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Absorption and emission spectra of Tl1+ with mixture of oxide and chloride ligands in glasses

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Abstract

Absorption and emission spectra of Tl1+ in a series of (16−x)R2O, 2x RCl, 84B2O3 glasses (where R refers to Na or K, andx varies from 0 to 4 mole) have been studied; and the results compared with those of Tl1+ in exclusively oxide and exclusively chloride co-ordinated polyhedra in crystalline phosphors. Both absorption and emission spectra of Tl1+ in chloride containing glasses gave strong evidence for complexes of the type: [Tl(oxide)6−n (chloride) n ]m−.

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Authors and Affiliations

  1. Indian Institute of Technology, Kanpur, India

    A. Paul, S. C. Sen & D. S. Srivastava

  2. Department of Glass Technology, University of Sheffield, UK

    A. Paul

Authors
  1. A. Paul
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  2. S. C. Sen
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  3. D. S. Srivastava
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Paul, A., Sen, S.C. & Srivastava, D.S. Absorption and emission spectra of Tl1+ with mixture of oxide and chloride ligands in glasses. J Mater Sci 8, 1110–1114 (1973). https://doi.org/10.1007/BF00632761

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  • DOI: https://doi.org/10.1007/BF00632761

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