SYD Recycling Guide Batteries PDF
SYD Recycling Guide Batteries PDF
Guidelines
Revised 09/2015
www.veolianorthamerica.com
Contents:
Battery Packaging Guidelines ................................................................................................................ 3
Alkaline Batteries, Dry-Cell ................................................................................................................. 6
Lead Acid Batteries, Wet-Cell ............................................................................................................. 7
Lead Acid Batteries, Non-Spillable ..................................................................................................... 8
Lithium Metal Batteries ..................................................................................................................... 10
Lithium Ion Batteries......................................................................................................................... 12
Magnesium Batteries........................................................................................................................ 14
Mercury Batteries ............................................................................................................................. 15
Nickel Cadmium Batteries, Wet-Cell................................................................................................. 16
Nickel Cadmium Batteries, Dry-Cell ................................................................................................. 17
Nickel Metal Hydride Batteries ......................................................................................................... 18
Silver Oxide Batteries ....................................................................................................................... 19
Carbon Zinc Batteries....................................................................................................................... 20
Battery Appendix ................................................................................................................................. 21
Historically, there were several incidents reported where a fire occurred as a result of small batteries being improperly packed
in a drum. Veolia’s goal is to assure that all batteries it manages are properly packaged and therefore the risk of such an
incident occurring is minimized.
All batteries pose potential hazards during transportation, therefore it is imperative that all batteries comply with the proper US
Department of Transportation (USDOT) packaging requirements that are referenced in this document. These guidelines were
specifically developed to address the shipment of batteries by highway, rail and cargo vessel. Additional requirements may
apply to air shipments.
Only chemically compatible battery types should be packed in the same package. Do not mix acidic batteries with
alkaline batteries.
USDOT requires that all batteries be packaged in a manner to prevent short circuiting and damage to the terminals.
Acceptable methods for short circuit prevention and terminal protection are described in the next section of this
document
Note that batteries with recessed terminals in which damage to the terminals or short circuits would not occur and
those batteries that fall under the exception for 9-volts or less as described below do not require additional short
circuit protection.
All methods employed to protect from short circuit and to protect the terminals of the batteries must be adequate to
withstand conditions normally incident to transportation. This includes the effects of shifting and vibration caused
during transportation and subsequent handling!
All batteries should be stored in a cool, dry environment.
Leaking batteries must be individually packaged and may require shipment as an EPA hazardous waste.
Incident reporting in accordance with §171.16 is required for ALL incidents involving shipments of batteries or
battery-powered devices including fire, violent rupture, explosion, or a dangerous evolution of heat. This requirement
applies to all battery shipments, including batteries that are excepted from the HMR requirements.
Exception for Spent Batteries of the Type “Batteries, Dry, Sealled, n.o.s.”
With a Marked rating of 9-volts or Less
In accordance with 49 CFR 172.102, Special Provision 130, used or spent dry, sealed batteries of both non-rechargeable
and rechargeable designs, described as “Batteries, dry, sealed, n.o.s.” and are not specifically covered by another proper
shipping name, with a marked rating up to 9-volts are not likely to generate a dangerous quantity of heat, short circuit, or
create sparks in transportation. Therefore, used or spent batteries of the type “Batteries, dry, sealed, n.o.s.” with a
marked rating of 9-volts or less that are combined in the same package and transported by highway or rail for recycling,
reconditioning, or disposal are not subject to the regulation and do not require terminal protection or protection against
short circuiting. Note that batteries utilizing different chemistries ( i.e., those battery chemistries specifically covered by
another entry in the §172.101 Table) as well as dry batteries with a marked rating greater than 9-volt may not be
combined with used or spent batteries in the same package.
The battery specific packaging information contained in this document is strictly to be used as guidance when packaging
batteries. Per USDOT regulation and agency guidance documents, any electrical device, even one not otherwise subject to
the HMR (either by specific exception from the HMR, or because the device and its power source contains no material meeting
the definition of a hazardous material), is forbidden from being offered for transportation, or transported, if the device is likely to
create sparks or a dangerous evolution of heat, unless packaged in a manner that precludes such an occurrence.
For some batteries the packaging guidelines contained within this document may be more stringent than the USDOT
packaging requirements. If circumstances dictate the use of a packaging method that is authorized by the USDOT but not
listed in this document is required, authorization must be obtained from the Veolia Corporate Transportation Department.
Exceptions to these packaging procedures must be approved by Veolia Branch and Corporate EHS&T management.
Packaging policy exceptions will only be approved when it can be shown that (1) the alternative packaging scenario complies
with USDOT requirements, and (2) the packaging required by company policy is not feasible or practical to use given the
unique characteristics of the batteries or the customer project.
The document will be amended as additional information regarding battery packaging is available.
To prevent short circuiting the USDOT has identified the following methods as acceptable methods of short circuit protection:
1. Packaging each battery or each battery-powered device when practicable, in fully enclosed inner packagings made of
non-conductive material.
2. Reattach the manufacturer’s original terminal caps/covers and further secure the covers in place with tape if loose or
seem likely to fall off during transportation/handling.
3. Separating or packaging batteries and battery-powered devices in a manner to prevent contact with other batteries,
devices or conductive materials (e.g., metal) in the packagings.
4. Ensuring exposed terminals are protected with non-conductive caps, non-conductive tape, or by other appropriate
means. Proper insulation includes taping the terminals of the batteries or packaging in individual clear plastic bags.
Clear tape is required for small batteries so that battery identification is still possible. The tape or protective covering
must be of sufficient durability and secured in a manner that it remains intact and abrasion-free during
transportation/handling. Other forms of insulation may also be used provided they do not obscure the battery
identification markings.
To prevent damage to terminals the USDOT has identified the following methods as acceptable methods for protecting battery
terminals:
Since these units will typically require a qualified electrician to remove them from service, it is recommended that the
electrician disconnects the batteries at the same time. Under no circumstances should industrial battery power supplies be
transported with the batteries in place and electrically connected.
Typical Uses: Flashlights, cameras, portable radios, audio players, and toys.
Composition: Alkaline batteries have a zinc anode and a manganese dioxide cathode. The electrolyte used in an alkaline
battery is a paste of either potassium hydroxide or sodium hydroxide. Each of these components, along with conductors and
separators are then assembled into or contained within a hermetically sealed unit. Typical household size alkaline battery is a
1.5 volt (AA, AAA, C, D).
US DOT Description:
Proper Shipping Name Batteries, dry, sealed, n.o.s.
Hazard Class N/A (NONE)
Identification Number N/A
Packing Group N/A
Batteries must be packaged in strong outer packagings or, if large enough, firmly secured to pallets capable of withstanding
the shocks normally incident to transportation.
Exception for Spent Batteries of the Type “Batteries, Dry, Sealed, n.o.s.” with a Marked Rating of 9-Volts or Less
Used or spent dry, sealed batteries of both non-rechargeable and rechargeable designs, described as “Batteries, dry, sealed,
n.o.s.” and are not specifically covered by another proper shipping name, with a marked rating up to 9-volts are not likely to
generate a dangerous quantity of heat, short circuit, or create sparks in transportation. Therefore, used or spent batteries of
the type “Batteries, dry, sealed, n.o.s.” with a marked rating of 9-volts or less that are combined in the same package and
transported by highway or rail for recycling, reconditioning, or disposal are not subject to the regulation and do not require
terminal protection or protection against short circuiting. Note that batteries utilizing different chemistries (i.e., those battery
chemistries specifically covered by another entry in the §172.101 Table) as well as dry batteries with a marked rating greater
than 9-volt may not be combined with used or spent batteries in the same package.
NOTE: Multiple 1.5-volt alkaline batteries interconnected or grouped in series are not included in this exception and must
continue to be packaged in accordance with SP130 (terminals must be protected against damage and short circuits).
US EPA Regulations: Since this class of battery does not fail the TCLP nor does it contain any free liquids, it is not classified
as a hazardous waste as defined by the US EPA and as such, is not subject to the universal waste requirements. Individual
states may adopt more stringent regulations than the federal regulations; therefore, alkaline batteries may be classified as a
universal waste in some states.
Composition: Lead acid batteries have a lead anode and a lead dioxide cathode. The electrolyte is an aqueous solution of
sulfuric acid. The battery cell contains 60 to 75 percent lead and lead oxide, by weight, and the electrolyte contains between
28 and 51 percent sulfuric acid, by weight.
US DOT Description:
Proper Shipping Name Batteries, wet, filled with acid
Hazard Class 8
Identification Number UN2794
Packing Group PG III
Non-Bulk Containers:
Specification packages listed in 49 CFR §173.159(c). The most common of these containers are the 4G fiberboard
box, the 1G fiberboard drum and the 1H2 poly drum. Metal drums are not authorized for shipping wet cell batteries,
To prohibit battery movement within drums or boxes, the use of folded cardboard, “honeycomb” cardboard or other
bulky packing materials should be utilized. The use of vermiculite, floor dry or other granular absorbents is not
recommended and may be subject to additional charges.
Batteries must be shipped in an upright configuration and must be secured within the package to prevent the battery
from reorienting in transport.
1H2 poly drums larger than 5 gallons should not be used for the transport of lead acid batteries. As an
alternative, multiple, larger-sized batteries should be secured to pallets for transport or packaged in lined 1G
fiberboard drums.
Palletized Batteries:
When secured to a pallet for transport, non-conductive strapping must be used. Metal banding is not permissible
due to the potential risk of short circuiting. When using non-conductive banding to secure batteries to pallets,
precautions should be taken to assure any metal clips used to connect the banding straps do not come in contact
with exposed battery terminals.
Firmly secured to skids or pallets capable of withstanding the shocks normally incident to transportation. The pallet
must not exceed a height of 1.5 times the width of the pallet and must be capable of withstanding a superimposed
weight of 2 times the weight of the pallet. The battery terminals must not be relied upon to support any of the
superimposed weight and must not short out if a conductive material is placed in direct contact with them,
US EPA Regulations: Rules specific to the recycling of lead acid batteries are contained in 40 CFR part 266 Subpart G. As
an alternative to this section, generators of lead acid batteries may choose to manage their lead acid batteries in accordance
with the universal waste standards. When managed as a universal waste, each battery or each package containing batteries
must be marked with the words “Universal Waste Batteries,” “Waste Batteries,” or “Used Batteries.” Broken or damaged
batteries that no longer qualify for either the recycling exemption or the universal waste exemption must be managed as a
hazardous waste. The RCRA waste codes D002 and D008 apply when the batteries or containers hold liquid electrolyte. The
RCRA waste code D008 only applies to batteries or containers that have no liquids within them.
Typical Uses: Camcorders, computers, portable radios, lawn equipment, portable industrial equipment, marine applications
Composition: Like wet cell lead acid batteries, non-spillable or Valve Regulated Lead Acid (VRLA) batteries also have a lead
anode, a lead dioxide cathode, and an aqueous sulfuric acid electrolyte. However, because of the way in which non-spillable
batteries are manufactured, the electrolyte will not spill out of the battery. Although somewhat of a misnomer, these batteries
are often referred to as sealed lead acid batteries. There are two primary categories of non-spillable batteries:
1. Absorbed glass mat (AGM) batteries, these batteries contain a liquid electrolyte that is absorbed into a glass mat
sandwiched between the electrodes.
2. Gel cell batteries, these are batteries which have a chemical added to the electrolyte which causes it to form a gel
which will not spill from the battery.
Non-spillable batteries authorized to be shipped under the below listed shipping name and packaging standards must be
clearly marked “NONSPILLABLE” or “NONSPILLABLE BATTERY” by the manufacturer.
US DOT Description:
Proper Shipping Name Batteries, wet, non-spillable
Hazard Class 8
Identification Number UN2800
Packing Group PG III
The batteries and outer packaging must be plainly and durable marked “NONSPILLABLE” or “NONSPILLABLE BATTERY”.
1. 1H2 poly drums larger than 5 gallons should not be used for the transport of lead acid batteries. As an
alternative, larger quantities of small non-spillable batteries should be packaged in lined 1G fiberboard drums.
2. Larger batteries, comparable to an automotive battery should be packaged following the packaging requirements of
49 CFR §173.159. (See the ‘Lead Acid, Wet Cell’ guidelines for packaging requirements of 49 CFR §173.159)
3. Batteries must be shipped in an upright configuration and must be packaged to prevent the battery from reorienting in
transport.
4. To secure batteries within drums or boxes, the use of folded cardboard, “honeycomb” cardboard or other bulky
packing materials should be utilized. The use of vermiculite, floor dry or other granular absorbents is not
recommended and may be subject to additional charges.
Broken or damaged batteries that no longer qualify for either the recycling exemption or the universal waste exemption must
be managed as a hazardous waste. The RCRA waste codes D002 and D008 apply when the batteries or containers hold
liquid electrolyte. The RCRA waste code D008 applies only to batteries or containers that have no liquids within them.
Composition: These cells and batteries are constructed with metallic lithium. The metallic lithium in a non-rechargeable
primary lithium battery is a combustible alkali metal that self-ignites at 352°F, and when exposed to water or seawater reacts
exothermically and releases hydrogen. Lithium metal batteries include lithium alloy batteries.
The table below lists several of the most common types of lithium batteries.
US DOT Description:
Lithium metal Lithium metal batteries Lithium metal batteries packed
Proper Shipping Name
batteries contained in equipment with equipment
Hazard Class 9 9 9
Identification Number UN3090 UN3091 UN3091
No PG
No PG No PG
Packing Group (PG II optional until
(PG II optional until 1/1/16) (PG II optional until 1/1/16)
1/1/16)
Due to the high degree of hazard presented by lithium batteries additional packaging restrictions are necessary to ensure the
safety of the general public as well as Veolia employees and facilities. These include applying short circuit protection to ALL
battery terminals and restricting the methods of short circuit protection to packaging lithium batteries individually in clear plastic
bags or packages or using clear tape over the terminals. This includes lithium batteries with recessed terminals and terminals
contained within plugs attached to the battery.
Lithium batteries and cells transported for recycling or disposal by motor vehicle only:
Packaged in non-bulk strong outer packagings, 49 CFR §173.185(d)
Strong outer packages must meet general packaging requirements of 49 §§173.24 and 173.24a
Not subject to testing and recordkeeping requirements of 49 CFR §173.185(a).
Lithium batteries shipped by vessel must be in UN specification packaging (PG II) per 173.185(b)(3).
US EPA Regulations: Lithium metal is a water reactive metal. As such lithium batteries should be managed as a universal
waste in accordance with 40 CFR Part 273. All containers of universal waste batteries must be marked with the words
“Universal Waste Batteries,” “Waste Batteries,” or “Used Batteries.”
Typical Uses: Cameras, computers, phones, power tools, etc. Various sizes including AAA, AA and button cell. Lithium ion
batteries are often contained in non-standard sizes and shape battery packs used for special applications. Button cells with
codes beginning in LIR are lithium ion.
Composition: Rechargeable secondary cells utilize lithium ions that are intercalated into graphite, lithium metal oxides and/or
lithium salts. Common metal oxides and salts include lithium cobalt oxide, lithium manganese oxide and lithium iron
phosphate. Metallic lithium is not used as either the anode or cathode in a lithium ion battery. The electrolyte in a lithium ion
battery is typically and organic solvent. Organic solvents may include one or more of the following: propylene carbonate,
dioxolane, dimethoxyethane, ethylene carbonate. Lithium ion batteries include lithium ion polymer batteries.
US DOT Description:
Lithium ion batteries Lithium ion batteries packed
Proper Shipping Name Lithium ion batteries
contained in equipment with equipment
Hazard Class 9 9 9
Identification Number UN3480 UN3481 UN3481
No PG
No PG No PG
Packing Group (PG II optional until
(PG II optional until 1/1/16) (PG II optional until 1/1/16)
1/1/16)
Due to the degree of hazard presented by lithium batteries additional packaging restrictions are necessary to ensure the safety
of the general public as well as Veolia employees and facilities. These include applying short circuit protection to ALL battery
terminals and restricting the methods of short circuit protection to packaging lithium batteries individually in clear plastic bags
or packages or using clear tape over the terminals. This includes lithium batteries with recessed terminals and terminals
contained within plugs attached to the battery.
Lithium batteries and cells transported for recycling or disposal by motor vehicle only:
Packaged in non-bulk strong outer packagings, 49 CFR §173.185(d)
Strong outer packages must meet the general packaging requirements of 49 §§173.24 and 173.24a
Not subject to testing and recordkeeping requirements of 49 CFR §173.185(a).
Lithium batteries shipped by vessel must be in UN specification packaging (PG II) per 173.185(b)(3).
Exceptions for small and medium sized lithium cells/batteries – Relief from certain DOT requirements can be found in 49
CFR §173.185(c) for certain small lithium metal and lithium ion cells and batteries. Special hazard communication and marking
requirements will need to be met.
Damaged, Defective or Recalled Cells or Batteries – According to §173.185(f), lithium cells or batteries that have been
damaged or identified as defective and have the potential of producing a dangerous evolution of heat, fire, or short circuit may
be transported by highway, rail or vessel only, and must be packaged as follows:
US EPA Regulations: Lithium metal is a water reactive metal. As such lithium batteries should be managed as a universal
waste in accordance with 40 CFR Part 273. All containers of universal waste batteries must be marked with the words
“Universal Waste Batteries,” “Waste Batteries,” or “Used Batteries.”
TYPICAL USES: Flashlights, cameras, portable radios, audio players, and toys.
COMPOSITION: Magnesium batteries have a magnesium anode, manganese dioxide cathode, and an electrolyte of a paste
containing magnesium bromide or magnesium perchlorate with a chromate inhibitor to prevent corrosion to the magnesium
anode. Each of these components, along with conductors and separators are then typically assembled into or contained within
a hermetically sealed unit. If the battery is not a hermetically sealed unit, the battery should be considered a specialty battery
and the following information is not applicable. For assistance in determining the proper packaging for these specialty batteries
please contact customer service.
US DOT DESCRIPTION:
Proper Shipping Name Batteries, dry, sealed, n.o.s.
Hazard Class N/A (NONE)
Identification Number N/A
Packing Group N/A
Batteries must be packaged in strong outer packagings or, if large enough, firmly secured to pallets capable of withstanding
the shocks normally incident to transportation.
EXCEPTION FOR SPENT BATTERIES OF THE TYPE “BATTERIES, DRY, SEALED, N.O.S.” WITH A MARKED RATING
OF 9-VOLTS OR LESS
In accordance with 49 CFR 172.102, Special Provision 130, used or spent dry, sealed batteries of both non-rechargeable and
rechargeable designs, described as “Batteries, dry, sealed, n.o.s.” and are not specifically covered by another proper shipping
name, with a marked rating up to 9-volts are not likely to generate a dangerous quantity of heat, short circuit, or create sparks
in transportation. Therefore, used or spent batteries of the type “Batteries, dry, sealed, n.o.s.” with a marked rating of 9-volts
or less that are combined in the same package and transported by highway or rail for recycling, reconditioning, or disposal are
not subject to the regulation and do not require terminal protection or protection against short circuiting. Note that batteries
utilizing different chemistries ( i.e., those battery chemistries specifically covered by another entry in the §172.101 Table) as
well as dry batteries with a marked rating greater than 9-volt may not be combined with used or spent batteries in the same
package.
US EPA REGULATIONS: Based on the original composition and charge state of the battery, these batteries may fail the
TCLP for chromium. As such magnesium batteries should be managed as a universal waste in accordance with 40 CFR Part
273. All containers of universal waste batteries must be marked with the words “Universal Waste Batteries,” “Waste Batteries,”
or “Used Batteries.”
COMPOSITION: Mercury batteries have a zinc anode and a mercuric oxide cathode. The electrolyte used in a mercury
battery is a paste of either potassium hydroxide or sodium hydroxide. Each mercury cell contains a total of 20 to 50 percent
mercury by weight. Each of these components, along with conductors and separators are then assembled into or contained
within a hermetically sealed unit.
US DOT DESCRIPTION:
Packages containing less than 3 pounds of mercury batteries
Packages which contain greater than 3 pounds of mercury batteries meet the US DOT definition of a hazardous substance
and must be prepared for transport in accordance with the US DOT regulations using the proper shipping name “RQ
Environmentally hazardous substance solid, n.o.s. (Mercury)”.
EXCEPTION FOR SPENT BATTERIES OF THE TYPE “BATTERIES, DRY, SEALED, N.O.S.” WITH A MARKED RATING
OF 9-VOLTS OR LESS
Used or spent dry, sealed batteries of both non-rechargeable and rechargeable designs, described as “Batteries, dry, sealed,
n.o.s.” and are not specifically covered by another proper shipping name, with a marked rating up to 9-volts are not likely to
generate a dangerous quantity of heat, short circuit, or create sparks in transportation. Therefore, used or spent batteries of
the type “Batteries, dry, sealed, n.o.s.” with a marked rating of 9-volts or less that are combined in the same package and
transported by highway or rail for recycling, reconditioning, or disposal are not subject to the regulation and do not require
terminal protection or protection against short circuiting. Note that batteries utilizing different chemistries (i.e., those battery
chemistries specifically covered by another entry in the §172.101 Table) as well as dry batteries with a marked rating greater
than 9-volt may not be combined with used or spent batteries in the same package.
US EPA REGULATIONS: Mercury batteries typically fail the TCLP for mercury. As such, all mercury batteries should be
managed as a universal waste in accordance with 40 CFR Part 273. All containers of universal waste batteries must be
marked with the words “Universal Waste Batteries,” “Waste Batteries,” or “Used Batteries.”
When not shipped as universal waste, the RCRA Waste code D009 (mercury) would need to be included on the manifest.
Composition: Nickel cadmium (NiCd) batteries have a cadmium anode and a nickel oxyhydroxide cathode. The electrolyte
within a wet cell NiCd battery is an aqueous solution of potassium hydroxide.
US DOT Description:
Proper Shipping Name Batteries, wet, filled with alkali
Hazard Class 8
Identification Number UN2795
Packing Group PG III
1. Specification packages listed in §173.159(c). The most common of these containers are the 4G fiberboard box and
the 1H2 poly drum. Metal drums are not authorized for shipping wet cell batteries,
2. Firmly secured to skids or pallets capable of withstanding the shocks normally incident to transportation. The pallet
must not exceed a height of 1.5 times the width of the pallet and must be capable of withstanding a superimposed
weight of 2 times the weight of the pallet. The battery terminals must not be relied upon to support any of the
superimposed weight and must not short out if a conductive material is placed in direct contact with them,
3. In accordance with one of the other packaging alternatives not specifically listed above.
US EPA Regulations: Wet cell NiCd batteries contain a liquid electrolyte which exhibits the characteristic of corrosivity and
when tested will fail the TCLP for cadmium. As such, wet cell NiCd batteries should be managed as a universal waste in
accordance with 40 CFR Part 273. All containers of universal waste batteries must be marked with the words “Universal Waste
Batteries,” “Waste Batteries,” or “Used Batteries.”
When not shipped as a universal waste, the RCRA Waste code D002 (Corrosivity) and D006 (cadmium) would need to be
included on the manifest.
Typical Uses: Cameras, rechargeable appliances such as portable power tools, hand held vacuums, etc.
Composition: Dry cell nickel cadmium (NiCd) batteries have a cadmium anode and nickel oxyhydroxide cathode. The
electrolyte used in a dry cell NiCd battery is a paste of potassium hydroxide. Each of these components, along with conductors
and separators are then assembled into or contained within a hermetically sealed unit.
US DOT Description:
Proper Shipping Name Batteries, dry, sealed, n.o.s.
Hazard Class N/A
Identification Number N/A
Packing Group N/A
Batteries must be packaged in strong outer packagings or, if large enough, firmly secured to pallets capable of withstanding
the shocks normally incident to transportation.
Exception for Spent Batteries of the Type “Batteries, Dry, Sealed, n.o.s.” with a Marked Rating of 9-Volts or Less
Used or spent dry, sealed batteries of both non-rechargeable and rechargeable designs, described as “Batteries, dry, sealed,
n.o.s.” and are not specifically covered by another proper shipping name, with a marked rating up to 9-volts are not likely to
generate a dangerous quantity of heat, short circuit, or create sparks in transportation. Therefore, used or spent batteries of
the type “Batteries, dry, sealed, n.o.s.” with a marked rating of 9-volts or less that are combined in the same package and
transported by highway or rail for recycling, reconditioning, or disposal are not subject to the regulation and do not require
terminal protection or protection against short circuiting. Note that batteries utilizing different chemistries (i.e., those battery
chemistries specifically covered by another entry in the §172.101 Table) as well as dry batteries with a marked rating greater
than 9-volt may not be combined with used or spent batteries in the same package.
SPECIAL REQUIREMENTS FOR "UN3208, Batteries dry containing potassium hydroxide solid, 8, III"
USDOT regulations contain Special provision 237 for the shipping name "Batteries, dry, containing potassium hydroxide solid,
electric storage". SP 237 states that the batteries must be prepared and packaged in accordance with the requirements of
173.159(a), (b), and (c) and that for transportation by aircraft, the provisions of 173.159(b)(2). On January 7, 2013 (HM-215L)
USDOT modified SP 237 by clarifying the applicability of the provision. Specifically language was added to state that the entry
for ``Batteries, dry, containing potassium hydroxide solid, electric storage'' may only be used for the transport of non-activated
batteries that contain dry potassium hydroxide and that are intended to be activated prior to use by the addition of an
appropriate amount of water to the individual cells. Therefore, spent or used dry cell Ni-Cad batteries that don't meet these
specifications described above should be assigned the proper shipping name “Batteries, dry, sealed, n.o.s. (Nickel Cadmium
Batteries)”.
US EPA Regulations: Dry cell NiCd batteries typically will fail the TCLP for cadmium. As such, dry cell NiCd batteries should
be managed as a universal waste in accordance with 40 CFR Part 273. All containers of universal waste batteries must be
marked with the words “Universal Waste Batteries,” “Waste Batteries,” or “Used Batteries.” When not shipped as a universal
waste, the RCRA Waste code D006 (cadmium) would need to be included on the manifest.
Typical Uses: Cameras, rechargeable appliances such as portable power tools, hand held vacuums, etc.
Composition: Nickel metal hydride (NiMH) batteries have a hydrogen-absorbing metal alloy anode and a nickel oxyhydroxide
cathode. The electrolyte in a NiMH battery is typically a potassium hydroxide paste. Each of these components, along with
conductors and separators are then assembled into or contained within a hermetically sealed unit.
US DOT Description:
Proper Shipping Name Batteries, dry, sealed, n.o.s.
Hazard Class N/A
Identification Number N/A
Packing Group N/A
Batteries must be packaged in strong outer packagings or, if large enough, firmly secured to pallets capable of withstanding
the shocks normally incident to transportation.
Exception for Spent Batteries of the Type “Batteries, Dry, Sealed, n.o.s.” with a Marked Rating of 9-Volts or Less
Used or spent dry, sealed batteries of both non-rechargeable and rechargeable designs, described as “Batteries, dry, sealed,
n.o.s.” and are not specifically covered by another proper shipping name, with a marked rating up to 9-volts are not likely to
generate a dangerous quantity of heat, short circuit, or create sparks in transportation. Therefore, used or spent batteries of
the type “Batteries, dry, sealed, n.o.s.” with a marked rating of 9-volts or less that are combined in the same package and
transported by highway or rail for recycling, reconditioning, or disposal are not subject to the regulation and do not require
terminal protection or protection against short circuiting. Note that batteries utilizing different chemistries (i.e., those battery
chemistries specifically covered by another entry in the §172.101 Table) as well as dry batteries with a marked rating greater
than 9-volt may not be combined with used or spent batteries in the same package.
US EPA Regulations: Since this class of battery does not fail the TCLP nor does it contain any free liquids, it is not classified
as a hazardous waste as defined by the US EPA and as such, is not subject to the universal waste requirements. Individual
states may adopt more stringent regulations than the federal regulations; therefore, NiMH batteries may be classified as a
universal waste in some states.
Composition: Silver oxide batteries have a zinc anode and a silver oxide cathode. The electrolyte used in a silver oxide
battery is a potassium hydroxide or sodium hydroxide paste. Each of these components, along with conductors and separators
are then assembled into or contained within a hermetically sealed unit. In addition to the above materials, many of the older
silver oxide batteries contained a significant amount of mercury. Batteries containing both silver and mercury should be
managed as mercury batteries. The below listed information is for non-mercury containing silver oxide batteries.
US DOT Description:
Proper Shipping Name Batteries, dry, sealed, n.o.s.
Hazard Class N/A
Identification Number N/A
Packing Group N/A
Batteries must be packaged in strong outer packagings or, if large enough, firmly secured to pallets capable of withstanding
the shocks normally incident to transportation.
Exception for Spent Batteries of the Type “Batteries, Dry, Sealed, n.o.s.” with a Marked Rating of 9-Volts or Less
Used or spent dry, sealed batteries of both non-rechargeable and rechargeable designs, described as “Batteries, dry, sealed,
n.o.s.” and are not specifically covered by another proper shipping name, with a marked rating up to 9-volts are not likely to
generate a dangerous quantity of heat, short circuit, or create sparks in transportation. Therefore, used or spent batteries of
the type “Batteries, dry, sealed, n.o.s.” with a marked rating of 9-volts or less that are combined in the same package and
transported by highway or rail for recycling, reconditioning, or disposal are not subject to the regulation and do not require
terminal protection or protection against short circuiting. Note that batteries utilizing different chemistries (i.e., those battery
chemistries specifically covered by another entry in the §172.101 Table) as well as dry batteries with a marked rating greater
than 9-volt may not be combined with used or spent batteries in the same package.
US EPA Regulations: Silver oxide batteries typically will fail the TCLP for silver and older silver oxide batteries will typically
fail the TCLP for silver and mercury. As such, silver oxide batteries should be managed as a universal waste in accordance
with 40 CFR Part 273. All containers of universal waste batteries must be marked with the words “Universal Waste Batteries,”
“Waste Batteries,” or “Used Batteries.”
When not shipped as a universal waste, the RCRA Waste code D011 (silver) would need to be included on the manifest.
Composition: Carbon zinc batteries, often referred to as Heavy Duty Batteries, have a zinc anode and a cathode that
contains a mixture of manganese dioxide, carbon and electrolyte. The batteries also contain a carbon electrode that serves as
a cathode current collector. The electrolyte is an aqueous solution of ammonium chloride and zinc chloride or a solution of zinc
chloride. The electrolyte is mixed the other components of the battery to form a paste. Each of these components, along with
conductors and separators are then assembled into or contained within a hermetically sealed unit.
US DOT Description:
Proper Shipping Name Batteries, dry, sealed, n.o.s.
Hazard Class N/A (NONE)
Identification Number N/A
Packing Group N/A
Batteries must be packaged in strong outer packaging or, if large enough, firmly secured to pallets capable of withstanding the
shocks normally incident to transportation.
Exception for Spent Batteries of the Type “Batteries, Dry, Sealed, n.o.s.” with a Marked Rating of 9-Volts or Less
Used or spent dry, sealed batteries of both non-rechargeable and rechargeable designs, described as “Batteries, dry, sealed,
n.o.s.” and are not specifically covered by another proper shipping name, with a marked rating up to 9-volts are not likely to
generate a dangerous quantity of heat, short circuit, or create sparks in transportation. Therefore, used or spent batteries of
the type “Batteries, dry, sealed, n.o.s.” with a marked rating of 9-volts or less that are combined in the same package and
transported by highway or rail for recycling, reconditioning, or disposal are not subject to the regulation and do not require
terminal protection or protection against short circuiting. Note that batteries utilizing different chemistries (i.e., those battery
chemistries specifically covered by another entry in the §172.101 Table) as well as dry batteries with a marked rating greater
than 9-volt may not be combined with used or spent batteries in the same package.
US EPA Regulations: Since this class of battery does not fail the TCLP nor does it contain any free liquids, it is not classified
as a hazardous waste as defined by the US EPA and as such, is not subject to the universal waste requirements. Individual
states may adopt more stringent regulations than the federal regulations; therefore, carbon zinc batteries may be classified as
a universal waste in some states.
The following contains excerpts from the US DOT regulations, 49 CFR Part 171-173, that are referenced in the guidance
document. For a complete version of the hazardous materials regulations consult the Code of Federal Regulations.
a) Incident reporting. For transportation by aircraft, a telephone report in accordance with §171.15(a) is required if a fire,
violent rupture, explosion or dangerous evolution of heat ( i.e., an amount of heat sufficient to be dangerous to
packaging or personal safety to include charring of packaging, melting of packaging, scorching of packaging, or other
evidence) occurs as a direct result of a dry battery. For all modes of transportation, a written report submitted,
retained, and updated in accordance with §171.16 is required if a fire, violent rupture, explosion or dangerous
evolution of heat occurs as a direct result of a dry battery or battery-powered device.
b) Preparation for transport. Batteries and battery-powered device(s) containing batteries must be prepared and
packaged for transport in a manner to prevent:
1) A dangerous evolution of heat;
2) Short circuits, including but not limited to the following methods:
i. Packaging each battery or each battery-powered device when practicable, in fully enclosed inner
packagings made of non-conductive material;
ii. Separating or packaging batteries in a manner to prevent contact with other batteries, devices or
conductive materials ( e.g., metal) in the packagings; or
iii. Ensuring exposed terminals or connectors are protected with non-conductive caps, non-conductive
tape, or by other appropriate means; and
3) Damage to terminals. If not impact resistant, the outer packaging should not be used as the sole means of
protecting the battery terminals from damage or short circuiting. Batteries must be securely cushioned and
packed to prevent shifting which could loosen terminal caps or reorient the terminals to produce short
circuits. Batteries contained in devices must be securely installed. Terminal protection methods include but
are not limited to the following:
i. Securely attaching covers of sufficient strength to protect the terminals;
ii. Packaging the battery in a rigid plastic packaging; or
iii. Constructing the battery with terminals that are recessed or otherwise protected so that the
terminals will not be subjected to damage if the package is dropped.
c) Additional air transport requirements. For a battery whose voltage (electrical potential) exceeds 9 volts-
1) When contained in a device, the device must be packaged in a manner that prevents unintentional activation
or must have an independent means of preventing unintentional activation ( e.g., packaging restricts access
to activation switch, switch caps or locks, recessed switches, trigger locks, temperature sensitive circuit
breakers, etc. ); and
2) An indication of compliance with this special provision must be provided by marking each package with the
words “not restricted” or by including the words “not restricted” on a transport document such as an air
waybill accompanying the shipment.
d) Used or spent battery exception. Used or spent dry batteries of both non-rechargeable and rechargeable designs,
with a marked rating up to 9-volt that are combined in the same package and transported by highway or rail for
recycling, reconditioning, or disposal are not subject to this special provision or any other requirement of the HMR.
Note that batteries utilizing different chemistries ( i.e., those battery chemistries specifically covered by another entry
in the §172.101 Table) as well as dry batteries with a marked rating greater than 9-volt may not be combined with
used or spent batteries in the same package. Note also that this exception does not apply to batteries that have been
reconditioned for reuse.
i. The outer package must be durably and legibly marked with the following handling marking, which
is durable, legible and displayed on a background of contrasting color:
A. The marking must be not less than 120 mm (4.7 inches) wide by 110 mm (4.3 inches) high
except markings of 105 mm (4.1 inches) wide by 74 mm (2.9 inches) high may be used on
a package containing lithium batteries when the package is too small for the larger
marking;
B. The symbols and letters must be black and the border must be red;
C. The “*” must be replaced by “lithium ion battery” and/or “Lithium metal battery” as
appropriate and the “xxx-xxx-xxxx” must be replaced by a telephone number for additional
information; and
D. When packages required to bear the handling marking are placed in an overpack, the
handling marking must either be clearly visible through the overpack, or the handling
marking must also be affixed on the outside of the overpack, and the overpack must be
marked with the word “Overpack”.
ii. Each shipment with packages required to bear the handling marking must include an indication the
shipment contains “lithium ion batteries” or “lithium metal batteries,” as appropriate, and when an
air waybill is used, an indication on the air waybill of compliance with this paragraph (c)(4) (or the
applicable ICAO Packing Instruction).
iii. For lithium batteries packed with, or contained in, equipment, the number of batteries in each
package is limited to the minimum number required to power the piece of equipment, plus two
spares, and the total net quantity (mass) of the lithium cells or batteries in the completed package
must not exceed 5 kg.
iv. Each person who prepares a package for transport containing lithium cells or batteries, including
cells or batteries packed with, or contained in, equipment in accordance with the conditions and
limitations in this paragraph, must receive adequate instruction on these conditions and limitations,
commensurate with their responsibilities.
Anode - The electrode where oxidation occurs in an electrochemical cell. It is the negative electrode on a battery.
Battery - A device consisting of one or more electrically connected electrochemical cells which is designed to receive, store,
and deliver electric energy.
Cathode - The electrode where reduction occurs in an electrochemical cell. It is the positive electrode on a battery.
Cell - A system consisting of an anode, cathode, and an electrolyte, plus such connections (electrical and mechanical) as may
be needed to allow the cell to deliver or receive electrical energy.
Electrolyte - A chemical compound (salt, acid, or base) that dissociates into electrically charged ions when dissolved in a
solvent. The resulting electrolyte (or electrolytic) solution is an ionic conductor of electricity.
Hermetically sealed - A device or unit that is sealed and for practical purposes is considered airtight.
Primary cells and batteries - Non-rechargeable cells and batteries.
Secondary cells and batteries - Rechargeable cells and batteries.