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DPP Physical Chemistry

Thermodynamics

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117 views7 pages

DPP Physical Chemistry

Thermodynamics

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subesingh
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© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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HY./INO. CHEMISTRY, va Resonence Educating for better tomorrow TARGET : JEE (Main + Advanced) 2017 Course : VIJETA (JP) 1. Course of the week as per plan : ATf, Osmotic Pressure. 2 Course covered till previous week : RLVP, ATD. 3. Target of the current week : ATf, Osmotic Pressure. 4. DPP Syllabus : All Topics of XI & XIl!"taught tll date. DPP No. #05 (JEE-ADVANCED) Total Marks : 78 Max. Time : 49 min. Single choice Objective ('~1" negative marking) Q.1 to Q.6 (3 marks, 2 min.) [18, 12] Multiple choice objective (‘-1" negative marking) Q.7 to 2.10 (4 marks, 2 min.) —_—[16, 08] Integer type Questions ('-1' negative marking) @.11 to Q.15, (4 marks 3 min.) ——_[20, 15] Match the Following (no negative marking) .16 (8 marks, 6 min.) __[08, 06] ChemINFO : 4 Questions ('-1" negative marking) Q.17 to @.20 (4 marks, 2 min.) [16, 08] ANSWERKEY DPP No. # 05 (JEE-ADVANCED) 1. © 2m A 3m © 4m © & A bm © 7° (ABCD) 8% (ABCD)9.* (BC) 10" (AD) Mm 0 12 2 13m 14, 19. mm 900mL15. 246atm16. [A-p.qs};[B-q):[C-1:[D-q] 17m © 18 A) A) 20% A) 1. Forthe given process on an ideal gas, which of the following statements is true : ww oneal tha & fy ay goH & feel es a a where woe Tee vw, (8) Work done by the gas during complete cycle is 6P.V, (8) Work done on the gas during complete cycle is 6P.V; sv (©) Work done on the gas during complete cycle is “8° FN 2 (A) ew 9h a & ers Ay aT OPV, 9r4 Pret aa | (8) ww qi aw & dem ta wOP,V, ore er oT (©) vo eh aw & eters He we PMO ors fea en #1 (0*) Work done by the gas during complete cycle is (0) wo wi aw & dam ta are Resonance” nalawar Road, Kola (Raj) 324005 Educating fr bettr tomorrow 228 Amonoatomic ideal gas (C,= 3 R)/s allowed to expand adiabatically and reversibly from initial volume of 8L at 200 K toa volume of V, at 260 K. The value of V, is: (Given (4.8)""=22) a ; ‘er ceparocaen areal hs (C,= FR) BN eT SHAT wy 8 BOOK aT He BR TI BL 250 K oe sift sree V, cr menter EY fer care B | ra V, ar AT te = (Fa TT BS (4.8) (A) 10.5L. (B)23L (C)85L (0)50.5L Sol. constant (frrretias) 250% (v)"" yess = a" = 48%2 3.2. Three solutions are prepared by adding ‘w' gm of 'A' into 1kg of water, ‘w' gm of 'B' into another 1 kg of water and ‘w' gm of 'C' in another 1 kg of water (A, B, C are non electrolytic). Dry airis passed from these solutions in sequence (A ——> B ——> C). The loss in weight of solution A was found to be 2 4m while solution B gained 0.6 gm and solution Clost 1 gm. Then the relation between molar masses Ora, Band Cis als PT kg Get A VA' S Ww OTH, aia tkg Gia A B'S WaT, aM aa kg Gar ACTS Ww OTH Promax art oid @ | (A,B, C ga aqme 2) | ge eri yew ary fet wa (A —> B—> C) a waried a ont 2 | fae AS gerard 4 ort 2 oTH oP eh cra B wT 0.5 aTH aoe 2 cen faa Ce gam 41 am OT aw at 8) AB en C & ater go H Fey wae eT) . 144 (A) Mg Mg:Mg=4:3:5 )MyrMg Mo gigi g (C*) Mg > M,> Mg, (D) Mg> My > Mg Sol. The loss in weight should be proportional to vapour pressure above that solution So, Ps, « 2gm Pe, «1.50m Py, «25am 0, meximum vapour pressure Is above C solution hence, tis having minimum lowering and hence minimum mole fraction (hence minimum number of moles of solute) So max. molar mass of substance. Sol. ae gra, wy aS egal ee Ps, «2am Py, « 1.50m Ps, = 2.5gm fe C Rawr wr amar afte 8, ore: ee ATA | oe ehh gafey eWaT ts TATE ATA eh aor geaftry gare aropare aiftewers eA | 42 A solution of0.2 mole Ki («= 100%) in 1000.9 water freezes at, °C. Now to ths solution 0.1 mole Hgl, is added and the resulting solution freezes atT,°C. Which ofthe following is correct (A)T,=T, (8)T,>T, (C)T,T, (77, KHal, 8. Which ofthe following compound has bond angles of 120° only, ether in cationic or anionic species ? fr 4 8 fre atte 4 oo at erate oa aerate eile 4, wa aI 120° & 7 (A N,O, (8) (8) PCI, (s) OULCo (0) XeF.(6) ReESONSNCE” bres mreneree Ema AERO Educating fr bettr tomorrow Sol. bs, Sol. Sol Sol N,0,{)—> NO! + NO; (trigonal planar, so bond angle 120°) (Prvivtra erecta, ora: a rT 120°) sp PCI,(s)—> + POL spe XeF(s) > eas Le—> cls I sp spi Consider the following statements with regard to magnesium sulphate 1. itis sparingly soluble in water. 2. Its solubility in water is less than calcium sulphate. 3. When heated to 900 °C, it gives magnesium oxide Which ofthe above statements is/are correct? (A) 1 and 3. (B)2 only (C*) 3 only (OD) 2and3 fre werii at Amhfires aobe & dew A oracrar afore 1. %@ Ga H arg faery ert 2] 2. aah rer A PAST fer aeabe A a a 8 | 3.0 BY 900C Te aM aed Bc ae Afr items Ba # fra 4 8 ara Gor aa 8/8 (A) 1 a3 (8) dai 2 (C*) daa 3 (0) 20813 MgSO, is more soluble than CaSO, in water and MgSO, gives MgO on heating to 900°C. MgSO, sit # CaSO, 8 ait FAI eet & a MgSO, 900°C we a ap GR MgO 2a An ideal gas at initial pressure P, and volume V, undergoes reversible expansion to the same volume V, either isothermally or adiabatically. Which ofthe following statement(s) is (are) correct ? Where the symbols have their usual meaning. (A*) |P, (adiabatic) 0, since expansion of gas occurs. orporate Office | GG Tower AaB & Neat City Mal bate va osotancaac in | Eval” coriai@rosonancaaeTh Fa Free ©1500 200 22 [OU PES SS] ONE UROSLOR OUT PLCOEODS nalawat Road, Kola (Raj) 324005 Resonance” Educating fr bettr tomorrow Sol. oe Sol. Mow Ans. Sol 12. Ans. 0, sit, W afer, norm Pra &, AU = 0. gait, AT = 0. wafie, AH = 0. A8,,.> 0, fo fa oH A ere B Which is the correct relation between osmotic pressure of 0.1 M NaCl solution & 0.1 M Na,SO, solution 0.1 MNaCl fact Ten 0.1 M Na.SO, far & aera ara aa wet were ave & (A) the osmotic pressure of Na,SO, is less than NaCl solution (B*) the osmotic pressure of Na,SO, is more than NaCI solution (C*) the osmotic pressure of Na,SO, is 1.5 times that of NaCl solution (©) the osmotic pressure of NaCl is 1.5 times that of Na,SO, solution (A) Na,SO, 21 ERTERM gra, NaCl fra aH siden aH ete 81 (G1) Na.SO, Br TERM Bra, NaCl Farr aH oe si eT B (C*) Na,SO, 3 TER Za, NaCl sar wh seen 1.5 THT ee 8 (O)Nachanr were" ara, Na,SO, PAT BH ote 1.537 aha 8 Forthe depression of freezing point experiment involving non-volatile solute, The correct statements) is/are (A*) Vapour pressure of pure solvent is more than that of solution (B) Vapour pressure of pure solvent is less than that of solution (©) Only solute molecules solidify atthe freezing point (0°) Only solvent molecules solidify at the freezing point feria fry } oor wan & fay, Pet aS haat wer a Ae (ay ag Ravers or areata Paar Pr Te a sire eta 8 (@) aye Pera a aTorera fra A ae A HH ela 8 (© ftnia fg w daa Read amy, ata A oRaffa ade (0% Resa Pog oe Sac Rear } ay sla H aRafeiar vd 8 From Roult's Law. uae fre 20g of a binary electrolyte (molecular weight = 100) are dissolved in 500 g of water. The freezing point of the solution is 0.74°C ; K,= 1.86 K molality", Calculate percentage degree of dissociation of electrolyte 500g we Hm Kara eye ore & 20g (sia He = 100) ay eH AT @ | Pera at Rais -0.74°C, K,= 1.86 K Arereer& eg rere ar ert ror tet RY ° AT, = 2K,m. 0.74 1.96 x04 => 2=0,9045=1 tast—az0 Consider the following trends in properties of hydrogen halides 1. Acidic strength : HF < HCI < HBr < HI 2. Thermal stability: HF > HCI> HBr> HI 3. Dipole moment : HF < HCI < HBr < HI 4. Reducing power: HF > HCI> HBr> HI Find number of correct trends. arggiors orgs & apr 3 Pre ght ar arash aA 4. ore area: HF < HCI < HBr < Hi 2. anita vente: HF > HCI> HBr> HI 3. fea omgel: HF HC1> HBr > Hl ah gh Bh a TET | 2 orporate Office | GG Tower AaB & Neat City Mal bate va osotancaac in | Eval” coriai@rosonancaaeTh Fa Free ©1500 200 22 [OU PES SS] ONE UROSLOR OUT PLCOEODS nalawat Road, Kola (Raj) 324005 Resonance” Educating fr bettr tomorrow 13.08 Ans. Sol. Ads Ans. Sol. 15. Sol 16. A membrane permeable only to water separates a 0.01 M solution of sucrose from a 0,001 Mone. Onwhich solution must pressure be applied to bring the system into equilibrium? Find this pressure ifthe T= 300 K. Report your answer as (pressure x 100) pact ret fry TH PRIA, Tw 0.001 Marler arta Paes wh 0.01 M Paar a ger ach 8, ea @ fore floes we ara aT arey fe, Favs ary A ot OT | ae ata Sra Miers, ae T= 298K er a8 Ge BH Ia 100) @ HH ar ae | 2 Pressure will be applied to higher conc. side = (10° 10°) x 0.082 x 300 = 0.22 x 100 = 22 2214 atm. How much water must be added to 300 mL of a 0.2 M solution of CH,COOH for the degree of dissociation of the acid to double ? (Assume K, of acetic acid is of order of 10M) CH,COOH 0.2M fers & 300 mi RecrH oTe Provan omy, Re org Reto a ay at yA a oe (ae A14 f, WHE ss IK, 10% M ae are) 900 mi Initially degree of dissociation so => Hencewehave 200 028¥, 22 soy 100 mi Hence water added = 1200 - 300 = 900 mi Calculate the osmotic pressure of a decinormal solution of cane sugar at 27°C. 27°C ara WR TH HY aaa gH Sesterey forrs B aera ara BY ora aA? 2.46 atm G =molarconcentraion=0.1M = R=0,082 litre atm K~' mo, T= 900K wehave P=; RT = 1 x 0.082 x 300 = 2.46 atm Mateh the Column Column4 Column @® 0.1 MAL(So), (©) Solution with highest boiling point. ® 0.1 MalPo, @ —_Van't Hoff factoris greaterthan 1 © 01 Murea (© Solution with lowest osmotic pressure. ©) 0.1 MMgcl, (8) Solution with lowest freezing point. rei rel ) — 0.1MAL(SO), ©) sear ae er PRCT | ® — 0.1MAIPO, @ te dw arnt a afte © 0.1 Murea, CS Ca ©) 0.1MMgCl,, ©) ayers fares ar fer | (A- pqs} : [Ba] [6-1]; [D-a) orporate Office | GG Tower AaB & Neat City Mal bate va osotancaac in | Eval” coriai@rosonancaaeTh Fa Free ©1500 200 22 [OU PES SS] ONE UROSLOR OUT PLCOEODS nalawat Road, Kola (Raj) 324005 Resonance” Educating fr bettr tomorrow ative Properties Immiscible Liquid immiscible Liquid |Wnen a volatile iquidis added to another volatile liquid, which are completely immiscible with each other, each liquid lwill behave independent ofthe other and will exer its own vapour pressure. The more dense liquid (A) wil form lower layer and less dense liquid (B) is passed into liquid (A). The total vapour pressure of the system will be the sumo \vapour pressure of both the volatile liquids, P. =P, +P,=P24P2 (5X, &X,=1) [The boiling point of a liquid system is the temperature at which its vapour pressure becomes equal to the external latmospheric pressure. The total vapour pressure of a mixture containing immiscible volatile liquids is greater than| either of the pure constituents, thus the mixture will boil at a temperature, which is lower than the boiling point of either of the pure constituents. This forms the basis of steam distillation, in which one of the volatile liquids is water. [This composition ofthe vapour above the liquid mixture can be calculated using ©0008 ®BO®D Daltor’s law of partial pressures. a P= P= Prag X 8 =P Pay vorigies bad P=P, © Aig We _ Pa xMg. Wa Pa *Ma |The masses of the constituents in the vapour (distillate) will be proportional to their respective molar mass of vapou pressure, [Memorize this theory as soon as you get the DPP. Revise it regularly and master this concept by practice] 17. A mixture of immiscible liquids of an organic liquid and water boils at 90°C and 732 torr pressure. The distillate contains 73% by weight of the organic liquid. Calouaite the motar mass of the organic liquid (vapour pressure of water at 90°C is 526 torr.) (A)168.2gmor* ——_(B) 228.8 mot" (C4)1222gmor* (0) 62.7 g mol 48. When a mixture of water and chlorobenzene (mutually immiscible) is distilled at an external pressure of 740.2 mm Hg, the mixture is found to boil at 90.3°C, at which temperature the vapor pressure of pure water is 350.1 mmHg, Calculate the per cent by weight of chlorobenzene in the disillate, (Molecular weight is 112). (&)0.71 (71%) (©)0.48 (48%) (©)0.25 (25%) (0)0.86 (86%) 19. Twoliquids X and Y are perfectly immisible. IfX and Y have molecular masses in ratio 1 : 2, the total vapour pressure of a mixture of X and Y prepared in weight ratio 2 : 3 should be (P? = 400 torr,P? =200 torr) (A*) 600 torr (8) 700torr (©) 850 torr (0) 900 torr 20.» An unknown compound is immiscible with water. Itis steam distilled at 98.0°C and P = 737 torr, P{H,0) = 707 torr at 98.0°C. This distillate was 75% by weight water. Calculate the molecular weight of the unknown. (A) M= 141.4 (B)M= 92.1 (C)M= 126.2 (0) M= 186.8 ReESONSNCE” bres mreneree Ema AERO , ducating for beter tomorrow IE emINF' ST el mero et CMake ke) Daily Self-Study Dosage for mastering Chemistry za faftentta aa a em areas xa ah oa arsreitel xa 4 ora sitet 8, ot eager } He gh ws 8 offsite 8 yee ea oy aa o Se tacts OS SE BAT Ba ge eae wT aera eT | wife Aca Te sa (A) Pract oe ETAT fa aa era aro sa (B) wl wa (A) A A wares we | Ta Yer aaa, eet Teta eal S aeaera wT ate eT) EPL+PS (fh X, &X,=1) eae at ot aerate roy & Fre See aS—ara ger are aia vray at | saftey arte wa yaa UH cor age aren ara, rh wet aq sraera fy ay ee | Be SUT Phan qe aTATE ew aera # of A a fret ah ae ora aertan aH tar & fae anita areas an ona ara 8, Roe ge aru ga wet 8) a Parr & oar aren gm ras wT RAH aT aga ae Raa Pra oT #1 fers erat ar ies Bo P, P= Pa 0 Pp= P= Pea ot eid X:aXy aed am sen A AGB wafer a) veftia oe & ities ProwiXe' _ Pa ProtatXa’ sy (srreae) H srerral at xara, anmera eh awe Hea eva | wager et | [Memorize this theory as soon as you get the DPP. Revise it regularly and master this concept by practice] Aim 90°C 4 732torr ara wR Ve ards aaa aS ofthe gas UH Ps a Tara TEN 8 | ATER ard aa aR HT 73% wa & | rie ea an AroR—gara oftefere aifory (GOO TE Ue aT ATETETA 626 torr’) (A)168.2gmol" (8) 228.8g mol" (C1)122.2gmol" (0) 62.7 g mol" 18, 5A740.2 mmHg, er are ara we TS TTA ger ae wave flea aa, a Ps a 00.39 1 Gare ay, HRT ATT WE YE TST TUTTE 360.1 mmHg # | seas A aires & ae ar ater feo fore SPAR 112). (a) 0.71 (71%) (©) 0.48 (48%) (©)0.25 25%) (0) 0.86 (86%) 19. aaa Xai wad aftswha @) af Xa s fy sm 1: Qargure 4 8, dt weg 2:34 gar wa _X aye ww fem a ga am aa Fe ae ate (A*) 600 torr == (B) 700 torr (C) 850 torr (0) 900 torr 202 Ue afer Py wet ee sista 2 | gerOT ATMA iTwaH 98,0°C «we B a P=737 torr, PHO) = 707 torr 81 ae ore ore Be aT 75% 8 | eT oT SMT ORR FETT | A’) 141.4 (B)M=92.1 (C)M=126.2 (0) M=186.8 TPIA, Near Cily Mall, Jhalawiar Road, Kola (Raj) 324005 operate Office = C6 To TART TeCoTaRN STA TERT DOT Fa Free ©1500 200 22 [OU PES SS] ONE UROSLOR OUT PLCOEODS Resonance Educating fr bettr tomorrow

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