Safety Data Sheet

according to Regulation (EC) No. 1907/2006 (REACH)

according to Regulation (EU) No 453/2010
Article no.: 01307SL30000
Date of print: 04.06.2013
Version:
SL 1307
Revision date: 08.04.2013 EN
Date of issue: 04.06.2013 Page:1 / 8
1. Identification of the substance/ preparation and of the company/ undertaking
1.1. Product identifiers:
Article no. (manufacturer / supplier):
Identification of the substance or preparation:
1.2. Relevant identified uses of the substance or mixture and uses advised against
1.3. Details of the supplier of the safety data sheet
Supplier (manufacturer/importer/downstream user/distributor):
Lackwerke Peters GmbH + Co KG
Hooghe Weg 13
47906 Kempen
Telephone: ++49-2152-2009-0
Telefax: ++49-2152-2009-70
Dept. responsible for information:
Arbeitssicherheit und Umweltschutz
E-mail (competent person): tilman.sehlen@peters.de
1.4. Emergency telephone number
Emergency telephone: ++49-2152-2009-78
Only available during office hours.
2. Hazards identification
2.1. Classification of the substance or mixture
Classification according to EC regulation 1272/2008 (CLP):
This mixture is classified as hazardous according to regulation (EC) No. 1272/2008 [CLP].
Flam. Liq. 3 / H226 Flammable liquids: Flammable liquid and vapour.
STOT SE 3 / H336 Specific target organ toxicity (single
exposure):
May cause drowsiness or dizziness.
Classification according to Directive 67/548/EEC or 1999/45/EC
The preparation is dangerous in the sense of Directive 1999/45/EC.
R10 Flammable.
R67 Vapours may cause drowsiness and dizziness.
2.2. Label elements
Labelling (CLP)
Hazard pictograms

Warning
Hazard statements:
H226 Flammable liquid and vapour.
H336 May cause drowsiness or dizziness.
Safety precautions:
P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
P233 Keep container tightly closed.
P243 Take precautionary measures against static discharge.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P303 + P361 + P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with
water/shower.
P304 + P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P312 Call a POISON CENTER or doctor/physician if you feel unwell.
P403 + P235 Store in a well-ventilated place. Keep cool.
contains:
1-methoxy-2-propanol
Supplemental Hazard information (EU):
EUH208 Contains dipentene.May produce an allergic reaction.
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH)
according to Regulation (EU) No 453/2010
Article no.: 01307SL30000
Date of print: 04.06.2013
Version:
SL 1307
Revision date: 08.04.2013 EN
Date of issue: 04.06.2013 Page:2 / 8
Labelling (67/548/EEC or 1999/45/EC)
Hazard statements:
10 Flammable.
67 Vapours may cause drowsiness and dizziness.
Safety precautions:
16 Keep away from sources of ignition. - No smoking.
33 Take precautionary measures against static discharge.
contains:
not applicable
Special provisions concerning the labelling of certain mixtures
99 Contains dipentene. May produce an allergic reaction.
2.3. Other hazards
3. Composition/ Information on ingredients
3.2. Mixtures
chemical characterization (preparation)
Description: .
Hazardous ingredients:
Classification according to EC regulation 1272/2008 (CLP):

EC No:
CAS No.:
INDEX no.:
REACH No:
Chemical name:
classification:
% by weight
Remark:
203-539-1
107-98-2
603-064-00-3
1-methoxy-2-propanol
Flam. Liq. 3 H226 / STOT SE 3 H336
50 - 100
216-455-5
1589-47-5
603-106-00-0
2-methoxypropanol
Flam. Liq. 3 H226 / Repr. 1B H360 / STOT SE 3 H335 / Skin Irrit. 2 H315
/ Eye Dam. 1 H318
< 0,5
205-341-0
138-86-3
601-029-00-7
dipentene
Flam. Liq. 3 H226 / Skin Irrit. 2 H315 / Skin Sens. 1 H317 / Aquatic Acute
1 H400 / Aquatic Chronic 1 H410
< 0,5
Classification according to Directive 67/548/EEC or 1999/45/EC

EC No:
CAS No.:
INDEX no.:
REACH No:
Identification of the hazard:
classification:
% by weight
Remark:
203-539-1
107-98-2
603-064-00-3
1-methoxy-2-propanol
R10 / R67
50 - 100

64742-95-6 mixture of aromatic hydrocarbons
R10 / Xi; R37 / N; R51-53 / Xn; R65 / R66 / R67
0,5 - 1
202-436-9
95-63-6
601-043-00-3
1,2,4-trimethylbenzene
R10 / Xn; R20 / Xi; R36/37/38 / N; R51-53
< 0,5
216-455-5
1589-47-5
603-106-00-0
2-methoxypropanol
R10 / Repr.Cat.2; R61 / Xi; R37/38-41
< 0,5
203-604-4
108-67-8
601-025-00-5
mesitylene
R10 / Xi; R37 / N; R51-53
< 0,5
205-341-0
138-86-3
601-029-00-7
dipentene
R10 / Xi; R38 / R43 / N; R50-53
< 0,5
Additional information
Full text of R-phrases: see section 16.
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH)
according to Regulation (EU) No 453/2010
Article no.: 01307SL30000
Date of print: 04.06.2013
Version:
SL 1307
Revision date: 08.04.2013 EN
Date of issue: 04.06.2013 Page:3 / 8
Full text of H-phrases: see section 16.
4. First-aid measures
4.1. Description of first aid measures:
General information:
In all cases of doubt, or when symptoms persist, seek medical advice. In case of unconsciousness give nothing by mouth,
place in unconscious position and seek medical advice.
After inhalation
Move victim to fresh air. Put victim at rest and keep warm. In case of irregular breathing or respiratory arrest provide artificial
respiration.
In case of skin contact:
Take off immediately all contaminated clothing. After contact with skin, wash immediately with plenty of water and soap. Do
not use solvents or thinners.
In case of eye contact:
Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Seek
medical advice.
After ingestion:
If swallowed, rinse mouth with water (only if the person is conscious). Consult physician immediately. Keep victim calm. Do
not induce vomiting.
4.2. Most important symptoms and effects, both acute and delayed:
4.3. Indication of any immediate medical attention and special treatment needed
5. Firefighting measures
5.1. Extinguishing media
Suitable extinguishing media:
Alcohol resistant foam, Carbon dioxide, Powder, spray mist, (water)
Extinguishing media which must not be used for safety reasons:
Strong water jet
5.2. Special hazards arising from the substance or mixture
Dense black smoke occurs during fire. Inhaling hazardous decomposing products can cause serious health damage.
5.3. Advice for firefighters
Provide a conveniently located respiratory protective device. Cool closed containers that are near the source of the fire. Do
not allow water used to extinguish fire to enter drains, ground or waterways. Treat runoff as hazardous.
6. Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
Keep away from sources of ignition. Ventilate affected area. Do not breathe vapours.
6.2. Environmental measures
Do not allow to enter into surface water or drains. If the product contaminates lakes, rivers or sewages, inform competent
authorities in accordance with local regulations.
6.3. Methods and material for containment and cleaning up
Isolate leaked material using non-flammable absorption agent (e.g. sand, earth, vermiculit, diatomaceous earth) and collect it
for disposal in appropriate containers in accordance with the local regulations (see chapter 13). Clean using cleansing
agents. Do not use solvents.
6.4. Reference to other sections
Observe protective provisions (see chapter 7 and 8).
7. Handling and storage
7.1. Precautions for safe handling

Advices on safe handling
Avoid formation of flammable and explosive vapour concentrations in the air and exceeding the exposure limit values. Only
use the material in places where open light, fire and other flammable sources can be kept away. Electrical equipment must
be protected meeting the accepted standard. Product may become electrostatically charged. Provide earthing of containers,
equipment, pumps and ventilation facilities. Anti-static clothing including shoes are recommended. Floors must be electrically
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH)
according to Regulation (EU) No 453/2010
Article no.: 01307SL30000
Date of print: 04.06.2013
Version:
SL 1307
Revision date: 08.04.2013 EN
Date of issue: 04.06.2013 Page:4 / 8
conductive. Keep away from heat sources, sparks and open flames. Use only spark proof tools. Avoid contact with skin, eyes
and clothes. Do not inhale dusts, particulates and spray mist when using this preparation. Avoid respiration of swarf. When
using do not eat, drink or smoke. Personal protection equipment: refer to chapter 8. Do not empty containers with pressure -
no pressure vessel! Always keep in containers that correspond to the material of the original container. Follow the legal
protection and safety regulations.
Precautions against fire and explosion:
Vapours are heavier than air and will spread at floor level. Vapours form explosive mixtures with air.
7.2. Conditions for safe storage, including any incompatibilities
Requirements for storerooms and containers:
Storage in accordance with the Ordinance on Industrial Safety and Health (BetrSiVO). Keep container tightly closed. Do not
empty containers with pressure - no pressure vessel! Smoking is forbidden. Access only for authorised persons. Store
carefully closed containers upright to prevent any leaks.
Hints on joint storage
Keep away from strongly acidic and alkaline materials as well as oxidizers.
Further information on storage conditions
Take care of instructions on label. Store in a well-ventilated and dry room at temperatures between 5 C and 25 C. Protect
from heat and direct sunlight. Keep container tightly closed. Remove all sources of ignition. Smoking is forbidden. Access
only for authorised persons. Store carefully closed containers upright to prevent any leaks.
7.3. Specific end use(s)
Observe technical data sheet. Observe instructions for use.
8. Exposure controls / Personal protection
8.1. Control parameters

EC No:
CAS No.:
Description: type:
Country:
Limit value
STEL (EC) TWA (EC)
Unit
203-604-4
108-67-8
mesitylene
EG
100
20
mg/m3
ppm
203-539-1
107-98-2
1-methoxy-2-propanol
EN
1120
300
375
100
mg/m3
ppm
202-436-9
95-63-6
1,2,4-trimethylbenzene
EG
100
20
mg/m3
ppm
-64742-95-6 mixture of aromatic hydrocarbons
EG
50 ppm
Additional information
TWA (EC): Occupational exposure limit value
STEL (EC): Short-term occupational exposure limit value
8.2. Exposure controls
Provide good ventilation. This can be achieved with local or room suction. If this should not be sufficient to keep aerosol and
solvent vapour concentration below the exposure limit values, a suitable respiratory protection must be used.
Occupational exposure controls:
Respiratory protection:
If concentration of solvents is beyond the occupational exposure limit values, approved and suitable respiratory protection
must be used. Use only respiratory protection equipment with CE-symbol including four digit test number.
Hand protection:
For prolonged or repeated handling the following glove material must be used: Nitrile rubber
Thickness of the glove material: > 0,4 mm ; Penetration time (maximum wearing period): > 480 min.
Observe the instructions and details for use, storage, maintenance and replacement provided by the protective glove
manufacturer. Penetration time of glove material depending on intensity and duration of exposure to skin. Recommended
glove articles: DIN EN 374
Barrier creams can help protecting exposed skin areas. In no case should they be used after contact.
Eye protection:
Wear closely fitting protective glasses in case of splashes.
Body protection:
Wear antistatic clothing of natural fibers (cotton) or heat resistant synthetic fibers.
Protective measures:
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH)
according to Regulation (EU) No 453/2010
Article no.: 01307SL30000
Date of print: 04.06.2013
Version:
SL 1307
Revision date: 08.04.2013 EN
Date of issue: 04.06.2013 Page:5 / 8
After contact clean skin thoroughly with water and soap oder use appropriate cleanser.
Environmental exposure controls
Do not allow to enter into surface water or drains. refer to chapter 7. No further action is necessary.
9. Physical and chemical properties
9.1. Information on basic physical and chemical properties
Appearance:
Physical state: liquid
Colour colourless
Odour: solvents
Safety relevant basis data Unit Method Remark:
Flash point: 32 C DIN 51755
Ignition temperature (AIT): 270 C DIN 51794
lower explosion limit: 1,5 Vol-%
Upper explosion limit: 13,7 Vol-%
Vapour pressure at 20 C: 8,82 mbar
Density at 20 C: 0,96 g/cm DIN 53217
Water solubility (g/l): partly soluble
pH at 20 C: not applicable
Viscosity at 20 C 60 s 4 mm DIN 53211
Solvent separation test (%): < 3 % ADR/RID
Solid content (%): 31 % by weight
solvent content:
Organic solvents: 68 % by weight
Water: 0 % by weight
9.2. Other information:
10. Stability and reactivity
10.1. Reactivity
10.2. Chemical stability
Stable when applying the recommended regulations for storage and handling. Further information on correct storage: refer to
chapter 7.
10.3. Possibility of hazardous reactions
Keep away from strong acids, strong bases and strong oxidizing agents to avoid exothermic reactions.
10.4. Conditions to avoid
Hazardous decomposition byproducts may form with exposure to high temperatures.
10.5. Incompatible materials
10.6. Hazardous decomposition products
Hazardous decomposition byproducts may form with exposure to high temperatures, e.g.: carbon dioxide, carbon monoxide,
smoke, nitrogen oxides.
11. Toxicological information
No data on preparation itself available.
11.1. Information on toxicological effects

Acute toxicity
Toxicological data are not available.

Irritant and corrosive effects
Toxicological data are not available.

Sensitisation
Toxicological data are not available.

Specific target organ toxicity
Toxicological data are not available.

Aspiration hazard:
Toxicological data are not available.
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH)
according to Regulation (EU) No 453/2010
Article no.: 01307SL30000
Date of print: 04.06.2013
Version:
SL 1307
Revision date: 08.04.2013 EN
Date of issue: 04.06.2013 Page:6 / 8
Practical experience
Other observations:
Inhaling of solvent components above the MWC-value can lead to health damage, e.g. irritation of the mucous membrane
and respiratory organs, as well as damage to the liver, kidneys and the central nerve system. Indications for this are:
headache, dizziness, fatigue, amyosthenia, dizziness, in serious cases: unconsciousness. Solvents may cause some of the
aforementioned effects through skin resorption. Repeated or prolonged contact with the preparation may cause removal of
natural fat from the skin resulting in non-allergic contact dermatitis and/or absorption through skin. Splashing may cause eye
irritation and reversible damage.
Overall Assessment on CMR properties:

EC No:
CAS No.:
Identification of the hazard: Classification according to
Directive 67/548/EEC or
1999/45/EC
216-455-5
1589-47-5
2-methoxypropanol Repr. Cat. 2
The preparation has been assessed following the conventional method of the Dangerous Preparations Directive 1999/45/EC
and classified according to the toxicological dangers.See chapters 2 and 15 for details.
12. Ecological information
Overall evaluation:
There is no information available on the preparation itself .
Do not allow to enter into surface water or drains.
12.1. Toxicity

Toxicological data are not available.
12.2. Persistence and degradability
Toxicological data are not available.
12.3. Bioaccumulative potential
Toxicological data are not available.
12.4. Mobility in soil
Toxicological data are not available.
12.5. Results of PBT and vPvB assessment
The components in this formulation do not meet the criteria for classification as PBT or vPvB.
12.6. Other adverse effects

13. Disposal considerations
13.1. Waste treatment methods
Appropriate disposal / Product
Recommendation:
Do not allow to enter into surface water or drains. This material and its container must be disposed of in a safe way. Waste
disposal according to EC directives 75/442/EEC and 91/689/EEC in the corresponding versions, covering waste and
dangerous waste.
Control report for waste code/ waste marking according to EAKV:
080111 waste paint and varnish containing organic solvents or
other dangerous substances
Contaminated packaging:
Recommendation:
Cleaned containers may be recycled. Vessels not properly emptied are special waste.

14. Transport information
14.1. UN-No.:
1263
14.2. UN proper shipping name
Land transport (ADR/RID): Paint
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH)
according to Regulation (EU) No 453/2010
Article no.: 01307SL30000
Date of print: 04.06.2013
Version:
SL 1307
Revision date: 08.04.2013 EN
Date of issue: 04.06.2013 Page:7 / 8
Sea transport (IMDG): PAINT
Air transport (ICAO-TI / IATA-DGR): Paint
14.3. Transport hazard class(es)
3
14.4. Packing Group:
III
14.5. Environmental hazards:
Land transport (ADR/RID) not applicable
Marine pollutant: not applicable
14.6. Environmental hazards
Transport always in closed, upright and safe containers. Make sure that persons transporting the product know what to do in
case of an accident or leakage.
Advices on safe handling: see parts 6 - 8
Further remarks:
Land transport (ADR/RID)
Tunnel restriction code: D/E
Sea transport (IMDG)
EmS-No.: F-E, S-E
14.7. Special precautions for user
not applicable
15. Regulatory information
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
EU legislation
Information according to 1999/13/EC about limitation of emissions of volatile organic compounds (VOC-guideline).
VOC-value (in g/l) ISO 11890-2: 648
VOC-value (in g/l) ASTM D 2369: 648
National regulations
Informations on working limitations:
Observe employment restrictions under the Maternity Protection Directive (92/85/EEC) for expectant or nursing mothers.
Observe restrictions to employment for juvenils according to the 'juvenile work protection guideline' (94/33/EC).
15.2. Chemical Safety Assessment
Chemical safety assessments for substances in this preparation were not carried out.
16. Other information
Relevant R-and H-phrases (Number and full text):
Flam. Liq. 3 / H226 Flammable liquids: Flammable liquid and vapour.
STOT SE 3 / H336 Specific target organ toxicity (single
exposure):
May cause drowsiness or dizziness.
Repr. 1B / H360 Reproductive toxicity: May damage the unborn child.
STOT SE 3 / H335 Specific target organ toxicity (single
exposure):
May cause respiratory irritation.
Skin Irrit. 2 / H315 Skin corrosion/irritation: Causes skin irritation.
Eye Dam. 1 / H318 Serious eye damage/eye irritation: Causes serious eye damage..
Skin Sens. 1 / H317 Respiratory or skin sensitisation: May cause an allergic skin reaction.
Aquatic Acute 1 / H400 Hazardous to the aquatic environment: Very toxic to aquatic life.
Aquatic Chronic 1 / H410 Hazardous to the aquatic environment: Very toxic to aquatic life with long lasting
effects.
R10 Flammable.
Xi; R37 Irritant Irritating to respiratory system.
N; R51-53 Dangerous for the environment Toxic to aquatic organisms. May cause
long-term adverse effects in the aquatic
environment.
Xi; R38 Irritant Irritating to skin.
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH)
according to Regulation (EU) No 453/2010
Article no.: 01307SL30000
Date of print: 04.06.2013
Version:
SL 1307
Revision date: 08.04.2013 EN
Date of issue: 04.06.2013 Page:8 / 8
R43 May cause sensitization by skin contact.
N; R50-53 Dangerous for the environment Very toxic to aquatic organisms. May cause
long-term adverse effects in the aquatic
environment.
R67 Vapours may cause drowsiness and dizziness.
Xn; R20 Harmful Harmful by inhalation.
Xi; R36/37/38 Irritant Irritating to eyes, respiratory system and skin.
Repr.Cat.2; R61 Reproductive toxic Cat.2 (Repr. Cat. 2) May damage the unborn child.
Xi; R37/38-41 Irritant Irritating to respiratory system and skin. Risk of
serious damage to eyes.
Xn; R65 Harmful Harmful: may cause lung damage if swallowed.
R66 Repeated exposure may cause skin dryness or
cracking.
Further remarks:
The information supplied on this safety data sheet complies with our current level of knowledge as well as with national and
EU regulations. Without written approval, the product must not be used for purposes different from those mentioned in
chapter 1. It is always the user's duty to take any necessary measures for meeting the requirements laid down by local rules
and regulations. The details in this safety data sheet describe the safety requirements of our product and are not to be
regarded as guaranteed attributes of the product.
Observe technical data sheet.
Annex
At present, data / information on exposure scenarios are not available, so that an evaluation of the preperation cannot yet be
made.