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Aits Pace

This document contains 60 multiple choice questions related to chemistry. The questions cover a range of topics including stoichiometry, equilibrium, organic chemistry reactions, IUPAC naming of complexes, and electrochemistry. For each question, there are 4 possible answer choices and only one choice is correct. The questions require understanding of fundamental chemical concepts to determine the right answer.

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Aditya Dev
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191 views9 pages

Aits Pace

This document contains 60 multiple choice questions related to chemistry. The questions cover a range of topics including stoichiometry, equilibrium, organic chemistry reactions, IUPAC naming of complexes, and electrochemistry. For each question, there are 4 possible answer choices and only one choice is correct. The questions require understanding of fundamental chemical concepts to determine the right answer.

Uploaded by

Aditya Dev
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd
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AITS - 1 CHEMISTRY (MAIN)

CHEMISTRY : PART (B)


SECTION I : SINGLE CHOICE QUESTIONS
This section contains 30 multiple choice questions. Each question has four choices (1),
(2), (3) and (4) out of which ONLY ONE is correct.
31.

You are given 5m (molal) aqueous solution of H2SO4 of density 1.49 gm/ml, then which of the following
is incorrect :
(1) molarity (M) of the solution = 5 M
(2) mole fraction of solute = 0.083
(3) % by weight of H2SO4 = 40%
(4) concentration of H+ ion = 10 M

32.

The enthalpy of neutralisation of a weak monoacidic base(1M) with strong acid is 56.9 KJ/mol. If the enthalpy
of ionisation of weak monoacidic base is 1.8 KJ/mol, the percentage ionisation of weak base in its molar solution
is [Given that DHneutralisation of strong acid and strong base = 57.3 KJ/mol]
(1) 100/3%
(2) 200/3%
(3) 25%
(4) 700 / 9%

33.

2SO 2 + O 2 2 SO3 starting with 2 mole of SO and 1 mole of O in 1 litre flask. Equilibrium mixture
2
2
( g)
(g )
(g )
required
(1) 2

34.

1
3

mole of K2Cr2O7 for titration in acidic medium. Hence KC for the given reaction is.
(2)

1
2

(3) 4

(4)

1
4

A hypothetical reaction X2 + Y2 2XY follows the mechanism given below..


X2
X + X
[Fast]
X + Y2 XY + Y [Slow]
X + Y XY [Fast]
The order of overall reaction is
(1) 2
(2) 1

(3) 1.5

(4) Zero

SPACE FOR ROUGH WORK

CENTERS : MUMBAI / DELHI / AKOLA / KOLKATA / LUCKNOW / NASHIK / GOA / PUNE # 10

AITS - 1 CHEMISTRY (MAIN)


35.

The IUPAC name of the complex


[Co(NH3)2Cl(ONO)(py)2]NO3 is :
(1) DiamminechloridodipyridinenitritoNcobaltate(III) nitrate.
(2) DiamminechloridonitritoObipyridinecobalt(III) nitrate.
(3) DiamminechloridonitritoObis(pyridine)cobalt(III) nitrate.
(4) ChloridodiamminenitritoObis(pyridine)cobaltate(III) nitrate.

36.

Two reactions, A products and B products have rate constants kA and kB at temperature, T and
activation energies EA and EB respectively. If kA > kB and EA < EB and assuming that A , pre-exponential factor
for both the reactions is same then. (EA - EB are independent of T)
(1) at higher temperatures kB will be greater than kA
(2) at lower temperatures kB > kA .
(3) as temperature rises kA and kB will be close to each other in magnitude.
(4) None of these

37.

Which of the following statement(s) is / are correct ?


(1) Hybridisation of carbon in C3O2 is sp2.
(2) In Cr2O72 , six Cr O bonds are identical.
(3) Three centre two electron bonds exist in B2H6 and Al2Cl6 .
(4) In AgI, the colour is attributed to charge transfer spectrum.

38.

In which of the following complex ion, the metal ion will have t 62g , e 0g configuration according to CFT::
(1) [FeF6]3
(2) [Fe(CN)6]3
(3) [Fe(CN)6]4
(4) None of these

39.

A soluteS undergoes a reversible trimerization when dissolved in a certain solvent. The boiling point
elevation of its 0.1 molal solution was found to be identical to the boiling point elevation in case of a 0.08
molal solution of a solute which neither undergoes association nor dissociation. To what percent had the
solute S undergone trimerization? (Assume the solvent to be same in both the solution)
(1) 30%
(2) 40%
(3) 50%
(4) 60%
SPACE FOR ROUGH WORK

CENTERS : MUMBAI / DELHI / AKOLA / KOLKATA / LUCKNOW / NASHIK / GOA / PUNE # 11

AITS - 1 CHEMISTRY (MAIN)


40.

An azeotropic mixture of two liquids boils at a lower temperature than either of them when :
(1) it is saturated.
(2) it does not deviate from Raoult's law
(3) it shows negative deviation from Raoult's law
(4) it shows positive deviation from Raoult's law .

41.

Action of PCl5 on SO2 chiefly yields


(1) POCl3
(2) P4S3

(3) SO2Cl2

(4) SO3

42.

Which statement is false.


(1) Glycine is amphoteric in nature.
(2) Hydrolysis of sucrose is known as inversion of cane sugar.
(3) Sucrose undergoes mutarotation.
(4) Maltose and Lactose both are reducing sugar.

43.

For a reaction P Q, the half life of the reaction was 3 hrs., when initial concentration of P was 0.5 M. As
the concentration of P was increased to 1.0M, half life changes to 6 hrs. The order of reaction with respect
to P is
(1) zero
(2) one
(3) two
(4) three

44.

Which one of the following statements is correct:


(1) Brownian movement is more pronounced for smaller particles than for bigger ones
(2) Sols of metal sulphides are lyophilic
(3) Schulze-Hardy law states, the bigger the size of the ion, the greater is its coagulating power
(4) One would expect charcoal to adsorb hydrogen gas more strongly than chlorine.

45.

In H2 - O2 fuel cell a reaction occuring at cathode is :


(1) 2 H2O + O2 + 4 e - 4 OH (2) 2 H2 + O2 2 H2 O (l)
(3) H+ + OH - H2O

(4) H+ + e -

1
H
2 2

SPACE FOR ROUGH WORK

CENTERS : MUMBAI / DELHI / AKOLA / KOLKATA / LUCKNOW / NASHIK / GOA / PUNE # 12

AITS - 1 CHEMISTRY (MAIN)


46.

In which of the following reactions, standard reaction entropy change (S) is positive and standard Gibbs
energy change (G) decreases sharply with increasing temperature ?
1
2

(1) C graphite + O2(g) CO(g)


(3) Mg(s) +

1
O (g) MgO(s)
2 2

(2) CO(g) +
(4)

1
O (g) CO2(g)
2 2

1
1
1
C graphite + O2(g) CO2(g)
2
2
2

47.

Aluminium is extracted from alumina (Al2O3) by electrolysis of a molten mixture of :


(1) Al2O3 + HF + NaAlF4
(2) Al2O3 + CaF2 + NaAlF4
(3) Al2O3 + Na3AlF6 + CaF2
(4) Al2O3 + KF + Na3AlF6

48.

pH of a saturated solution of Ba(OH)2 is 12. The value of solubility product (KSP) of Ba(OH)2 is :
(1) 3.3 107M3
(2) 5.0 107M3
(3) 4.0 106M3
(4) 5.0 106M3

49.

In the given reaction sequence.


Br

(i) SOCl2
2
(i)KMnO 4 / H /

Y
CH3 14CH2 OH

X (
Z
ii) NH3 /
OH ,
(Z) will be

(1) CH3NH2

(2) 14CH3NH2

(3) CH314CH2NH2

(4)

SPACE FOR ROUGH WORK

CENTERS : MUMBAI / DELHI / AKOLA / KOLKATA / LUCKNOW / NASHIK / GOA / PUNE # 13

AITS - 1 CHEMISTRY (MAIN)


50.

In which option all compounds can show geometrical isomerism


(1)

(2)

, C2FClBrI.

(3)

, Ph CH = N OH, Ph2N2

(4) CH3CH = NOH

51.

Which of the following will not show keto enol tautomerism

(1)

52.

, H2C = CHCH = CHCN.

(2)

(3) CH2=CHCHO

(4)

(3) IV > II > III > I

(4) IV > III > II > I

The stability order of the following species is :


I:

II :

III :

IV :

(1) I > II > III > IV

(2) III > I > II > IV

SPACE FOR ROUGH WORK

CENTERS : MUMBAI / DELHI / AKOLA / KOLKATA / LUCKNOW / NASHIK / GOA / PUNE # 14

AITS - 1 CHEMISTRY (MAIN)

53.

NaOH /

P ; the major product 'P' is

(1)

(2)

(3)

(4)

Peroxyacid

Ph CH Mg Br

H O

(1)

( 2)

( 3)

2 2

54.
The product is :
(1)

(2)

(3)

(4)

SPACE FOR ROUGH WORK

CENTERS : MUMBAI / DELHI / AKOLA / KOLKATA / LUCKNOW / NASHIK / GOA / PUNE # 15

AITS - 1 CHEMISTRY (MAIN)


55.

In the following conversion,


(i) MeMgBr

NaOH / I

(ii) H3O+

H3O+

2

X
Y

the major products X and Y, respectively, are :

56.

(1)

(2)

(3)

(4)

Which of the following undergoes decarboxylation most readily on being heated ?


(1)

(2)

(3)

(4)

SPACE FOR ROUGH WORK

CENTERS : MUMBAI / DELHI / AKOLA / KOLKATA / LUCKNOW / NASHIK / GOA / PUNE # 16

AITS - 1 CHEMISTRY (MAIN)

57.

OH
O3
Y + Z
X

Zn,H2 O

Compound X in the above reaction is

(1)

(2)

(3)

(4)

SPACE FOR ROUGH WORK

CENTERS : MUMBAI / DELHI / AKOLA / KOLKATA / LUCKNOW / NASHIK / GOA / PUNE # 17

AITS - 1 CHEMISTRY (MAIN)


58.

final product is

(1)

(2)

(3)

possible products

59.

60.

possible products

( m)

the value of m and n are respectively


(1) 2,4
(2) 3,6

(4)

(n )

(3) 3,4

(4) 3,5

Which of these reaction gives meso compound as product


(1)
(3)

D / Ni

D / Ni

(2)
(4)

Bayer 's reagent


PhCO H

H3 O

SPACE FOR ROUGH WORK

CENTERS : MUMBAI / DELHI / AKOLA / KOLKATA / LUCKNOW / NASHIK / GOA / PUNE # 18

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