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Electrophilic Species in Eas

1) The document discusses electrophilic species that are involved in electrophilic aromatic substitution reactions, including the nitronium ion and the acylium ion. 2) It examines the effects of different substituents on benzene, including both activating and deactivating groups, and whether they are ortho/para or meta directing. 3) The document also mentions synthetic strategies that can be used with aromatic compounds.

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Mihir Jain
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33 views8 pages

Electrophilic Species in Eas

1) The document discusses electrophilic species that are involved in electrophilic aromatic substitution reactions, including the nitronium ion and the acylium ion. 2) It examines the effects of different substituents on benzene, including both activating and deactivating groups, and whether they are ortho/para or meta directing. 3) The document also mentions synthetic strategies that can be used with aromatic compounds.

Uploaded by

Mihir Jain
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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Download as PDF, TXT or read online on Scribd
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ELECTROPHILIC SPECIES IN EAS

+
Nitronium O=N=O

Benzene
+

Acylium CH3C=O

I. Strongly activating, ortho/para directing (LP electrons)


(eg. -OMe, Inductive and Resonance effects)
NH2 OMe
Aniline Anisole

II. Weakly activating, ortho/para directing (eg. -CH3 inductive)

III. Weakly deactivating, ortho/para directing


(eg. -Cl, Inductive/Resonance)

IV. Deactivating, meta directing (eg. -NO2, inductive)


NO2
O2N NO2

SYNTHETIC STRATEGIES WITH AROMATIC COMPOUNDS

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