Scribd
Upload
101 views6 pages

Thermophysical Properties Compounds

The document provides equations and parameter values for estimating vapor pressure, liquid density, and liquid viscosity of various compounds as a function of temperature. The equations include terms for vapor pressure (Pvp), liquid density (ρliq), and liquid viscosity (μliq). Parameter values like A, B, C, etc. are provided for each compound to calculate the properties over a given temperature range with accuracy of less than 5% deviation from experimental values.

Uploaded by

Anonymous oVRvsdWzfB
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as XLSX, PDF, TXT or read online on Scribd
101 views6 pages

Thermophysical Properties Compounds

The document provides equations and parameter values for estimating vapor pressure, liquid density, and liquid viscosity of various compounds as a function of temperature. The equations include terms for vapor pressure (Pvp), liquid density (ρliq), and liquid viscosity (μliq). Parameter values like A, B, C, etc. are provided for each compound to calculate the properties over a given temperature range with accuracy of less than 5% deviation from experimental values.

Uploaded by

Anonymous oVRvsdWzfB
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as XLSX, PDF, TXT or read online on Scribd
You are on page 1/ 6

Equation

B
Pvp EXP( A C LN (T ) D T E )
T
where:
Pvp = Vapor Pressure in Pa
T = Temperature in K

Deviation from
experimental
Compound Temp. Range (K) values A B C D E
Methane 90.7 190.6 < 1% 3.9205E+01 -1.324E+03 -3.4366E+00 3.1019E-05 2
Ethane 90.4 305.3 < 1% 5.1857E+01 -2.599E+03 -5.1283E+00 1.4913E-05 2
Propane 85.5 369.8 < 3% 5.9078E+01 -3.4926E+03 -6.0669E+00 1.0919E-05 2
Isobutane 113.5 407.8 < 3% 1.0843E+02 -5.0399E+03 -1.5012E+01 2.2725E-02 1
n-Butane 134.9 425.1 < 3% 6.6343E+01 -4.3632E+03 -7.046E+00 9.4509E-06 2
Isopentane 113.2 460.4 < 3% 7.1308E+01 -4.976E+03 -7.7169E+00 8.7271E-06 2
n-Pentane 143.4 469.7 < 3% 7.8741E+01 -5.4203E+03 -8.8253E+00 9.6171E-06 2
n-Hexane 177.8 507.6 < 3% 1.0465E+02 -6.9955E+03 -1.2702E+01 1.2381E-05 2
n-Heptane 182.6 540.2 < 3% 8.7829E+01 -6.9964E+03 -9.8802E+00 7.2099E-06 2
Water 273.2 647.1 < 0.2% 7.3649E+01 -7.2582E+03 -7.3037E+00 4.1653E-06 2
Oxygen 54.4 154.6 < 1% 5.1245E+01 -1.2002E+03 -6.4361E+00 2.8405E-02 1
Nitrogen 63.2 126.2 < 1% 5.8282E+01 -1.0841E+03 -8.3144E+00 4.4127E-02 1
Hydrogen Sulfide 187.7 373.5 < 3% 8.5584E+01 -3.8399E+03 -1.1199E+01 1.8848E-02 1
Carbon Dioxide 216.6 304.2 < 1% 1.4054E+02 -4.735E+03 -2.1268E+01 4.0909E-02 1

Temperature, C
5 10 15 20 25 30 35 40 45 50 55 60
Vapor Pressure, kPa
Ethane 2690.087 3019.343 3377.463 3766.205 4187.439 4643.159 NA NA NA NA NA NA
Propane 551.70 637.33 732.39 837.49 953.26 1080.33 1219.4 1371.04 1536.05 1715.11 1908.97 2118.40
Isobutane 187.52 221.41 259.75 302.91 351.24 405.14 465.00 531.22 604.22 684.43 772.28 868.23
n-Butane 124.45 148.70 176.44 207.99 243.68 283.85 328.85 379.04 434.78 496.44 564.41 639.09
Isopentane 42.69 52.29 63.53 76.61 91.71 109.05 128.84 151.31 176.68 205.21 237.12 272.68
n-Pentane 30.57 37.86 46.49 56.61 68.40 82.05 97.76 115.72 136.15 159.27 185.30 214.48
n-Hexane 7.85 10.11 12.88 16.23 20.27 25.08 30.77 37.44 45.23 54.25 64.64 76.52
n-Heptane 2.05 2.74 3.61 4.70 6.07 7.75 9.80 12.28 15.26 18.81 23.02 27.96
Water 0.87 1.23 1.71 2.34 3.17 4.25 5.63 7.39 9.60 12.35 15.76 19.94
Hydrogen Sulfide 1192.62 1369.77 1565.44 1780.76 2016.87 2274.95 2556.20 2861.86 3193.19 3551.52 3938.19 4354.59
Carbon Dioxide 3976.57 4511.61 5099.21 5743.25 6447.89 7217.63 NA NA NA NA NA NA

Compiled by: Ankur Srivastava


Chemical Engineer
e-mail: ankur_2061@hotmail.com
Disclaimer: The excel worksheet is a compilation of data from the DIPPR database. While the author has made every
effort to provide an error free compilation no warranty whatsoever is provided for the accuracy of the data
and users are advised to use it at their own discretion.
Equation

A
liq T
1 (1 C ) D
B

where:
liq = Liquid Density, kg-mole / m3
T = Temperature in K

For Water the following equation shall be used

water A ( B t ) (C t 0.66 ) ( D t ) ( E t 1.33 )


where:
t 1 Tr
and
T
Tr
Tc

where:
T = Temperature of Interest, K
Tc = Crtitical Temperature of Water, K

Deviation from
experimental
Compound Temp. Range (K) values A B C D E
Methane 90.7 190.6 < 1% 2.9214E+00 2.8976E-01 1.9056E+02 2.8881E-01
Ethane 90.4 305.3 < 1% 1.9122E+00 2.7937E-01 3.0532E+02 2.9187E-01
Propane 85.5 369.8 < 1% 1.3757E+00 2.7453E-01 3.6983E+02 2.9359E-01
Isobutane 113.5 407.8 < 1% 1.0631E+00 2.7506E-01 4.078E+02 2.7580E-01
n-Butane 134.9 425.1 < 1% 1.0677E+00 2.7188E-01 4.2512E+02 2.8688E-01
Isopentane 113.2 460.4 < 1% 9.1991E-01 2.7815E-01 4.604E+02 2.8667E-01
n-Pentane 143.4 469.7 < 1% 8.4947E-01 2.6726E-01 4.697E+02 2.7789E-01
n-Hexane 177.8 507.6 < 1% 7.0824E-01 2.6411E-01 5.08E+02 2.7537E-01
n-Heptane 182.6 540.2 < 1% 6.1259E-01 2.6211E-01 5.402E+02 2.8141E-01
Water 273.2 647.1 < 1% 1.7863E+01 5.8606E+01 -9.5396E+01 2.1389E+02 -1.4126E+02
Oxygen 54.4 154.6 < 1% 3.9143E+00 2.8772E-01 1.5458E+02 2.924E-01
Nitrogen 63.2 126.2 < 1% 3.2091E+00 2.861E-01 1.262E+02 2.966E-01
Hydrogen Sulfide 187.7 373.5 < 1% 2.7672E+00 2.7369E-01 3.7353E+02 2.9015E-01
Carbon Dioxide 216.6 304.2 < 1% 2.768E+00 2.6212E-01 3.0421E+02 2.908E-01
Equation

B
liq EXP( A C LN (T ) D T E )
T
where:
liq = liquid viscosity, Pa-s
T = Temperature in K

Deviation from
experimental
Compound Temp. Range (K) values A B C D E
Methane 90.7 188 < 3% -6.1572E+00 1.7815E+02 -9.5239E-01 -9.0606E-24 10
Ethane 90.4 300 < 3% -7.0046E+00 2.7638E+02 -6.0870E-01 -3.1108E-18 7
Propane 85.5 360 < 5% -1.7156E+01 6.4625E+02 1.1101E+00 -7.3439E-11 4
Isobutane 110 311 < 5% -1.3912E+01 7.9709E+02 4.5308E-01 0 0
n-Butane 134.9 420 < 3% -7.2471E+00 5.3482E+02 -5.7469E-01 -4.6625E-27 10
Isopentane 150 310 < 1% -1.2596E+01 8.8911E+02 2.0469E-01 0 0
n-Pentane 143.4 465.2 < 3% -5.3509E+01 1.8366E+03 7.1409E+00 -1.9627E-05 2
n-Hexane 174.6406.1 < 3% -6.3276E+00 6.40E+02 -6.94E-01 5.6884E+21 -10
n-Heptane 180.2-432.2 < 3% -9.4622E+00 8.7707E+02 -2.3445E-01 1.4022E+22 -10
Water 273.2 646.2 < 3% -5.2843E+01 3.7036E+03 5.866E+00 -5.879E-29 10
Oxygen 54.4 150 <25% -4.1476E+00 9.404E+01 -1.207E+00 0 0
Nitrogen 63.2 124 <5% 1.6004E+01 -1.8161E+02 -5.1551E+00 0 0
Hydrogen Sulfide 187.7 350 <5% -1.0905E+01 7.6211E+02 -1.1863E-01 0 0
Carbon Dioxide 216.6 303.2 < 10% 1.8775E+01 -4.0292E+02 -4.6854E+00 -6.9171E-26 10

Temperature, C
5 10 15 20 25 30 35 40 45 50 55 60
Liquid Viscosity, cP
Ethane 0.053 0.049 0.045 0.041 0.037 NA NA NA NA NA NA NA
Propane 0.12 0.11 0.11 0.10 0.10 0.09 0.09 0.08 0.08 0.07 0.07 0.06
Isobutane 0.20 0.20 0.19 0.18 0.17 0.17 0.16 NA NA NA NA NA
n-Butane 0.19 0.18 0.17 0.17 0.16 0.15 0.14 0.14 0.13 0.13 0.12 0.12
Isopentane 0.26 0.25 0.24 0.22 0.21 0.20 0.20 NA NA NA NA NA
n-Pentane 0.27 0.25 0.24 0.23 0.22 0.21 0.21 0.20 0.19 0.18 0.17 0.17
n-Hexane 0.36 0.34 0.32 0.31 0.29 0.28 0.27 0.26 0.24 0.23 0.23 0.22
n-Heptane 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00
Water 1.48 1.30 1.15 1.02 0.91 0.82 0.74 0.67 0.61 0.56 0.51 0.47
Hydrogen Sulfide 0.15 0.14 0.13 0.13 0.12 0.12 0.11 0.11 0.10 0.10 0.09 0.09
Carbon Dioxide 0.10 0.09 0.08 0.07 0.06 0.06 NA NA NA NA NA NA
Equation

AT B
vap
C D
1
T T2
where:
vap= vapor viscosity, Pa-s
T = Temperature in K
Note: At Low Pressures

Deviation from
experimental
Compound Temp. Range (K) values A B C D
Methane 90.7 1000 < 3% 5.2546E-07 5.9006E-01 1.0567E+02 0
Ethane 90.4 1000 < 5% 2.5906E-07 6.7988E-01 9.8902E+01 0
Propane 85.5 1000 < 3% 4.9054E-08 9.0125E-01 0.0000E+00 0
Isobutane 150 1000 < 5% 1.0871E-07 7.8135E-01 7.0639E+01 0
n-Butane 134.9 1000 < 3% 3.4387E-08 9.4604E-01 0 0
Isopentane 150 1000 < 5% 2.4344E-08 9.7376E-01 -9.1597E+01 1.872E+04
n-Pentane 143.4 1000 < 5% 6.3412E-08 8.4758E-01 4.1718E+01 0
n-Hexane 177.8-1000 < 5% 1.7514E-07 7.07E-01 1.5714E+02 0
n-Heptane 182.6-1000 < 5% 6.6720E-08 8.2837E-01 8.5752E+01 0
Water 273.2 1073.2 < 1% 1.7096E-08 1.1146E+00 0.000E+00 0
Oxygen 54.4 1500 <5% 1.1010E-06 5.634E-01 9.63E+01 0
Nitrogen 63.2 1970 <3% 6.5592E-07 6.08E-01 5.4714E+01 0
Hydrogen Sulfide 250 480 <3% 3.9314E-08 1.0134E+00 0 0
Carbon Dioxide 194.7-1500 < 5% 2.1480E-06 4.6E-01 2.9E+02 0

Temperature, C
5 10 15 20 25 30 35 40 45 50 55 60
Vapor Viscosity, cP
Methane 0.011 0.011 0.011 0.011 0.011 0.011 0.012 0.012 0.012 0.012 0.012 0.012
Ethane 0.009 0.009 0.009 0.009 0.009 0.010 0.010 0.010 0.010 0.010 0.010 0.010
Propane 0.008 0.008 0.008 0.008 0.008 0.008 0.009 0.009 0.009 0.009 0.009 0.009
Isobutane 0.007 0.007 0.007 0.007 0.008 0.008 0.008 0.008 0.008 0.008 0.008 0.008
n-Butane 0.007 0.007 0.007 0.007 0.008 0.008 0.008 0.008 0.008 0.008 0.008 0.008
Isopentane 0.006 0.007 0.007 0.007 0.007 0.007 0.007 0.007 0.007 0.008 0.008 0.008
n-Pentane 0.007 0.007 0.007 0.007 0.007 0.007 0.007 0.007 0.007 0.008 0.008 0.008
n-Hexane 0.006 0.006 0.006 0.006 0.006 0.007 0.007 0.007 0.007 0.007 0.007 0.007
n-Heptane 0.005 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.007
Water 0.009 0.009 0.009 0.010 0.010 0.010 0.010 0.010 0.011 0.011 0.011 0.011
Oxygen 0.019 0.020 0.020 0.020 0.021 0.021 0.021 0.021 0.022 0.022 0.022 0.023
Nitrogen 0.017 0.017 0.017 0.017 0.018 0.018 0.018 0.018 0.019 0.019 0.019 0.019
Hydrogen Sulfide 0.012 0.012 0.012 0.012 0.013 0.013 0.013 0.013 0.014 0.014 0.014 0.014
Carbon Dioxide 0.014 0.014 0.014 0.015 0.015 0.015 0.015 0.016 0.016 0.016 0.016 0.017
Equation
2 2
C E

Cp A B T D T
C E
Sinh Cosh
T T

where:
Cp = Ideal Gas Heat Capacity, J/kmol-K
T = Temperature in K

Deviation
from
experimental
Compound Temp. Range (K) values A B C D E
Methane 50-1500 < 1% 3.3298E+04 7.9933E+04 2.0869E+03 4.1602E+04 9.9196E+02
Ethane 200-1500 < 1% 4.0326E+04 1.3422E+05 1.6555E+03 7.3223E+04 7.5287E+02
Propane 200-1500 < 1% 5.192E+04 1.9245E+05 1.6265E+03 1.168E+05 7.236E+02
Isobutane 200-1500 < 1% 6.549E+04 2.4776E+05 1.587E+03 1.575E+05 7.0699E+02
n-Butane 200-1500 < 1% 7.134E+04 2.43E+05 1.63E+03 1.5033E+05 7.3042E+02
Isopentane 200-1500 < 1% 7.46E+04 3.265E+05 1.545E+03 1.923E+00 6.667E+02
n-Pentane 200-1500 < 1% 8.805E+04 3.011E+05 1.6502E+03 1.892E+05 7.476E+02
n-Hexane 200-1500 < 1% 1.044E+05 3.523E+05 1.6946E+03 2.369E+05 7.616E+02
n-Heptane 200-1500 < 1% 1.2015E+05 4.001E+05 1.6766E+03 2.74E+05 7.564E+02
Water 100-2273.2 < 1% 3.3363E+04 2.679E+04 2.6105E+03 8.896E+03 1.169E+03
Oxygen 50-1500 < 1% 2.9103E+04 1.004E+04 2.5265E+03 9.356E+03 1.1538E+03
Nitrogen 50-1500 < 1% 2.9105E+04 8.6149E+03 1.7016E+03 1.0347E+02 9.0979E+02
Hydrogen Sulfide 100-1500 < 1% 3.3288E+04 2.6086E+04 9.134E+02 -1.7979E+04 9.4940E+02
Carbon Dioxide 50-5000 < 1% 2.937E+04 3.454E+04 1.428E+03 2.64E+04 5.880E+02

Temperature, C
5 10 15 20 25 30 35 40 45 50 55 60
Heat Capacity, KJ/kg-K
Methane 2.181 2.191 2.202 2.213 2.224 2.236 2.248 2.261 2.274 2.287 2.301 2.316
Ethane 1.661 1.681 1.701 1.721 1.742 1.763 1.785 1.806 1.827 1.849 1.871 1.893
Propane 1.572 1.596 1.619 1.642 1.666 1.690 1.714 1.738 1.762 1.786 1.810 1.834
Isobutane 1.562 1.586 1.611 1.635 1.660 1.685 1.710 1.735 1.761 1.786 1.811 1.836
n-Butane 1.602 1.624 1.646 1.669 1.692 1.715 1.738 1.761 1.785 1.808 1.831 1.855
Isopentane 1.042 1.044 1.045 1.047 1.049 1.052 1.054 1.057 1.060 1.063 1.067 1.070
n-Pentane 1.572 1.594 1.616 1.638 1.660 1.683 1.706 1.729 1.752 1.775 1.798 1.821
n-Hexane 1.557 1.579 1.601 1.623 1.646 1.669 1.692 1.715 1.739 1.762 1.786 1.809
n-Heptane 1.551 1.573 1.595 1.618 1.641 1.664 1.687 1.710 1.734 1.758 1.781 1.805
Water 1.860 1.861 1.862 1.863 1.864 1.866 1.867 1.868 1.870 1.871 1.873 1.874
Oxygen 0.914 0.915 0.916 0.916 0.917 0.918 0.919 0.919 0.920 0.921 0.922 0.923
Nitrogen 1.039 1.039 1.040 1.040 1.040 1.040 1.040 1.040 1.040 1.040 1.040 1.041
Hydrogen Sulfide 0.997 0.998 1.000 1.001 1.003 1.005 1.007 1.008 1.010 1.012 1.014 1.016
Carbon Dioxide 0.822 0.828 0.834 0.840 0.846 0.852 0.858 0.863 0.869 0.874 0.880 0.885
Equations:

C p ,liq A BT CT 2 DT 3 ET 4

where:
Cp,liq = Liquid Heat Capacity, J/kmol-K
T = Temperature in K

Deviation
from
experimental
Compound Temp. Range (K) values A B C D E
Isobutane 113.5-380 < 3% 1.7237E+05 -1.7839E+03 1.4759E+01 -4.7909E-02 5.8050E-05
n-Butane 134.9-400 < 1% 1.9103E+05 -1.675E+03 1.25E+01 -3.8740E-02 4.6121E-05
Isopentane 113.2-310 < 3% 1.083E+05 1.46E+02 -2.920E-01 1.510E-03 0.000E+00
n-Pentane 143.4-390 < 1% 1.5908E+05 -2.705E+02 9.9537E-01 0.000E+00 0.000E+00
n-Hexane 177.8-460 < 1% 1.7212E+05 -1.8378E+02 8.8734E-01 0.000E+00 0.000E+00
Water 273.2-533.2 < 1% 2.7637E+05 -2.0901E+03 8.125E+00 -1.4116E-02 9.3701E-06
Carbon Dioxide 220-290 < 3% -8.3043E+06 1.0437E+05 -4.333E+02 6.0052E-01 0.000E+00

Temperature, C
5 10 15 20 25 30 35 40 45 50 55 60
Heat Capacity, KJ/kg-K
Isobutane 2.314 2.341 2.370 2.401 2.433 2.469 2.507 2.548 2.592 2.640 2.692 2.749
n-Butane 2.316 2.339 2.363 2.389 2.417 2.447 2.480 2.515 2.552 2.593 2.637 2.685
Isopentane 2.201 2.225 2.249 2.274 2.299 2.326 2.353 NA NA NA NA NA
n-Pentane 2.229 2.249 2.270 2.291 2.313 2.336 2.360 2.384 2.408 2.434 2.460 2.487
n-Hexane 2.201 2.219 2.238 2.257 2.277 2.297 2.318 2.339 2.361 2.383 2.406 2.430
Water 4.216 4.206 4.198 4.191 4.186 4.182 4.179 4.178 4.177 4.178 4.179 4.182
Carbon Dioxide 2.809 3.155 3.588 NA NA NA NA NA NA NA NA NA

You might also like

pFad - Phonifier reborn

Pfad - The Proxy pFad of © 2024 Garber Painting. All rights reserved.

Note: This service is not intended for secure transactions such as banking, social media, email, or purchasing. Use at your own risk. We assume no liability whatsoever for broken pages.


Alternative Proxies:

Alternative Proxy

pFad Proxy

pFad v3 Proxy

pFad v4 Proxy