Scribd
Upload
137 views2 pages

Formulas For Thermodynamics 1

This document provides key equations and concepts in thermodynamics. It defines measures of amount like specific volume and molar volume. It describes the first law of thermodynamics which relates changes in internal energy to heat and work. Key concepts covered include enthalpy, heat capacity, and material and energy balances for open systems. Equations are given for ideal gas processes and equations of state like the van der Waals and virial equations. Cubic equations of state including the Soave-Redlich-Kwong and Peng-Robinson models are also summarized.

Uploaded by

Stefani Ann Cabalza
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as DOCX, PDF, TXT or read online on Scribd
137 views2 pages

Formulas For Thermodynamics 1

This document provides key equations and concepts in thermodynamics. It defines measures of amount like specific volume and molar volume. It describes the first law of thermodynamics which relates changes in internal energy to heat and work. Key concepts covered include enthalpy, heat capacity, and material and energy balances for open systems. Equations are given for ideal gas processes and equations of state like the van der Waals and virial equations. Cubic equations of state including the Soave-Redlich-Kwong and Peng-Robinson models are also summarized.

Uploaded by

Stefani Ann Cabalza
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as DOCX, PDF, TXT or read online on Scribd
You are on page 1/ 2

FORMULAS FOR THERMODYNAMICS 1

MEASURES OF AMOUNT OF SIZE FIRST LAW OF THERMODYNAMICS



Specific volume = Esystem + Esurroundings = 0
Esurroundings = Q W
Molar volume, Vm =
Esystem = U + PE + KE
Q W = U + PE + KE
FORCE
1 For closed systems: (PE and KE are constant)
=
E = U = Q + W
For finite changes: U = Q + W
PRESSURE For differential changes: dU = dQ + dW

= =
Enthalpy:
H = U + PV
WORK For finite changes: H = U + (PV); H = U + VP +
= U PV
For differential changes: dH = dU + d(PV)
ENERGY For constant pressure process: H = U + PV
a. Kinetic energy
1 2 Heat Capacity:
= 2 =
2 2 Constant pressure: Q = H = nCpT
b. Potential energy Constant volume: Q = U = nCvT

= =
MATERIALS & ENERGY BALANCES FOR OPEN SYSTEMS
1u1A1 = 2u2A2 (continuity equation)

OVERALL ENERGY BALANCE EQUATION


2
W + Q = Z + 2 + H

EQUATIONS FOR PROCESS CALCULATIONS: IDEAL GAS


(Mechanically Reversible Closed-System Processes)
Q U H W
Isochoric U nCvT nCpT 0
Isobaric nCvT nCpT U - Q

Isothermal -W 0 0 RT 1 = RT 2
2 1
Adiabatic 0 nCvT nCpT U
EQUATIONS OF STATE
Virial Equations
1. Application of virial equations

= = 1 + where B 2nd virial coefficient (equation 1)

= =1+ truncated in two terms (equation 2)


=
=1+ + 2
truncated in three terms (equation 3)

2. Extended virial equation: Benedict/Webb/Rubin Equation

0 0 0 / 2 2
= + 2
+ 3
+ 6 + 3 2 (1 + 2 ) /

3. Cubic equations of state


a. Van der Waals Equation of state

= 2

272 2
Where = =
64 8

b. Vapor & vapor-like roots of the generic cubic equation of state


()
= + [ ]
( )( + )


For Z: = 1 +
(+)(+)

= =

c. Vapor & vapor-like roots of the generic cubic equation of state


+
= + ( + )( + ) [ ]

For Z:
1+
= + ( + )( + ) [ ]

d. Other equations: Soave/Redlich/Kwong SRK Equation and Peng Robinson PR
Equation

Equation of
Tr Zc
state
VDW 1 0 0 1/8 27/64 3/8
RK Tr1/2 1 0 0.08664 0.42748 1/8
SRK SRK 1 0 0.08664 0.42748 1/8
PR PR 1 + 2 1 2 0.07779 0.45724 0.3074
1/2 2
= [1 + (0.480 + 1.574 0.1762 ) (1 )]
1/2 2
= [1 + (0.37464 + 1.5422 0.269922 ) (1 )]

You might also like

pFad - Phonifier reborn

Pfad - The Proxy pFad of © 2024 Garber Painting. All rights reserved.

Note: This service is not intended for secure transactions such as banking, social media, email, or purchasing. Use at your own risk. We assume no liability whatsoever for broken pages.


Alternative Proxies:

Alternative Proxy

pFad Proxy

pFad v3 Proxy

pFad v4 Proxy