Hydrogen Production
Hydrogen Production
Tapan K. Bose, Kodjo Agbossou, Mohan Kolhe, Jean Hamelin Institut de recherche sur lhydrogne, Universit du Qubec Trois-Rivires, Canada
1. PROJECT GOALS
Energy storage can play an important role in the development and operation of environmentally friendly renewable energy (RE) systems. The integrated wind and solar energy system, based on long-term seasonal storage of electrolytic hydrogen (H2), is considered as a promising solution to overcome the limitations associated with the intermittency of the RE sources. In comparison to commonly used battery storage, H2 is well suited for seasonal storage, because of its inherent high mass energy density and longevity of energy storage (compared to batteries). A stand-alone RE system based on hydrogen production from wind and solar energy has been developed and installed at the Hydrogen Research Institute (HRI). It includes a fuel cell and both short-term and long-term energy storage devices. It is the goal of this project to demonstrate that an autonomous renewable energy system may be realized with long-term energy storage in the form of hydrogen, and that the operation of such a system is safe and reliable. The major objectives are: Assessment of the hydrogen production sub-assembly undergoing intermittent operation Assessment of the fuel cell performance for matching residential electric and heat load profiles Integrating the various sub-assemblies via hardware/software control systems Overall assessment of the technology for residential use in remote areas
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The overall RE system performance is very sensitive to local weather conditions. To achieve an adequate performance from such a system requires appropriate components and a welldesigned control system. The design and implementation of a control system for proper energy management in a stand-alone RE plant is challenging. We have designed and developed a control system with power conditioning devices to integrate the different components of the RE system and to manage the energy flow in the system to assure a continuous supply of electricity to meet the load demand. Each component of the renewable energy system has been studied for long-term operation by using this control algorithm. The system parameters are monitored continuously for real time operation and control. The system operation has been tested for autonomous operation and technical feasibility of the stand-alone RE system based on hydrogen production. Our integrated RE system has been in operation since May 2001.
Electrical load Wind Turbine and Regulator PV Array and Regulator Inverter DC / AC
Buck DC / DC Converter
Micro Controller
Boost DC / DC Converter
Rectifier
PEMFC
3. DESCRIPTION OF COMPONENTS
The stand-alone RE system based on hydrogen production was successfully tested at the HRI. The system consists of a 10 kW wind turbine generator (WTG) and a 1 kW (peak) solar photovoltaic (PV) array as primary energy sources. The renewable electricity that is produced in excess of the load demand is stored as hydrogen, produced using a 5 kW electrolyser. The hydrogen is stored and later used to produce electricity using a 5 kW fuel cell system for the times when there is not sufficient wind and solar energy to meet the demand requirement. The -2-
RE system components have substantially different voltage-current characteristics and are integrated through the developed power conditioning devices on a 48V DC bus, which allows power to be managed between input power, energy storage and load. The DC-DC converters are used as power conditioning devices to connect the fuel cell and the electrolyser on the DC bus, which have different voltage ratings. Also the DC-DC converters give high flexibility to control power flow and operation of the electrolyser and the fuel cell. Compared to the DC bus voltage, the fuel cell output voltage is low and hence the DC-DC boost converter is used to transfer the power effectively to the DC bus. Similarly, the DC-DC buck converter has been used between the electrolyser and the DC bus to transfer the excess power effectively to the electrolyser. In addition, the system is equipped with AC and DC programmable loads and with a 10 kW programmable power source. The schematic of the RE system is shown in Figure 1 and the system components specifications are given in Table 1.
Table 1: Specifications of the renewable energy system components Component Wind Turbine Generator Specifications 10 kW, 3 permanent magnet alternator, VCS-10 - 48 V DC, Bergey BWC Excel 1 kW (peak) PV array, Golden Genesis GP 64 PV Modules (4S*4P) with Charge Controller 5 kW, alkaline electrolyser with compressor, Stuart Energy System 5 kW, multiphase PWM, 36-48 Volt, HRI System 5 kW, proton exchange membrane fuel cell stack (MK5-E), 19-35 Volt, Ballard Power System 5 kW, multiphase PWM, 24-48 Volt, HRI System energy management control system, HRI System 12 kW (programmable), water cooled, Dynaload 3 kW (programmable), California Instruments 5 kW, Trace Engineering 42.240 kWh 10 kW (programmable), Elgar 10 bar, 3.8 m3 represents 125 kWh of stored energy
Photovoltaic Array
Boost Converter Controller DC Load AC Load Inverter Battery Power Source H2 Storage
Current from the DC bus bar keeps batteries (short-term energy storage) charged, feeds power to the load bank via an inverter and also supplies power to electrolyser via the powerconditioning device. To simulate any type of electrical load profile, we used DC and AC programmable loads. Our RE system also has a programmable power source at DC bus and can be used to test the system, when there is no power available from wind and solar energy system. The programmable power source can simulate any type of intermittent power output. -3-
We studied the electrolyser and the fuel cell polarization characteristics, which depend mainly on voltage, current and temperature. Sensors were used to record real-time voltages and currents of WTG, PV array, DC bus / battery, electrolyser, fuel cell, load, hydrogen detectors, electrolytic hydrogen flow rate from the electrolyser, hydrogen consumption rate in the fuel cell, oxidant consumption rate in the fuel cell, hydrogen and oxidant pressure in the fuel cell, fuel cell stack temperature, electrolyser cell temperature, DC-DC converter (boost and buck) duty ratio. Additional sensors in the electrolyser and the fuel cell systems provide the secondary information.
electrolyser and fuel cell on / off operations are controlled automatically as a function of predefined limits of energy levels in the control algorithm.
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Figure 2: Power available from wind turbine generator and PV array on Dec 10, 2001
Figure 3: Power, H2 flow rate and consumption rate in RE system on Dec 10, 2001
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5000 Battery Charging / Discharging Power Load Battery Charging / Discharging Power (W) 3000
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6. CONCLUSIONS
The successful long-term autonomous operation and performance of a stand-alone RE system based on hydrogen production has been demonstrated using a control system and power conditioning devices. The components of the RE system, which have substantially different voltage-current characteristics, were integrated using power conditioning devices on the DC bus for effective operation. The system was tested successfully for autonomous operation. The sensors collected real-time data and utilized this information in the control algorithm for effective energy management in the system. The buffer energy storage provided by batteries managed the load transients, electrolyser ripples and the intermittent power peaks from the RE sources efficiently. The developed control system and power conditioning devices were tested for different load profiles and for various intermittent input power patterns, which were also generated through the programmable DC power source. We also used a programmable power source as input to our RE system, which can simulate any type of intermittent power output by using the wind or solar energy profile of any region. The different load profiles were generated using a programmable load to test the system operation and performance. The stand-alone RE system developed at the HRI can thus be utilized to test the operation and performance of any stand-alone RE system based on electrolytic hydrogen.
Acknowledgement:
This work was supported in part by the Ministre des ressources Naturelles du Qubec, Natural Resources Canada, Natural Sciences and Engineering Research Council of Canada, Canada Foundation of Innovation, the AUTO21 Centre of Excellence. We would like to thank Ballard Power for the fuel cell system and Stuart Energy Inc. for the electrolyser.
7. CONTACT INFORMATION
Institut de recherche sur lhydrogne / Hydrogen Research Institute Tapan K. Bose, director Universit du Qubec Trois-Rivires C.P. 500 Trois-Rivires, Qubec, G9A 5H7, Canada Telephone: Fax: E-mail: 001 819 376-5139 001 819 376-5164 Tapan_Bose@uqtr.ca
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