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IPTP Chlorine GoochClRef

The document lists five references used by a program to calculate various chlorine and water parameters: 1) A 1993 McGraw-Hill reference is used to calculate water density as a function of temperature. 2) Two 1959 and 1946 references are combined to calculate the pK for chlorine hydrolysis as a function of temperature. 3) A 1966 reference is used to calculate the pK for HOCl ionization as a function of temperature. 4) A 1912 reference is used to calculate the weight of chlorine in water as a function of temperature. 5) A 2006 reference is used to calculate the pK for the water ionization product as a function of temperature.

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31 views1 page

IPTP Chlorine GoochClRef

The document lists five references used by a program to calculate various chlorine and water parameters: 1) A 1993 McGraw-Hill reference is used to calculate water density as a function of temperature. 2) Two 1959 and 1946 references are combined to calculate the pK for chlorine hydrolysis as a function of temperature. 3) A 1966 reference is used to calculate the pK for HOCl ionization as a function of temperature. 4) A 1912 reference is used to calculate the weight of chlorine in water as a function of temperature. 5) A 2006 reference is used to calculate the pK for the water ionization product as a function of temperature.

Uploaded by

Shooeib
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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Download as PDF, TXT or read online on Scribd
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References

Used in the Chlorine in Water Parameters Calculator

The program calculates the density of water in kg/L at temperature T in ºC using:


McCutcheon, S.C., Martin, J.L, Barnwell, T.O. Jr.,”Water Quality”, in Maidment,
D.R. (Editor), “Handbook of Hydrology”, McGraw-Hill, New York, NY, 1993 (p.
11.3).

The program calculates the pK for the hydrolysis of chlorine gas in water at a
temperature of T ºC using:
R.E. Connick et. al., “The Hydrolysis of Chlorine and its Variation with
Temperature”, J. Amer. Chem. Soc. Vol. 81, 1959 (pp. 1280-1284).
J.C. Morris, “The Mechanism of the Hydrolysis of Chlorine”, J. Amer. Chem. Soc.
Vol. 68, 1946 (pp.1692-1694).
(The two data sets were combined.)

The program calculates the pK for the ionization of HOCl in water at a temperature
of T ºC using:
J.C. Morris, “The Acid Ionization Constant of HOCl from 5 to 35º”, J. Phys. Chem.
Vol. 70, 1966 (pp. 3798-3805).

The program calculates the weight of Cl2 in 100g water at a temperature of T ºC


using:
L.W. Winkler, Landolt and Bornstein, "Physikalish-Chemische Tabellen", 4th ed.
1912 (pp. 597,601).

The program calculates the pK for the ionization product of water at a temperature
of T ºC using:
A.V. Bandura et. al., “The Ionization Constant of Water over Wide Ranges of
Temperature and Density”, J. Phys. Chem. Ref. Data. Vol. 25, No. 1, 2006 (pp. 15-
30).

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