Bauxite Explr
Bauxite Explr
The aluminium industry is interested in the quantity, quality and confidence of the
reserves/resources in a mineral deposit and its potential, the miners in the shape, size
(dimension), location of the bodies (both in horizontal and vertical terms), variance in thickness
and grade, the physical parameters of the ore and host rocks (overburden and bedrock) and the
investors in the possible returns and the risks involved.
All parties in the investment must be aware of the risks, that is, of the reliability of the basic data,
first of all that of the resource/reserve estimate and then the related parameters.
When the industrial value of any mineral resource is judged and before a decision to invest and
develop is taken, that decision takes into account further information:
• Mineability of the bauxite
• Processability of the bauxite (the ability to make economic alumina)
• Geographical position (close to users or a trade route)
• Infrastructure (accessibility, power, water, housing, communications)
• Environmental (locality, impact, local regulations and management)
• Political (basis, legality, stability)
• Cost
However, to emphasise, all of this construct and the subsequent decisions are based on the
fundamental data, i.e.. the geological knowledge of the deposit and its reliability.
An understanding of the further prospect of the area is also necessary for the value of the area
and a decision to develop is taken (blue sky).
The author gives an overview through the stages of the geological activities necessary to develop
a bauxite deposit such as:
1. Delineation of the prospective areas
2. Prospection and exploration of the resource from the reconnaissance up to the detailed
exploration.
3. Mine development exploration
4. Methods of exploration (some technical questions, drilling grid, sampling, etc)
5. Representative sampling
6. Material tests (analytical methods)
7. Reserve/resource estimate (tonnage vs. grade calculation)
As a consequence it is concluded that the geology, the mining (transport) and alumina production
is one single economic unit. Criterion for economic grade bauxite can only be deduced from the
technological parameters of the alumina production in order to attain an optimum for the
industry in which the a geologist has to play a much larger role than it is (generally) expected.
2
Bauxite reserves and resources that have been revealed in the world vary between 50 billion
tons of crude ore (as per 1999 – P.A. LYEW-AYEE) and 90 billion (as per 2005 – I.V.
MAMEDOV). The latter figure seems to be an overestimation, probably lots of bauxite deposits
were included in the inventory which do not satisfy the industrial requirements. According to the
Author’s estimation the total world bauxite reserves + resources could be about 60 billion tons
from which 20 – 30 billion tons are identified reserves while the remainder are undiscovered
resources in hypothetical and speculative categories. In spite of the fact that this huge volume
theoretically may satisfy the demand of the world consumption up to 350 - 650 years - based on
140 Mt/annum world consumption and total reserves and undiscovered resources, there is an
accelerated demand to find new, easily accessible deposits. The reasons are different, most
frequently:
(1) setting up new modern alumina plants of large capacity (1 – 5 million t/a) which are
competitive in a large region or in the world market,
(2) capacity of the alumina plant has been decided to be increased and no adequate
quantity of reserves are available (or are not explored yet) in the vicinity,
(3) viability of the alumina plant is not competitive enough. In order to reduce the
operating costs the refinery, it has been decided to feed a better quality bauxite and
for this purpose the available reserves must be increased for a better selection.
(4) old alumina plant is running out of its existing (licensed) reserves..
ad (1).A refinery is planned to be set up either close to the mine, or bauxite is planned to be
supplied from a long distance to the plant. In the first case the analyses of the transport cost
between the plant and source is entirely an economic question but in the second case the
geologist has to select among the given possibilities, so that:
(a) It is necessary to clarify whether there is any prospective area between the
plant (along the existing transport route ) and the already discovered and
explored deposits.
(b) Exploration program of already discovered (reconnaissanced) deposit(s)
should be managed in such a manner that the deposits - which are situated
in the best position - have to be taken in preference. .
There are huge bauxite deposits in the world which can not be economic at the present time
because of the missing infrastructure (e.g. Surinam (Bakhius Mts., Mali, Bissau, Guinea,
Vietnam, etc.). In the recent situation the alumina projects are not able to cover the costs of
significant development of infrastructure. In those countries, or regions, where bauxite has been
found in abundant quantity not all of the already discovered bauxite deposits have to be
explored in detail, but bauxite prospecting should be focused to those areas where
infrastructure is available and the area has not been investigated adequately for bauxite. (e.g.
Guinea, India). In the utilisation of the Trombetas bauxite (Brazil) and Los Pijiguaos
(Venezuela) the existing natural transport routes (Rio Negro - Amazon and Orinoco rivers resp.)
played an important role. Other deposits became important because of their close location to a
deepwater port.
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It may also happen that the development of the infrastructure is financed by the state making
viable by this way, the establishment of the bauxite – alumina – aluminium industry (as it is
planned e.g. in Saudi Arabia for the Az Zabirah deposit.). The utilisation of the South
Vietnamese bauxite deposits was abandoned in the late eighties because the State dropped the
idea of the construction a railway track between Ho Chi Minh City (Saigon) and Phnom Penh
(Cambodia).
ad 2,3,4 There is no difficulty provided the owner of the refinery has a long-term project and
the further prospects of the surroundings are clarified at least in a reconnaissance stage.
Nevertheless, it is worth mentioning that the decision making for increasing the plant capacity
or increasing the grade of the bauxite to be used in the plant may come easily and fast and the
geologists are urged to provide for bauxite immediately. According to the Author’s experience
the decisions are not always well prepared geologically. In these cases such solutions are forced
and – because of the inadequate geological preparation – may result in industry losses For
example when bauxite is transported to the plant from a much longer distance than all accounts
would be necessary. For example the BALCO (India) supplies bauxite to its Korba plant from
about 250 km (on road by track) without investigating the area in between the known deposits
and the plant.
Bauxite deposits have been discovered so far, from the historical point of view, may be classified
into three main groups:
- Deposits discovered by chance (during some agricultural or construction activities)
- Deposits discovered by general geological mapping, aerial photograph interpretations
or prospecting for some other raw material,
- Deposits discovered for the sake of finding new deposits
Detailed investigation of the history of bauxite discoveries belongs to the scope of the “history of
sciences”. Bauxite target oriented prospecting has shared a more and more important role at the
time.
The range of application of analogies can be very narrow: from some km (within one deposit or
group of the deposits) or some tens of km in distance (e.g. applied in the Dinarids – Croatia –
Bosnia-Herzegovina or in the Bakony Mts. Hungary) but sometimes the analogies are extended
far from the known deposits (applied e.g. in the Mediterranean bauxite belt) or even in a longer
distance, their application may bridge continents (India – Africa – South America – that is,
applied to the ancient Gondwana continent).
4
Delineation of the prospective areas, in the case of karst bauxite, is restricted practically to the
delineation of the possible stratigraphical gap(s) and lithofacies of the bedrock and immediate
covers where the expected depth of the deposit is also important. In the following, (in this
Chapter) the emphasis is put on the laterite bauxites because the main developments in the
aluminium industry are expected to relate to this type of ore.
Delineation of potential areas of laterite bauxites, provided they are not covered by younger
sediments, can basically be based on:
(a) parent rock ,
(b) morphology,
(c) absolute elevation,
(d) vegetation.
for these purposes:
- geological and topographic maps in different scales (from 1:25,000 to max.
1:100,000),
- radar photos ( Digital Elevation Models – (DEM), Shuttle Radar Topographic
Mission (SRTM).
- Landsat TM images (752, 457, 453) can be used.
Channel combination must be fitted to the local conditions. In case of adequate bauxite
geological knowledge and favourable geo-morphological conditions bauxite contours can
be identified within a maximum error of 100 m. (G. KOMLÓSSY – Z. UNGER, 2004, G.
KOMLÓSSY 2006)
It is also essential to be aware of the type of the deposit expected to be found. Based on the
morphology bauxite deposits can be classified into:
(1) Plateau type where bauxite accumulated on flat (sub)horizontal, or moderately inclined
or slightly undulating surfaces and pinches out at the rim of the plateau. When the rim of
the plateau is a sharp one (e.g. Deccan bauxites in India, Kindia in Guinea) ore body
contours are well definable outlines. (Photo 1.) ). In some cases the rim of the plateau is
defined by slopes and the bauxite pinches out at inclination between 150 and 200 as at Los
Pijiguaos – Venezuela, and between 50 and 150 at the East Coast bauxites - India. The
grade of slopes can be correctly measured on landsat maps applying SRTM. See Fig. 1.
When the surface is an undulating one and bauxite developed in lenses restricted to mounds
(with relative elevation of about some 10 metres) the contours can also be well detected
after some field experience (Lichenya plateau in Malawi (Photo 2), Bao Lok in Vietnam,
etc.
q -Syenite
Photo 2. bedrock
Lichenya plateau
Malawi
bauxite
bodies
Fig. 1.
Slope and TM 453 maps of the Sapparla Deposit – AP India
after
A. MENENDEZ
AND
A. SARMENTO
1982
Fig.2.
Morphological terraces at the Guyana Shield - Venezuela
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(2). Slope type deposits: there are laterite bauxite deposits accumulated along the slopes of hills
or ridges where the inclination may reach 23 – 30 degrees (Darling Range – Western Australia)
(See Fig. 3.)
(3) Dome and slope deposits: Fongo Tongo - Cameroon. (Fig. 4.)
Photos 3. and 4.
Whale back plateaux at Los Pijiguaos - Venezuela
Fig. 3.
Topographical maps of 1:100.000 scale can only be applied in the delimitation of prospective
areas provided the topography is not very abrupt and where large and quasi flat planation
surfaces have been formed (e.g. in Guinea) in other cases, topographical maps must be available
for this purpose in a scale of minimum 1:50,000 (e.g. India Deccan bauxites). Where the
topography is very dissected and no large and flat planation surfaces formed or where the bauxite
is common on the mounds, the minimum scale for ore body delineation is 1:25,000 (e.g. Los
Pijiguaos – Venezuela) and 1:10.000 (e.g. Bao Lok Vietnam, Lichenya – Malawi).
Fig.4.
Legend: 1. Duricrust partially disintegrated, 2.Hardened bauxite on the top of the hill,
3. Bauxite, 4. Saprolite.(after: HYERONIMUS, 1985)
1.3. Reconnaissance
Identification of bauxite deposits based on morphology, elevation, parent rock, vegetation, must
always be checked on the field. It may occur that in the same morphological pattern, on similar
topographical level on the same parent rock – even side by side – a plateau is productive while
the other one is absolutely barren. This phenomenon due to the different physical property of
the parent rocks resulting in considerably different drainage conditions. Hence the escarpments
must be checked, sampled and analysed. If bauxite has been verified at the rim of the plateau the
escarpment should be surveyed, by walking around and being measured by GPS. Using portable
auger drilling equipment is highly recommended to make some randomly spaced holes inside the
plateaux , because it also may occur that there is no bauxitisation inside the plateau.
barren Deccan
bauxite free trap basalt
When the plateaux are proven to be laterite
productive, selection should be made
based on the function of the
expected:
• quantity and quality (processability),
• mineability and
• accessibility of each ore body or groups of
the ore bodies (haulage cost)
Western Ghats – Maharastra – India
Photo 5.
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By this way deposits (group of the ore bodies) can be ranked in their economic values and
preferences given in planning and itemising of the exploration and mining accordingly,
beginning the mining operation of the deposits which provide the highest possible profit.
2. Bauxite exploration
2.1.Exploration methods.
The basis of the reliability of the reserve calculation/resource estimate is the correctly applied
techniques in the exploration (see details under Paragraph 2.1.3.). When the value of a
proposed bauxite/alumina industry is checked by an auditor or when a “Competent Person
Report” is made special attention should be paid to this critical topic.
2.1.1.Trenching
In case of outcrops or near surface deposits – mainly in the reconnaissance phase – trenching is
used for clarifying the bauxite thickness, lithology, grade (also mineralogy), dip and strike of
bauxite. Trenches can be one metre in width and several ten metres long. Trenches are mapped
in scales of 1:100 to 1:500. Geological sketches are made of the trenches, the sampling
intervals and the grade of bauxite.
There are several cases when non other then pitting is the only method applied in the exploration
e.g. at Mulanje Mts. (Malawi) because of the topographical difficulties no drilling machine can
be carried up the mountain, or when the drilling does not provide representative samples. The
latter case is typical when relatively hard industrial grade bauxite (sand, nodules, gravel,
boulders) are cemented by soft low grade bauxite or clay. In such cases beneficiation is
necessary. Selection can be made either manually during the mine operation (e.g. Balco and
Halco mines in India) or by mechanised dry or wet screening. The latter procedure was used in
Vietnam both for the young laterite bauxite (Southern Vietnam) and for the paleozoic karst
bauxite deposits ( Northern Vietnam) Bauxite upgrading, by applying scrubbing wet screening
and hydrocyclones, is known to be very efficient for the Trombetas (Brazil) deposits.
It is recommended to require (as a general rule) that not less than 70% of core recovery
for any one m interval, 80% for the whole penetrated section and 90% for deposit
average. Thanks to the advances in drilling technology the average core recovery has
considerably been increased, therefore the input data of the reserve calculation became
much more reliable in the last decades.
Diameter of cores must be NQ (52mm) minimum. Both in the laterite and karst bauxites
bits of HQ (63mm) is preferred.. When the bauxite is very hard (rigid) and heterogeneous
in hardness, PQ(84mm) is recommended to apply.
Non-core drilling
(1) Auger drilling: Where physical properties of the bauxite allow to the use of an auger
it is an acceptable method, however, its reliability is far behind that of the diamond
core drilling. The biggest possible errors in quality should be taken into account when
reserves/resources are categorised. Let us consider the following example:
In Guinea samples were taken for technological purposes and auger bore holes drilled at
the close vicinity of previous exploration holes. The alumina and silica contents were
compared in the identical intervals of the twin bore holes. Remarkable deviations were
revealed as they are shown in Fig 7 and Fig 8.
Bias in alumina and silica content in an auger (A) and auger(B) twin hole (Guinea)
AlaO3 % SiO2 %
50 2,5
45
40 2
35
30 1,5
25 A A
20 B 1 B
15
10 0,5
5
0 0
1 2 3 4 5 6 7 1 2 3 4 5 6
intervals
7
intervals
Fig. 7.
Deviation
21% 17%
>10%
5-10%
2-5%
<2%
Bias in Al2O3 % was bigger than 5 abs.% in almost half of the samples. In such cases
the reserves can hardly be assigned to the measured (proven) category even if the bore
holes are spaced in 50m x 50m grid.
In order to avoid the discrepancies described above the following procedure is proposed :
(2) Vacuum drilling.. It is a very efficient and acceptable method provided the bauxite
is homogenous in its physical properties. This method was applied at the Worsley mine
- Darling Range – Western Australia - and it has been proved to be reliable when
exploration data (forecast) are compared with those of subsequent mining (actual).
This type of bauxite is loose, friable and quasi homogenous. Encouraged by the success
this equipment was also applied for the Indian Daccan bauxite which is quite different
12
as it is composed of hard bauxite boulders and soft clayey matrix. In such a case this
method is absolutely inconvenient as the soft clay and hard bauxite are mixed by
drilling and nothing can be known about the quantity and quality of the ore to be
extracted, but an average of the bauxitic complex. are not of the manually selected hard
bauxite.
Vacuum flush drilling at Jamirapat
Chattisgarh State - India
Fig 9.
Photos 7. and 8.
Bias in alumina and silica contents in a DC (A) and RC (B) twin drilling
70 35
60 30
50 25
20
40 A
A
15
30 B
B
10
20
5
10
0
0 1 3 5 7 9 11 13
1 3 5 7 9 11 13
Fig 11.
Fig. 12.
14
Let us suppose:
In this example:
The drilling/pitting grid must be fitted to the orientation of the ore body. Where the ore body is
covered the expected orientation of the deposit can be predicted by the main structural pattern.
In case of the karst bauxite, as the process of the karstification itself (including the drainage) is
also controlled by the pre-existing fault zones, the shape of the buried deposit can also be
established prior to the exploration start. See Figs 13 and 14.
15
Fig 13.
In the Timan bauxite district (Russia) exploration grid was fitted to the main
structural pattern
Also in case of the laterite bauxites the shape of the ore deposit is determined by the prominent
structural lines as a consequence of the tectonics When the shape and orientation of the
possibly productive areas are well defined, as is shown in Fig.15., the orientation of the grid
should be fitted accordingly.
Fig. 15.
Where the ore bodies do not show elongated forms and there are no privileged directions the
grid orientation has no significance.
Drilling and pitting must be located in such density that at the end of the exploration reliable data
be available for the general mine planning in long- and short term basis.
Data are reliable provided the errors in all of the measured parameters ( thickness, grade, depth,
dip, etc) can be kept within such a range that the extraction can reliably be planned for long and
short term, in a way that, under the given geological conditions, maximum profit can be
attained (the possible maximum tonnage - minimum loss with the best possible grade –
minimum dilution on a cheapest way). For mining plan data are gained from the mine
development exploration ( Chapter 5.). Reliability of the geological information, including the
number of measured data, depends - beyond the techniques used in drilling (2.1.3) - on the
density of the drilling/pitting grid.
It is a general rule that any data which are extrapolated in any direction must be consistent
bearing the same range in possible error in the same distance.
17
Apart from rather unusual geological conditions such as Severuralsk – Russia where the point
of the penetration of the bauxite can not be determined in advance because of the significant bore
hole inclination at big depth (600m – 1,200m) regular grids are applied and developed in
square or oblong arrangement.
(1)Square grid:
Its application is acceptable if there is no privileged direction(s) along which the
variance of the most important elements of the parameters do not depend on any
direction. It means that the ore body is quasi isotropic in horizontal term. Such a case
does not exist in karst bauxites, unless the bauxite accumulated in a simple and single
sink hole but may occur in case of laterite bauxites where the ore body is in a large
mantle non-elongated, but in a rounded-like form such as e.g. Shinthiourou and
Bidikum in Guinea, Trombetas in Brazil, etc.
The isotropic characters of the bauxite can be derived from the drainage intensity when it
does not depend on any direction. This geological phenomenon is provoked by
- relative tectonic tranquillity for a long period and
- the physical nature of the parent rock such as e.g. non-orogenetic granites, other
intrusive rocks, schists, sandstone of marine origin, etc.
The spacing of the bore holes/pits in the stage of reconnaissance is dependent on the
drilling grid decided to apply in the stage of detailed exploration. Two versions are
common:
(a) reconnaissance commenced in 300m x 300m or 600m x 600m and detailed
exploration completed in 75m x 75m or 37.5m x 37.5m ( Fig. 16.).
(b) reconnaissance commenced in 400m x 400m and exploration finished 50m x
50m in the detailed stage.
It is to be mentioned that in the overwhelming majority regular grids are unfortunately
applied in spite of the fact that ore bodies are mainly anisotropic in their inner structure.
Fig. 16.
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Range in directions
R-1: 66m, R-2: 45m
Range in directions:
R-1: 72m, R-2: 48m
Fig. 17.
Semi-variograms of thickness computed along four directions
Csabpuszta – Hungary
E-W
NW-
SE
Fig 16
Fig 18.
19
Fig. 19.
Optimum spacing of the grid is determined by the following factors:
(1) size of the ore body,
(2) shape ( orientation) of the ore body,
(3) depth of the ore body.
(4) anisotropy of the main parameters.
Each bauxite deposit (single ore body or group of ore bodies) has its own nature. Not only the
orientation of the grid but also the spacing of the bore holes must be fitted to it.
As a guideline the following drilling grids are recommended to apply for detailed exploration
dedicated to satisfy the demand of the long- and short-term (minimum one year) mine planning.
For short term plans the following conditions are deemed to be followed in the case of laterite
bauxites:
Maximum error (95% confidence level) are:
for tonnage: +/- 10%
for alumina: +/- 10%
for silica: ….+/- 20%
For karst bauxites for tonnage +/- 20% error is also acceptable.
Error in contaminants of accessory elements such as Corg, ΣS, carbonates of Ca, Mg and P2O5 are
out of consideration because their concentration always varies extremely. Distribution of these
elements can only be clarified by the mine development exploration or better by regular grade
control during mining
1
At the Trombetas mine 200m x 200m grid was applied and verified to be reliable to classify the bauxite into
proved (measured) category.
20
It is obvious that delimitation of the rim of the deposits needs closer spacing of bore holes than
the inner part. It is the same for those deposits where in the inner part, barren “islands” or
bedrock outcrops can be found on the surface (e.g. East Coast bauxites Orissa – India).
Apart from the guideline, summarised in the Table 1, for the establishing of the optimum
detailed grid (by which reserves of measured category can be gained) there are two empirical
methods:
(1) Subsequent reserve calculations (direct method)
This method is recommended when new deposit(s) is/are discovered and there are no data for the
variance of parameters in the close vicinity which can be used as an analogous pattern for
establishing the drilling grid to be applied in the stage of detailed exploration
As the exploration is going ahead from the reconnaissance stage (600m x 600m, 400m x 400m)
reserve (resource) calculations should be made at the end of each subsequent stage of the
exploration. As the infill drillings are performed the modification of the reserves should be
checked with re-estimation carried out step by step. When there is no more significant change
in tonnage, in alumina (or in available alumina) and silica (or in reactive silica) contents, the
exploration is completed, because by further decreasing of space distance no new relevant
information can be gained and error can be kept within an acceptable range ( Paragraph 2.2.1.).
In the explorations conducted at the Timan (Russia) deposits this principle was adapted
correctly.
It is worth mentioning that according to the experiences of the author several laterite deposits are
over explored.
(b) Cross validation (indirect method)
When an ore body, or a group of the ore bodies are explored in detail applying a grid of closely
spaced drill holes calculation can be made for the main parameters and check how the
parameters are changing when every second bore hole is dropped from the calculation step by
step. For this purpose an attempt was made by the author for one of the ore bodies of the Kindia
(Guinea) deposit as it is shown in Table 2
Table 2.
Change of the expected parameters with increased bore hole spacing
Sec- Parameters 25m intervals 50m intervals 75m intervals 100m intervals
tion N EV N EV N EV N EV
A thickness(m) 17 4.35 8 3.88 6 4.00 4 3.75
Al2O3 % 45.57 46.27 48.04 44.78
SiO2 % 2.23 2.08 2.10 2.08
B thickness(m) 22 4.73 11 4.73 8 4.88 6 4.17
Al2O3 % 45.77 45.38 45.40 45.48
SiO2 % 1.97 2.00 2.05 2.18
C thickness(m) 38 4.74 19 4.90 13 4.85 10 5.10
Al2O3 % 45.73 45.86 45.75 46.44
SiO2 % 1.97 2.08 1.84 2.01
For thickness(m) 77 4.65 38 4.63 27 4.67 20 4.55
Al2O3 % 45.71 45.80 46.16 45.82
A+B+ SiO2 % 2.03 2.12 1.96 2.07
C
3. Analyses
3.1 Sample preparation
Most of the analytical errors may derive from incorrect sample preparation. For taking a
representative sample from bauxite the Richards-Cherrchette’s formula is advised to follow:
Q = k x d2
where Q = the reliable weight of the sample crushed down for quartering in kg, d = diameter of
the largest particles in mm and k= factor which is for bauxites 0.05. For example 1 kg of sample
can be taken from a bigger quantity provided the maximum grain size is less than 4.47mm. For
chemical analyses generally samples of 100 grams are taken and sent to the labs. In this case
the gradual pulverisation (and gradual quartering) should be done to achieve particles of
maximum 1.41mm. In practice sieves of -14 tyler mesh (1.17mm) are used.
(1) Wet, traditional chemical analysis is still widely used. The alumina is determined directly
(most frequently by complexometric method) or indirectly (four main components analysed,
results added and alumina calculated by difference from 99% or 99.5%). Permitted error
in alumina is +/- 1 % abs. and for silica 0.5% abs.
(2) Bomb digestion for alumina soluble at different temperatures (e.g. 1450C and 2350C (this
method applied at the Sangaredi mine – Guinea)
(3) Atomic absorption spectrometry (ICP)
(4) X-ray fluorescence spectrometry (XRF)
(5) Neutron activation analyses (Tatar method)
It is beyond doubt that the most reliable method is still the traditional chemical analysis. Among
the rapid analyses, both the ICP and XRF may satisfy the demand of the exploration but for this
purpose carefully prepared standards and calibration are needed to be applied and prepared
directly for the investigated deposit because the high mineralogical effects, including variations
in crystallinity may result in significant errors (G. BARDOSSY – G. J.J. ALEVA, 1990).
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In bauxite usually each 1m interval of drilling or pitting is analysed which is correct. In some
cases at the contacts of between the ore and overburden and bedrock sampling in 0.5.m interval
may be needed.
It is firmly believed by the author that, in general, too many superfluous analyses are made. No
five component analyses are needed in the detailed and mine development explorations for every
sample. The average titania and iron contents can be calculated from the averages obtained
from the preliminary explorations and they must be sufficient to calculate with their average.
What is important for the alumina industry is the exact determination of the total or available
alumina and the total or reactive silica contents in the detailed and mine development stages of
the exploration. For that reason the wide application of the Bayer bomb digestion method is
recommended in the detailed and mine development explorations more than it is now used all
over the world. It is also worth mentioning that the cost of a five component analyses more or
less equals the cost of a bomb digestion, but plenty of time can be spared by much lesser data
processing. Of course, there are several cases when the concentration of the other impurities such
as Corg, ΣS, and carbonates are also important in mining block units or even in daily
production which must be analysed regularly.
4. Mineralogy
It is a general rule, all over the world, that the mineralogical make up of the bauxites is much less
investigated than necessary. In many cases the mineralogical make up is known by several
composite samples or by representative samples only collected for technological purposes which
do not provide always adequate information for the alumina industry. It may happen that
bauxites of quasi same chemical compositions determined by traditional five component
analyses may be significantly different in their mineralogical make up: such as at the Worsley
mine where both the greenstone rocks and the granite have weathered to bauxite and the
difference of parent rock controls the gangue mineralogy rather than the alumina or reactive
silica level ( R.A. HINDE AND D.M. MARANTELLI, 1992). Mineralogy may be variable in karst
bauxite: mono - tri-hydrate, hematite - goethite ratios are varying between extreme values (both
laterally and vertically) in the same ore grade of the same ore body (KOMLÓSSY, GY. 1969). In
the Jamaican bauxite the mono - tri-hydrate ratio depends on the actual topographic level (HILL,
V. G. 1955).
An alumina refinery can be operated well if it is fed by bauxite which is, as much as
possible, steady both in its chemical and mineralogical composition. For that reason the
bauxite deposits must be explored adequately also from the mineralogical point of view.
It is obvious that less mineralogical tests are sufficient if the bauxite has a simple “homogenous”
mineralogy :
• alumina minerals are either in tri- or in mono-hydrates,
• iron minerals are mainly in hematite or the hematite/goethite ratio is more or less
constant,
• the alumina bound in iron minerals is negligible,
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• the silica bound in quartz and clay mineral(s) can be foreseen on the basis of
chemical analyses.
Even in these cases the mineralogy of bauxite deposit(s) must be thoroughly clarified. The
horizontal and vertical distribution of the main mineralogical components must be known. The
phenomena of the mineral individualism: the grade of crystallinity and regularity of the crystal
structure (size of crystals) along with their distribution must also be considered (G. BÁRDOSSY,
K. JÓNÁS, A. IMRE,.K. SOLYMÁR 1997)
In case of a large deposit (reserves >50 mil. tons) 10-20 whole profiles are recommended to be
analysed for each 1m interval. Thus one profile section would represent 2.5 – 5.0 mil. tons of
ore. The sampling profiles (bore holes, pits) must be horizontally evenly distributed. If the
deposit has been developed on different parent rocks it has also to be taken into consideration
and sampling made proportionally. In case of medium or small sized deposits more samples are
advised to take (one profile for each 1 – 2.5 mil. tons).
It may occur that a bauxite deposit has mono-hydrate rich lenses ( boehmite > 10%) inside the
tri-hydrate ore body representing significant and valuable tonnage. Provided selective mining is
economical, the “mono-bauxite” should be separately stored and sold on the market to feed a
high temperature plant (Sangaredi). In such a case there is no other solution but – for
establishing the mono-hydrate content - the regular bomb digestion analyses for soluble alumina
at different temperatures
When the mineralogical make up of the bauxite is even more complex and alumina and iron may
also be bound in chamosite and iron in pyrite and/or siderite, mineralogical tests (comprising
the whole industrial grade section) and recommended to be performed for each 2.0 – 2.5 mil.
tons of bauxite. Otherwise no reliable representative sample can be taken for technological tests.
The aim of the grade control is to provide data for making short term plans (shift, daily, weekly
and monthly basis) making possible extraction of uniform grade bauxite shipped to the plant.
Mining companies have to pay penalty if the grade drops below the contracted values, the
premium paid for better quality shipments hardly compensates for the penalty loss. For this
purpose tonnage, grade (and contaminants) have to be determined for each mining unit more
precisely than by the detailed exploration.
In order to avoid fluctuations in grade and contaminants, stockpiles for blending purposes are
set up for higher and lower grade products. Blending made from these stockpiles can
proportionally satisfy the demand of the plant. Operating a blending system increases the
mining cost about by 4% - 6% because of the increased capital expenditures for stockpile(s)
maintaining.
When bauxite mining is well prepared by mine development exploration and the ore body is
homogenous enough, no blending is needed. In this case the operation can be managed
according to the consumer’s demand directly by proportional extraction from different mining
faces.
24
In practice, in some open pits, when the overburden have been stripped off and the bauxite
prepared for mining, the ore is drilled in 25m x 25m or in 10m x 10m grid in each bench. In
several cases the variances may be so high that samples are necessary to be taken also from
the blast holes (say 6m x 6m). In open pits the bauxite is often extracted in benches varying
between 2m and 3m in thickness (depending on the total thickness of the ore to be mined out).
The depth of the grade control drilling is determined by the thickness of the benches and
samples are analysed for the whole thickness.
At the Trombetas mine (Brazil) channel samples ( 20cm x 10cm) were taken from both sides of
the walls of the formerly excavated stripes and bauxite recovery was also checked in laboratory.
If necessary the grade of bauxite production is to be checked continuously. Grade control of the
ore mining should be carried out on each shift based on the analyses of the ore discharged from
the haulage system. Sample cuts are taken regularly: and periodically from the conveyor belts
(e.g. in every 15 – 30 minutes) or from each truck and composite samples analysed for
(available) alumina and (reactive)silica. The results are reported to the geological or mining
department where adjustments are made to the mining programme for the following day(s) as
required (as at Worsley in Australia, Sangaredi, Kindia in Guinea, Accaribo in Surinam, Los
Pijiguaos in Venezuela, etc.).
There are several methods developed for resource estimate and reserve calculation. More and
more sophisticated procedures have been introduced during the past 20 years. Application of
computer aided geostatistical methods, geo-mathematical models, and krieging gave a
remarkable impetus to the development.
It is common in any bauxite deposit that the range of variances are different with different
parameters (see Paragraph 2.2.2.). In the case of karst bauxites, when the bedrock is highly
karstified, the variance is the greatest in thickness, the second in rank is the silica and the third is
the alumina.
In the case of laterite bauxites, in general, the variance in thickness is much less than that of the
other parameters in a distance of 50m -100m. It may occur that in a short distance the surface of
the bedrock (non-commercial grade bauxite) forms a very undulating surface in about ten meters
distance with an amplitude of 1-2 metres, see Photo 10. It makes the mining difficult and
results in significant mining loss or dilution or both, (e.g. Accaribo mine in Surinam, Kindia in
Guinea, etc.). In other cases the bedrock surface is relatively smooth such as in case of Deccan
bauxite deposits (India).
Photo 10.
25
Unfortunately the fact that the error in different parameters over the same distance may be
different. It is often not indicated in the reserve categorisation which is dedicated to express the
uncertainty of the exploration. It may happen that the reserves are explored in measured (B, or
proved category) for tonnage while for alumina and silica it is in only in indicated (C1, possible)
category. For solving this contradiction the fuzzy method was proposed recently by G. BÁRDOSSY
(2002) to be applied in the bauxite reserve calculation. As a matter of fact the method seems to
be appropriate to express the possible different uncertainty in the different basic parameters
(alumina, silica, thickness, etc).Fig. 20.
t= tonnage
t
applied Al
t= tonnage
Si
Compiled after G. BÁRDOSSY 2003
increasing uncertainty
Fig 20.
t = tonnage
Notes on above:
(1). This rule is absolutely obvious, nevertheless, the Author had to face many times that it had
not been followed and the computer was fed incorrect data. In case of a South American laterite
deposit about 3 % of total silica was revealed by drilling. Mining verified bauxite of some 5 %
of silica. The difference is too much to be due to dilution. Two absolute percent of silica in the
alumina plant of 1 mil. tpa set up for this deposit resulted in ten million USD surplus in expenses
per year. Consequently during the drilling some kind of “ore beneficiation” went on resulting
much better quality bauxite (probably very fine powder of kaolinite was flushed out). The bias
was decided to be eliminated by applying a complicated geo-mathematical model. The operating
mine was stopped and a new one opened for a better bauxite. It turned out that the new deposit
was not better either, because it had been drilled with the same method. In such cases not a
geo-mathematical model but application of a reliable drilling technique should have been
introduced.
(2.) Figure of the tonnage and grade of the bauxite may also depend on the method used in
calculation. It is shown in the Table 3.
26
Table 3
Reserve assessment comparison applying different methods in a test area
All methods used the same raw data of the detailed exploration. Current polygonal method was
accepted and applied when after the mine development explorations verified its correctness for
tonnage, however the bias was bigger (but acceptable) in grade. For grade the R. polygonal
method was proved to be perfect.
In many cases cut-off values – standards - are set up for reserve/resource calculation without
analysing their effect on the tonnage and grade of the deposit(s), ie. economical considerations
are neglected. Sometimes old standards are used established in the early 20th century in the
Soviet Union and never investigated how far it satisfies the interest of the economy. Such a
cut-off criteria was used also in the socialist countries called “silica modulus” (MSi). Criteria for
the industrial grade ore, according to this pattern is as follows:
The qualification of the bauxite has to express its value which has to be in harmony with the
processing cost of the alumina, that is the available alumina content (ABEA) which is the
amount of alumina extractable in the plant in case of low temperature procedure (ca 1450 C):
ABEA= Al2O3%total – (x) SiO2 reactive, in case of high temperature procedure ( > 2350 C)
Al2O3 % total – (x)2 SiO2 % total.
2
Value of (x) is determined by the actual technological conditions varying between 1 and 2.
27
6.2.2. Genetical and geochemical considerations: theoretical basis of the tonnage vs.
grade calculation.
Photo 1l.
Relative concentration of the alumina is going on up to a maximum rate permitted by the iron.
As the system can not get rid of the iron therefore the iron content of the parent rock restricts
within the weathered profile. The alumina accumulation: Al2O3 % + Fe2O3 % tends to be a quasi
constant value: 65%-67%, provided the free silica content is negligible. (theoretical Al2O3
content of the pure gibbsite is 66% ). The degree of the bauxitisation, as a consequence, is
limited by the iron content of the system. Laterite bauxite deposits, based on the degree of the
bauxitisation - which is manifested in their lithological and geochemical features – have been
grouped into three main types such as young, matured and overmatured deposits, see Fig. 21.
(G. KOMLÓSSY 1973, 1997). In all of these types vertical zoning is common with a zone of
gradual transition: the best quality bauxite is bordered by lower grade ore horizons both
upward and downward, making a selection possible by cutting off gradually the upper and lower
zones from the reserves. In older bauxite a thinner transition zone is typical.
28
Lateritisation - bauxitisation
iron-rich crust
ascendency max.ground water
table
zone of oscillation
Parent rock
Fig. 22.
G. KOMLÓSSY: 1976
The three main types of laterite bauxites are as follows
(a) Young soft (clayey) bauxite which is sandy, pseudo-fragmented, containing gibbsite
or gibbsitic nodules, sands, angular bauxite “fragments” in bauxitic clay: Mexico,
Bao Lok (Vietnam), Lichenya Plateau (Malawi), Trombetas (Brazil, etc). Lithification
has only been commenced. Geochemical features are:
- strong negative correlation between the Al and Si,
- strong positive correlation between the total and reactive Si,
- negative correlation between the Al and Fe may exist.
(b)Matured (hard, pisolotic, pseudo-brecciated) bauxite such as Ghandamardan,
Panchpatmali in India, Los Pijiguaos in Venezuela, etc.Geochemical features are::
29
- negative correlation between the Al and Si still exists, tightness of correlation is:
around 0.5 – 0.6,
- positive correlation between the reactive and non-reactive silica,
- strong negative correlation between the Al and Fe, tightness of this correlation is
>0.8
(c) Over-mature: characterised by white bauxite layers/lenses which consist almost
entirely of gibbsite: Sangaredi in Guinea, Betul – Goa, Deccan bauxites in India, Az
Zabirah in Saudi Arabia. See Photo 12 Geochemistry:
- the negative correlation between the Al and the Si is almost negligible. In the white
(Fe-poor) bauxite the correlation may even turn into a positive one because depletion
of the iron provokes relative enrichment of the both elements,
- the negative correlation between the Al and Fe is very strong.
Bauxitisation is completed in the nature when change in Al2O3%(abs.) is accompanied by no
more than 0.5% (abs.) change in SiO2.
Photo 12.
(2). Karst bauxite
The sandwich structure is typical here also, because during the culmination of the ore forming,
better quality bauxite accumulated on the karst surface where the bauxitisation might have
proceeded in situ. The result is the same as in the laterite sections, the geochemical structure of
the ore body permits cut off-s to be made at different levels.
In order to satisfy the demand of the permanently changing economic conditions the geologist
has to offer options for the decision makers to decide which part of the bauxite body should
be extracted, i.e. what type of bauxite should be regarded as industrial grade ore..
Let us investigate how the tonnage changes in function of grade in several bauxite deposits.
30
30000,00
20000,00
10000,00
0,00
>40% >42,5% >45% >47,5% >50%
55,00
50,00
45,00
40,00
>40% >42,5% >45% >47,5% >50%
20,00 reactive
15,00
non-reactive
10,00
5,00
0,00
>40% >42,5% >45% >47,5% >50%
TAl2O3 TSiO2
proposed to
extract
Fig. 25
source:Y. Lissov – V. Zmeev 1997
31
Figures of 23., 24., and 25. show that the reactive silica content does not drop significantly
by the increasing average alumina content.
6.2.4. Specific bauxite consumption and operating cost calculation (D. DONALDSON 2003)
(1) The usage of the bauxite can easily deduced from the available alumina content. First, the
overall recovery of the bauxite available alumina in a refinery will be close to 95 % and
the purity of the product close to 98.8 %.
(1) x (0.988 = dry tons bauxite)
Therefore: bauxite usage = (TAA) (0.95)ton product alumina
(1)(0.988)
For 36% TAA bauxite usage: (0.36)(0.95) = 2.89 t bx/t al.
Total available or recoverable alumina can be obtained by laboratory digest procedure. This
measures the amount of the alumina put into solution by attacking the bauxite with hot caustic
soda (an empirical test): consequently, other reactions have already occurred in the laboratory
digest, such as the reaction with silica. The laboratory result (TAA) is assumed to be the
available or recoverable alumina in the bauxite sample. Total chemical alumina (TCA) is the
actual aluminium metal content in the bauxite built in minerals such as Al oxi-hydroxides, Al
hydroxides, iron minerals (alumo-goethites), clay, and phosphates. This is the value used in
geological surveys. TAA can sometimes be estimated fairly close by subtracting the alumina in
the clay equivalent of TSiO2 or, perhaps a factor times this value if the quartz content is
significant.
Mono-hydrate bauxite may have a lower recovery (93% – 94 %) because the mono-hydrate
alumina may not be attacked by caustic soda as with tri-hydrate alumina.
The operating cost, excluding the bauxite supply price to the plant and the bauxite silica content,
will change only slightly with bauxite usage. A lower TAA will mean more bauxite to be
conveyed and ground and more mud will be washed and pumped to disposal. Process investment
cost is an other question.
(2) Attacked silica (ASiO2) is the silica that is attacked by caustic in the digester. 100% of
the clay silica or reactive silica (RSiO2) will be attacked. The other silica in the bauxite is
quartz. In a tri-hydrate digest (e.g. < 1600C digest) there is essentially O% attack of
quartz silica. In a mono-hydrate digest (~ 2500C digest) the amount of the quartz will be
depend on the time the bauxite slurry is above 1600C (the higher temperature the higher
the rate of attack) and on the particle size of the quartz (the smaller particle the higher the
rate). However, for estimating purposes 50 % - 60% quartz is attacked in high
temperature digest.
Attacked silica (i.e. clay silica + attacked quartz silica) consumes about 1.18 tons of caustic
soda: Therefore:
Bauxite usage (%RSiO2 + % Quartz attack x % QSiO2 ) 1.18
For total caustic soda consumption about 0.025 kg must be added for other process losses per ton
of alumina product. For actual caustic (NaOH) to achieve caustic soda must be multiplied by
0.755 (NaOH/Na2CO3 = 80/106=0.755).
6.2.5. Specific bauxite consumption and caustic soda price in the function of bauxite
quality
Following the principles given above, the results for the Deccan bauxite are summarised in
Figs. 26. and 27. The difference in silica concentration between the highest and the lowest
bauxite grades is 0.4 abs. %, but because of the high caustic soda price this difference results in
about 5 USD/ton alumina. The profit can also be gained by increasing available alumina
content, that is, from the decreasing specific bauxite consumption which is much as 2 USD/ton
alumina. In our concept the increasing mining costs are compensated by the lower transport cost.
50 price/ton of
2,57 40 alumina
2,6
2,51
2,47 30 bauxite price/ton
2,5 2,43
20 of alumina
2,4 2,35 tbx/t alu
10
2,3
0
2,2
%
4
>3
>3
>4
>4
>4
Fig 26 Fig 27
In order to demonstrate the expected operating costs of the alumina - in the function of the
bauxite grade - an “Iso-operating cost contour map” was plotted for a Suriname bauxite deposit,
in the early nineties, making it possible to follow the changing economic conditions in the
mining. see Fig. 28. Such a map may be very useful in mine production management.
Iso-operating cost
contour map
33
Cut off Al2O3 % profit on quality life time of mine total extra profit
million USD year in million USD
>36 0 40.1 0
>38 14.04 39.4 550
>40 22.92 37.6 861
>42 29.60 35.0 1.036
>44 46.68 31.0 1.447
Calculating bauxite reserves higher than > 44% of Al2O3 the reserves drop in tonnage in such a
measure that the total revenue decreases by 1,447 million USD and quantity drop from 80
million to 59 million tons of reserves 3.
In consequence:
• the best grade bauxite offers the maximum profit, provided sufficient bauxite is available, if
not
• exploration of new deposits (provided the tonnage does not meet the demand of the plant)
should be shared in priority, bauxite exploration cost is negligible (0.0725 %) when
compared with alumina production cost (see Paragraph 2.1.4).
3
In this figure two items are not taken into account, namely, the increasing mining cost/ton of bauxite from the
higher stripping ratio which increases from 0.7 to 1.17 and transport cost which drops from US 40 million/a to US
37 million/a.
34
In some cases the possibility of discovering new deposits is limited. When a given quantity of
resources must be economised the following concept is proposed ( B. FODOR., 1999):
Fig. 29.
6.2.8. Economic block modelling
When the concept of the “industrial grade ore” has been established and reserve calculation
made applying inverse distant square method, the following main parameters are recommended
to calculate for each mining block unit - in order to evaluate the bauxite pit limits with
changing economic factors - as it was introduced for a Suriname deposit:
• Available alumina content (diluted) of the block,
• Reactive silica content (diluted) of the block,
• Bauxite tonnage of the block,
• Overburden to be stripped to expose the industrial grade ore,
• Cost of stripping, blasting and haulage of the block,
35
• Cost of overhead (fixed cost) must be borne from the revenue of the block,
• Refining cost of the block: caustic soda and energy prices,
• The unit price (revenue) provided by the refinery
.
7. Summary
Typical Exploration Programme
Flow sheet of an exploration program
proposed for a Deccan bauxite occurrences
Landsat interpretation
(DEM, TM) checking their possible
application
(+) (-)
(+) ( -)
Reconnaissance
sampling of escarpment
using portable auger drilling at
reference points of plateaux
( +) ( -)
Application for
exploration
Licence(s)
36
First selection
based on: potential, accessibility,
infrastructure,
B Seconddistance, mineability
Stage: Exploration
B Second Stage: Exploration:
(of the deposits identified and selected at the end of the First Stage)
(1)Drilling/pitting in
400 m x 400m grid
(2) Beneficiation test:
determination of method, technology
min. grain size and recovery
(3) Characteristic sample:
alumina technology, establishment of the
INDUSTRIAL GRADE ORE
(4) Resource estimate:
(inferred and indicated categories)
(5). Second selection:
priorities given to deposits in the function
of grade, tonnage and transport distance
Deposits of second
Deposits of first rank
rank:
(1) Infill drilling/pitting
(125m x 100m) for further exploration
(2) Beneficiation test (spare resources)
(3) Reserve calculation
(measured – inferred category)
(4) Third Selection:
Deposit ranked into order of Spare reserves
profit expected to be attained for further possible
in the refinery utilisation
(5)Representative sample
Conclusions
(1) There is no use to spare money on the geological activities. Fast decisions – which may
be essential in the economy – can only be made when they had reliably been prepared
by geological reconnaissance, exploration and data evaluation.
(2) Landsat interpretation offers an excellent tool in finding new deposits and establishing
the bauxite potential in a large area.
(3) Geological (mining) risks can considerably reduced by correctly made exploration and
data evaluation, - For this reason, the best available drilling techniques must be
applied which provide the most reliable data.
(4) In the data evaluation (reserve/resource calculation) consistent data must be processed,
drilling/pitting grid should be established accordingly.
(5) Exploration techniques, drilling/pitting grid, reserve calculation and resource estimate
must be fitted to the nature of the deposits. Even the best experiences, obtained at a
bauxite occurrence, can be only carefully applied on an other (unknown) one. The
different nature of the deposits (geology, petrography, mineralogy, etc) determines the
exploration techniques and strategy.
(6) Tonnage vs. grade reserve calculation provides economical options by which the
maximum profit can be established.
(7) The decision makers of the bauxite-alumina industry have to utilise the geological
knowledge in a more extended manner than generally it has been done so far, because
it may improve the economy of the bauxite-alumina industry.
(8) More effective contribution to the economy of the bauxite alumina-industry belongs to
a geologist’s responsibility.
38
Selected references
A Geologist’s Responsibilities
in the
Aluminium Industry
G. Komlóssy
Budapest – Hungary
2006