This document discusses industrial applications of surfactants. Surfactants are amphipathic molecules with a hydrophobic tail and hydrophilic head that allow them to act as emulsifiers, dispersants, and solubilizers. Some key applications of surfactants mentioned include using them to form and stabilize foams, emulsions, and suspensions. Surfactants are also widely used in cosmetics, pharmaceuticals, agrochemicals, and the food industry.
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Surfactants, Industrial Applications
This document discusses industrial applications of surfactants. Surfactants are amphipathic molecules with a hydrophobic tail and hydrophilic head that allow them to act as emulsifiers, dispersants, and solubilizers. Some key applications of surfactants mentioned include using them to form and stabilize foams, emulsions, and suspensions. Surfactants are also widely used in cosmetics, pharmaceuticals, agrochemicals, and the food industry.
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Surfactants, Industrial
Applications Tharwat F. Tadros Imperial Chemical Industries
I. Introduction IX. Surfactants in Foams
II. General Classification of Surfactants X. Surfactants in Wetting Phenomena III. Physical Properties of Surfactant Solutions XI. Application of Surfactants In Cosmetics IV. Adsorption of Surfactants at Various Interfaces and Personal Care Products V. Surfactants as Emulsifiers XII. Application of Surfactants VI. Surfactants as Dispersants in Pharmaceuticals VII. Role of Surfactants in Stabilization of Emulsions XIII. Application of Surfactants in Agrochemicals and Suspensions XIV. Application of Surfactants in the Food Industry VIII. Role of Surfactants in Solubilization and Microemulsions
GLOSSARY SURFACE-ACTIVE agents (usually referred to as sur-
factants) are amphipathic molecules consisting of a non- Cloud point Temperature at which a surfactant solution polar hydrophobic portion, usually a straight or branched of a given concentration becomes turbid (cloudy). hydrocarbon or fluorocarbon chain containing 8–18 car- Critical micelle concentration (cmc) Concentration at bon atoms, which is attached to a polar or ionic portion which the physical properties of a surfactant solution (hydrophilic). The hydrophilic portion can, therefore, be show an abrupt change. nonionic, ionic, or zwitterionic, accompanied by coun- Emulsion Dispersion of a liquid in a liquid. terions in the last two cases. The hydrocarbon chain in- Krafft temperature Temperature at which the surfactant teracts weakly with the water molecules in an aqueous shows a sudden increase in solubility. environment, whereas the polar or ionic head group in- Micelles Association units of surfactant molecules. teracts strongly with water molecules via dipole or ion– Microemulsion Thermodynamically isotropic system of dipole interactions. It is this strong interaction with the water, oil, and surfactant. water molecules which renders the surfactant soluble in Solubilization Incorporation of an insoluble substance in water. However, the cooperative action of dispersion and a surfactant solution. hydrogen bonding between the water molecules tends to Suspension Dispersion of a solid in a liquid. “squeeze” the hydrocarbon chain out of the water and