For the next 15-20 years, most ammonia will continue to be produced via the classic process of combining nitrogen and hydrogen over an iron-based catalyst at high temperature and pressure. The proposed process design can produce over 1,000 metric tons per day of ammonia using a conventional plant as a model. Further optimization may be possible through a more efficient reactor design and lower-cost ruthenium-based catalyst.
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Conclusion
For the next 15-20 years, most ammonia will continue to be produced via the classic process of combining nitrogen and hydrogen over an iron-based catalyst at high temperature and pressure. The proposed process design can produce over 1,000 metric tons per day of ammonia using a conventional plant as a model. Further optimization may be possible through a more efficient reactor design and lower-cost ruthenium-based catalyst.
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Conclusion
For the major part, ammonia production in the next 15 to 20
years will rely on the classic ammonia synthesis reaction combining nitrogen and hydrogen using a catalyst at elevated temperature and pressure in a recycle process. The proposed ammonia synthesis design produces 1,016 metric tons/day of ammonia at a feed of 5,500 kmol/hr. Although the lack of kinetic data deterred the completion of the plug flow simulation, a Gibbs reactor successfully emulated the desired results. The Haldor-Topsoe plant in Clear Lake, Texas, was chosen as the model for the conventional ammonia plant due to its comparable operation to the proposed simulation and its use of iron-based catalyst. This process could be further optimized by lowering compression costs and utilizing a more efficient reactor. Replacing the conventional catalyst with the new ruthenium- based catalyst in a multi-bed reactor can achieve these goals. The industrial process may be safely and productively operated at lower temperatures, thus reducing costs and increasing profit. M.W. Kellogg takes full advantage of this superior catalyst in its breakthrough technology known as the Kellogg Advanced Ammonia Process, or KAAP. KAAP, implemented as either a retrofit, expansion, or grassroots design, has proven to have significant benefits, such as reduced capital costs and energy savings. Kellogg's new ammonia synthesis configuration leads to a economically advantageous and flexible ammonia plant Reference
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