Mock Test - 7 Chemistry (Paper - 1)

PART (B) : CHEMISTRY

SECTION-I : (SINGLE ANSWER CORRECT TYPE)

This section contains 05 multiple choice questions. Each question has four choices (A),
(B), (C) and (D) out of which ONLY ONE is correct.
Marking Scheme : Correct Marks : 3 , Negative Marks : 1

  
i MeMgBr 2eq
19. Ethylmethanoate 
 ii  H3O
W X


organic product

W  CHCl3  Y
CaOCl2

X 
CaOCl2
CHCl3  Z
Y  Z Dry
Distillation
 Organic product(s) + CaCO3
Which of the following organic product can be formed on dry distillation reaction ?
(I) CH3  COOH (II) CH3  CO  CH 3
(III) CH 3  CH  CH  CH 3 (IV) HCHO
(A) I and II (B) II and III (C) I, II and III (D) II and IV
19. (D)
W and X are CH 3CH 2 OH and  CH 3  2 CHOH .
Y and Z are  HCOO 2 Ca and  CH 3 COO 2 Ca .

20. Which of the following are correct statement?

(A) Spontaneous adsorption of gases on solid surface is an endothermic process as entropy
decreases during adsorption
(B) Formation of micelles takes place when temperature is below Kraft Temperature  Tk  and
concentration is above critical micelle concentration (CMC)
(C) A colloid of Fe  OH 3 is prepared by adding a little excess (required to completely precipitate
Fe3 ions as Fe  OH 3 )) of NaOH in FeCl3 solution the particles of this sol will move towards
anode during electrophoresis.
(D) According to Hardy–Schulze rule for the coagulation of As 2S3 sol flocculation value of Fe3 ion
will be more than Ba 2 or Na  .
20. (C)
(A) G  H  TS  O as S  O so S  O so H has to be negative
(B) Micelles formation will take place above Tk and above CMC
(C) This solution will be negatively charged.
(D) Fe3 ions will have greater flocculatibility power so smaller flocculating value.

21. For a solution of 0.849 g of mercurous chloride in 50 g of HgCl 2    the freezing point depression is
1.24o C . K f for HgCl2 is 34.3 K-kg/mol. What is the state of mercurous chloride in HgCl2 ?
(Hg – 200, Cl – 35.5)

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(A) As Hg 2 Cl 2 molecules (B) As HgCl molecules


(C) As Hg  and Cl ions (D) As Hg 22 and Cl ions
21. (A)
 0.849 
 
1.24  34.3  M   M  469.68
 0.05 
 
 as Hg 2 Cl2 molecules.

22. Packing fraction of CsCl crystal is (assume crystal to be ideal)

(A) 0.729 (B) 0.68 (C) 0.9251 (D) 0.524
22. (A)
4   3
3 

 r    r     r  3 
 3

p.f .       1
 2r  
3
6  r  


 
   2 3  3  0.729
2

23. Among the following reaction sequences identify incorrect step

(A) I  a;II  b;III  c;IV  d (B) I  b;II  a;III  d;IV  d

(C) I  a; II  a;III  b;IV  d (D) I  b; II  a;III  d;IV  c
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23. (C)

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SECTION-II : (MULTIPLE ANSWER(S) CORRECT TYPE)

This section contains 08 multiple choice questions. Each question has four choices (A),
(B), (C) and (D) out of which ONE or MORE than one is/are correct.
Marking Scheme : Correct Marks : 4 , Negative Marks : 2, Partial Mark : 1

d A
 k  A  . If initial concentration of A is
12
24. For the reaction A  B , the rate law expression is 
dt
A 0 . Which of the following statements is/are true regarding this reaction?
(A) The plot of A against ‘t’ will be linear

(B) The half life period is t1 2  A0

2  2 1 
K
(C) The rate of reaction decreases linearly with time.
K
(D) The integrated form of rate expression is A  t  A0
2
24. (ABCD)
d A
 k A
12
(A) 
dt
dA
Or   Kdt
A
12

On integrating

   A
1 2
dA  K  dt,  2A1 2  Kt  C ………… (1)
At t  0; A  A 0 C  2A 01 2 ………… (2)
By Eqs. (2) and (1),
2A1 2  Kt  2A10 2
Or Kt  2  A10 2  A1 2  ………… (3)
(B) plot of A1 2 vs , t will be linear because
Eq. (3) yields,
K
Or A1 2   t  A10 2 (similar to y  mx  C )
2
(C) If t 1 2 A  A0 2
12
 A 
By equation (3), Kt 12
 2  A10 2  0 
 2 
1
 2A10 2 
2
2  2  1 1 2
Kt1 2  
2
A0  2  
2  1 A10 2

 t1 2 
2  2 1 A 12
0
K

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25.

Correct statement(s) for above reaction?

(A) The reaction mechanism is SN1.
(B) Alcohol formed gives yellow ppt. with I 2 / NaOH
(C) Alcohol formed do not give yellow ppt. with I 2 / NaOH
(D) alkyl iodide formed reacts with NaOH / I 2 and form yellow ppt.
25. (AB)

  P     Q     R  

 ii  Zn   Q    S ,  S 
 3
 T
i O
26. CaC2 
H2 O HgSO4
H 2SO4  dil.
dil.NaOH

conc.NaOH


Correct statement(s) for the above reaction:

(A) (S) to (T) is intramolecular cannizaro
(B) (Q) can show cannizaro reaction
(C) (P) on reaction with Red hot iron tube forms aromatic compound
(D) (R) can show tautomerism
26. (ACD)

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27.

The reactant A can be:

(A) (B)

(C) (D)

27. (ABD)

28. Which of the following statements is/are CORRECT for I 2O5 :

(A) It is an oxidising agent
(B) It is used to estimate CO in a gas mixture
(C) It is an anhydride of HIO 4 (periodic acid)
(D) When it reacts with mixture of CO  CO 2 all the CO 2 is converted to CO.
28. (AB)
I 2 O5 acts as an oxidising agent, It oxidises CO into CO 2 .
I 2O7 is a hydride of HIO 4 .

29. The PH 3 can be prepared by which of the following reaction:

(A) Mg 3 P2  H 2 O  (B) White  'P ' NaOH 
  KOH
(C) H 3 PO 2   (D) PH 4 Br  
29. (ABCD)
Phosphine is prepared by the reaction of phosphide with water.

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In the laboratory, it is prepared by heating white phosphorus with concentrated NaOH solution in an
inert atmosphere of CO 2 .
o
3H3PO2 (concentrated solution) 
40 or more
 PH 3  2H 3PO3
PH 4 Br  KOH  PH3  KBr  H 2 O

30. Which of the following compounds contain PbO?

(A) Pb 2O3 (B) Pb3O4 (C) PbO2 (D) None
30. (AB)
Pb 2O3  PbO.PbO2
Pb3O4  2PbO.PbO2

31. Which of the following reactions take place during the extraction of Ag from Ag 2S by cyanide
process?
  2
(A) Ag 2S  CN    Ag  CN  2   S2 (B) Zn  2  Ag  CN 2    Zn  CN 4   2Ag 
(C) S2   O 2  SO 24 (D) None of these
31. (ABC)

Ag 2S (conc. ore) 2NaCN 
Air
 2AgCN  Na 2S
Ag 2S and AgCN are in equilibrium so Na 2S is oxidised by air in to Na 2SO4 . Hence equilibrium
shifts towards right side.
4Na 2S  5O2  2H 2O  2Na 2SO4  4NaOH  2S
AgCN  NaCN  Na  Ag  CN 2   soluble complex 

2Na  Ag  CN 2   Zn  dust   2Ag   Na 2  Zn  CN 4 

SECTION-III : (INTEGER ANSWER TYPE)

This section contains 05 questions. The answer to each question is a NUMERICAL

VALUE. For each question, enter the correct numerical value (in decimal notation,
truncated/rounded-off to the second decimal place ; e.g. 6.25, 7.00, 0.33, 30.27, 127.00)
Marking Scheme: Correct Marks : 3, Negative Mark : 1

32. Ionisation energy of H–atom is 13.6 eV. If H–atoms in the ground state are excited by photons of
energy 12.1 eV, then the total number of different spectral lines emitted according to Bohr’s theory
will be.
32. (3.00)
By absorbing 12.1 eV, electrons will be excited to n = 3
On returning maximum 3 lines can be obtained.

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33.

Identify total numbers of steps involving aldol reaction?

33. (1.00)

(1) Aldol will occur (one   H )

(2) Cannizaro will occur

34. For the cell: Pt Hg 2Cl 2  s  KCl 1M  H  Q H 2Q Pt

E cell  0.1239V at 298K, hence pH of cathodic compartement is.
 2.303RT 
Given: E oCalomel, RP  0.28V, E oQ H 2 Q  0.699V   0.059 
 F 
34. (5.00)
E cell  E oAO  E oCR  0.059 / 2 log Q
0.059 1
0.1239  0.28  0.699  log 2
2  H  
pH  5


35. For any vanderwaals gas PC  70 atm and VC  0.183 hence ‘a’ in atm   2 mol2 is ……….
mol
35. (7.03 to 7.04)
a  3PC VC 2  3  70  0.1832
 3  70  0.033
7

36. How many of the following elements have +3 as their most stable oxidation state in their compounds
Al,TI, Mn,Bi, P,Cr,Cu,Sc,Si .
36. (4.00)
Most stable staes:
+1 State TI
+2 State Cu
+3 State Al, Bi, Cr, Sc

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+4 State Si
+5 State P
Most stable state of Mn is +2 in acidic medium and +4 in alkaline/neutral media.

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