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3ProblemSet2Problem9 PDF

This document contains Matlab code to calculate and plot the molar heat capacity (Cv) as a function of temperature based on a two-state model. It defines constants, creates temperature and Cv vectors, calculates Cv values for each temperature using the two-state model equation, plots the Cv values against temperature, and finds the maximum Cv value.

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AlexGeorge
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45 views1 page

3ProblemSet2Problem9 PDF

This document contains Matlab code to calculate and plot the molar heat capacity (Cv) as a function of temperature based on a two-state model. It defines constants, creates temperature and Cv vectors, calculates Cv values for each temperature using the two-state model equation, plots the Cv values against temperature, and finds the maximum Cv value.

Uploaded by

AlexGeorge
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd
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9/15/15 1:28 PM

\\base\root...\CBE353ProblemSet2Problem9.m

R=8.314; %Gas contant in J/mol*K


T=1:5000; %Temperature in K
%Assume energy of the state = 1
E=1000; %cm^-1
K=0.69486; %cm^-1
Cv=1:length(T);
%Creating a vector of Cv_m values using the expression for molar Cv_m

for i=1:length(T)
Cv(i)=R*((((E^2)/((K^2)*(T(i)^2)))*exp(-E/(K*T(i))))/(1+exp(-E/(K*T(i))))^2);
end
plot(T,Cv)%Plotting the values
xlabel('Temperature in Kelvin')
ylabel('Molar Heat Capacity')
%Calculating the maximum
f = @(x) R*((((E^2)/((K^2)*(x^2)))*exp(-E/(K*x)))/(1+exp(-E/(K*x)))^2);
max_x = fminbnd(@(x) -f(x),1,5000)

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