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Worksheet G10 AnalyticalChemistry

The document contains questions related to analytical chemistry. It asks to distinguish between various salts based on chemical tests, identify unknown salts and cations based on results of chemical reactions, fill in blanks in tables describing chemical tests on unknown samples, and solve a crossword puzzle with clues related to chemical properties of salts. The questions involve common chemical tests like formation of precipitates with reagents such as barium chloride, silver nitrate, sodium hydroxide and ammonium hydroxide. Properties tested also include solubility, color of precipitates and gases formed.

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184 views2 pages

Worksheet G10 AnalyticalChemistry

The document contains questions related to analytical chemistry. It asks to distinguish between various salts based on chemical tests, identify unknown salts and cations based on results of chemical reactions, fill in blanks in tables describing chemical tests on unknown samples, and solve a crossword puzzle with clues related to chemical properties of salts. The questions involve common chemical tests like formation of precipitates with reagents such as barium chloride, silver nitrate, sodium hydroxide and ammonium hydroxide. Properties tested also include solubility, color of precipitates and gases formed.

Uploaded by

Santanu
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd
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Analytical Chemistry

Question 1: Give a test to distinguish between


1. Sodium carbonate and sodium sulphate
2. Potassium chloride and potassium nitrate
3. Copper carbonate and copper sulphate
4. Lead chloride and lead sulphate
5. Iron (II) sulphate and iron (III) sulphate
6. Calcium sulphate and zinc sulphate
7. Zinc sulphate and aluminium sulphate
8. Ammonium sulphate and ammonium chloride
9. Hydrated copper sulphate and anhydrous copper sulphate
10. Ammonium chloride and sodium chloride

Question 2: Identify the following from the given list [Copper nitrate, Iron (II) sulphate, Iron (III)
chloride, Zinc chloride, Magnesium sulphate, Lead nitrate]
1. Which two solutions will give white ppt when treated with dilute hydrochloric acid
followed by barium chloride solution?
2. Which two solutions will give a white ppt when treated with dil HNO3 and AgNO3
solution?
3. Which solution will gave a white ppt when HCl or H2SO4 is added to it?
4. Which solution will become inky blue on addition of excess ammonia?
5. Which solution will give a white precipitate with excess ammonium hydroxide solution?

Question 3: Substance A is water-soluble and gives a curdy white ppt, B with silver nitrate
solution. B is soluble in ammonium hydroxide but insoluble in dil HNO3. Substance A reacts
with ammonium hydroxide solution to give a white precipitate C, which is soluble in conc.
Ammonia. Another solution of D is added to barium nitrate solution. A white ppt E is formed,
which is insoluble in dil HCl or HNO3. A dirty green ppt F is formed on addition of ammonium
hydroxide to a solution of D and the precipitate is insoluble in excess ammonia. The third sample
G is a coloured salt, which on heating decomposes leaving a black residue; H. on addition of
copper turning and concentrated H2SO4 to G produce a coloured acidic gas, J. A solution of G is
added to NaOH solution until in excess, a pale blue ppt, I is obtained, which is insoluble in excess
of sodium hydroxide, A solution of G is then added to NH4OH solution in excess to give an inky
blue solution K, A solution of G is warmed and hydrogen sulphide gas is passed through it, A
black ppt L is formed, identify all A-L elements. And write a balanced chemical equation for all
the above reactions.
Question 4: Fill in the blanks in the following table:
Test
Observation
To a solution A, barium
chloride solution and dil HCl
is added
To a solution B, sodium
hydroxide solution was
added
To a solution C ammonium
hydroxide is added in excess
To a solution D silver nitrate
solution with dil HNO3 is
added

Worksheet-G10-analyticalChemistryJaydip_Chaudhuri

Inference
A contains SO42- ion
Contains Fe3+ ion
Contains Cu2+ ion
Contains Cl- ion

Question 5: Identify the following cations:


Sodium hydroxide solution is added to solution A. A white ppt is formed which is insoluble in
excess sodium hydroxide solution. When ammonium hydroxide is added to solution B, a pale
blue precipitate appears, this pale blue ppt disappears with excess of NH4OH is added to for form
a inky blue solution. Solution C produces a dirty green ppt on addition of sodium hydroxide
where as solution D produces a yellowish brown ppt.
Question 6: Name the following
1. Two compounds, which produces a white ppt on addition of dil HCl solution.
2. Two compounds which produces a white ppt when NaOH is added in small amount but
dissolves in it when added in excess
3. Two compounds which does not produce coloured ppt on addition of aqueous ammonium
hydroxide
4. Name three samples, which produces a brown acidic gas on addition of copper turning
and concentrated H2SO4 and produces coloured ppt on addition of aqueous sodium
hydroxide solution.
5. Name two solutions that produce white ppt with small amount of NaOH but dissolve in
excess but only one shows similar action with NH4OH not the other.
Question 7: Fill in the crossword with the given clue below
Across
8. This chloride produces two gases
on heating, one of which is acidic
another is basic
10. A chloride sample imparts a
golden yellow flame on Bunsen
flame
Down
1. This metal nitrate produces a lilac
flame
2. This metal chloride produces a
brown gelatinous ppt on addition of
sodium hydroxide
3. A metal sulphate produces a pale
blue ppt with small amount of
aqueous ammonia
4. This lead salt produces a brown
gas when copper turning with
concentrated sulphuric acid is added
5. This nitrate precipitate a chalky
white ppt when sulphuric acid is
added and has apple green flame
6. This metal chloride produces a
chalky white ppt on addition of dil
sulphuric acid and imparts an
reddish flame in flame test.
7. This metal sulphate produces a
dirty green ppt on addition of
sodium hydroxide
9. The copper salt produces a white ppt when dil silver nitrate and hydrochloric acid is added to it

Worksheet-G10-analyticalChemistryJaydip_Chaudhuri

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