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Chapter 3 Practice

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86 views9 pages

Chapter 3 Practice

Uploaded by

cwod
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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Chapter 3 Practice

Matching 3-1
MATCH a structure below to each of the following descriptions and place the letter corresponding to the
structure in the blank.

1. Refer to Matching 3-1. __________ is an amino aldehyde.


2. Refer to Matching 3-1. __________ is an aromatic ketone.
3. Refer to Matching 3-1. __________ is a tertiary chloride.
4. Refer to Matching 3-1. __________ is a cyclic alkane with two cis methyl groups.
5. Circle and name each functional group in the following structure.

Structure 3-1
Label the indicated atoms in the structure below as 1°, 2°, 3°, or 4°.
6. Refer to Structure 3-1. This atom is __________.
7. Refer to Structure 3-1. This atom is __________.
8. Refer to Structure 3-1. This atom is __________.
9. Refer to Structure 3-1. This atom is __________.

Compounds 3-1
Label the following pairs of compounds as:

a. identical
b. constitutional isomers
c. stereoisomers

Place the letter of the correct answer in the blank to the left of the structures.

10. Refer to Compounds 3-1. __________

11. Refer to Compounds 3-1. __________

12. Refer to Compounds 3-1. __________

13. Provide proper IUPAC names for each compound.

(CH3)2CHCH2CH2CH(CH2CH3)CH2C(CH3)3
14. Provide proper IUPAC names for each compound.
15. Provide proper IUPAC names for each compound.

Representation
Consider the representation below to answer the following questions.

16. Refer to Representation. Provide the IUPAC name for compound Z.


17. Refer to Representation. Draw a constitutional isomer of compound Z that contains an isopropyl group.
18. Draw structures corresponding to each of the following names.

cis-1-sec-butyl-2-ethylcyclopentane
19. Draw structures corresponding to each of the following names.

3-cyclobutylpentane
20. Draw structures corresponding to each of the following names.

4-(2,2-dibromoethyl)-3,5-dichloroheptane
21. There are seven (7) constitutional isomers for cycloalkane formula C6H12. Draw them.
22. Cipro® (Ciprofloxacin) is a synthetic broad spectrum antibacterial agent. It was most recently in the news as
the antibiotic of choice for the treatment of anthrax. The structure of Cipro is shown below.
Circle the functional groups in the Cipro representation above.

Cipro
Predict the hybridization of the indicated atoms in Cipro.

23. Refer to Cipro. The hybridization of this nitrogen atom is __________.


24. Refer to Cipro. The hybridization of this carbon atom is __________.
25. Refer to Cipro. The hybridization of this carbon atom is __________.

Cipro Bond Angles


Predict the indicated bond angles in Cipro.

26. Refer to Cipro Bond Angles. Bond angle A. is __________ degrees.


27. Refer to Cipro Bond Angles. Bond angle B. is __________ degrees.
28. Put a box around the most polar bond in Cipro.
29. Draw the two stereoisomers of 1,3-dibromocyclobutane.
Chapter 3 Practice
Answer Section

PROBLEM

1. ANS:
B.

PTS: 1
2. ANS:
E.

PTS: 1
3. ANS:
C.

PTS: 1
4. ANS:
C.

PTS: 1
5. ANS:

PTS: 1
6. ANS:
4°

PTS: 1
7. ANS:
2°

PTS: 1
8. ANS:
3°

PTS: 1
9. ANS:
1°

PTS: 1
10. ANS:
b

PTS: 1
11. ANS:
c

PTS: 1
12. ANS:
a

PTS: 1
13. ANS:
4-ethyl-2,2,7-trimethyloctane

PTS: 1
14. ANS:
trans-1-tert-butyl-4-ethylcyclohexane or trans-1-(1,1-dimethylethyl)-4-ethylcyclohexane

PTS: 1
15. ANS:
3-methyl-5-isopropyloctane or 3-methyl-5-(1-methylethyl)octane

PTS: 1
16. ANS:
5-ethyl-3,4-dimethyloctane

PTS: 1
17. ANS:

PTS: 1
18. ANS:

PTS: 1
19. ANS:
PTS: 1
20. ANS:

PTS: 1
21. ANS:

PTS: 1
22. ANS:

PTS: 1
23. ANS:
sp3

PTS: 1
24. ANS:
sp2
PTS: 1
25. ANS:
sp3

PTS: 1
26. ANS:
120°

PTS: 1
27. ANS:
109.5°

PTS: 1
28. ANS:

PTS: 1
29. ANS:

PTS: 1

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