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Ore genesis of the Wusihe carbonate-hosted Zn-Pb deposit in the Dadu River Valley district, Yangtze Block, SW China: evidence from ore geology, S-Pb isotopes, and sphalerite Rb-Sr dating

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Abstract

The Wusihe carbonate-hosted Zn-Pb deposit (3.7 Mt. Zn + Pb at a grade of 8.6% Zn and 2.0% Pb) is the largest deposit in the Dadu River Valley district of the Sichuan-Yunnan-Guizhou metallogenic province of southwest China. Three types of orebodies occur: (1) stratiform, banded and lamellar, within dolomite of the Neoproterozoic Dengying Formation; (2) vein type; and (3) breccia type. Four stages of mineralization are distinguished: (i) pyrite stage, (ii) pyrite-pyrrhotite-galena-sphalerite-bitumen stage, (iii) sphalerite-galena stage, and (iv) bitumen-calcite stage. Sphalerite and galena from stages II and III show δ34S ranges from +7.1 to +9.7‰ and +9.1 to +13.1‰, respectively. High-precision in situ lead isotope analyses of sulfides show 208Pb/204Pb, 207Pb/204Pb, and 206Pb/204Pb ratios of 37.938 to 38.336, 15.579 to 15.682, and 17.951 to 18.195, respectively, which suggest a mixing of lead from the basement and the host rocks. Rb-Sr isotope analyses for six sphalerite samples of stage II yielded an isochron age of 411 ± 10 Ma (MSWD = 1.4). Combining all available ore geology and geochemical data, together with fluid inclusion data reported previously, we suggest that the Wusihe deposit is a Mississippi Valley-type (MVT) deposit.

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References

  • Appold MS, Wenz ZJ (2011) Composition of ore fluid inclusions from the Viburnum Trend, Southeast Missouri District, United States: implications for transport and precipitation mechanisms. Econ Geol 106:55–78

    Article  Google Scholar 

  • Bertram CJ, Elderfield H, Aldridge RJ, Morris SC (1992) Sr-87 Sr-86, Nd-143 Nd-144 and REEs in Silurian phosphatic fossils. Earth Planet Sci Lett 113:239–249

    Article  Google Scholar 

  • Bodnar RJ, Lecumberri-Sanchez P, Moncada D, Steele-MacInnis M (2014) Fluid inclusions in hydrothermal ore deposits. In: Holland HD and Turekian KK (eds) Treatise on geochemistry, second eition. Elsevier, Oxford, p 119–142

  • Bowring SA, Grotzinger JP, Condon DJ, Ramezani J, Newall MJ, Allen PA (2007) Geochronologic constraints on the chronostratigraphic framework of the Neoproterozoic Huqf Supergroup, Sultanate of Oman. Am J Sci 307:1097–1145

    Article  Google Scholar 

  • Casadevall T, Ohmoto H (1977) Sunnyside mine, Eureka mining district, San Juan County, Colorado: geochemistry of gold and base metal ore deposition in a volcanic environment. Econ Geol 72:1285–1320

    Article  Google Scholar 

  • Cao L, Duan QF, Zhou Y (2015) Rb-Sr dating of sphalerites from the Aozigang zinc deposit in Hubei Province and its geological significance. Geol China 42:235–247

    Google Scholar 

  • Chen YL, Chu XL, Zhang XL, Zhai MG (2015) Carbon isotopes, sulfur isotopes, and trace elements of the dolomites from the Dengying Formation in Zhenba area, southern Shaanxi: implications for shallow water redox conditions during the terminal Ediacaran. Sci China Earth Sci 58:1107–1122

    Article  Google Scholar 

  • Christensen JN, Halliday AL, Kesler SE (1996) Rb-Sr dating of sphalerite and the age of Mississippi Valley-type Pb-Zn deposits. In: Sangster DF (ed) Carbonate-hosted lead-zinc deposits. Society of Economic Geologists, Special Publication 4, College Station, p 307–319

  • CIGMR (Chengdu Institute of Geology and Mineral Resources) (2003) Geology map of the Yunnan-Guizhou-Sichuan-Chongqing provinces, scale 1:2,500,000

  • Chaussidon M, Albarède F, Sheppard SMF (1989) Sulphur isotope variations in the mantle from ion microprobe analyses of micro-sulphide inclusions. Earth Planet Sci Lett 92:144–156

    Article  Google Scholar 

  • Condon D, Zhu M, Bowring S, Wang W, Yang A, Jin Y (2005) U-Pb ages from the Neoproterozoic Doushantuo Formation, China. Science 308:95–98

    Article  Google Scholar 

  • Corbella M, Ayora C, Cardellach E (2004) Hydrothermal mixing, carbonate dissolution and sulfide precipitation in Mississippi Valley-type deposits. Miner Depos 39:344–357

    Article  Google Scholar 

  • Claypool CE, Holser WT, Saki IR, Zak I (1980) The age curves for sulfur and oxygen isotopes in marine sulfate and their mutual interpretation. Chem Geol 28:199–260

    Article  Google Scholar 

  • Czamanske GK, Rye RO (1974) Experimentally determined sulfur isotope fractionations between sphalerite and galena in the temperature range 600 °C to 275 °C. Econ Geol 69:17–25

    Article  Google Scholar 

  • Deng HL, Li CY, Tu GZ, Zhou YM, Wang CW (2000) Strontium isotope geochemistry of the Lemachang independent silver ore deposit, northeastern Yunnan, China. Sci China Earth Sci 43:337–346

    Article  Google Scholar 

  • Dong YP, Liu XM, Neubauer F, Zhang GW, Tao N, Zhang YG, Zhang XN, Li W (2013) Timing of Paleozoic amalgamation between the North China and South China Blocks: evidence from detrital zircon U-Pb ages. Tectonophysics 586:173–191

    Article  Google Scholar 

  • Du GM, Cai H, Mei Y (2012) Application of Rb-Sr isochron dating method in sphalerite of sulphide deposit: a case study from Dagoudong Pb-Zn deposit in Xinhuang, western Hunan Province. Geol Miner Resour South China 28:175–180 (in Chinese with English abstract)

    Google Scholar 

  • Duan QF, Cao L, Zeng JK, Zhou Y, Tang ZY, Li K (2014) Rb-Sr dating of sphalerites from Shizishan Pb-Zn deposit in Huayuan ore concentration area, western Hunan, and its geological significance. Earth Sci J China Univ Geosci 39:977–999 (in Chinese with English abstract)

    Google Scholar 

  • GT207SGMB (The Geological Team 207 of the Sichuan Geology and Mineral Bureau) (1993) Geological reconnaissance survey of Hanyuan County zinc-lead mining area, Sichuan Province. Unpublished, Geol Survey Paper, Chengdu, p 16 (In Chinese)

  • GT207SGMB (The Geological Team 207 of the Sichuan Geology and Mineral Bureau) (2006) Geological survey of Wusihe zinc-lead deposit, Hanyuan County. Unpublished, Geol Survey Paper, Chengdu, p 20 (In Chinese)

  • Han RS, Liu CQ, Huang ZL, Chen J, Ma DY, Lei L, Ma GS (2007) Geological features and origin of the Huize carbonate-hosted Zn-Pb-(Ag) district, Yunnan, South China. Ore Geol Rev 31:360–383

    Article  Google Scholar 

  • Huang ZL, Chen J, Liu CQ, Han RS, Li WB, Zhao DS, Gao DR, Feng ZH (2001) A preliminary discussion on the genetic relationship between Emeishan basalts and Pb–Zn deposits as exemplified by the Huize Pb–Zn deposit, Yunnan Province. Acta Mineral Sinica 21:681–688 (in Chinese with English abstract)

    Google Scholar 

  • Jiang YH, Li SR (2005) Study on the isotope data tracing and isotopic chronology in the black-rock series type Ni–Mo deposit in the Lower Cambrian in Hunan and Guizhou provinces. J Mineral Petrol 25:62–66 (in Chinese with English abstract)

    Google Scholar 

  • Jørgensen BB, Isaksen MF, Jannasch HW (1992) Bacterial sulfate reduction above 100 °C in deep-sea hydrothermal vent sediments. Science 258:1756–1757

    Article  Google Scholar 

  • Kesler SE, Reich M, Jean M (2007) Geochemistry of fluid inclusion brines from Earth’s oldest Mississippi Valley-type (MVT) deposits, Transvaal Supergroup, South Africa. Chem Geol 237:274–288

    Article  Google Scholar 

  • Leach DL, Bradley D, Lewchuk MT, Symons DT, Marsily G, Brannon J (2001) Mississippi Valley-type lead-zinc deposits through geological time: implications from recent age-dating research. Miner Depos 36:711–740

    Article  Google Scholar 

  • Leach DL, Sangster DF, Kelley KD, Large R, Garven G, Allen CR, Gutzmer J, Walters S (2005) Sediment-hosted lead–zinc deposit: a global perspective. Econ Geol 100:561–607

    Google Scholar 

  • Leach DL, Bradley DC, Huston D, Pisarevsky SA, Taylor RD, Gardoll S (2010) Sediment-hosted lead-zinc deposits in Earth history. Econ Geol 105:593–625

    Article  Google Scholar 

  • Li TZ (2007) The genesis and metallogenic model of lead-zinc deposits in the middle part of Dadu River Valley. MSc thesis, Chengdu Institute of Technology, Chengdu, China, pp 1–55 (in Chinese with English abstract)

    Google Scholar 

  • Li WB, Huang ZL, Wang YX, Chen J, Han RS, Xu C, Guan T, Yin MD (2004) Age of the giant Huize Pb–Zn deposits determined by Sm–Nd dating of hydrothermal calcite. Geol Rev 50:189–195 (in Chinese with English abstract)

    Google Scholar 

  • Li WB, Huang ZL, Wang YX (2007) Dating of the giant Huize Zn–Pb ore field of Yunnan province, southwest China: constraints from the Sm–Nd system in hydrothermal calcite. Resour Geol 57:90–97

    Article  Google Scholar 

  • Li XH, Li WX, Li ZX, Liu Y (2008) 850–790 Ma bimodal volcanic and intrusive rocks in northern Zhejiang, South China: a major episode of continental rift magmatism during the breakup of Rodinia. Lithos 102:341–357

    Article  Google Scholar 

  • Lin FC (2005a) Hydrothermal exhalative metallogeny of stratiform Pb-Zn deposits on western margin of the Yangtze Craton. PhD thesis, Chengdu Institute of Technology, Chengdu, China, pp 1–104 (in Chinese with English abstract)

    Google Scholar 

  • Lin FC (2005b) Geological and geochemical characteristics and genesis of supper-large-scale Sedex-type stratiform lead-zinc deposits in the Dadu River Valley on the western margin of the Yangtze Craton. Acta Geol Sin 79:540–556 (in Chinese with English abstract)

    Article  Google Scholar 

  • Lin ZY, Wang DH, Zhang CQ (2010) Rb–Sr isotopic age of sphalerite from the Paoma lead–zinc deposit in Sichuan Province and its implications. Geol China 37:488–494 (in Chinese with English abstract)

    Google Scholar 

  • Liu HC, Lin WD (1999) Study on the Pb–Zn–Ag ore deposits in northeast Yunnan, Yunnan, China. Yunnan University Press, Kunming, pp 1–468 (in Chinese)

    Google Scholar 

  • Ludwig KR (2005) Isoplot/EX rev. 3.32: a geochronological toolkit for Microsoft Excel. Berkeley Geochronology Center, Special Publication 4, Berkeley, p 1–71

  • Machel HG (2001) Bacterial and thermochemical sulfate reduction in diagenetic settings—old and new insights. Sediment Geol 140:143–175

    Article  Google Scholar 

  • Nakai S, Halliday AN, Kesler SE, Jones HD, Kyle JR, Lane TE (1993) Rb-Sr dating of sphalerites from Mississippi Valley-type (MVT) ore deposits. Geochim Cosmochim Acta 57:417–427

    Article  Google Scholar 

  • Ohmoto H (1972) Systematics of sulfur and carbon isotopes in hydrothermal ore deposits. Econ Geol 67:551–578

    Article  Google Scholar 

  • Ohmoto H, Rye RO (1979) Isotopes of sulfur and carbon. In: Barnes HL (ed) Geochemistry of hydrothermal ore deposits. Wiley, New York, p 509–567

  • Ohmoto H, Goldhaber MB (1997) Sulfur and carbon isotopes. In: Barnes HL (ed) Geochemistry of hydrothermal ore deposits, 3rd edn. Wiley, New York, pp 517–611

    Google Scholar 

  • Sakai H (1968) Isotopic properties of sulfur compounds in hydrothermal processes. Geochem J 2:29–49

    Article  Google Scholar 

  • Symons DTA, Sangster DF, Leach DL (1996) Paleomagnetic dating of Mississippi Valley-type Pb-Zn-Ba deposits. In: Sangster DF (ed) Carbonate-hosted lead-zinc deposits. Society of Economic Geologists, Special Publication 4, College Station, p 515–526

  • Wang CM, Deng J, Carranza EJM, Lai XR (2014) Nature, diversity and temporal-spatial distributions of sediment-hosted Pb-Zn deposits in China. Ore Geol Rev 56:327–351

    Article  Google Scholar 

  • Wu Y, Zhang CQ, Mao JW, Ouyang HG, Sun J (2013) The genetic relationship between hydrocarbon systems and Mississippi Valley-type Zn–Pb deposits along the SW margin of Sichuan Basin, China. Int Geol Rev 55:941–957

    Article  Google Scholar 

  • Xiong SF, Yao SZ, Gong YJ, Tang MT, Zeng GP, Wang W (2016) Ore-forming fluid and thermochemical sulfate reduction in the Wusihe lead-zinc deposit, Sichuan Province, China. Earth Sci J China Univ Geosci 41:105–120 (in Chinese with English abstract)

    Google Scholar 

  • Yuan H, Yin C, Liu X, Chen KY, Bao ZA, Zong CL, Dai MN, Lai SC, Wang R, Jiang SY (2015) High precision in-situ Pb isotopic analysis of sulphide minerals by femtosecond laser ablation multi-collector inductively coupled plasma mass spectrometry. Sci China Earth Sci 58:1713–1721

    Article  Google Scholar 

  • Zartman RE, Doe BR (1981) Plumbotectonics—the model. Tectonophys 75:135–162

    Article  Google Scholar 

  • Zhang CQ (2008) The genetic model of Mississippi Valley-type deposits in the boundary area of Sichuan, Yunnan and Guizhou Province, China. PhD thesis, Chinese Academy of Geological Sciences, Beijing, p 177 (in Chinese with English abstract)

  • Zhang CQ, Li XB, Yu JJ, Mao JW, Chen FK, Li HM (2008) Rb–Sr dating of single sphalerites from the Daliangzi Pb–Zn deposit, Sichuan, and its geological significances. Geol Rev 54:145–151 (in Chinese with English abstract)

    Google Scholar 

  • Zhang CQ, Wu Y, Lin H, Mao JW (2015) Geodynamic setting of mineralization of Mississippi Valley type-deposits in world class Sichuan-Yunnan-Guizhou Zn-Pb triangle district, southwest China: implications from age-dating studies in the past decade and the Sm–Nd age of Jinshachang deposit. J Asian Earth Sci 103:103–114

    Article  Google Scholar 

  • Zhang TG, Chu XL, Zhang QR, Feng LJ (2004) The sulfur and carbon isotopic records in carbonates of the Dengying Formation in the Yangtze Platform, China. Acta Petrol Sinica 20:717–724 (in Chinese with English abstract)

    Google Scholar 

  • Zheng MH, Wang XC (1991) Ore genesis of the Daliangzi Pb–Zn deposit in Sichuan, China. Econ Geol 86:831–846

    Article  Google Scholar 

  • Zheng XZ (2012) Geological features and genesis of Wusihe Pb-Zn deposit, Sichuan. MSc Thesis,Chang’an University, Xi’an, China, p 66 (in Chinese with English abstract)

  • Zhou MF, Yan DP, Kennedy AK, Li YQ, Ding J (2002) SHRIMP zircon geochronological and geochemical evidence for Neoproterozoic arc-related magmatism along the western margin of the Yangtze Block, South China. Earth Planet Sci Lett 196:1–67

    Article  Google Scholar 

  • Zhou JX, Huang ZL, Bao G (2013a) Geological and sulfur-lead-strontium isotopic studies of the Shaojiwan Pb-Zn deposit, southwest China: implications for the origin of hydrothermal fluids. J Geochem Explor 128:51–61

    Article  Google Scholar 

  • Zhou JX, Huang ZL, Yan Z (2013b) The origin of the Maozu carbonate-hosted Pb-Zn deposit, southwest China: constrained by C-O-S-Pb isotopic compositions and Sm-Nd isotopic age. J Asian Earth Sci 73:39–47

    Article  Google Scholar 

  • Zhou JX, Huang ZL, Zhou MF, Li XB, Jin ZG (2013c) Constraints of C–O–S–Pb isotope compositions and Rb–Sr isotopic age on the origin of the Tianqiao carbonate-hosted Pb–Zn deposit, SW China. Ore Geol Rev 53:77–92

    Article  Google Scholar 

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Acknowledgements

This work is supported by grants from the National Natural Science Foundation of China (41603042 and 41672140), China Geological Survey (121201103094200), and the Fundamental Research Funds for the Central Universities, China University of Geosciences, Wuhan (CUGQYZX1733). We thank Dr. Tan Mantang and Mr. Wang Wei for their help in field investigations. We are grateful to Mr. Bao Zhian and Ms. Lu Jue for helping with LA–MC-ICP–MS Pb isotope analyses and to Mrs. Cai Hong for helping with Rb-Sr isotope analyses. Thanks are given to Prof. Yao Shuzhen, Prof. Shen Chuanbo, Dr. Jiang Manrong, and Mr. Chen Qizhi for their helpful suggestions. We acknowledge Prof. Bernd Lehmann, Prof. David Huston, Prof. Chen Huayong, Prof. Chris Eastoe, and anonymous reviewers for their constructive reviews and valuable suggestions that led to great improvement in the presentation of the paper.

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Xiong, SF., Gong, YJ., Jiang, SY. et al. Ore genesis of the Wusihe carbonate-hosted Zn-Pb deposit in the Dadu River Valley district, Yangtze Block, SW China: evidence from ore geology, S-Pb isotopes, and sphalerite Rb-Sr dating. Miner Deposita 53, 967–979 (2018). https://doi.org/10.1007/s00126-017-0776-y

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