4.4.

2 Energy Balance for Sulphur Burner

Stream 2

Sulphur

(l, T= 131.8˚C, P=15 atm)

Stream 4 Dry Air

Stream 5 SO2 N2
(g, T= 142.8˚C, P=15 atm)
(l, T= 1127˚C, P=15 atm)
O2

N2

ENERGY BALANCE FOR SULPHUR BURNER

Inlet Outlet
Stream
Stream 2 Stream 4 Stream 5
Molar Molar Molar
Enthalpy Enthalpy
Components flowrate flowrate flowrate Enthalpy (kJ/kmol)
(kJ/kmol) (kJ/kmol)
(kmol/hr) (kmol/hr) (kmol/hr)
O2 - - 58.023 1016.1457 - -
N2 - - 218.277 890.0986 266.23 3017.3082
SO2 - - - - 70.77 6890.7130
S 118.82 177.646 - - - -
Total nH 21107.95 nH 253247.8741 nH 1290953.72
Q (kW) 574.7007

STREAM IN

Stream 2

ΔHsulphur

(l, 25˚C, 1atm) (l, 131.8 ˚C, 15atm)

ΔH1 ΔH2

(l, 131.8˚C, 1atm)

 T
Δ H sulphur = ∫ Cp dT + ṽΔP
Tref

T
1
Δ H sulphur = ∫ Cp dT +( ) ΔP
Tref ρ @25 ˚ C

131.8˚ C
1 kg
Δ H sulphur = ∫
25 ˚C
−3 −5
15.2 x 10 +2.68 x 10 T +
kg
2070 3
(256.53 mol ) ( 1519.88−101.32 ) ( 1 kPa1 kJ.m ) 3

Δ H sulphur =1.8478+175.7986

Δ H sulphur =177.6464 kJ /kmol

kmol kJ
n sulphur H sulphur =118.8 x 177.6464
hr kmol

n sulphur H sulphur =21107.95 kJ /hr

Stream 4

ΔHoxygen

(g, 25˚C, 1atm) (g, l42.8 ˚C, 15atm)

ΔH1 ΔH2

(g, 142.8˚C, 1atm)

T
Δ H oxygen= ∫ Cp dT + ṽΔP
Tref

T
RT
Δ H oxygen= ∫ Cp dT + ΔP
Tref P

142.8 ˚C
( 0.0815 kPa .m3 kg . K ) ( 416 K ) kg
Δ H oxygen= ∫
25 ˚C
−3
29.10 x 10 +1.158 x 10 T +(
−5
1519.88 kPa
)(32
kmol (
) ( 1519.88−101.32 )
1

Δ H oxygen=3.5424+ 1012.6033

Δ H oxygen=1016.1457 kJ /kmol
 kmol kJ
n oxygen H oxygen=58.023 x 1016.1457
hr kmol

n oxygen H oxygen=58959.8220 kJ /hr

ΔHnitrogen

(l, 25˚C, 1atm) (l, 142.8 ˚C, 15atm)

ΔH1 ΔH2

(l, 142.8˚C, 1atm)

T
Δ H nitrogen = ∫ Cp dT + ṽΔP
Tref

T
RT
Δ H nitrogen = ∫ Cp dT + ΔP
Tref P

142.8 ˚C
−3 −5 ( 0.0815 kPa . m3 kg . K ) ( 416 K ) kg
Δ H nitrogen = ∫ 29.00 x 10 +0.2199 x 10 T +( )(28.02 ) ( 1519.88−101.3
25 ˚C 1519.88 kPa kmol

Δ H nitrogen =3.4379+886.6607

Δ H nitrogen =890.0986 kJ /kmol

kmol kJ
n nitrogen H nitrogen =218.277 x 890.0986
hr kmol

n nitrogen H nitrogen =194288.0521 kJ /hr

kj kJ
Total stream 4 = 58959.8220 +194288.0521
hr hr

= 253247.8741 kJ /hr
STREAM OUT

Stream 5

ΔHSO2

(g, 25˚C, 1atm) (g, 1127 ˚C, 15atm)

ΔH1 ΔH2

(g, 1127˚C, 1atm)

T
Δ H SO 2= ∫ CpdT + ṽΔP
Tref

T
RT
Δ H SO 2= ∫ CpdT + ΔP
Tref P

1127 ˚C
( 0.0815 kPa . m3 kg . K ) ( 1400 K ) kg
Δ H SO 2= ∫
25˚ C
−3 −5
38.91 x 10 +3.904 x 10 T +(
1519.88 kPa
)(64.07
kmol
) ( 1519.88−101.32 )
(
Δ H SO 2=67.6595+6823.0535

Δ H SO 2=6890.7130 kJ /kmol

kmol kJ
n SO 2 H SO 2 =(0.21)(337) x 6890.7130
hr kmol

n SO 2 H SO 2 =487655.759 kJ /hr

ΔHnitrogen

(l, 25˚C, 1atm) (l, 1127 ˚C, 15atm)

ΔH1 ΔH2

(l, 1127˚C, 1atm)

T
Δ H nitrogen = ∫ Cp dT + ṽΔP
Tref

T
RT
Δ H nitrogen = ∫ Cp dT + ΔP
Tref P
 1127 ˚ C
−3 −5 ( 0.0815 kPa . m3 kg . K ) ( 1400 K ) kg
Δ H nitrogen = ∫ 29.00 x 10 +0.2199 x 10 T +( )(28.02 ) ( 1519.88−101.
25˚ C 1519.88 kPa kmol

Δ H nitrogen =33.3538+2983.9544

Δ H nitrogen =3017.3082 kJ /kmol

kmol kJ
n nitrogen H nitrogen =(0.79)(337) x 3017.3082
hr kmol

n nitrogen H nitrogen =803297.9671 kJ /hr

Q=∑ noutHout −∑ ninHin

kJ kJ
Q=(803297.9671+487655.759) −( 21107.95+253247.8741 )
hr hr

kJ hr
Q=1016597.902 x1
hr 3600 s

Q=282.3883kW