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CBSE Sample Paper Class 12 Chemistry Set 6

This document provides a sample paper for Class 12 Chemistry with four sections. Section I contains 6 short answer questions worth 1 mark each. Section II contains 5 short answer questions worth 2 marks each. Section III contains 13 questions requiring explanation worth 3 marks each. Section IV contains 3 long answer questions worth 5 marks each. The paper covers topics such as chemical equations, acid-base reactions, organic chemistry, coordination compounds and their properties.

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Sidharth Sabharwal
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118 views4 pages

CBSE Sample Paper Class 12 Chemistry Set 6

This document provides a sample paper for Class 12 Chemistry with four sections. Section I contains 6 short answer questions worth 1 mark each. Section II contains 5 short answer questions worth 2 marks each. Section III contains 13 questions requiring explanation worth 3 marks each. Section IV contains 3 long answer questions worth 5 marks each. The paper covers topics such as chemical equations, acid-base reactions, organic chemistry, coordination compounds and their properties.

Uploaded by

Sidharth Sabharwal
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd
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CBSE Sample Paper Class 12 Chemistry

Set 6

Section I: Each question carriers 1 mark: 1 x 6 = 6 marks

1. Why is ferric chloride preferred over potassium chloride in case of a cut leading to bleeding?
2. Among octahedral and tetrahedral crystal fields, in which case the magnitude of crystal field
splitting is larger?
3. Write the IUPAC name of the compound
CH2(Cl)COCH(CH3)CONH2
4. Which of the following compounds has a lone pair of electrons at the central atom?
H2SO3 , H2SO4
5. How will you distinguish between phenol and cyclohexanol by suitable chemical test?
6. Draw the strcture of Hex-2-enoic acid.

Section II: Each question carriers 2 marks: 2 x 5 = 10 marks

1. Determine the molarity of an antifreeze solution containing 250g water mixed with 222g
ethylene glycol (C2H6O2) (molar mass 62 g mol–1) The density of this solution is 1.07g/mL.
2. An aqueous solution containing urea was found to have boiling point more than the normal
boiling point of water (373.13K). When the same solution was cooled, it was found that its
freezing point is less than the normal freezing point of water (273.13K). Explain these
observations.
–1
3. The conductivity of 0.20 M solution of KCl at 298 K is 0.025Scm . Calculate its molar
conductivity.
4. How will you distinguish between the following pairs of compounds?

(i) C2H5Br and C2H5Cl (ii) Phenol and chlorobenzene

5. Write the following name reaction.

(i) Sand mayers reaction (ii) Gabriel's Phthalimide synthesis.

Section III: Each question carriers 3 marks: 3 x 13 = 39 marks

1. Write balanced chemical equations for the following reactions.

XeF6 undergoes hydrolysis.


Phosphorus is treated with concentrated nitric acid.
Orthophosphorous acid is heated.

2. Account for the following

A delta is formed at the point where the river water enters the sea.
Direct current is passed through a colloidal solution.
Ferric hydroxide sol is positively charged.
Primary alkyl halide (A) C 4 H 9 Br reacted with alcoholic KOH to give compound
(B). Compound (B) is reacted with HBr to give (C) which is an isomer of (A).
When (A) was reacted with sodium metal it gave a compound (D) C 8H18 that
was different than the compound when n-butyl bromide was reacted with
sodium. Give the structural formula of (A) and write the equations for all the
reactions.
What happens when?

(i) N-Butyl chloride is treated with alcoholic KOH.


(ii) Bromobenzene is treated with Mg in the presence of dry ether.
(iii) Chlorobenzene is subjected to hydrolysis.

5. Convert :

phenol to benzyl alcohol


phenol to aspirin
Methyl magnesium bromide to 2-methylpropan-2-ol

What are vitamins and how are they classified? Name the vitamin responsible
for coagulation of blood.
State a reason for each of the following statements:

Soaps do not work in hard water


The use of aspartame is limited to cold food and drinks
Aspirin helps in the prevention of heart attack.

8.

Write the zwitter ionic structure of glycine?


What is meant by inversion of sugar?
Name the vitamin in each case whose deficiency causes

Night blindness.
Poor coagulation of blood.

9. Write chemical equations for following reactions:

(i) Oxidation of nitrite ion by MnO 4 in acidic medium.


Acidification of potassium chromate solution.
Disproportionation of manganese (VI) in acidic solution.

10. How would you account for the following?

Transition metals exhibit variable oxidation states.


Zr (Z = 40) and Hf (Z = 72) have almost identical radii.
Transition metals and their compounds act as catalyst.

11. Write the IUPAC names of the following coordination compounds:

(i) [Cr(NH3)3Cl3]
(ii) K3 [Fe(CN)6]
+
(iii) [CoBr2(en)2] , (en = ethylenediamine)

12. (a) Name one substance which can act as both

(i) Analgesic and antipyretic


(ii) Antiseptic and disinfectant

(b) Write the composition of Dettol.

13.

(i) Draw the structure of phosphinic acid (H 3PO2).


(ii) Write a chemical reaction for its use as reducing agent.
(iii) Suggest a quantitative method for estimation of the gas which protects us
from UV rays of the sun.

Section IV: Each question carriers 5 marks: 3 x 5 = 15 marks

1. (a) Describe the following reactions.


 Canni zaro's reaction
 Cross aldol condensation.

(b) How will you convert?


 Methyl cyanide to acetamide
 Acetaldehyde to but 2 enal.
 Ethyl benzene to benzoic acid.

OR
(a) A compound a on oxidation given B (C 2 H 4 O 2). A reacts with dil.NaOH and on
subsequent heating forms C. C on catalytic hydrogenation gives D. Identify A, B, C and
D and write down the reaction involved.

(b) Write short notes on.


 Clemmenson reaction.
 Hell – Volhard – Zelinsky reaction.

2. (a) Why is chloroacetic acid more acidic than acetic acid?


(b)Write the mechanism of nucleophilic addition reaction.
(c) Give chemical tests to distinguish between the following pairs of compounds:
(i) Acetaldehyde and bezaldehyde
(ii) Propanone and propanol

OR

(a) Arrange the following pairs of compounds in an increasing order of their indicated
property:
 Benzoic acid, 4- Nitrobenzoic acid, 3,4-Dinitrobenzoic acid, 4-Methoxybenzoic
acid (acid strength)
 CH 3 CH 2 CH(Br)COOH, CH 3 CH(Br)CH 2COOH, (CH 3 )CHCOOH,
CH 3 CH 2 CH 2 COOH (acid strength)
(b) How would you account for the following?
 Aldehydes are more reactive than ketones towards nucleophilic addition
reaction.
 The boiling points of aldehydes and ketones are lower than of the
corresponding acid
 The aldehydes and ketones undergo a number of addition reactions.
3. (a) An organic compound ‘A’ on treatment with ethyl alcohol give carboxylic acid ‘B’ and
compound ‘C’. Hydrolysis of ‘C’ under acidic conditions gives ‘B’ and ‘D’. Oxidation of
‘D’ with KMnO 4 also gives ‘B’. ‘B’ on heating with Ca(OH) 2 gives ‘E’ with molecular
formula C 3 H 6O, ‘E’ does not give Tollen’s reagent test or reduce Fehling’s solution but
forms 2, 4 – dinitrophenyl hydrazone. Identify A to E.
(b) Write the conditions to maximize the yield of H 2SO4 by contact process.
(C) Write balanced equations for the following reactions

(i) Cu + H 2 SO 4 (conc) 
(ii) Ca3 P2 + H2O 

OR

(a) Write chemical equations for the following processes.


 Chlorine reacts with a hot concentrated solution of sodium hydroxide
 Orthophosphorous acid is heated.
 Pt.F6 and xenon are mixed together.
(b) Complete and Write balanced equations for the following reactions.
 SF4 + H2O 
 P4O10 + H2O 

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