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Extra Practice Week 6

The document provides 13 practice chemistry problems related to thermochemistry and calculating enthalpy changes. For each problem, multiple choice answers are provided and the correct answers are listed at the end. The problems cover calculating enthalpy changes from thermochemical equations, determining standard enthalpies of formation, using Hess's law to calculate enthalpy changes from multiple reaction steps, and combustion reactions.

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147 views2 pages

Extra Practice Week 6

The document provides 13 practice chemistry problems related to thermochemistry and calculating enthalpy changes. For each problem, multiple choice answers are provided and the correct answers are listed at the end. The problems cover calculating enthalpy changes from thermochemical equations, determining standard enthalpies of formation, using Hess's law to calculate enthalpy changes from multiple reaction steps, and combustion reactions.

Uploaded by

Shawn
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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Week 6 Practices with Answers

Answers are posted at the end on the last page.

1. Given: 2 Al(s) + (3/2) O2(g)  Al2O3(s), ΔH° = –1,670 kJ/mol for Al2O3 (s).
Determine ΔH° for the reaction: 2Al2O3(s)  4Al(s) + 3O2(g).
A) 3,340 kJ/mol C) –3,340 kJ/mol E) –835 kJ/mol
B) 1,670 kJ/mol D) –1,670 kJ/mol

2. Given the thermochemical equation: 2 SO2 + O2  2 SO3, ΔH°rxn = –198 kJ/mol, what is the enthalpy
change for the decomposition of one mole of SO3?
A) 198 kJ/mol C) 99 kJ/mol E) –198 kJ/mol
B) –99 kJ/mol D) 396 kJ/mol

3. Given that CaO(s) + H2O(l)  Ca(OH)2(s), ΔH°rxn = –64.8 kJ/mol, how many grams of CaO must react in
order to liberate 525 kJ of heat?
A) 6.92 g B) 56.1 g C) 454 g D) 606 g E) 3.40 × 104 g

4. When 0.560 g of Na(s) reacts with excess F2(g) to form NaF(s), 13.8 kJ of heat is evolved at
standard-state conditions. What is the standard enthalpy of formation (ΔH°f) of NaF(s)?
A) 567 kJ/mol B) –24.8 kJ/mol C) –7.8 kJ/mol D) 24.8 kJ/mol E) –567 kJ/mol

5. The highly exothermic thermite reaction, in which aluminum reduces iron (III) oxide to elemental
iron, has been used by railroad repair crews to weld rails together.
2 Al(s) + Fe2O3(s)  2 Fe(s) + Al2O3(s) ΔH = –850 kJ
What mass of iron is formed when 725 kJ of heat are released?
A) 47 g B) 65 g C) 95 g D) 112 g E) 130 g

6. Which of the following has an enthalpy of a formation value (ΔHf) of zero?


A) H2O (g) B) O (g) C) H2O (l) D) O2 (g) E) O3 (g)

7. The equation for the formation reaction for hydrazine, N2H4, is


A) 2 N2H4(g)  2 NH3(g) + H2(g) D) 2 NH3(g) + H2(g)  N2H4(g)
B) N2(g) + 2 H2O(g)  N2H4(g) + O2(g) E) N2(g) +2 H2(g)  N2H4(g)
C) 2 NO2(g) + 6 H2(g)  N2H4(g) + 4 H2O(g)

8. Calculate the ΔH for the reaction: NO2(g) + CO(g)  CO2(g) + NO(g)


using the standard enthalpies of formation:
NO = 90 kJ/mol NO2 = 34 kJ/mol CO = –111 kJ/mol CO2 = –394 kJ/mol
A) 339 kJ B) 381 kJ C) –227 kJ D) –339 kJ E) 227 kJ

9. Ethanol, C2H5OH, is used as an additive in many gasoline mixtures. Calculate the ΔH°rxn for the
combustion of ethanol.
ΔH°f [C2H5OH(l)] = –277.7 kJ/mol; ΔH°f [CO2(g)] = –393.5 kJ/mol; ΔH°f [H2O(g)] = –241.8 kJ/mol.
C2H5OH(l) + 3 O2(g)  2 CO2(g) + 3 H2O(g)
A) –1234.7 kJ B) –751.1 kJ C) –357.6 kJ D) 357.6 kJ E) 1234.7 kJ
10. Use Hess's Law to calculate the enthalpy change for the reaction:
WO3(s) + 3 H2(g)  W(s) + 3 H2O(g)
from the following data:
2 W(s) + 3 O2(g)  2 WO3(s) ΔH = –1685.4 kJ
2 H2(g) + O2(g)  2 H2O(g) ΔH = –477.84 kJ
A) 125.9 kJ C) 364.9 kJ E) None of these choices is correct.
B) 252.9 kJ D) 1207.6 kJ

11. Calculate the enthalpy change for the reaction:


NO(g) + O(g)  NO2(g)
from the following data:
NO(g) + O3(g)  NO2(g) + O2(g) ΔH = –198.9 kJ
O3(g)  1.5 O2(g) ΔH = –142.3 kJ
O2(g)  2 O(g) ΔH = 495.0 kJ

A) –551.6 kJ B) –304.1 kJ C) 190.9 kJ D) 153.8 kJ E) 438.4 kJ

12. Calculate ΔH for the reaction:


C6H6(l) + 15/2 O2(g)  6 CO2(g) + 3 H2O(l)
given the following information:
6 C(graphite) + 3 H2(g)  C6H6(l) ΔH1 = +49.0kJ
C(graphite) + O2(g)  CO2(g) ΔH2 = –393.5kJ
H2(g) + O2(g)  H2O(l) ΔH3 = –285.8kJ

A) –630.3kJ B) –2597.8kJ C) –3169.4kJ D) –3267.4kJ E) +630.3kJ

13. Use Hess's Law to calculate the enthalpy change for the reaction:
WO3(s) + 3 H2(g)  W(s) + 3 H2O(g)
from the following data:
2 W(s) + 3 O2(g)  2 WO3(s) ΔH = –1685.4 kJ
2 H2(g) + O2(g)  2 H2O(g) ΔH = –477.84 kJ

A) 125.9 kJ C) 364.9 kJ E) None of these choices is correct.


B) 252.9 kJ D) 1207.6 kJ

Answers:
1A, 2C, 3C, 4E, 5C, 6D, 7E, 8C, 9A, 10A, 11B, 12D, 13A

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