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Informe 4 (Datos)

The document contains data from an experiment measuring absorbance over time for a solution at different temperatures (40°C, 60°C, and 333.15°C). It shows the absorbance measurements in a table and plots the natural log of (initial absorbance - absorbance at time t) versus time for each temperature condition. It also plots the natural log of the observed rate constant versus the inverse of temperature and includes a linear regression analysis.
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0% found this document useful (0 votes)
38 views5 pages

Informe 4 (Datos)

The document contains data from an experiment measuring absorbance over time for a solution at different temperatures (40°C, 60°C, and 333.15°C). It shows the absorbance measurements in a table and plots the natural log of (initial absorbance - absorbance at time t) versus time for each temperature condition. It also plots the natural log of the observed rate constant versus the inverse of temperature and includes a linear regression analysis.
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as XLSX, PDF, TXT or read online on Scribd
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Solución D Solución D

Temperatura Ambiente 40°C 60°C


Tiempo Absorbancia Absorbancia Absorbancia Tiempo
0 0.363 0
1 0.323 0.347 0.317 1
2 0.289 0.331 0.197 2
3 0.259 0.279 0.118 3
4 0.23 0.233 0.072 4
5 0.204 0.199 0.048 5
6 0.182 0.169 0.039 6
7 0.162 0.141 0.033 7
8 0.145 0.122 0.028 8
9 0.129 0.102 0.026 9
10 0.115 0.086 0.027 10
11 0.102 0.074 0.029 11
12 0.091 0.064 0.029 12
13 0.082 0.056 0.029 13
14 0.072 0.048 0.029 14
15 0.064 0.04 0.029 15
16 0.057 0.034 0.029 16
17 0.051 0.029 0.029 17
18 0.046 0.025 0.029 18
19 0.04 0.023 0.029 19
20 0.036 0.02 0.029 20

t vs. ln⁡〖 (𝐴0−


0.00000
0 2 4= −=0.0820075279
f(x)f(x) 6 8
− 0.08521532

-0.50000
ln⁡〖 (𝐴0−𝐴𝑓)/𝐴0 〗

-1.00000

-1.50000

-2.00000

-2.50000
T

0.1 T 1/T Kobs Kreal


6.76E-05 298.15 1 2135.4 3158875.74
313.15 2 3993.7 5907840.237
333.15 3 10496.7 15527662.72
Solución D

Ln((A-Af)/A)
-0.10444 - -
-0.11817 -0.05936 -0.09594
-0.13304 -0.06233 -0.15924
-0.14966 -0.07438 -0.28205
-0.17022 -0.08975 -0.51547
-0.19416 -0.10592 -0.92676
-0.22040 -0.12595 -1.36098
-0.25131 -0.15297 -2.11021
-0.28539 -0.17905 -
-0.32721 -0.21825 -
-0.37548 -0.26469 -
-0.43532 -0.31508 -
-0.50353 -0.37469 -
-0.57808 -0.44183 -
-0.69315 -0.53900 -
-0.82668 -0.69315 -
-0.99853 -0.88730 -
-1.22378 -1.17007 -
-1.52606 -1.60944 -
-2.30259 -2.03688 -
- - -

t vs. ln⁡〖 (𝐴0−𝐴𝑓)/𝐴0 〗


0000
0 2 4= −=0.082007527902053
f(x)f(x) 6 8 10x +x0.208212784020231
− 0.085215324461156 12 14 16
+ 0.272195792699681 18 20

0000

0000

0000

0000

0000
T(min)

17

LnKreal 16.5
14.965726744 f(x) = 0.796203469644509 x + 14.1128101630533
R² = 0.985007311454224
15.59179088 16
16.558133683
LnKreal

15.5

15

14.5
16.5
f(x) = 0.796203469644509 x + 14.1128101630533
R² = 0.985007311454224
16

LnKreal
15.5

15

14.5

14
0.5 1 1.5 2 2.5 3 3.5
1/T
3.5

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