the [[solvent]] is [[Water purification#Demineralized water|demineralized water]]. The urea solution is clear, non-toxic and safe to handle. However, it can [[Corrosion|corrode]] some metals and so must be stored and transported carefully.
DEF is stored in a tank on board the vehicle, and injected into the exhaust stream by a metering system at a rate of 2% of
Diesel
In the UK the storage of DEF is now under scrutiny of the Environment Agency who are proposing new controls following an number of spills of DEF into the environment. Although not toxic, DEF can cause the catastrophic de-oxidation of water bodies leading to damage of the aquatic environment.<ref>{{brokenlink}}{{cite web|url=http://www.environment-agency.gov.uk/business/topics/pollution/39083.aspx|title=Large spills into water bodies}}</ref>
==References==
Line 23:
*[http://www.discoverdef.com Diesel Exhaust Fluid search engine for North America]
*[http://www.FactsAboutSCR.com FactsAboutSCR.com] North American SCR Stakeholders Group
*[http://www.noxblue.com/products/NOxBLUE-msds.pdf MSDS sheet]
<!-- PLEASE DISCUSS ON THE TALK PAGE BEFORE ADDING COMMERCIAL LINKS. See also http://en.wikipedia.org/wiki/WP:EL -->
|