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EOCQ Ans 26

This document provides answers to end-of-chapter questions from Chapter 26 of an A Level Chemistry textbook. The answers include chemical equations and structural formulas. Full marks are provided for each multi-part question.

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Muhammad Ahmed Zaman
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86 views1 page

EOCQ Ans 26

This document provides answers to end-of-chapter questions from Chapter 26 of an A Level Chemistry textbook. The answers include chemical equations and structural formulas. Full marks are provided for each multi-part question.

Uploaded by

Muhammad Ahmed Zaman
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd
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Cambridge International A Level Chemistry Answers to end-of-chapter questions

Answers to EOCQs
Chapter 26
1 a i ethanol;[1]
ethanoic acid; [1]
a few drops of concentrated sulfuric acid as
catalyst[1]
ii C2H5OH + CH3COOH ∏ CH3COOC2H5 + H2O[1]
b i phenol;[1]
benzoyl chloride;  [1]
warm reaction mixture [1]
ii C6H5OH + C6H5COCl → C6H5COOC6H5 + HCl [1]
Total = 8

2 a H H H
O
H C C C C

H H H Cl [1]

b i phosphorus(V) chloride, PCl5 /


phosphorus(III) chloride, PCl3 /
sulfur dichloride oxide, SOCl2[2]
ii C4H9COOH + PCl5 → C4H9COCl + POCl3 + HCl
or
heat
3C4H9COOH + PCl3 3C4H9COCl + H3PO3
or
C4H9COOH + SOCl2 → C4H9COCl + SO2 + HCl [1]
iii Chlorine atom withdraws electrons from
the –COOH group [1]
weakening the O–H bond so it is easier for
2-chlorobutanoic acid to lose an H+ ion. [1]
iv Cl
O
H
[1]
O

v
2,2-dichlorobutanoic acid /
2,3-dichlorobutanoic acid [1]
Total = 8

Cambridge International AS and A Level Chemistry © Cambridge University Press 2014

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