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Chem 26.1 Experiment 8 Atq Questions, Data Sheet

This document describes an experiment to quantify dissolved oxygen content in water samples using Winkler redox titration. The experiment involves standardizing a sodium sulfite solution and then titrating water samples with the standardized solution. Key steps include adding reagents to the samples in a specific sequence to produce iodine from oxygen, which is then titrated with the sodium sulfite. Calculations will determine the dissolved oxygen content and classification of water quality based on these results.

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John Christian Mapalo
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292 views3 pages

Chem 26.1 Experiment 8 Atq Questions, Data Sheet

This document describes an experiment to quantify dissolved oxygen content in water samples using Winkler redox titration. The experiment involves standardizing a sodium sulfite solution and then titrating water samples with the standardized solution. Key steps include adding reagents to the samples in a specific sequence to produce iodine from oxygen, which is then titrated with the sodium sulfite. Calculations will determine the dissolved oxygen content and classification of water quality based on these results.

Uploaded by

John Christian Mapalo
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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Download as PDF, TXT or read online on Scribd
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EXPERIMENT 8

QUANTITATIVE DETERMINATION OF DISSOLVED OXYGEN


CONTENT BY WINKLER REDOX TITRATION

CALCULATIONS (35 pts)


Determine the:
1. molarity of the standard Na2S2O3 solution
2. ppm O2 of the water samples (mg/L) as well as its classification.
3. Relative Standard Deviation, and Confidence Interval (95% level) for the ppm O2 quantified within the
group/ class.

GUIDE FOR DISCUSSION (65 pts)


1. Give the pertinent chemical equations and stoichiometry in the standardization of Na2S2O3. (10 pts)
2. Explain the purpose of the addition of H2SO4 and excess KI during standardization and why KI was added
before the acid. (10 pts)
3. Explain stepwise how I3- was produced from the dissolved O2 in the water sample. Explain briefly why the
reagents are added in a definite sequence. (10 pts)
4. Give the reason why starch was used as the indicator in this analysis and why it was added towards the
end of the titration. (5 pts)
5. How is this analysis (an iodometric process) different from an iodimetric one? (5 pts)
6. From the calculated ppm O2, identify the degree of water pollution and ability of the water sample source
to sustain aquatic life. (5 pts)
7. Predict the effect, if any, of each of the following on the DO oxygen content obtained:
a. The water sample is made to stand overnight before analysis. (5 pts)
b. MnSO4 is added and the solution made to stand for an hour before the alkaline KI solution is added.
(5 pts)
8. What are the possible sources of errors and their effect on the calculated parameters? Rationalize. (10 pts)

Chem 26.1: Introduction to Quantitative Chemical Analysis Laboratory 2018


Name:

Co-Worker:
Date Performed:
INSTRUCTOR’S COPY

EXPERIMENT 8
QUANTITATIVE DETERMINATION OF DISSOLVED OXYGEN
CONTENT BY WINKLER REDOX TITRATION

Standardization of Na2S2O3 Solution


Primary standard used:
Formula mass of 1° standard:
% Purity of 1° standard:
Weight of standard, g:
Volume of standard solution:

Trial 1 2 3
Volume of KIO3 Standard, mL
Final volume of Na2S2O3, mL
Initial volume of Na2S2O3, mL
Net volume of Na2S2O3, mL

Sample Analysis
Location of sampling:
Total volume of sample:

Trial 1 2 3
Final volume of Na2S2O3, mL
Initial volume of Na2S2O3, mL
Net volume of Na2S2O3, mL

Chem 26.1: Introduction to Quantitative Chemical Analysis Laboratory 2018


Name:
Co-Worker:
Date Performed:
STUDENT’S COPY

EXPERIMENT 8
QUANTITATIVE DETERMINATION OF DISSOLVED OXYGEN
CONTENT BY WINKLER REDOX TITRATION

Standardization of Na2S2O3 Solution


Primary standard used:
Formula mass of 1° standard:
% Purity of 1° standard:
Weight of standard, g:
Volume of standard solution:

Trial 1 2 3
Volume of KIO3 Standard, mL
Final volume of Na2S2O3, mL
Initial volume of Na2S2O3, mL
Net volume of Na2S2O3, mL
M Na2S2O3
Average M Na2S2O3

Sample Analysis
Location of sampling:
Total volume of sample:

Trial 1 2 3
Final volume of Na2S2O3, mL
Initial volume of Na2S2O3, mL
Net volume of Na2S2O3, mL
DO content, ppm O2
Average DO content, ppm O2
RSD
Confidence interval ±

Instructor’s Signature: Date:

Chem 26.1: Introduction to Quantitative Chemical Analysis Laboratory 2018

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