Scribd
Upload
1K views26 pages

Conversion of ASTM To TBP and EFV

This document contains tabular and graphical data related to distillation of a hydrocarbon mixture. The data includes temperature-volume percent curves for true boiling point (TBP), distillation range limits (DRL), flash range limits (FRL) and estimated final volatility (EFV). Graphs show the relationship between these different distillation properties and allow calculation of values like the 50% distillation point from the TBP curve slope.

Uploaded by

syedmuhammadtarique
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as XLSX, PDF, TXT or read online on Scribd
1K views26 pages

Conversion of ASTM To TBP and EFV

This document contains tabular and graphical data related to distillation of a hydrocarbon mixture. The data includes temperature-volume percent curves for true boiling point (TBP), distillation range limits (DRL), flash range limits (FRL) and estimated final volatility (EFV). Graphs show the relationship between these different distillation properties and allow calculation of values like the 50% distillation point from the TBP curve slope.

Uploaded by

syedmuhammadtarique
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as XLSX, PDF, TXT or read online on Scribd
You are on page 1/ 26

Volume Distilled (%)

ASTM oC TBP by API oC


TBP by Daubert's oC
0
36.5 14.1240923602
-5.3279387608
10
54 33.3576257773
27.5278511349
30
77 68.9623034308
66.7361563686
50
101.5 101.6357041039
101.6588879292
70
131 135.1645344031
138.1440625513
90
171 180.5120296261
184.6282359444
95
186.5 194.0885107583
201.1166863444

R
97.7
129.2
170.6
214.7
267.8
339.8
367.7

a
557.7
589.2
630.6
674.7
727.8
799.8
827.7

b
0.9167
0.5277
0.7429
0.892
0.8705
0.949
0.8008

TBP by API oR
oF
517.4233662483 57.42337
552.0437263991 92.04373
616.1321461754 156.1321
674.944267387 214.9443
735.2961619256 275.2962
816.9216533269 356.9217
841.3593193649 381.3593

index no. i
1.0019
1.09
1.0425
1.0176
1.0226
1.011
1.0355

1
2
3
4
5
6
7

del
del
del
del
del
del

T1
T2
T3
T5
T6
T7

ASTM
TBP by API Method
TBP by Daubert's Method

Ai

Bi
7.4012
4.9004
3.0305
0.8718
2.5282
3.0419
0.118

Ti

0.6024
0.7164
0 10 20 30 40 50 60 70 80 90 100
0.8008
1.0258
0.82
0.775
1.6606

Daubert's Method
Ti'
TPB Temp. oF oF
31.5 59.14042 T0'
22.40971
41.4 70.57495 T10'
81.55013
44.1 62.86092 T30'
152.1251
53.1 65.67331 T50'
214.986
72 83.67151 T70'
280.6593
27.9 29.67921 T90'
364.3308
T95'
394.01

Data from Sheet 1

Volume Distilled (%)

ASTM oC oF
0
36.5
10
54
30
77
50
101.5
70
131
90
171
95
186.5

VABP (oF)=

224.42

Slope

2.6325

ln

2.905729
18.27856

MeABP (oF)=

206.1414

Kw =

11.91659

97.7
129.2
170.6
214.7
267.8
339.8
367.7

When Sp. Gr. is 0.7313 at 60 oF/60 oF

at 60 oF/60 oF

Vol %

TBP oC oF
0
-5.3
10
27.5
30
66.7
50
101.7
70
138.1
90
184.6
95
201.1
100

Slope 10%-70%

DRL oF
DRL oF
(from graph) (Calculated)
22.4
48.4 48.36526862
81.6
81.6
81.6
152.1
147 147.9198589
215.0
216 214.2895857
280.7
280.7 280.6593126
364.3
347
347
394.0
363 363.6214712
432
380 380.2139029

3.32 oF / percent

t50% point (DRL) oF 214.29


t0% oF
48.3653
t100% oF
380.214

Slope of EFV
from Maxwell's graph
t50 =(DRL -FRL)
from Maxwell's graph
T50% FRL oF
T0% FRL oF
T100% FRL oF

1.4 oF / percent

14

200.29
130.29
270.29

Raito of
T'/t'
from fig in
t' (TBP-DRL)
Maxwell T'(FLASH-FRL)
FRL
-26.0
0.22
-5.7102228452
0.0 -0
4.2
0.34
1.4297756741
0.7
0.34
0.2367802602
0.0 -0
17.3
0.33
5.719172151
30.4
0.33
10.0282262075
51.8
0.33
17.0894120539

oF
T EFV oF
130.3 124.5898
144.3
144.3
172.3 173.7298
200.3 200.5368
228.3
228.3
256.3 262.0192
263.3 273.3282
270.3 287.3894

410.0
f(x)
= 1.70169256875269E-007x^5 - 4.25888661158362E-005x^4 + 0.0041889618x^3 - 0.1970972111x^2 + 7.4858
400.0
R390.0
= 0.9999963502
380.0
370.0
360.0
350.0
340.0
330.0
320.0
310.0
300.0
290.0
280.0
270.0
260.0
250.0
240.0
230.0
220.0
210.0
200.0
190.0
180.0
170.0
160.0
150.0
140.0
130.0
120.0
110.0
100.0
90.0
80.0
70.0
60.0
50.0
40.0
30.0
20.0
10.0

TB

Po

DR

FR

EF

90.0
80.0
70.0
60.0
50.0
40.0
30.0
20.0
10.0
0.0
0

10

20

30

40

50

60

70

80

90

100

x^3 - 0.1970972111x^2 + 7.4858840358x + 22.4660266724

TBP
Poly
DRL
FRL
EFV Curve

80

90

100

You might also like

pFad - Phonifier reborn

Pfad - The Proxy pFad of © 2024 Garber Painting. All rights reserved.

Note: This service is not intended for secure transactions such as banking, social media, email, or purchasing. Use at your own risk. We assume no liability whatsoever for broken pages.


Alternative Proxies:

Alternative Proxy

pFad Proxy

pFad v3 Proxy

pFad v4 Proxy