KI2141-2015 SIK Lecture02b VibrationalMotion
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Achmad RochliadiKI2141-2015 SIK Lecture02b VibrationalMotion
Uploaded by
Achmad Rochliadi.
Quantum
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Theory :
Techniques & Applications
Vibrational Motion
Achmad Rochliadi, Ph.D.
Program Studi Kimia
Institut Teknologi Bandung
Vibrational motion
A particle will have harmonic motion if the restoring force
is propotional to its displacement.
Relation with potential energy is,
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Giving,
The Schrodinger equation for the particles,
The energy level
Boundary condition, allowed solution are for those:
The permitted energy are :
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Energy different between two level are
Zero point energy of harmonic oscillator
Energy of harmonic oscilator
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The energy levels of a
harmonic oscillator are
evenly spaced with
separation. Even in its
lowest state, an
oscillator has an energy
greater than zero.
The wave function
Particle having harmonic motion is trapped in a
symmetrical well with the energy climb as x2.
Its follow a Gausian function.
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The form of the wave function
A solution to the Schrodinger equation of the harmonic
oscilation will have the form of
The precise form of the wavefuncions are
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With
is a Hermite polynomial.
See Followin table
Hermite polynomials
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The wave function for the ground state
For the ground state, the lowest energy state, the wave
function is
The probability density is
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The wavefunction for the first exited state
The wave function for the ground state
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Wavefunction and
probability distribution for
ground state
Wavefunction and
probability distribution for 1st
exited state
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The wave function for the ground state
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Probability distribution for
the first 5 states up to 20th
Wavefunction for the 5 first
states
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Thank You
Lecture Outline
The structure & spectra of hydrogenic atoms
The structure of hydrogenic atoms
Atomic orbital and their energies
Spectroscopic transitions and selection rules
The structures of many-electron atoms
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The orbital approximation
Self-consistent field orbital
The spectra of complex atoms
Impact on astrophysics : Spectroscopy of star
Quantum defects & ionization limits
Singlet and triplet coupling
Spin-orbit coupling
Term symbol and selection rules
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Role of quantum mechanics in hidrogen like atom
Quantum mechanics is used to describe :
Electronic structure of atom
Arrangement of electron around nucleus
Types of atom :
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Hydrogenic atom : one-electron atom or ion, H, He+, Li+, O7+
Many-electron atom (polyelectronic atom), all neutral atom
other than H
Schrodinger equation can be solved exactly for
hydrogenic atoms
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Lecture Outline
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Nunc ullamcorper hendrerit justo.
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Topic 1
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Simple harmonic oscilation
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