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Quiz No 3

The document contains a quiz with multiple choice questions on thermodynamics concepts such as entropy, enthalpy, Gibbs free energy, heat capacity, phase changes, and the second law of thermodynamics. It also contains problems involving calculating thermodynamic properties for processes like gas expansion, heat transfer, phase changes of substances, and protein unfolding.

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692 views3 pages

Quiz No 3

The document contains a quiz with multiple choice questions on thermodynamics concepts such as entropy, enthalpy, Gibbs free energy, heat capacity, phase changes, and the second law of thermodynamics. It also contains problems involving calculating thermodynamic properties for processes like gas expansion, heat transfer, phase changes of substances, and protein unfolding.

Uploaded by

von_science08
Copyright
© Attribution Non-Commercial (BY-NC)
We take content rights seriously. If you suspect this is your content, claim it here.
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Download as PDF, TXT or read online on Scribd
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DICUANGCO, Sarah Jane A.

2010106946
Quiz no.3 1. One mole of a perfect gas contained in a 10-L vessel at 27C is permitted to expand freely into an evacuated vessel of 10-L capacity so that the final volume is 20-L. What is the change in entropy (in Joules) accompanying the process? (Note that for this process q=0 because w=0 for an expansion against a vacuum and that U=0 for an ideal gas.) a. 0 b. 5.76 c. 8.31 d. 12.56 2. Calculate the change in entropy (in J/K) involved in heating 2 moles of an ideal gas from a volume of 100 L at 50C to a volume of 150 L at 150C. Cv = 7.88 cal mol-1 K-1. a. 5.5 b. 11.0 c. 24.0 d. 24.5 3. The atomic heat capacity of solid Mo is given by the equation Cp= 5.69 + 1.88 x 10-3T
0.503 105 2

Find the change in entropy (in eu) which accompanies the heating of one mole of Mo from 0C to its melting point 2620C. (An entropy unit, eu, is equal to 1 cal/K-1) a. 13.7 b. 18.6 c. 25.3 ANSWER: NONE OF THE CHOICES. 18.02 d. 28.9

4. Three moles of N2 (g) , originally at 1atm pressure, are mixed isothermally with 5 moles of H2(g) , also at 1 atm pressure, to yield a mixture whose total pressure is 1 atm. What is the molar entropy of mixing (in J mol-1 K-1)? a. 3.36 b. 4.98 c. 5.50 d. 6.56 5. Repeat problem 4 on the basis that the total pressure of the mixture is 10 atm. a. -65.6 b. 40.5 c. 73.7 d. -109.1 6. Stream is condensed at 100C and the water is cooled to 0C and frozen to ice. What is the molar entropy change of water in kJ mol-1 K-1 ? Consider that the average specific heat of liquid water is 4.2 J K-1 g-1 . The enthalpy of vaporization at the boiling point and the enthalpy of fusion at the freezing point are 2258.1 and 333.5 J g-1 , respectively. a. -57.9 b. -90.0 c. -121.7 d. -154.4 ANSWER: NONE OF THE CHOICES. -0.154.4 KJ/mol 7. The purest acetic acid is often called glacial acetic acid because it is purified by fractional freezing at its melting point of 16.6C . A flask containing several moles of acetic acid at 16.6C is lowered into an ice-water bath briefly. When it is removed it is found that exactly 1 mole of acetic acid has frozen. Given: Hfus(CH3CO2H)= 11.45 KJ mol-1 and : Hfus (H2O)= 5.98 KJ mol1 . What is the entropy change (in J K-1) for the combined system? a. 1.67 b. 1.98 c. 2.40 d. 2.75

8. Calculate the molar Gibbs energy of fusion (in J mol-1) when supercooled water at -3C freezes at constant T and P. The enthalpy fusion of ice is 6000 J mol-1 at 0C. The heat capacities of water and ice in the vicinity of the freezing point are 75.3 and 38 J mol-1 K-1, respectively? a. -63. 6 b. -45.7 c. -23.4 d. -5.8 9. Metal block 1 and block 2 at temperatures T K and 2T K , respectively, were allowed to equilibrate to the same temperature. What is the change in entropy associated with the process given that block 1 and block 2 are of the same sizes and are made from the same material? a. Cp ln (1/2) b. Cp ln (3/8) c. Cp ln (9/4) d. Cp ln (9/8) 10. When a liquid is compressed its Gibbs energy is increased. Assuming a constant molar volume, what is the change in Gibbs energy (in k J mol-1) for liquid water when it is compressed from 1 bar to 1000 bar? Assume that water has a density of 1.0 g cm-3? a. 0.6 b. 1.2 c. 1.8 d. 2.4

B. 1. Prove that two adiabatic paths can never cross. Assume that the energy of the system under consideration is a function of temperature only. (Hint: Suppose that two such paths can intersect, and complete a cycle with the two paths plus one isothermal path. Consider the changes accompanying each stage of the cycle and show that they conflict with the Kelvin Statement of the Second Law. ) 10pts. 2. If the Gibbs energy varies with temperature according to

= + +

How will the enthalpy and entropy vary with temperature? Check that these three equations are consistent. 10pts. 3. Derive the thermodynamic equation of state ( 4. Derive the relationship (
)

= ( )

and confirm that it applies to a perfect gas.

5. One mole of a perfect gas expanded isothermally and reversibly at 0C from 1 to 1/10 bar. Calculate (a) w , (b) q , (c) H, (d) G, and (e) S for the gas. One mole of a perfect gas in 22.8L is allowed to expand irreversibly into and evacuated vessel such that the final volume total volume total volume is 228 L. Calculate (f) w , (g) q , (h) H, (i) G, and (j) S for the gas. Calculate (k) S for the system and its surroundings involved in the reversible isothermal expansion and calculate (l) ) S for the system and its surroundings involved in the irreversible isothermal expansion. Comment on the values obtained. 20pts.

6. The protein lysozyme unfolds at a transition temperature of 75.5C and the standard enthalpy of transition is 509 kJ mol-1. Calculate the entropy of unfolding lysozyme at 25C given that the difference in constant-pressure heat capacities upon unfolding is 6.28 kJ K-1 mol-1 and can be assumed to be independent of temperature .

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