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Hess Law Worksheet

1. Hess's Law allows calculation of enthalpy change (ΔH) for chemical reactions from data on the enthalpies of related reactions. 2. The document provides examples of using Hess's Law to calculate ΔH for various reactions from standard enthalpy of formation/combustion values. 3. Ten problems are presented where the user is given reaction equations and associated ΔH values and asked to calculate the ΔH for another related reaction using Hess's Law.

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2K views4 pages

Hess Law Worksheet

1. Hess's Law allows calculation of enthalpy change (ΔH) for chemical reactions from data on the enthalpies of related reactions. 2. The document provides examples of using Hess's Law to calculate ΔH for various reactions from standard enthalpy of formation/combustion values. 3. Ten problems are presented where the user is given reaction equations and associated ΔH values and asked to calculate the ΔH for another related reaction using Hess's Law.

Uploaded by

natsmd
Copyright
© Attribution Non-Commercial (BY-NC)
We take content rights seriously. If you suspect this is your content, claim it here.
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Download as PDF, TXT or read online on Scribd
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SCH4U Hess's Law

Hess's Law Worksheet


1. Calculate L1H for the reaction: C2H4 (g)+ H2 (g)~C 2 H 6 (g), from the following
data.
C2H4 (g)+ 3 02 (g) ~2 C02 (g)+ 2 H20 (I)

L1H = -1411. kJ

C2H6 (g) + 3Yz 02 (g) ~2 C02 (g) + 3 H20 (I)

L1H = -1560. kJ
L1H

2.

3.

4.

=-285.8 kJ

Calculate L1H for the reaction 4 NH 3 (g)+ 5 0 2 (g) 1111114 NO (g)+ 6 H20 (g), from
the following data.
N2 (g) + 02 (g) ~2 NO (g)

L1H = -180.5 kJ

N2 (g)+ 3 H2 (g) ~2 NH3 (g)

L1H

=-91.8 kJ

2 H2 (g) + 02 (g) ~2 H20 (g)

L1H

=-483.6 kJ

Find L1H for the reaction 2H 2(g) + 2C(s) + 0 2(g) ~ C2H5 0H(I), using the following
thermochemical data.
C2H 5 0H (I)+ 2 0 2 (g) ~2 C02 (g)+ 2 H20 (I)

L1H = -875. kJ

C (s) + 02 (g) ~C02 (g)

L1H = -394.51 kJ

H2 (g) + Yz 02 (g) ~H20 (I)

L1H = -285.8 kJ

Calculate li!H for the reaction CH 4 (g)+ NH 3 (g) ~HCN (g)+ 3 H2 (g), given:
N2 (g)+ 3 H2 (g) ~2 NH3 (g)

L1H = -91.8 kJ

C (s) + 2 H2 (g) ~CH4 (g)

L1H = -74.9 kJ

H2 (g) + 2 C (s) + N2 (g) ~2 HCN (g)

L1H

=+270.3 kJ

SCH4U Hess 's Law


7. Given the following reactions and their enthalpy changes, calculate the enthalpy
change for

I Change in Heat Energy

j Equations
N2(g) + 2 02(g) ~ 2 N02(g)

67.8 kJ

Nz(g) + 2 02(g) ~ N204(g)

9.67 kJ

8. Given the following reactions and their enthalpy changes, calculate the enthalpy
change for

IChange in Heat Energy

!Equations
i

] Ca(g) + 2 C(s)
I

~ CaC2(S)

ICaC03(s) + C02(g) ~ CaC2(s) + 5/2 02(g)

-62.8 kJ

394 kJ

1538 kJ

9. Calculate the heat change for the formation of l.OOmol of strontium carbonate from
its elements. Given the following experimental information:

1
Sr(s)+-02 (g)
2
SrO(s) + C0 2 (g)

SrO(s)

/ill = -592kJ

SrC0 3

11H = -234kJ

C(graphite) + 0 2 (g)

C02 (g)

/ill= -394kJ

10. Calculate the D. Ht for 6 C(s) + 6 H2 (g) + 3 0 2 (g) -------tC6H12 06 (s) given that:
C6H1206 (s) + 6 Oz (g)
>6 C02 (g)+ 6 H20 (g) ~He= -2537.3 kJ
Hz (g) + 1/2 02 (g) ~H20 (g) D,. Ht = -241.8 kJ
0
C (s) + 02 (g) ~ C02 (g) ~Ht = -393.5 kJ

S;irl'eC!I ~."5

\\ \=e.-b

;2.<::>\\

3
\.

C~H'-1
2c o

'--">

+ 3 \-\!-0

---:.:;..

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->

\-l z.o

:2

+ o.s ol.

Hl.-

C2 H'i +
2.

-')

+ I 02.

4~H 3

~-;::>

b\-1 2.

4.

~ Hz

'

b.. \-(

-.::;;.

2D;a.

+ 20 2

- )

2 (_ OJ..

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~~

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c..

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~ ;?_

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' \--\c..,

--?>

.\-

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2 {) l.

->

+-

Cz HsDH

...,.I

-\-

I.S\-1 2.
2~ l

AI-\-:. ~75 1-< j

b,.

H " - 7'6Cf .D2

~ \-\

..\- 2_0 ;!...

N 04
~?. Oy.

Lj'S.Cl

1-<j .

"" 74.q \-\,j _

'

:s \-1,_

k~

- - s11 . (, (..( j

At!~

He..~

1!.1so. et.<j

V-J

6-1-1,. 0

+-

0.5 t'\.

->
- >

Nl.L

~ tl

+ \~ 3 - "

"

2 H:t.o

li

CH "

+ 2N2.

~b I 1..<.~

=-

l.f ~0

- :>
1-

c,..q

4No

->

t-

o.s \-\,_

D-H "' - 2<[S -~ t.<j

5o:<.

-\--

: : \ 'SC.o 1.< j

DH

t; 1-l '- o

~ \-~ 3,

c \-(

6.-t-\"' - l{fl ( l4'J

C :~- H ,

H~_o

->

N ~-

2H2

3 Q,

1-

2 C. D 2
2 c.

A-

-::;,

HL

2 W z.

co

+ ?:,o"'

\35 . \ ') k .).

6\--\= 2~5~L1~ \-<_) .

.6. 1-\ =- f,7. 8 1.(_)

D-H = q .67 t-<S

D- H

==

S'6 .Is

kj

<6.

C8
e.a C 2

-\-

-\-

2C

--::::>

C0 2

->

3.5

-;:>

2.

cJ-\ ~ - 6 2 -<t k.)

CaC
-t

CaC03

-\

02...
Cu 2

.6.-\-\::

-t 3 qlf I'd .

cd-l :: - \ 5~ r; I<J.

C.aC.D 3

/0.

")

(:, D 2

+ ;o2

->

0 H1-o

~02...

-~

b Co.?-

Q;, \-\ .,0

-+

b H2
(;;,C

-1

b CO ?..

+ C :,Hol oG .
.

~H:::
6

2s3l- s

r..{ J

H : -lt+rso.'(S" ~ ,

.c::. l-{ "' - 23b l \..<..).

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