Biomass-Gasifier Gas Turbine
Biomass-Gasifier Gas Turbine
Introduction
Biomass energy substituted for fossil fuels could help reduce processes. One potentially large market for BIG/GT units is
carbon dioxide emissions that are contributing to the green- in the sugar cane processing industries, where bagasse (residues
house warming of the earth, since biomass absorbs the same left after crushing the cane) and barbojo (the tops and leaves
amount of carbon in growing as it releases when consumed as of the cane plant) could be used as fuel. The 1987 global level
fuel. A major challenge to using biomass for energy is to of cane production could support 95 GW of BIG/GT cogen-
identify conversion technologies for providing more conven- eration capacity, which would permit large quantities of elec-
ient energy forms, like electricity or liquid fuels, at competitive tricity in excess of on-site process needs to be produced
costs and at the modest scales dictated by the low efficiency competitively (Ogden et al., 1990). The pulp and paper industry
of photosynthesis. Power generation and cogeneration systems represents another possible near-term application of BIG/GT
using pressurized, air-blown biomass gasifiers integrated with technology where processing by-products would be the fuel.
power cycles involving aeroderivative gas turbines are one This paper assesses the performance, cost, and prospects for
promising set of technologies for "modernizing" bioenergy. commercialization of BIG/GT technologies for kraft pulp mills
These technologies have the potential for high efficiency and and explores the potential for cogenerating electricity in excess
low unit capital cost at modest scale (Larson et al., 1989; of on-site needs.
Larson and Williams, 1990).
Biomass-gasifier/gas turbine (BIG/GT) systems might even-
tually be fueled by biomass grown on dedictated energy plan- BIG/GT Technology
tations (Hall et al., 1990), but initial applications are likely to Two BIG/GT technologies are described here. One would
be where biomass fuels already exist as residues of industrial use solid fuels (e.g., wood chips, wood waste, crop residues,
etc.); the other, black liquor from kraft pulp production. Steam-
Contributed by the International Gas Turbine Institute and presented at the injected gas turbines (STIGs) and intercooled steam-injected
36th International Gas Turbine and Aeroengine Congress and Exposition, Or- gas turbines (ISTIGs) are alternative aeroderivative turbine
lando, Florida, June 3-6, 1991. Manuscript received at ASME Headquarters
March 4, 1991. Paper No. 91-GT-280. Associate Technical Editor: L. A. Riek- cycles that are considered (Larson and Williams, 1987; Wil-
ert. liams and Larson, 1989). Gas-turbine/steam-turbine combined
Journal of Engineering for Gas Turbines and Power OCTOBER 1992, Vol. 114 / 665
HEAT
RECOVERY
STEAM
GENERATORS
2000
BOOST
COMP.
— G
STEAh INJECTED
GAS TURBINE 100 200 300
Power Output, MWe
Fig. 1 Biomass-gasifier/steam-injected gas turbine cycle Fig. 2 Cost comparison (in 1988 $) of coal-gasifier/gas turbine power
plants (Pitrolo and Graham, 1990). The upper curve represents technol-
ogy like the Cool Water commercial demonstration plant that uses a
Texaco entrained-bed gasifier, cold-gas cleanup, and a combined cycle.
The lower curve represents systems using air-blown fixed-bed gasifi-
cycles based on advanced aeroderivative turbines are also po- cation with hot gas clean up and either combined cycles or steam-
tential candidates. 1 injected gas turbines. The points on this curve are calculated costs for
specific plants using integral numbers of gasifiers and commercial gas
Solid-Biomass Gasifier/Gas Turbines. A biomass-gasi- turbines. See also Synthetic Fuels Associates (1983) for additional dis-
cussion of effects of scale on the cost of Cool Water technology.
fier/steam-injected gas turbine (BIG/STIG) fueled with solid
biomass (Fig. 1) would be similar in many respects to the more
familiar coal-gasifier/gas turbine (IGCC) technology com-
mercially demonstrated at Cool Water (Clark, 1988). Impor- make alternative biomass feedstocks acceptable for this gasifier
tant differences would include the use of air-blown instead of and the suitability of this design for biomass/gas turbine ap-
oxygen-blown gasification and a steam-injected gas turbine plications.
instead of a combined cycle. The sensitivity to scale of oxygen Fluidized-bed gasifiers have higher throughput capabilities
plants and conventional combined cycles makes the Cool Water and greater fuel flexibility than fixed-beds, including the ability
technology uneconomic for relatively smaller applications (Fig. to handle low-density feedstocks like undensified crop residues
2). Also, while the gas exiting the gasifier must be cleaned, so or sawdust (Larson et al., 1989). A major drawback of flu-
doing would not require developing advanced cleanup tech- idized-beds is the higher level of particulates in the raw gas,
nologies (as required for hot sulfur removal from coal), because which makes gas cleanup more challenging. Large-scale at-
most biomass contains negligible sulfur. Furthermore, biomass mospheric-pressure fluidized-bed gasifiers are commerically
is more reactive than coal and thus easier to gasify (Fig. 3), operating with biomass fuels to produce boiler fuel, and a
so that fixed-bed and fluidized-bed gasifiers, which operate at significant amount of work was also done in the late 1970s
lower average temperatures than entrained beds such as the and early 1980s on pressurized biomass-fueled units designed
one at Cool Water, can provide essentially complete carbon for use in methanol production.
conversion and high gasification efficiency (Larson et al., 1989). Perhaps the most important development issue for BIG/GT
technology relating to gasifier design is gas cleanup, specifically
Gasifier Design Options. The fixed-bed gasifier is attrac- removal of alkali compounds (formed primarily from potas-
tive for relatively dense fuels (wood chips, hog fuel, or densified sium and sodium in the feedstock) and particulates at elevated
biomass) because of its simplicity and high efficiency (Larson temperatures. Estimates of the tolerable concentration of alkali
et al., 1989). Among several fixed-bed units on which there vapors in fuel gas for gas turbine applications are very low—
has been development work during the last decade, the Lurgi 100 to 200 parts per billion (Horner, 1985; Scandrett and Clift,
dry-ash gasifier appears to be a good candidate for biomass 1984). The extent of alkali production and required removal
applications (Corman, 1987). Its use in coal-IGCC applications from biomass gas has not been measured. Based on coal-related
has been extensively evaluated (Corman, 1986). Limited pilot- work, however, the gasifier exit temperature appears to be the
scale testing has been carried out by the General Electric Com- most important controlling parameter. At fixed-bed gasifier
pany using biomass pellets and RDF/coal briquettes (Larson exit temperatures (500-600 °C) most of the alkalis appears to
et al., 1989). More extensive testing is required to determine condense on particulates and can thus be controlled by con-
the degree of fuel processing (e.g., densification) needed to trolling particulates. Particulate cleanup with fixed-bed gasi-
fiers appears possible using cyclones, based on data for coal
(Corman and Horner, 1986). Alkali that manages to reach the
Some advanced aeroderivative turbines with low expected costs will be better combustor would be in a chemically bound form and would
suited to combined cycles than to steam injection. For example, the LM-6000, not vaporize in short residence-time combustors (Corman,
which will enter commercial service in 1992, will produce 42.4 MW at a simple-
cycle efficiency greater than 36 percent (HHV basis, natural gas fuel) and will 1989). With fluidized-bed gasifiers (800-900°C exit tempera-
have an estimated gen-set equipment price of $230/kW to $250/kW (de Biasi, tures), some cooling of the gas would be required to condense
1990), much less than the $400/kW price for the most efficient (33 percent) alkalis. Also, more efficient particle removal technology would
aeroderivative gas turbine available today (Jersey Central, 1989). An LM-6000 be needed, e.g., barrier filters. Demonstration of a significant
based combined cycle would produce 53.3 MW at an expected efficiency of
some 48 percent (HHV). Because the gas turbine involved in this combined cycle new design for ceramic barrier filters, intended in part to over-
would be cheap and because the steam turbine would provide only 1/5 of the come the problems that traditional candle filters have in with-
output (compared to 1/3 for a combined cycle based on the use of industrial standing thermal and mechanical shock, is ongoing in Finland
gas turbines), the LM6000 combined cycle may prove competitive with much (Isaksson, 1989). Other designs are under development in the
larger combined cycles based on industrial turbines. See Stambler (1990) for
discussion of other advanced aeroderivative engines. US (Pitrolo and Graham, 1990).
§„.,
0-8
' V. •
fil •D/ /I
*/ //
7 111
a.)
J:/ j
(A) " °- 6 ^"^
(II)
S
3
0.5
- f I 1 I
° 0.4 . CELLULOSE
'a/ /
ON
5 °--i'
0.2
Fig. 3 Comparison of gasification characteristics of biomass and coal (Larson et al., 1989): (a) weight loss
as a function of pyrolysis temperature for coal and cellulose (a major component of biomass); (b) gasification
rates in steam of chars from different feedstocks
Table 1 Performance and capital cost estimates of biomass power generating systems 3
System Performance and Cost. Table 1 gives estimates of ogies offer flexibility in handling variable process steam de-
the performance of B I G / S T I G a n d B I G / I S T I G systems in m a n d s ( L a r s o n a n d W i l l i a m s , 1987). O p e r a t e d in the
cogeneration and power-only modes of operation assuming cogeneration m o d e , the gas turbine systems would produce
biomass fuel input with 15 percent moisture content (mc). 2 much less steam (as a fraction of fuel input) than the C E S T .
Gasifiers for B I G / G T systems require fuel with less than about Operated in either cogeneration or power-only modes, the gas
25 percent mc to produce a gas of acceptable quality for gas turbine is a more efficient electricity producer.
turbines. Gas turbine systems would also have capital cost advantages
Table 1 also compares the performance of a B I G / S T I G and over C E S T systems (Table 1). A 53-MW B I G / S T I G based on
a double-extraction condensing steam turbine (CEST) system the LM-5000 gas turbine would have a total installed cost of
(a commercially available option for biomass cogeneration), $1150/kW (or $ 1 2 5 0 / k W if costs for drying equipment are
taking account of the energy losses associated with drying the included). 3 The B I G / G T cost estimates are based on detailed
fuel for the B I G / S T I G . Both C E S T and B I G / S T I G technol- cost estimates for similar systems using coal as fuel, from which
3
Unless indicated otherwise, higher heating values are used for fuels through- Unless indicated otherwise, all costs in this paper have been converted to
out this paper. first-quarter 1990 dollars using the US GNP deflator.
Journal of Engineering for Gas Turbines and Power OCTOBER 1992, Vol. 114 / 667
Energy per
Mass Energy tonne pulp°
flow flow Hard Soft
(kg/hr) (GJ/hr) (GJ/tp) (GJ/tp)
Inputs
Black liquor dry solids' 909 13.93 19.9 23.3
Outputs
Fuel gas (10.6 MJ/Nm3 HHV) 518.5 7.884 11.2 13.16
Export steam (42 bar, sat.) 950 2.557 3.65 4.27
Carbon recoverable 15 0.516 0.74 0.86
Losses
Flue at stack 3171 1.586 2.27 2.65
Hot salts discharge 392 0.265 0.378 0.44
Process gas to scrubber 1222 0.925 1.32 1.54
Heat loss from gasifier 0.193 0.276 0.32
Journal of Engineering for Gas Turbines and Power OCTOBER 1992, Vol. 114 / 669
Steam Steam
@ 13 bar @ 4.4 bar Total Steam Electricity
End Use OVrir) (GJ/tp) (t/hr) (GJ/tp) (t/hr) (GJ/tp) (kWh/tp)
(a) Based on measurements from a mill in the Southeastern region of the US producing 1000
tonnes of air-dried pulp per day. The mill was started up in 1981. The data here are for
typical summer operation. The powerhouse requires approximately an additional 24% steam
and 19% electricity over the totals shown in this table.
(b) Consists of 35.3 kWh/tp, 117.1 kWh/tp, and 0.96 kWh/tp for stock preparation, dryer, and
finishing & shipping, respectively.
(c) Consists of 43.2 kWh/tp and 102.7 kWh/tp for digester and washing/screening, respectively.
(d) Consists of 10.1 kWh/tp and 63.4 kWh/tp for chemical preparation and oxygen supply to the
delignification stage, respectively.
(e) Consists of 41.5 kWh/tp and 47.3 kWh/tp to the bleach plant and the oxygen delignification
stage, respectively.
(f) Consists of 25 kWh/tp, 15.8 kWh/tp, 24.7 kWh/tp, 1.92 kWh/tp, and 14.1 kWh/tp to wood
preparation, water supply, air supply, odor control, and miscellaneous, respectively.
Table 5 Energy use (net of powerhouse) at Swedish bleached kraft pulp 3000
mills 3
(a) Quantities are expressed per air-dried tonne of pulp. For 1973,
the average Swedish mill (Jonsson et al., 1977). For 1980, the most
efficient Swedish mill; for 1984, representing the most efficient
Swedish mill; and for 1990, the technically and economically •Si 1000
feasible level of demand in a new Swedish mill (Alsefelt, 1990). J-
(a) From (Waddell et al., 1989). The Southeastern region of the US includes the states of Florida, Georgia,
North and South Carolina, and Virginia.
(b) Growing stock is defined as the main stem of live trees on timberland, between a 1-ft. (30.5 cm)
stump and 4-inch (10.2 cm) diameter top (of central stem) excluding bark, or to the point where the
central stem breaks into limbs. Roundwood from growing stock includes logs, bolts, and other round
timber generated from harvesting trees for industrial or consumer use. Logging residues include downed
and dead growing stock left on the ground after harvest. Other removals refer to unutilized wood from
cut or otherwise killed growing stock during cultural operations (e.g., from precommercial thinning), or
from timberland clearing.
(c) Roundwood "other sources" include salvable dead trees, rough and rotton cull trees, noncommercial
tree species, trees less than 5-inches (12.7 cm) diameter at breast height, tops, and roundwood harvested
from non-forest land (e.g., fence rows). Logging residues include wood other than growing stock left
on the ground after harvest that is sound enough to chip, including dead and downed cull tress and tops
to a 4-inch (10.2 cm) diameter (measured without bark) and excluding stumps and limbs. Other removals
include wood other than growing stock left on the ground after cultural operations (e.g., precommercial
thinning), or timberland clearing that is sound enough to chip (including dead and downed cull trees
and tops to a 4-inch (10.2 cm) diameter—excluding bark) and excluding stumps and limbs.
(d) Estimates based on (Tansey, 1990), assuming the same specific density for residues and roundwood
(38 lb/ft3 (609 kg/m3) for bone-dry wood). The first two numbers in this columns are weighted averages
for residues from the harvest of sawtimber and poletimber trees for pulpwood, assuming that 30% of
pulpwood comes from sawtimber and 70% from poletimber trees. The disaggregated residue ratios for
growing stock are 0.062 t/t (softwood) and 0.220 t/t (hardwood) for sawtimber trees and 0.007 t/t
(softwood) and 0.068 t/t (hardwood) for poletimber trees. [Sawtimber trees are those larger than 11
inches (27.9 cm) in diameter at breast height (dbh) for softwood and larger than 13 inches (33.0 cm)
dbh for hardwood. Poletimber trees are 5 to 10.9 inches (12.7 to 27.7 cm) dbh for softwood and 5 to
12.9 inches (12.7 to 32.8 cm) dbh for hardwood.] For "other sources," the residue ratios are assumed
to be the same as the average ratios calculated from the first three columns of this table. The last three
numbers in the column are weighted according to the percentage of pulpwood produced.
(e) Calculated assuming that 2.8 dry tonnes of pulpwood are used to produce one tonne of kraft pulp.
This is the average 1983 value for US sulphate pulp mills (American Pulpwood Association, 1989).
25 percent savings in electricity use would be cost-effective," considered in the analysis here, since pulp producers could
an estimate consistent with others that have been made (Larson reasonably be expected to be able to acquire these residues,
and Nilsson, 1991), which would reduce demand from 656 to but not necessarily the others.
492 kWh/tp. Reduced on-site electricity demand would permit It may be entirely feasible to remove all the residues in the
the BIG/GT systems to produce even greater excess electricity Southeastern US without damage to long-term soil productivity
that could be marketed off-site, e.g., sold to the local utility. (Larson, 1990), but local effects of residue removal must be
well understood before beginning residue use for power. In
Forest Residue Use. The exportable electricity production the harvest of coniferous trees today, about 3/4 of the above-
from the hypothetical mill could be increased further if cur- ground biomass is typically removed as merchantable wood,
rently unutilized forest residues, produced during commercial containing 40 to 50 percent of the tree's above-ground nitrogen,
harvest of forests, were used at the mill. Residues, as defined phosphorus, potassium, calcium, and magnesium (Freedman
here, exclude roots, stumps, branches, needles and leaves. The etal., 1981). Some additional nutrients would be removed with
volume of forest residues currently produced in the South- residue use, but may not necessarily result in excessive nutrient
eastern US is about 1/3 the volume of harvested roundwood depletion (Carlisle and Methven, 1979) or degradation of soil
(Table 6). Some 0.42 tonnes of currently unutilized residues organic matter status. Knowing the nutrient balance alone
(equivalent to 8 GJ in energy terms) are associated with each appears insufficient to predict the effects of residue removal
tonne of kraft pulp produced. Additional residues equivalent on subsequent soil productivity, because of complex, site-spe-
to 21 GJ/tp are produced in forest-industry operations other cific climatologic, geologic, hydrologic, and biological con-
than pulpwood production. Only the 8 GJ/tp of residues are siderations (Carlisle and Methven, 1979; Norton, 1976; Mann
et al., 1988). It is clear, however, that forest productivity over-
all can be raised substantially through improved forest man-
11
agement and advanced genetic manipulations (Farnum et al.,
This estimate is based on a 3-week on-site audit of the existing electrical 1983; Wells and Jorgensen, 1978; Linder, 1989; Davey, 1989).
system at the mill. The potential savings would come largely from trimming Residue removal for power generation might be made an in-
pump impellers to reduce inefficiencies due to oversizing and installation of
variable speed drives on large pumps and fans. tegral consideration of such developments. Modifications in
Journal of Engineering for Gas Turbines and Power OCTOBER 1992, Vol. 114 / 671
Private Electricity
Fuels and Utility Ownership b Ownership' Sales Revenues
Cogeneration (Busbar Cost, cents per kWh) (Internal rate (GWh/ @ $0.05c/kWh
Technologies" Capital" O&M'! Fuel r TOTAL of return) year) ($/tp)
Black liquor
+ hog fuel
CEST 7.06 0.72 0.0 7.8 2.8 113 16
BIG/STIG 1.93 0.72 0.56 3.2 18.7 417 60
BIG/ISTIG 1.56 0.60 0.43 2.6 25.1 . 546 78
+ Forest residues
(low-cost case)
CEST 3.83 0.72 2.00 6.6 2.7 275 39
BIG/STIG 1.63 0.72 1.53 3.9 16.1 683 97
BIG/ISTIG 1.37 0.60 1.20 3.2 23.0 866 124
(high-cost case)
CEST 3.83 0.72 3.00 7.6 neg. 275 39
BIG/STIG 1.63 0.72 1.92 4.3 13.5 683 97
BIG/ISTIG 1.37 0.60 1.51 3.5 20.6 866 124
(a) Steam demands met by the cogeneration systems are 9.6 GJ/tp for CEST and BIG/STIG and 8.2
GJ/tp for BIG/ISTIG. Electricity demand is 492 kWh/tp in all cases. Typical annual operating hours
for a large pulping operation are assumed (8400 hours/yr).
(b) Assuming a 6.1% annual discount rate, an insurance charge equal to 0.5% of the initial capital cost
per year and a 30-year life. With property and corporate taxes and existing tax preferences for renewable
resource generating plants, the capital recovery factor (CRF) is 0.101 (Technology Evaluation Section,
1986).
(c) Real (inflation-corrected) internal rate of return before taxes, assuming a 25-year life, an insurance
charge equal to 0.5% of the initial capital cost per year, and electricity revenues of 5 cents per kWh.
(d) Separate gasifier/gas-turbine units are assumed for black liquor and solid feedstocks. Also, a capital
cost credit (equivalent to the cost of a Tomlinson recovery boiler) is assumed since the gasification system
would also be serving the mill's chemical recovery requirements (see footnote 8). The capital cost for
drying equipment needed with the BIG/GT units is included in the fuel cost (see footnote 12). In estimating
the CEST capital cost, use of a single steam turbine is assumed, and a credit is taken equal to the cost
of a Tomlinson recovery boiler.
(e) The O&M costs for the BIG/ISTIG are based on (Williams, 1989). BIG/STIG O&M costs are scaled
from the ISTIG number by the ratio of STIG to ISTIG efficiency. The CEST O&M costs are assumed
to be the same as for BIG/STIG.
(f) Fuel costs for CEST are assumed zero for hog fuel and black liquor. For BIG/STIG and BIG/ISTIG,
$1/GJ is charged for hog fuel for drying (see footnote 12) and other pre-gasification handling. No charge
for black liquor. The low and high forest-residue costs are assumed to be S3/GJ and $4/GJ charged to
the gas turbine systems, respectively. CEST charges are $2/GJ and S3/GJ. The lower costs for CEST
account for less required pre-processing (e.g., drying).
Table 8 Global potential for production of electricity in excess of on-site needs with BIG/ISTIG cogeneration
technology in the kraft pulp industry
1988 2020
Chemical Potential Utility fossil- Projected Potential
pulp electricity fuel electricity pulp electricity
production" from pulph generation' production* from pulph
Region (106 t/yr) (TWh/yr) (TWh/yr) s
(10 tp/yr) (TWh/yr)
Industrialized 95.8 238 5,231 204.6 507
N. America 57.8 143 2,106 105.1 262
USSR 7.1 18 1,181 34.7 86
W. Europe 19.5 48 954 30.4 75
Japan 7.9 19 470 19.0 48
Oceania 0.93 3 116 11.2 27
E. Europe 2.7 7 404 3.7 9
Developing 8.8 23 1,432 68.6 169
Latin Am. 5.6 14 216 35.4 88
Asia 2.5 7 1,021 24.0 59
Africa 0.67 2 194 9.2 22
World 104.7 261 6,662 273.1 676
Journal of Engineering for Gas Turbines and Power OCTOBER 1992, Vol. 114/673
This volume presents the latest technology in the industrial power area, including papers on plant
operations and improvement, environmental technology and regulations, and cogeneration.
To order write ASME Order Department, 22 Law Drive, Box 2300, Fairfield, NJ 07007-2300
or call 800-THE-ASME (843-2763) or fax 201-882-1717.
Journal of Engineering for Gas Turbines and Power OCTOBER 1992, Vol. 114/675