Resource Exploration Week 3
Resource Exploration Week 3
Mineral Resource
Exploration
3.1 Introduction – 122
3.6 Questions – 219
References – 220
3. It is undertaken in various stages of investiga- means unknown territories where ore deposits
tion, each phase conditioned by the results of are not already known to be present (. Fig. 3.2).
The mineral deposits to explore now for the of the mineral deposit. The target is later drilled
mining companies are mainly hidden by leached to study the mineralization in depth; drilling is
and weathered outcrops, with soil or other cover. undertaken only in advanced mineral explora-
For this reason, very sophisticated exploration tion. In increasing order of cost per km2, the main
techniques are actually needed to find them since methods used in mineral exploration are remote
most mineral deposits located at or near the sensing, geological mapping, geophysical surveys,
Earth’s surface have probably been discovered. geochemical surveys, and drilling.
As a general rule, the first stage of prospection/ Regarding the exploration trends in the world,
exploration involves locating prospective deposits mining companies reacted to the poor market
using knowledge of ore genesis and occurrence conditions of the last years with a strong decrease
models. Thus, geological environments associated in their exploration expenditures. The result was a
with the wanted type of mineral deposit are tar- 19% decline in worldwide nonferrous metal explo-
get of investigation. Methods such as geological ration budgets in 2015, compared with the previ-
mapping and sampling, geophysical surveys, and ous year, with final investment of about USD 9.2
geochemical analysis are commonly used at an billion (SNL Metals &Mining). . Figure 3.3 shows
early stage of exploration to define potential ore the main destinations for nonferrous exploration
deposits. Thus, the goal of geophysical/geochemi- in 2015. Nonferrous exploration means to look
cal exploration is to find an anomaly something for precious and base metals, uranium, diamonds,
different from the normal or expected; anomalies and several industrial minerals; it particularly pre-
can indicate the presence of minerals and could cludes exploration for commodities such as iron
be a target for drilling. An anomaly is a geological ore, coal, aluminum, or oil and gas. Regarding
incongruity that has the possibility of being an ore allocation of exploration, «Latin America has been
deposit. Obviously, an anomaly does not neces- considered the leading region for mineral explo-
sarily imply a mineral deposit, but every mineral ration by many companies for the past decade
deposit was first an anomaly, that is, something owing to its promising geology, its long history of
out of the ordinary (Hartman and Mutmansky world-class discoveries, the perception of its min-
2002). Where a mineral deposit has been identi- eral policies and its successful historical record of
fied, the next step is to map it more extensively to mineral production and development» (Wilburn
obtain a first evaluation of the grade and tonnage and Karl 2016).
3.2 · Mineral Resource Exploration Stages
125 3
.. Fig. 3.3 Top destinations for nonferrous exploration in 2015 (SNL Metals & Mining)
Technicians, usually geologists and/or geophysi- contrary, negative results reveal that the prospect
cists, design the exploration program that prom- will be commonly abandoned, although further
ises the best results in the search for such target. follow-up is possible if the economic conditions
According to Sillitoe (2000), the keystone to have changed. The first stage of mineral exploration
prospecting organization is to have the best forth- is the reconnaissance exploration, although it can
coming staff and appropriate finance in order to be named also in a variety of ways: simply prospec-
3 generate confidence throughout the organization. tion, target identification, early and extended
The economic parameters vary widely depend- reconnaissance, and many others. In turn, it typi-
ing on the expected exploration and development cally includes two steps: regional appraisal and
of the type of mineral deposit sought and on the reconnaissance of region. The main goal of the
economic factors and mine life. The conduct of a process is to identify an ore deposit that can be the
good prospecting program is aimed at the discov- target for subsequent exploration; the quantities
ery of a maximum number of mineral deposits at estimated for the deposits are with a low level of
minimum cost. In this searching process, geolo- confidence, and these estimates are inferred, that is,
gists decide the types of deposits to explore and based on interpretation of geological, geophysical,
which geological and exploration models should and geochemical results.
be applied. Previously, the management staff Reconnaissance exploration aims at rapid and
chooses the commodity or commodities. low-cost sorting out of prospective parts of an
The intensive use of mineral deposit models area. Regions ranging from 2000 to 200,000 km2
is a defining feature at this stage. This is because are evaluated with an analysis of accessible infor-
the first step in a new program is to acquire infor- mation, and parts of a region that cover 100–
mation about the study areas to be investigated. 5000 km2 are studied through field examination,
Thus, favorable regions are selected, either on the spaced geochemical sampling with wide grids,
basis of known potential as expressed by existing and geophysical exploration. In this sense, an
mines or mineral occurrences or on the basis of invaluable information to surface regional geol-
general knowledge of their geological characteris- ogy is that obtained with regional geophysics.
tics. In summary, the area to be explored is identi- Airborne magnetic, radiometric, and regional
fied based on literature search, looking at history, gravity data are available in a great part of the
reports and maps, and thesis works, among many developed world (. Fig. 3.4), and these tech-
others; these are called desktop studies. At the niques lead to refining geological interpretation.
end of this stage, exploration procedures are rec- Regional geochemical surveys also provide much
ommended to the management by the geological information in areas of poor outcrop.
staff, and a time schedule and general budget are
established. Regarding the exploration costs, the
exploration manager commonly considers them
as an expenditure within an organization while
it is as a geologist on a specific exploration proj-
ect that one becomes involved in the exploration
costs within the context of the project (Moon and
Whateley 2006). Prospection can be commodity-
or site-specific. In other words, the search can be
limited to a particular mineral or metal or to a
particular geographic area.
Classical techniques for this stage are com- they must be sent to a laboratory for their analysis
prehensive geological mapping and sampling; (. Fig. 3.6). Cost should not be the main factor to
detailed geochemical surveys, with an elaborated select the laboratory. For this decision, accuracy,
grid pattern sampling and analysis; detailed geo- precision, and an effective proceeding are also
physical surveys, usually on the ground; drilling, requested (Moon and Whateley 2006). Before
logging, trenching, and geophysical survey in the samples are submitted to the laboratory, it must be
3 holes; and bulk sampling. Drilling involves vari- ensured that all the elements that can be associated
ous types, initially with a relatively wide spacing of with the explored ore deposit are incorporated in
holes. In areas of poor outcropping, trenching or the analysis and very important that this analysis
pitting is essential (. Fig. 3.5) to verify the bedrock
comprises possible pathfinder elements.
source of a geological, geochemical, or geophysical The further decision to carry out a feasibil-
anomaly. Once the samples have been obtained, ity study can be obtained from the information
.. Fig. 3.6 Preparing
samples for analysis in the
laboratory (Image courtesy
of Anglo American plc.)
3.2 · Mineral Resource Exploration Stages
129 3
provided by detailed exploration, since resource/ that a pre-feasibility study is almost always carried
reserve estimations for the deposits are with a out during the previous step. Thus, the main goal of
high level of confidence. This is probably the most this type of study is to assess the various possibilities
critical stage of exploration because decisions and possible combinations of technical and business
involving high costs and potential costs have to be issues, to evaluate the project sensitivity to changes
made in view of the results. If a decision is taken in the individual parameters, and to rank various
that a potential ore deposit has been delineated, scenarios prior to selecting the most likely for fur-
the costs of subsequent exploration will drasti- ther and more accurate study. Upon completion of
cally increase, usually at the expense of other a pre-feasibility study, geological confidence is such
prospects. At this stage, it is essential to consider that it should be possible to publicly declare ore
that if it is decided to make the decision to close reserves (from measured and indicated resources)
prospection of a mineral deposit after this stage, (. Table 3.1) and any other mineral resources that
there is always the option that an ore body has can become mineable in the future with further
been lost (Marjoribanks 2010). study (Scott and Whateley 2006). The results of the
pre-feasibility study determine whether the increas-
ingly large expense derived from full geological,
3.2.4 Pre-feasibility/Feasibility technical, and economic evaluation of a prospect
Study is justified. In other words, this study will detect if
the costs involved in exploration are suitable for the
The final step in mineral exploration process is earnings that logically can be expected.
the preliminary feasibility study that analyzes all The feasibility study is the final evaluation of
components (geological, mining, environmental,
the profitability of a mining venture in light of the
sociopolitical, and economical) relevant to the results of exhaustive geological exploration; assess-
determination to develop a mine. In very large ment of mining and processing cost; environmental
projects, the costs involved in evaluation are high so factors, including mine reclamation; and market
.. Table 3.1 Example of mineral resource and reserve data presented in a pre-feasibility study of a mining
project
Total proven and 528.0 0.585 0.321 6.02 6.8 5.45 102.1
probable
130 Chapter 3 · Mineral Resource Exploration
analysis. This study usually forms the basis for the 3.3 Mineral Deposit Models
«go/no go» decision on developing a mine (Gocht
et al. 1988), that is, it is the basis for an investment To predict and have a better knowledge of how and
decision or decision to proceed to the next stage where an ore deposits can be present, scientists
of development. Obviously, feasibility studies are developed mineral deposit models (. Fig. 3.7). A
of higher level of rigor than pre-feasibility studies. working definition of «model» in the context of
3 Thus, in feasibility studies, social, environmental, mineral deposits is «the systematically arranged
and governmental approvals, permits, and agree- information describing the essential attributes
ments, commenced during the pre-feasibility study, (properties) of a class of mineral deposits» (Cox
will be in place or will be approaching finalization. and Singer 1986). Models are very useful to orga-
A feasibility study incorporates all types of nize the information about a mineral deposit
detailed information obtained in previous stages of because they are simplifications and abstractions
mineral exploration such as geology, mining, envi- based on a large number of individual observa-
ronmental, infrastructure and service, financial data, tions. As such, they need refinement as new data
marketing, economic viability, and many other fac- are acquired and have to be set as exploration is
tors. Moreover, sufficient sample collection and test carried out. In fact, it is very difficult to find a
work have taken place during a feasibility study for paper in the contemporary literature on economic
more of the resource estimate to be reported in the geology of a mineral deposit that does not utilize
measured category. Several million dollars are com- the expression «mineral deposit model.»
monly spent in large projects, to bring the project to Mineral deposit models are developed from
feasibility study level and sensitivity analyses. They the information of a particular important deposit
will have been established to analyze the main fac- or the combined information of several equivalent
tors that can have a definitive impact upon the deposits. Thus, the grouping of deposits based
reserve estimation. This will help to calculate the risk on common characteristics forms the basis for a
associated with the reserve data, which at this stage classification, but the specification of the features
will enter within the acceptable risk category of the needed for being included in the group is the basis
company. It is very common that financial institutes for a model (Barton 1993). Consequently, mod-
utilize independent consultants to audit the resource els contain an element of prediction, particularly
and reserve estimations. where certain physical attributes are characteristic
Oceanic Continental
intraplate Continental rift/back-arc
Mid-ocean volcanoes margin arc
Island arc basin
Back-are ridge
g
basin
Sea level
Continental
lithosphere
Mantle
plume
Subducting
slab
Explanation
Volcanogenic massive sulfide deposits
.. Fig. 3.7 Model showing volcanogenic massive sulfide deposits in different tectonic settings (Schulz 2012)
3.3 · Mineral Deposit Models
131 3
of ores of a well-defined deposit type. Models try be classified or the data that cannot be explained
to be constructed as much as possible «inde- by a previous existing model are commonly those
pendent of site-specific attributes and therefore that originate an advance in the knowledge of ore-
contain only those features that are transferable forming processes.
from one deposit to another; this goal is difficult However, some pitfalls in the utilization of
to attain, because it is not always known which mineral deposit models have been frequently
features are site-specific» (Cox and Singer 1986). developed. Thus, Hodgson (1990) suggests up to
According the definition of a mineral deposit a total of five different pitfalls in the making and
model, it can aid in identifying areas favorable for using of models all related to corporate or insti-
finding valuable deposits since they describe all of tutional cults and affect industry, academic, and
the essential features of a selected group of min- government institutions to an equal extent:
eral deposits (Singer 1995). Obviously, there are 1. The cult of the fad or fashion: an obsession
a great number of mineral deposit models, new with being up to date and in possession of the
models being created as new types of deposits newest model.
are identified. The scale of the models can vary 2. The cult of the panacea: the attitude that one
from regional size (regional-scale models are con- model is the ultimate and will end all
structed through metallogenic studies) to smaller controversy.
local ore bodies, or even refer to some highlighted 3. The cult of the classicists: all new ideas are
part of an ore body. rejected as they have been generated in the
The application of a particular deposit model hot house research environment.
will depend on the quality of the database. Some 4. The cult of the corporate iconoclasts: only
deposit types (e.g., placer gold) are easy to under- models generated within an organization are
stand and supported by well-developed models valid; all outside models are wrong.
while other deposits such as the Olympic Dam 5. The cult of the specialist: in which only one
mineral deposit model are not still well established aspect of the model is tested and usually not
and can be represented only by a single deposit. In in the field.
these cases, the information about the deposit is
very difficult to obtain. Thus, the models should
be used with caution and with understanding of 3.3.1 Types of Models
their limitations. The current trend in exploration
and mineral deposit modeling is to incorporate A subdivision of mineral deposit models into var-
every possible component of individual metal ious subtypes can be proposed (Cox and Singer
deposits in a database and carry out correlative 1986). These are dependent on the attributes used
analyses using computers. This approach is sim- in their definition and on the specific fields of
ply a continuation of the mindset that created the application the modeler has in mind (e.g., appli-
descriptive model and the availability of a new cations such as exploration/development, sup-
tool: the computer. Nonetheless, this model is in ply potential, land use, education, and research
reality a simulation, with its inherent case-specific guidance). The following subtypes are proposed
limitations, and as well can give misleading results (Cox and Singer 1986): (1) descriptive models, (2)
with limited utility for an emergent phenomenon occurrence models, (3) grade and tonnage mod-
(Robinson 2007). els, (4) occurrence probability models, (5) quanti-
The geological surveys of Canada and the tative process models, and (6) genetic models. The
USA have originated the vast majority of min- first three are empirical or descriptive models and
eral deposit models as well as a great number of the last three are conceptual or genetic models.
publications describing various mineral deposit Previously, three basic model types, descriptive,
types. They are the main source to obtain a com- grade and tonnage models, and genetic models,
plete information about the topic. Interactions were considered. Basically, the model can be
between the constructors of published models empirical (descriptive), in which several attri-
and the explorationists who use them are criti- butes are considered essential, or it can be theo-
cal to the evolution of more accurate and useable retical (genetic). In the latter, the attributes are
models. In this regard, the deposits that cannot interrelated using some fundamental concepts.
132 Chapter 3 · Mineral Resource Exploration
Thus, the empirical or descriptive model is based Attributes can be considered on at least two
on deposit descriptions, and the genetic model scales: the first deals with local characteristics
explains deposits in terms of causative geological that can be obtained immediately in the field
processes. (mineralogy, local chemical halos, among many
Another model type that is very useful for others), whereas the second incorporates features
initial economic analyses is the so-called grade related to the regional geological setting and that
3 and tonnage model. This type of model displays must be interpreted from the local studies or can
grade and tonnage data for known deposits, being be inferred from global tectonic considerations.
possible from this information to assess the aver- For instance, «the rock sequence under study
age size and grade of a mineral deposit and the represents a deep-water, back-arc rift environ-
cash-flow if one was met (Evans and Moon 2006). ment, or the area is underlain by anomalously
Ideally, mineral deposit types should reflect how radioactive high-silica rhyolite and granite» (Cox
the mineral deposit was actually formed. In many and Singer 1986).
cases, there is considerable debate among geolo-
gists as to how a specific deposit was formed, and Grade and Tonnage Models
thus classifications based purely on a given genetic Grade and tonnage models had a profound influ-
model will encounter problems. ence on the creation of mineral deposit mod-
els. The idea of relating grade and tonnage data
Descriptive Models appears to have originated long time ago (e.g.,
The classification of mineral deposits based on Lasky 1950). Grade and tonnage models of ore
empirical features will lead to the unique finger- deposits are very helpful for quantitative resource
print of a particular deposit (Herrington 2011). estimations as well as to schedule an exploration
Thus, descriptive models derive from the docu- program. They are useful to classify the known
mentation of the geological, geochemical, and deposits in a region and provide information
geophysical characteristics of individual mineral about the potential value of undiscovered depos-
deposits. Of the various kinds of mineral deposit its in the exploration area. Thus, the frequency
models, well-documented descriptive models are distributions of average grades and tonnages of
of the most direct use in mineral exploration or deposits of various types are calculated and dis-
resource assessment. A descriptive model can be played graphically. In a limited area showing
constructed from a single deposit but more com- favorable geological features, grade or tonnage
monly includes the essential common informa- frequency distribution curves are used to estimate
tion of a group of related deposits. The attributes the amount of metal that possibly exists in the
or properties of a mineral occurrence are, of area (. Box 3.1: Grade and Tonnage Models for
Box 3.1
different from the normal distribu- form at least 60% of the ore. For chromite deposits can be used
tion at the 1% significance level. In chemical ores, the chromite must as models of the grades and ton-
most cases, the departures of the be fine grained, and the chromic nages of undiscovered deposits.
grades from normality appear to oxide grades can be very low as Some examples of these frequen-
be typical for grades greater than long as there is enough to make cies are plotted in . Figs. 3.8 and
10% in other deposit types. chromium salts at a feasible rate. 3.9. Grade and tonnage models are
The reporting of very low Such a range of chromic oxide presented in a graphical format to
grades may be influenced by grades can contribute to multiple make it easy to compare deposit
favorable economics or technol- peaks or skewness in the data set. types and to display the data. The
ogy in processing low-grade If there were no differences grade and tonnage plots show the
ores and may indicate regional in grades or tonnages among cumulative proportion of deposits
differences that allow lower cutoff deposit types, it could be used versus the tonnage or grade of
grades. Because these are at the one model for all types. However, the deposits. Individual symbols
low-grade tail of the distributions differences in tonnages or grades represent the deposits, and inter-
and represent a small number of among the subtypes suggest cepts for the 90th, 50th, and 10th
deposits, they may not be impor- they should be represented by percentiles are plotted. Percentiles
tant for modeling purposes. For different models. For example, the of grades and tonnages are based
this analysis, grades lower than deposits associated with major on the observed distributions.
30% chromic oxide are excluded. podiform chromite are signifi- Relations among grade and ton-
Reports of very high grades may cantly larger than those associated nage variables are important for
be from deposits where hand with minor podiform chromite simulations of grades, tonnages,
sorting of ore was an important and banded podiform chromite, and estimated number of undis-
processing practice. For metal- and banded podiform chromite covered deposits. These relations
lurgical ores, grades less than deposits are significantly larger also affect the understanding
45% chromic oxide are usually than minor podiform chromite of how deposits form and the
rejected at the mills and a Cr to deposits. assumptions about resource avail-
Fe ratio of 3:1 is preferred. For Frequency distributions of the ability. Correlation tests among
refractory ores, coarser chromite tonnages and grades of chromic the variables reveal the relations
is preferred, and chromic oxide oxide, rhodium, iridium, ruthe- of grades and tonnage. In general,
grades can be low as long as the nium, palladium, and platinum in most of the variables show no rela-
alumina content combines to the three subtypes of podiform tion to each other.
.. Fig. 3.8 Cumula-
tive frequency of ore n = 246
tonnages of major 0.9
podiform chromite
deposits. Each red
dot represents an 0.8
individual deposit (n
is the total number of 0.7
deposits). Intercepts
Proportion of deposits
0.2
0.1
0.0004 0.011
0.54
0.0
0.0000016 0.000025 0.0004 0.0063 0.1 1.6 25
Tonnage in million tons
134 Chapter 3 · Mineral Resource Exploration
0.4
0.3
0.2
0.1
34 45 51
0.0
0 10 20 30 40 50 60 70 80 90 100
Chromite grade in percent Cr2O3
The mineral deposit density area is a variation understanding of the physics and chemistry of
of the grade and tonnage model. Deposit density ore-forming processes. Therefore, the developing
modeling can be used to produce a quantitative of a mineral deposit model is an iterative process
mineral resource assessment by estimating the (Duke 1990). Genetic models are more power-
number of undiscovered deposits (Singer et al. ful than descriptive models because they provide
2001). In this type of model, the grade and ton- a basis to distinguish essential from extraneous
nage model is carried out, and then the number of attributes. In general, the information of a descrip-
deposits per unit area is determined for a specific tive model is a necessary precondition to create a
deposit type from a well-explored region. The genetic model.
process originates a frequency distribution that Genetic models describe the origin of a deposit
is utilized either directly for an estimate of the or deposit type and represent the combination of
resources in a mineral deposit or indirectly as a a descriptive model with one or more process
guideline in some other method. models. Process models simulate physical and
chemical ore-forming processes (. Fig. 3.10), and
a
Initial surge of magma Entrained sulfide
droplets
.. Fig. 3.10 Illustration of the continued flow of magma through an idealized magma conduit (process model) in mag-
matic sulfide-rich nickel-copper-(platinum-group element) deposits (Schulz et al. 2014)
by the appropriate grade and tonnage models, problems at abandoned mine sites; (3) land-use
occurring within a given area. The latter are planners that are involved in permitting proposed
models that describe quantitatively some process mines or reclaiming abandoned mine lands; and
related to ore deposit formation, being in fact (4) industry interested in mine planning and min-
only branches of the genetic model. All these eral exploration (Seal et al. 2002).
models can be parts of the «final» model, and
3 recycling of the model back to the early grouping 3.3.2 Maturity of Descriptive-
phase assists in refining the selection procedure
Genetic Models
(Cox and Singer 1986).
Other types of models have also been described
The current level of genetic knowledge varies con-
by different authors and applied to mineral depos-
siderably from one deposit type to another. For
its: cause-effect models (Knox-Robinson 2000;
example, placers and evaporites are genetically
Sirotinskaya 2004), fractal and multifractal mod-
well-known types of deposits, and the problems in
els (Mandelbrot 1983), fluid flow-stress mapping
their exploration concern mainly local site-specific
models (Heinrich et al. 1996), statistical/probabi-
geological problems rather than mineral genesis.
listic models (Agterberg 1974), structural models
In contrast, deposits such as the Coeur d’Alene
(Kutina 1969), and spatial-temporal models (Lud-
Ag-Pb-Zn veins remain genetic enigmas despite
ington et al. 1993). As an example, probabilistic
extensive research for a long time. Other deposits
regression models have been especially attractive
are geologically well understood regarding their
and useful to mineral resource exploration. In
origin but still very poorly understood in terms of
this model, an area of concern is splitted into a
the reasons for their existing at any particular site.
grid of square cells, and the presence or absence
Thus, the rate of acquisition of information is very
of the various predictive attributes (e.g., different
irregular. The several scarps between plateaus in
lithologies, hydrothermal alteration, geophysical
the knowledge curve for some mineral deposit
or geochemical anomalism) is expressed for each
models might mark, successively, the recognition
cell, in the form of magnitude, counts or occur-
of very important aspects related to the genesis
rences, or percentage area occupied.
of the deposit, while plateaus denote periods of
absence of new knowledge. For instance, «a scarp
Geoenvironmental Models in the Mississippi Valley-type ores might involve
Geoenvironmental models are specific because recognition, from fluid-inclusion evidence, that
they are designed as natural extensions of mineral the ores were deposited from warm, about 100 °C,
deposit models. A geoenvironmental model of a highly saline solutions that could represent nei-
mineral deposit can be defined as «a compilation of ther simple surface nor marine waters» (Cox and
geological, geochemical, geophysical, h ydrologic, Singer 1986).
and engineering information pertaining to the Moreover, some aspects of any model always
environmental behavior of geologically similar remain to be determined and the model never
mineral deposits prior to mining» (Plumlee and reaches a definitive format. Indeed, «the approach
Nash 1995). Thus, the model offers information to complete understanding is asymptotic, and a
about natural geochemical variations associated lot of additional effort to clear up the last uncer-
with a particular deposit type and geochemical tainty in a nearly perfect model is probably
variations associated with its mining effluents, unwarranted» (Cox and Singer 1986). However,
wastes, and mineral processing facilities, includ- new ideas and new technologies can provide the
ing smelters. Such information should prove ben- impetus for new improvements in knowledge for
eficial to (1) environmental scientists interested until now incomplete models. Obviously, differ-
in mitigating potential environmental problems ent deposit types can require different amounts of
associated with proposed mines; (2) environmen- effort to achieve a similar level of genetic under-
tal scientists interested in remediating existing standing.
3.4 · Exploration Methods
137 3
3.4 Exploration Methods forthcoming since the late 1970s, the data from land
observation satellites have supplied a powerful tool
The geological, geophysical, and geochemical meth- for the exploration of mineral resources. Moreover,
ods applied at different stages of mineral resource satellite imagery (. Fig. 3.11) investigates the geo-
exploration are described in the next sections. The logical characteristics of remote areas of the surface
methods are organized in order of scale and stage, of the Earth without the requirement to access the
from remote sensing to drilling, through photoge- region on the ground. Thus, remote sensing is pro-
ology, geophysical, and geochemical surveys. viding information on mineral deposit exploration
targets without being in contact with the objects.
Remote sensing can highlight ore bodies and
3.4.1 Remote Sensing their respective mineralization or alteration sig-
natures as well as associated other features such as
Remote sensing is the characterization of the surface lineaments and faults. For instance, this method
of the Earth based on measurements of its reflected originates strong signals where gossans associated
or emitted electromagnetic radiation in wavelengths with hydrothermal alteration and oxidation of
from 0.3 to 3 m, being satellites the main observa- porphyry deposits are present. Another example
tion platforms. These wavelengths cover the range would be the discovery of fractures and faults in
from the ultraviolet to the microwave radar spec- volcanic regions with veins of precious metals.
trum although a great number of measurements On the other hand, the interpretation of satellite
are made in the visible range by passive methods, in imagery can originate very useful models before
which the reflected natural radiation is estimated. the start of geophysical investigations. In turn,
Remote sensing lead to the recognition of major geological and geophysical data can gage models
regional topographic features and geologic rela- obtained from this technique.
tionships and helping in the discovering of regions The resolution of remote sensing is restricted
with mineral potential. Since remote sensing was by the resolution of the imagery. According to this
.. Fig. 3.11 Satellite
image (Landsat) used
in mineral exploration
(pixel = 14.5 m × 14.5 m)
138
Chapter 3 · Mineral Resource Exploration
factor, satellites can be classified into three main features. In the context of geological mapping, elec-
categories: (1) VHR (very high resolution), sub- tromagnetic methods can be classified as (1) pas-
meter pixels; (2) HR (high resolution), 2.5–10 m sive optical methods (utilize the sunlight as the
pixels; and (3) MR (mid resolution), greater source and estimate the reflectance of the surface of
than 10 m pixels. An image with 50 m resolu- the Earth in the visible and infrared spectral bands)
tion would start to pixelate at scales larger (more (e.g., Landsat 7 ETM+ and the ASTER instrument
3 detailed) than 1:100,000. By contrast, a very high- from the Terra satellite) and (2) active microwave
resolution (VHR) satellite scene with a 50 cm res- radar methods (use a microwave source onboard of
olution could be viewed at scales to 1:2500 before the satellite and calculate the backscatter from the
pixelation became apparent. Mid resolution data Earth) (e.g., Radarsat-1 and the radar sensor from
can be used for the initial, broad-scale study, to the Shuttle Radar Tomographic Mission [SRTM]).
derive, locate, and designate smaller areas of For its part, infrared imagery is divided into three
interest, while higher-resolution data are utilized classes: (1) very near infrared, which detects partic-
for subsequent analyses. ularly vegetation; (2) short wave infrared, the best
In contrast to electrical, magnetic, and gravity possibility to discriminate sedimentary rocks; and
methods that compute force fields, remote-sensing (3) thermal infrared, utilized to discriminate dark
technique is usually referred to methods that use the materials such as non-sedimentary rocks (Laake
electromagnetic energy as radio waves, light, and 2011). The most famous satellite used in geological
heat as the means of finding and measuring target studies is Landsat (. Box 3.2: Landsat Program).
Box 3.2
Landsat Program
The Landsat program is a series of Since 1972, Landsat satellites the Landsat series was designed
Earth-observing satellite missions have continuously acquired initially to provide multispectral
jointly managed by NASA and the space-based images of the Earth’s imagery for the study of renew-
US Geological Survey. In the mid- land surface, coastal shallows, able and nonrenewable resources,
1960s, stimulated by the USA’s and coral reefs. Landsat satellites geologists immediately recog-
successes in planetary exploration image the Earth’s surface along nized the geological potential
using unmanned remote-sensing the satellite’s ground track in a of the Landsat images, and the
satellites, the Department of the 185 km-wide swath as the satel- bands 5 and 7 in the TM were cho-
Interior, NASA, and the Depart- lite moves in a descending orbit sen specifically for their geologi-
ment of Agriculture embarked on (moving from north to south) cal applicability. The approximate
an ambitious effort to develop over the sunlit side of the Earth. scene size of TM images is 170 km
and launch the first civilian Earth Landsat 7 and Landsat 8 orbit north-south by 183 km east-west,
observation satellite. Their goal the Earth at 705 km altitude. and the radiance measured by the
was achieved on July 23, 1972, They each make a complete orbit Landsat sensor is a measure of the
with the launch of Landsat 1, every 99 min, complete about integration of soil, rock, and veg-
originally named «ERTS» for Earth 14 full orbits each day, and cross etation characteristics. Landsat
Resources Technology Satellite. every point on Earth once every 7 carries the Enhanced Thematic
Thus, the Landsat program, a 16 days. Mapper Plus (ETM+), with 30 m
joint effort of the US Geological For most geologists and other visible, near-IR, and SWIR bands,
Survey (USGS) and the National Earth scientists, multispectral a 60 m thermal band, and a 15 m
Aeronautics and Space Adminis- imagery is synonymous with panchromatic band. Landsat 8 is
tration (NASA), was established NASA’s Landsat series. The primary the latest satellite (2013) in this
to routinely gather land imagery sensor onboard Landsats 1, 2, and series (. Fig. 3.12) and operates
from space. NASA develops the 3 was the Multispectral Scanner in a near-circular, near-polar,
remote-sensing instruments and (MSS), with an image resolution sun-synchronous orbit with a
spacecraft, then launches and of approximately 80 m in four 705 km altitude at the equator. It
validates the performance of the spectral bands ranging from the carries two push-broom sensors:
instruments and satellites. The visible green to the near-infrared the Operational Land Imager
USGS then assumes ownership (IR) wavelengths. In July 1982, the (OLI) and Thermal Infrared Sen-
and operation of the satellites, in launch of Landsat 4 saw the inclu- sor (TIRS), both of which provide
addition to managing all ground sion of the Thematic Mapper (TM) improved signal to noise ratio and
reception, data archiving, product sensor with a 30 m resolution 12-bit radiometric quantization of
generation, and distribution. and 7 spectral bands. Although the data.
3.4 · Exploration Methods
139 3
The use of satellite imagery associated with mineral deposits, IR) of Landsat satellite, with wave-
is now a standard technique in and to produce maps of regional lengths between 2.08 and 2.35
mineral exploration, and Landsat and local fracture patterns, which micrometers and resolution of
imagery has been used to pro- can have controlled mineralization 30 m, is very useful for mapping
vide basic geological maps, to or hydrocarbon accumulations. hydrothermally altered rocks asso-
detect hydrothermal alteration For instance, TM band 7 (reflected ciated with mineral deposits.
.. Fig. 3.12 Artist concept of Landsat 8 (Image courtesy of NASA’s Goddard Space Flight Center)
3.4.3 Geological Mapping this early mapping was done to locate bedrocks
suitable for construction of canal systems, geo-
Publication in 1815 of the first colored, hand- logical maps (. Fig. 3.14) are used as a means of
painted geological map of England and Wales by presenting the observations as well as construct-
William Smith heralded the birth of modern geol- ing geological hypotheses. Geological mapping
ogy (Winchester 2001). Today, two centuries after plays an important role throughout the mine life
142 Chapter 3 · Mineral Resource Exploration
cycle, from regional- to district-scale exploration based mapping tools, recent technological
targeting, through drilling and ore discovery, to advances incorporate global positioning systems,
deposit assessment, ore-reserve estimation, pre- pen tablet computers, and laser ranging devices
production mine planning to production, and, that all support direct (paperless) field-based digi-
ultimately, mine closure. tal geological mapping. In this sense, geographic
Geological mapping has been used exten- information systems (GIS) revolutionized explora-
3 sively for mineral exploration for more than tion practices (. Box 3.3: Geographic Information
Box 3.3
.. Fig. 3.15 GIS image released with QGIS (a free and open-source geographic information system) including
different types of information such as geology or mining data (Image courtesy of Miguel Ángel Sanz)
There are two main reasons that mapping as the basis for preliminary examinations to assess
remains an essential part of mineral explora- mineral potential, frequently in conjunction with
tion. First, mapping creates the geometric pat- geochemical, geophysical, or remote-sensing sur-
terns that represent the geological attributes of veys or compilation of mine and prospect data.
an exploration target. Second, there are scientific, However, geological maps available today,
engineering, and financial implications of map- either published by government surveys or in
ping because subsequent geophysical modeling, many scientific journals, are generally not well
ore-reserve estimation, financial forecasting, and suited for special needs of mineral exploration
economic evaluation are based on the interpreta- and development and require exploration geolo-
tion of such work (Brimhall et al. 2006). The qual- gists to undertake specialized mapping. Whereas
ity and scale of the geological map will vary with published maps of general geology do outline
the importance of the program and the finance information essential to exploration, including
available. Scales of geological maps range from rock units, stratigraphy, ages of rocks, and general
reconnaissance (1:24,000 or smaller) to detailed structure, they are in most cases not sufficiently
project scale (1:100 to 1:12,000). detailed to help delineate mineral deposits that
Geological mapping is widely used in planning are typically 1–2 km2 in outcrop area even for
exploration strategies such as the selection of regions world-class deposits. Consequently, the geologi-
to explore for certain types of ore deposits. Prior to cal mapping at this stage generally is done at a
mapping campaigns, existing geological maps are more detailed and larger scale than published
examined and can be compiled to emphasize key mapping, and key lithologic units and features
geological features to assess exploration potential. of mineralization or hydrothermal alteration are
Exploration geologists commonly use existing maps mapped using the reconnaissance techniques.
144 Chapter 3 · Mineral Resource Exploration
Since geological information is commonly economic minerals will produce them, but even
recorded on maps and cross sections at a scale the presence of a clear physical contrast between
appropriate to the aims, property geology must be mineralization and surrounding rocks does not
defined at a scale of 1:5000, while mineral deposit imply a significant anomaly (Milson 2006).
geology must be mapped to a scale of 1:1000 or Geophysical measurements in the natu-
even more detailed. Information displayed in this ral environment will be contaminated with
3 type of map includes faulting, folding, rock types, unwanted information. This is called noise, which
fracture/vein density and orientation, evidence is a source of error, while the information being
of primary porosity/permeability, and phases of sought in the measurement is known as signal.
mineralization, among many others. Signal amplitude should be as high as possible
Regarding geological mapping in underground whereas noise signal should be as low as possible,
mines, it can play an essential role in mineral explo- in order to obtain an accurate measurement of the
ration. Abandoned mine workings are the most parameter of interest. In any case, suppression of
direct guides of the mineralization in a region and noise is of outmost importance and must be con-
provide the immediate information on ore occur- sidered at every stage of the geophysical program,
rences. If the workings are active, they provide a from data acquisition to presentation of the data
series of fresh geological exposures with each for interpretation (Dentith and Mudge 2014).
meter of advance, and they supply well-located Geophysical methods can be classified as
sites for underground drilling and sampling. passive (magnetism, specific gravity, and radio-
activity) and active methods (electric conductiv-
ity, electromagnetic properties, and seismicity).
3.4.4 Geophysical Exploration Passive methods use natural sources of energy,
of which the Earth’s gravity and magnetic fields
Introduction are two examples, to investigate the ground. The
Mineral exploration is increasingly being geophysical measurement is made with a detector,
addressed to searching for buried and deep tar- sensor, or receiver, which measures the response
gets since there are few large ore bodies to be of the local geology to the natural energy. In turn,
found at the surface. Unlike geochemistry and active geophysical methods involve the deliber-
other remote-sensing techniques, geophysics ate introduction of some form of energy into the
helps to look at into the subsurface and to provide ground, for example, seismic waves or electric
information about the concealed geology. Thus, currents. Again, the response of the ground to the
geophysics is an integral part of most mineral introduced energy is measured with some form
exploration programs. Geophysical techniques of detector (. Fig. 3.16). These methods are more
have been used in mineral prospecting for the complicated and expensive to work with.
past 300 years, beginning in Sweden around 1640
with the use of magnetic compasses in explor-
ing for iron ore. These techniques are essential in
areas where outcrop is poor or has been subject
to intense mineral search over a long period. In
some cases, geophysical techniques also enable
for quick regional appraisal of areas where ground
access is almost impossible, for instance, rain for-
est terrain or developing countries with insuffi-
cient infrastructure (Marjoribanks 2010).
For a geophysical technique to be useful in
mineral exploration, there must be a clear contrast
in the physical characteristics of the minerals,
rocks, and ores related to the existence of valu-
able minerals. Geophysical anomalies, defined
as differences from a constant or slowly varying .. Fig. 3.16 Geophones for receiving seismic signal
background, can be recorded. Ideally, the actual (Image courtesy of International Geophysical Technology)
3.4 · Exploration Methods
145 3
The geophysical signal can be directly related matched with surface geological data to decide if it
to mineral deposits, for example, a magnetic is worth proceeding with further exploration.
anomaly caused by magnetite ore in an iron Geophysical techniques are routinely used in
deposit. More commonly, geophysical methods exploration programs to help the project geologist
provide indirect evidence that leads to interpre- delineate areas favorable for the type of target being
tations of the subsurface geological distribution pursued. They can be used to directly detect some
of rocks, but it does not directly or necessarily minerals, indirectly detect others, and map geologi-
reflect the presence of a mineral deposit. These cal and structural features in exploration programs.
types of methods are applied to both mineral Direct detection includes using induced polariza-
discovery and geological mapping. They are use- tion (IP) to find disseminated sulfides, magnetics
ful because geophysical responses of materials to delineate magnetite-hosting rocks, and gravity
can be measured through vegetation, soil cover, and electrical techniques for massive sulfides. For
and extraneous overburden. In many cases, geo- instance, indirect detection of targets includes
physical measurements provide the only means of «using IP to detect pyrite in association with
interpreting the geological characteristics of the sphalerite and gold (both non-responders to IP
subsurface short of drilling, which is much more geophysical techniques), and copper and molybde-
expensive (Gocht et al. 1988). num in porphyry systems; magnetics are routinely
Over the area of interest, geophysical instru- used to search for hydrothermal alteration in asso-
ments are deployed in the field to measure varia- ciation with porphyry systems, and can be used to
tions in a physical parameter associated with map buried stream channels (e.g. magnetite sands)
variations in a physical property of the subsur- that might host placer gold» (Mukherjee 2011).
face, and the measurements are used to infer Seismic surveys are highly effective for investigat-
the geology of the survey area. Of particular sig- ing layered stratigraphy, so they are the mainstay
nificance is the ability of geophysical methods to of the petroleum industry but are comparatively
make these inferences from a distance and, for rarely used in the minerals industry. Regarding
some methods, without contact with the ground. costs of geophysical surveys, the seismic method is
A considerable number of geophysical explora- the most expensive, while airborne magnetic and
tion methods are available for mineral explora- radiometrics are the less expensive.
tion, and each method exists in several variants. It is very important to note that most impor-
The specific choice is a function of the geological tant advances in geophysical exploration for ore
and exploration model of the targeted deposits; of deposits in the last 25 years dealt with advances
general conditions such as remoteness, climate, in theory or practice of the different methods but
and human land use; and of the costs (Shen et al. also with the development of more sophisticated
2008). Through either ground, airborne, or in- instrumentation and especially more powerful
ground (downhole) methods, geophysical studies data processing. These advances together with the
employ the types of surveys cited above to detect use of GPS for survey positioning control have
anomalous signals related to the presence of min- greatly reduced the cost and time involved in
erals. all geophysical surveys and have increased their
The chief advantages of airborne surveying resolution in the detection of anomalous signals
relative to ground surveying are the greater speed in the data.
of data acquisition and the completeness of the Traditionally, most geophysical data has been
survey coverage. After their introduction in the presented for interpretation in the form of contoured
1950s, airborne geophysical surveys became com- or raster plans and sections that can be interpreted
monly used as a first step in geophysical explora- in terms of the geology and ore mineralization that
tion. They provide the quickest, and often the most they represent. However, new methods of analyzing
cost-effective, ways of obtaining geological infor- and presenting geophysical data have been intro-
mation about large areas. Two or more methods duced in the last two decades to revolutionize the
are commonly combined in one survey to obtain interpretation process. These methods are gener-
data that are more accurate. In surface geophysics, ally referred to as «data inversion» (McGauchy
geophysical work on the ground is normally rather 2007; Oldenburg and Pratt 2007) (. Box 3.4: Data
slow. Results from airborne and surface surveys are Inversion in Geophysical Exploration).
146 Chapter 3 · Mineral Resource Exploration
Box 3.4
.. Fig. 3.17 3-D
geophysical inversion a
images. a 3-D con-
ductivity model from
frequency-domain
electromagnetic field
inversion (Geosoft
VOXI Earth Modelling);
b 3-D susceptibility
model from magnetic
field inversion (Geosoft
VOXI Earth Modelling) b Gridded
observed
(Images courtesy of data
Geosoft)
Y X
3.4 · Exploration Methods
147 3
models, the product of inversion its construction. It is a feature of measured in the field. Choosing
modeling is only as good as the geophysical inversion models between different possible mod-
geological choices made in set- that shows they are not unique: els requires geological knowledge
ting up the model parameters many different models can be about the area, and the better
and the accuracy of the geophysi- constructed that will reproduce that knowledge, the more useful
cal properties that are used in the geophysical pattern that was and realistic the inversion model.
mGal
57.574
57.547
57.531
57.514
57.502
3
57.488
57.478
57.467
57.456
57.448
57.438
57.431
57.421
57.414
57.405
57.398
57.389
57.381
57.373
57.364
57.357
57.348
57.340
57.330
57.322
57.311
57.300
57.290
57.277
57.265
57.248
57.231
57.205
57.173
.. Fig. 3.19 Bouguer anomaly map (Illustration courtesy of International Geophysical Technology)
heavy minerals will also affect gravity at a given used for mineral exploration if substantial density
point and will produce an anomaly above nor- contrasts are expected. Thus, chromite and sulfide
mal background levels. Anomalies of exploration bodies possess very high densities, and buried
interest are often about 0.2 mgal, and data have to channels, which can contain gold or uranium,
be corrected for variations due to elevation, lati- can be detected because they have relatively low
tude, and other factors. density. In fact, gravity surveying is rarely used
Much less can be deduced about the shape or in reconnaissance exploration because it is rela-
the depth of the investigated mineral deposit. A tively slow to execute and therefore expensive.
deeper body will, other things being equal, give However, gravity methods are very useful as a
rise to a broader and flatter anomaly. Likewise, the follow-up method utilized on a target defined
peaks of gravity anomalies are generally situated by another, more cost-effective method. In this
just above the causative bodies (a causative body sense, gravity surveys, along with regional aero-
is a rock unit of different density from its sur- magnetic data, played a significant role in the dis-
roundings), which is not the case for many other covery of the giant deeply buried Olympic Dam
geophysical methods. Regarding the interpreta- mineral deposit in Australia (Rutter and Esdale
tion of the measurements, «the reliability of any 1985), and the discovery of the Neves Corvo sul-
interpretation, no matter how sophisticated the fide deposits in Portugal was carried out utilizing
technique, depends, of course, on the validity of regional gravity surveys of the Portuguese pyrite
the input assumptions» (Milson 2006). belt on 100 and 200 m grids (Leca 1990).
Gravity surveys can be carried out either from
airborne or ground surveys, but the most sensi- Magnetic Methods
tive measurements are currently achieved from Magnetic methods, which are probably the oldest
the ground. They are used to evaluate the amount of geophysical exploration methods, thrived after
of high-density mineral present in an ore body, the World War II. Magnetic surveys (. Fig. 3.20)
and as a general rule, gravity prospecting is only measure variations of the Earth’s magnetic field
3.4 · Exploration Methods
149 3
Diamagnetic minerals show negative susceptibili-
ties and examples of these materials are quartzite
and salt although many of the elements and com-
pounds exhibit diamagnetism. Salt domes thus give
diamagnetic anomalies (weak negative anomalies).
Paramagnetic minerals are ones where the electron
shells are incomplete; as a result, they generate weak
magnetic fields. By definition, all materials that are
not diamagnetic are paramagnetic. Examples of
materials that are paramagnetic are the 20Ca to
28Ni element series. Finally, ferromagnetic miner-
als are minerals that are paramagnetic, but where
groups of atoms align to make domains. There are
only three ferromagnetic elements: iron, cobalt,
and nickel. Almost all natural magnetic minerals
are of this kind. Magnetite, which is the most abun-
dant, ilmenite, hematites, titanomagnetite, and the
oxides of iron or iron and titanium are common
ferromagnetic minerals. Magnetite (Fe3O4) is found
disseminated through most rocks in differing con-
.. Fig. 3.20 Magnetic survey (Image courtesy of Interna-
tional Geophysical Technology)
centrations. The magnetization can be either tem-
porary (induced) in the same direction as the field
of the Earth or permanent (remanent) and fixed
caused by the presence of magnetic minerals. in direction with respect to the rock, regardless
Magnetic outcomes result primarily from the mag- of folding or rotation. All geologically significant
netization induced in susceptible rocks by the mag- magnetic minerals lose their magnetic properties at
netic field of the Earth: everywhere in the Earth about 600 °C, a temperature reached near the base
there is a natural magnetic field. These methods of the continental crust. Consequently, local fea-
are widely used, both as an essential assistance in tures on magnetic maps are virtually all of crustal
regional mapping and for direct location of those origin (Milson 2006).
mineral deposits that show distinct magnetic sig- As a rule, the magnetite content and, therefore,
nature. Magnetic and gravity methods have much the susceptibility of rocks are very variable, being
in common. The magnetic map, however, is gener- present a considerable overlap between different
ally more complex, and the variations in field are mineralogies and lithologies (. Table 3.2). Basic
more erratic and localized than the gravity map. igneous rocks are commonly highly magnetic
Thus, the precise interpretation of magnetic field because this type of rock has a relatively high
data is usually much more difficult than for gravity. magnetite content. In this sense, the proportion of
Magnetic surveys are often utilized in metallic magnetite in igneous rocks usually decreases with
mineral exploration, particularly locating iron ores. increasing acidity; for this reason, acid igneous
However, ordinary hematite, the most abundant rocks are generally less magnetic than basic rocks.
ore of iron, rarely produces anomalies large enough Metamorphic rocks are also very different in their
to be detectable in conventional aeromagnetic sur- magnetic character, depending of the metamor-
veys. The combination effect of several geophysical phism grade. Regarding sedimentary rocks, they
techniques such as aeromagnetic interpretation are effectively nonmagnetic unless they contain
with study of regional gravity and radiometric data a significant amount of magnetite in the heavy
can produce further gains in the interpretation of mineral fraction. Thus, if magnetic anomalies are
the underlying rocks. detected in areas covered with sediments, these
Minerals can be diamagnetic, paramagnetic, or anomalies are mainly originated by an underlying
ferromagnetic. In diamagnetic minerals, all the elec- igneous or metamorphic basement or by intru-
tron shells are full; there are no unpaired electrons. sions into the sediments.
150 Chapter 3 · Mineral Resource Exploration
displayed in the form of a contour map of the utilizing a portable spectrometer. Radiometric
magnetic field, interpretation is often made on surveys for mineral exploration are made from
profiles. According to Kearey et al. (2002), mag- the air, on the ground, and within drillholes.
netic anomalies range in amplitude from a few Airborne radiometrics is particularly common
tens of nT over deep metamorphic basement in mineral exploration where the radiometric
to several 100 nT over basic intrusions and can data are acquired simultaneously with magnet-
3 reach an amplitude of several 1000 nT over mag- ics during airborne surveying, measurements
netite ores. usually calculated from a low-flying aircraft
Direct search for magnetic targets related simultaneously as air magnetic studies. As afore-
to mineralization is an important exploration mentioned, aerial and ground use are restricted
method, especially in those provinces with to areas with little soil cover, because most radia-
banded iron formations, IOCG mineralization tion on the surface comes from the uppermost
types, strongly oxidized porphyry copper intru- 10–50 cm.
sives, magnetite skarns, or pyrrhotite-bearing Although the Geiger-Muller radiation detec-
massive sulfides. In such cases, favorable anom- tor was used in the early era of radiometric
alies are commonly obtained from high-quality surveying, the instruments used nowadays are
low-level aeromagnetics, followed up then by scintillometers, the simplest form of instru-
ground magnetometer traverses and magnetic ment, and spectrometers, a more complex type,
modeling to define a drill target. «Magnetics that detect gamma rays by their interaction
have been also used to define subtle explora- with matter. Small handheld and larger portable
tion targets such as heavy mineral concentra- spectrometers for ground surveying have inter-
tions in palaeo-strand lines and potential iron nal memories to store the large quantity of data
ore and gold orebodies in palaeochannels» acquired, which is generally restricted to mea-
(Marjoribanks 2010). Examples of ore depos- surements in the K, U, and Th energy windows
its found largely as a result of their magnetic and the total count (Dentith and Mudge 2014).
response are the Olympic Dam mineral deposit The presentation of the obtained data in radio-
(Reeve et al. 1990) and the Broken Hill-type metric methods is similar to that of magnetic
deposit of Cannington in Australia. This deposit data. In this sense, the high geochemical mobility
was discovered as a consequence of drill test- of elements such as K and U in surficial environ-
ing and an air magnetic anomaly, generated by ments is the motive for the common use of ratios
associated pyrrhotite, in a zone of thick younger (U/Th, K/Th) in these maps due to the almost
cover (Walters et al. 2002). immobile Th. With respect to the presentation
of the obtained data in radiometric methods, it
Radiometric Methods is similar to that of magnetic data. As in grav-
Radiometric surveys carried out the estimation ity and magnetic methods, corrections must be
of the gamma rays emitted from the Earth by also made in radiometric surveys for the effects
natural decomposition of frequent radiogenic of scattered thorium radiation in the uranium
minerals, being a useful technique to map fault window and for the effect of both thorium and
zones or boundaries between geological units. uranium in the potassium window.
Natural radioactive decay produces alpha par- There are over 50 occurring naturally radioac-
ticles, beta particles, and gamma rays. These tive elements, but the elements of main concern
are very high-frequency electromagnetic waves. in radiometric studies are uranium (238U), tho-
Thus, radiometric survey is a passive geophysi- rium (232Th), and potassium (40K). The latter is
cal method because it measures a natural source common in potassium-rich rocks that cannot be
of energy, similar to gravity and magnetic meth- related to concentrations of U and Th. The most
ods. Most gamma rays are produced in the top abundant radioactive element in the crust is the
30 cm of soil and rocks that can be sensed by potassium isotope 40K, which is widely included
airborne investigations and on surface rocks into the crystal structure of the rock-forming
3.4 · Exploration Methods
153 3
.. Fig. 3.21 Instrumen-
tation for ground radio-
metric (Image courtesy of
International Geophysical
Technology)
minerals are scattered in their host rocks. The self- methods, operate much better in the upper few
potential method uses natural currents present 100 m of the surface with unweathered rocks rela-
in the ground and originated by electrochemical tively close to the surface.
processes with the aim of finding shallow bodies As a rule, the resistivity method is scarcely
that display anomalous conductivity. Although used in mineral resource exploration. Conversely,
the origin of the potentials is not well understood, IP is important in base metal exploration because
conductive mineralization can be associated with it depends on the surface area of the conduc-
a negative self-potential anomaly. tive mineral grains rather than their connectiv-
Electrical methods are used at regional and ity, being successfully employed to a maximum
prospect scale for direct detection of electri- depth of around 600 m. Induced polarization (IP)
cally anomalous targets and, in particular, to surveys cause an electric field in the ground and
detect metal sulfide and metal oxide mineraliza- calculate the chargeability and resistivity of the
tion. Establishing the depth of the source of the subsurface. Thus, this method is capable of iden-
response is problematic in electrical methods. tify changes in the electric currents produced by
Varying the position of the electrode array and the existence of different rocks and minerals. IP
the separation of the electrodes (. Fig. 3.22), lat-
surveys are conducted along grid lines with read-
eral and vertical variations in electrical properties ings taken at receiving electrodes planted in the
can be mapped and used to produce data pseu- ground and moved from station to station.
dosections, volumes, and maps. However, moving IP is especially sensitive to disseminated min-
cables, electrodes, and equipment from one point eralization that can produce no resistivity anomaly.
to the next makes these methods laborious and After magnetic methods, IP technique is probably
slow. Electrical methods, as with electromagnetic one of the oldest geophysical methods utilized in
3.4 · Exploration Methods
155 3
NW SE
30 Gravel or sand 30
Water
25 500 25
Elevation (m)
15 200
15
10 Fresh granite 10
1000 1500
1000
5 5
0m 20 m 40 m 60 m 80 m 100 m
Fresh granite
Weathered granite
50
55
61
67
74
81
90
99
109
120
132
146
160
177
195
215
237
261
287
317
349
385
424
467
515
568
629
689
760
837
923
1017
1121
1235
Resistivity
(Ohm.m)
Clay Gravel
Sand
.. Fig. 3.23 Graphic display of an IP survey (Illustration courtesy of International Geophysical Technology)
conductivity of layers down to 300 m below sur- metal producers in eastern Canada is immediately
face. Unlike conventional resistivity techniques, related to the development of airborne electro-
EM works without a physical contact to the magnetic surveys (Lulin 1990).
ground, without electrodes, which is in advantage EM surveys can be also applied in drillholes
for use above ice, water, swamps, frozen, or arid (DHEM) measuring the effects of currents flow-
ground. ing between the drillhole and the surface or
EM surveys are conducted from the air (AEM), between contiguous holes. This method can
on the ground surface, and in drillholes (down- reduce the amount of delineation drilling
hole electromagnetics – DHEM) (. Fig. 3.24).
required. In general, DHEM is one of the most
Ground-based EM methods are relatively expen- important geophysical tools in the exploration
sive, being used mainly to define targets for drill- for conductive massive sulfide mineralization,
ing in specific mineralization styles. For its part, especially deep nickel sulfide bodies. For many
airborne investigations incorporating this geo- reasons (e.g., many host rocks and mineralization
physical method have been commonly utilized for can give a similar geophysical signal), electromag-
direct ore location and sometimes in regional geo- netic methods are useful in locating ores in some
logical mapping. They were originally developed regions of the world where fresh and not oxidized
in the frequency domain to detect conductive rocks are present near the surface. An example of
massive sulfide bodies within the resistive rocks of this type of regions is the recently glaciated areas
the Precambrian shield of Canada. The subsequent of North America, northern Europe, and Russia.
need to explore other kinds of geological environ- Besides the described techniques, the mag-
ments, combined with developments in EM sys- netotelluric method (MT) is a passive elec-
tems, has led to higher-sensitivity time-domain tromagnetic technique used for exploring the
systems now being used almost exclusively for conductivity structure of the Earth from tens of
mineral exploration. Airborne electromagnetic meters to a depth of more than 10,000 m. It is a
surveys are used in mineral exploration to discover survey method that utilizes the Earth’s telluric
mineral deposits such as sulfides containing cop- current produced in the ground by variations of
per or lead, magnetite, pyrite, unconformity-style the Earth’s magnetic field. The main applications
uranium mineralizations, kimberlite pipes, certain of this technique are in hydrocarbon explora-
manganese minerals, and paleochannels as poten- tion. Finally, ground-penetrating radar (GPR)
tial hosts for placer deposits and sandstone- and is a geophysical method that uses radar pulses
calcrete-hosted uranium deposits (Dentith and to image the subsurface, being utilized in rock,
Mudge 2014). On the other hand, the discovery soil, ice, fresh water, structures, etc. It can detect
of massive sulfide deposits that form major base changes in material as well as voids and cracks.
3.4 · Exploration Methods
157 3
–8.0
–10.0
–12.0 Contact
–14.0 Intensely
or clayey level
–15.0
karstified zone
–18.0
85+640 85+660 85+680 85+700 85+720 85+740
Karstified zone
–8.0
–10.0
–12.0 Contact
–14.0 Intensely
or clayey level
–16.0 karstified zone
–18.0
85+640 85+660 85+680 85+700 85+720 85+740
.. Fig. 3.25 Results of a GPR survey (Illustration courtesy of International Geophysical Technology)
This method has a great similarity with seismic Most seismic work uses reflection methods
method and may be considered as a mini reflec- because they produce better resolution than other
tion seismic survey. . Figure 3.25 is an example
techniques, with the exception of measurements
of a GPR survey. made in close proximity (e.g., as with borehole
logs). Seismic methods dominate oil industry since
Seismic Methods reflection seismic is the most important geophysi-
Seismic methods are based on measurements of cal method to prospect for oil and gas at greater
the time interval between initiation of a seismic depths. As aforementioned, these techniques are
(elastic) wave and its arrival at detectors in order comparatively little used in mineral exploration,
to obtain an image of the subsurface. The seismic mainly due to their high cost and because most
wave can be generated by an explosion, a dropped mineralizations in igneous and metamorphic rocks
weight, a mechanical vibrator, a bubble of high- display incoherent layering. Applications of these
pressure air injected into water, and other sources. techniques include searching offshore placers or
The seismic wave is detected by a geophone on land subsea resources of bulk minerals such as sands
or by a hydrophone in water. Since seismic waves and gravels. Where ores occur in sedimentary rocks
(e.g., P-waves and S-waves), which propagate with that are just gently folded or faulted, seismic surveys
different velocities in different rock types, are can be useful. However, reflection work onshore is
reflected and refracted at bedding or fault contacts, slow and expensive because geophones have to be
reflection and refraction are the most commonly positioned individually by hand and sources can
used seismic techniques. Refraction methods use need to be buried. The use of reflection in onshore
simpler equipment (. Fig. 3.26) and need less pro- exploration for solid minerals other than coal is
cessing than reflection methods. Compared with consequently rare, although Witwatersrand gold
other geophysical methods, the seismic method, in reefs, flat-lying kimberlite sills, and some deep
any of its forms, is rarely used in mineral explora- nickel sulfide bodies have all been investigated in
tion. this way (Eaton et al. 2003).
158 Chapter 3 · Mineral Resource Exploration
.. Fig. 3.27 Electromag-
netic airborne survey (Image
courtesy of Geotech)
Likewise, the mining industry uses detector therefore, they can be carried out from aircraft.
and/or seismic sources located in the subsurface, Obviously, there is a loss of sensitivity because
with access provided by drillholes or underground detectors are far away from sources. The main
workings. Thus, seismic surveys can map miner- merit of airborne work is that it enables coverage
alization between drillhole intersections and are of large areas quickly and inexpensively per unit
used for exploration at a prospect scale and dur- area. Moreover, airborne surveys measure physi-
ing mining. Seismic survey also utilized seismic cal properties of rocks and ores through dense
waves that are deliberately guided through coal vegetation, swamps, lakes, and soils, among
seams to gather information of its characteristicsmany others. They are usually part of the recon-
prior to mining (Dentith and Mudge 2014). naissance phase of mineral resource exploration,
although some modern airborne systems offer
Airborne Geophysics higher resolution by surveying very close to
Magnetic, electromagnetic (. Fig. 3.27), gamma- the ground and can find application in the later
ray, and more recently gravity measurements stages of exploration. Airborne geophysical sur-
do not need physical contact with the ground; veys are typically undertaken using low-flying
3.4 · Exploration Methods
159 3
helicopters or light aircraft that fly in a grid pat-
tern, being the instruments mounted on the air-
craft or positioned underneath. According to the
survey type, the aircraft can fly ranging from 20
to 70 m above the ground and the flight lines can
be delimited from 20 to 200 m apart. Airborne
investigations can be flown either at a constant
altitude or at a nominally constant height above
the ground, which is more common in mineral
exploration.
Since airborne methods need a very good
navigational control, airborne surveys have been
completely transformed by the use of global
positioning satellites (GPS). With this instru-
ment, velocities can be estimated with great
accuracy, making airborne gravimetry, which
requires velocity corrections, usable for the first
time in mineral exploration. In the near future,
pilotless drones can fly some airborne surveys,
especially aeromagnetic surveys. In fact, drones
are already used in topographic applications
(. Fig. 3.13).
with magnetics. Finally, airborne gravimetry mea- Borehole Geophysical Logging). Borehole geo-
sures the changes in the gravity field with an air- physical surveys result in the higher resolution
borne gravimeter on a helicopter or an aircraft. It of data, especially in conjunction with geologi-
involves using ultra-sensitive equipment, called a cal, physical, and chemical core logging results
gravimeter, to look at the structure density of rock (Ellis and Singer 2007). Downhole geophysical
in the subsurface of the Earth. New generation surveys increase the radius and depth of inves-
gravimeters back out the movement of the aircraft tigation and provide greater resolution of buried
from the data, providing a more accurate mea- targets. For instance, in the uranium industry,
surement. Once corrections are made to the data, borehole logging is actually a basic tool in the
critical information can be derived for mapping exploration and delineation of uranium deposits
purposes. (Mwenifumbo and Mwenifumbo 2013).
160
Chapter 3 · Mineral Resource Exploration
Box 3.5
.. Fig. 3.29
Borehole geophysical
logs Log10 (conductivity) Temperature gradient
(mK/m)
Low
High
12
0
60
60
70
70
80
80
Depth (m)
90
90
Depth (m)
100
100
110
110
120
120
130
3.4 · Exploration Methods
161 3
indicate the direction and even gamma, single-point resistance, emit relatively high gamma
the shape of targets. For instance, spontaneous potential, normal radiation because they include
downhole electromagnetic survey resistivity, induced polarization, weathering products of potassium
detects conductivity variations, fluid resistivity, temperature, flow- feldspar and mica and tend to
probably owing to mineralization, meter, television, and acoustic and concentrate uranium and thorium
in the volume surrounding the optical televiewer (. Fig. 3.30).
by ion absorption and exchange.
drillhole. Downhole geophysical For instance, the caliper probe The optical televiewer probe gets
surveys increase the radius and (. Fig. 3.28) measures the diame-
optical views of the wall and is
depth of investigation and provide ter of the borehole as a continuous useful in locating structures such
greater resolution of buried tar- record against depth and is used as faults and also bed boundaries
gets. For instance, exploration of an as a check of borehole condition where there is a significant change
iron ore body could be improved before casing operations or before in rock formation colors. Acoustic
by a density log. The located min- running more expensive log- televiewer tools have a transmitter
eralization can be split into layers ging probes. Gamma logs record that scans the borehole wall with
of magnetite and hematite using a the amount of natural gamma an acoustic beam, and the acoustic
magnetic susceptibility log. radiation emitted by the rocks sur- energy reflected at the borehole
Common geophysical logs rounding the borehole; clay- and fluid and rock interface is recorded
and/or probes include caliper, shale-bearing rocks commonly by a receiver.
.. Fig. 3.30
Acoustic and
optical televiewer
probes (Image
courtesy of
Enviroscan)
densities. Most exploration programs begin with during the 1930s (Garret et al. 2008). Modern
regional stream sediment sampling followed by surveys are conceptually similar to earlier sur-
soil and then rock sampling. Geochemical surveys veys but are considerably more complex in their
in mineral exploration are based on two features details. This complexity in modern geochemical
of an ore deposit: (1) association with abnormal surveys arises from several sources (Adcock et al.
concentrations of elements in the nearby rocks, 2013): (1) the number of samples collected in a
and/or (2) association with secondary scattered single survey can sometimes reach several thou-
patterns of elements in the surficial materials sand, and national- or continental-scale projects
of their weathering and erosion; it substantially can involve numerous surveys carried out over
increases the area in which evidence for the pres- several years. (2) different sample types (e.g.,
ence of a mineral target can be detected. glacial sediment, multiple soil horizons, water,
The most commonly measured chemical prop- vegetation) can be collected at each sampling
erty in a mineral or rock is the trace content of an site. (3) a sample can be processed in various
element or cluster of elements. The analyzed mate- ways (crushing, sieving, heavy and/or magnetic
rial can be rock, soil (. Fig. 3.31), gossan, glacial
mineral separation, washing, etc.) before being
debris, vegetation, stream sediment, or water. Thus, subjected to chemical analysis. (4) the sample
«the purpose of the measurements is the discovery can be analyzed by a variety of different meth-
of a geochemical anomaly or area where the chem- ods, by different laboratories, over a time period
ical pattern indicates the presence of ore in the of years or even decades. A clear example of this
vicinity» (Hawkes 1957). Obviously, the absence of complexity is the China Geochemical Baselines
such anomalies helps to eliminate areas for further project, which was carried out in 2008, being
consideration. However, it is essential to bear in sampling completed in 2012. The main goal was
mind that the basic geochemical question required to establish the abundance and spatial distribu-
60 years of discussion: what constitutes a geo- tion of chemical elements throughout the whole
chemical anomaly and how can this be enhanced China. Running the project, 6617 samples from
(sample processing and analytical methods) and 3382 sites were collected across the country
detected (a number of univariate and multivariate (Wang 2015).
mathematical techniques)? (Cohen et al. 2007). In general, a geochemical survey is divided
The modern techniques of geochemical pros- into the following phases: (1) planning, (2) sam-
pecting originated in the Soviet Union and Scan- pling, (3) chemical analysis, and (4) interpretation
dinavia where extensive research was conducted of data. As a general rule, samples are collected in
3.4 · Exploration Methods
163 3
689700 690000 690300 690600
ain
Sp
4162500
4162500
Murcia Region
Sp47 Sp48
Sp49
4162200
4162200
Sp45
S16 S18
Sp46 Legend
Sp42 Sp43
Sp44 Zn (Total sediments)
<P25
S10 S11 S12 P25 - Median
Sp36 Sp37 Sp38 Median - P85
>P85
4161900
4161900
Sp39
Sp40 S21 Sampling point
Sp31 Sp32
S3 Sp33 Sp41
S1 S2 S4 Sp34
Sp30 S5 N
S6 Sp35
Portman Bay
4161600
4161600
Mediterranean Sea
Tragsa
Research group:
689700 690000 690300 690600 Soil contamination E048-08
.. Fig. 3.32 Color contour map of a geochemical survey (Spain) (Illustration courtesy of Mari Luz García)
the field. They are brought to a laboratory facil- rocks at the time of ore formation. For instance,
ity where they are subjected to preparation prior some of the fluid permeates into wall rocks in
to analysis, including crushing, sieving, drying, hydrothermal deposits causing different altera-
and filtering. The prepared samples are then sent tions which include chemical changes. Halos of
to different laboratories for chemical analysis. this type are very useful in exploration since they
Where the data are returned, they are verified and can commonly be hundreds of times larger than
reported typically in a spreadsheet format, with a the mineralization they surround. Moreover, they
set of rows and columns. Finally, these data are extended both laterally and vertically, hence being
processed using different statistical methods (e.g., easier to locate. Primary dispersion halos have a
multivariate analysis) and displayed commonly as great variety of sizes and shapes due to the numer-
color contour map (. Fig. 3.32). The objective is
ous variables that influence fluid movement in
to establish a geochemical anomaly that separates rock. Thus, some halos can even be identified at
the mineral deposit from enhancements in back- distances of hundreds of meters from their related
ground and nonsignificant deposits. mineralization. The factors that control the devel-
opment of primary halos are manifold: fractures
rimary and Secondary Geochemical
P in the host rock, porosity and permeability of
Anomalies the host rock, inclination of mineralizing fluids
Geochemical anomalies are commonly divided to react chemically with the host rock, and so
into primary or secondary. The primary geo- on. Obviously, the composition and distribution
chemical anomalies are formed as by-product of of these primary halos depend on the type of
the processes that concentrate ore; they are larger deposit. For instance, porphyry copper deposits
than the ore target itself. As defined originally by usually display chemical halos that measure hun-
Safronov (1936), «the primary halo of a mineral dreds of meters horizontally and vertically.
deposit is an area including rock, surrounding Since trace elements of mineralization and
mineral deposit (ore bodies) and enriched ele- their linked primary halos are commonly dis-
ments that make up that deposit.» In general, charged by weathering processes to soils, overbur-
primary dispersion halos are produced in the host den, and vegetation, they generate a subsequent
164 Chapter 3 · Mineral Resource Exploration
generation of enrichment called secondary halos. by classical analytical procedures (. Table 3.3).
Thus, secondary geochemical anomalies or halos For instance, arsenic is commonly utilized as a
are formed by processes that acted on the deposit pathfinder in exploration for gold. The choice of
after its formation. These types of halos are gen- pathfinder elements/metals depends on many
erated by mechanical breakdown and chemical factors such as consistency of association with
dissolution of rocks and ores. Chemical weather- the ore deposits sought, characteristics of primary
3 ing involves breakdown of rocks and minerals by dispersion, and ease with which geochemical
chemical means with further discharge of their analysis can be performed (Levinson 1974).
contained trace elements to the environment. The variable mobility of elements is of great
It requires abundant water, oxygen, and carbon significance in the process that causes secondary
dioxide. In general, chemical weathering is more dispersion. Elements with high mobility under sur-
abundant in tropical regions although it can also ficial conditions enlarge the anomalous zone. For
be substantial in temperate areas. In turn, physi- instance, a project targeting polymetallic deposits of
cal weathering includes all processes of rock dis- Pb, Zn, and Cu would use mobile Zn for regional
integration not involving chemical changes, being sampling with a low density, whereas dense sam-
more frequent in very cold or hot arid regions. pling of Zn anomalies for Cu and Pb should reveal
Mechanical breakdown and further trans- the drilling targets (Pohl 2011). In this context, there
port in surface water runoff concentrate resistant are many important properties in the elements such
minerals such as cassiterite, rutile, monazite, as electronic configuration, ionic potential, pH and
diamonds, gold, etc. Therefore, anomalies are Eh, trend to originate complexes with organic mat-
detected by heavy mineral panning of stream sed- ter, and trend to coprecipitate or to be absorbed with
iments or soils. Other minerals can be dissolved iron or manganese hydroxides.
and the metals can be either redeposited locally or The mobility of elements in secondary disper-
carried away into solution by ground- and surface sion is strongly influenced by factors including
water. Groundwater frequently dissolves some of the nature of rocks, climate, vegetation, relief, and
the constituents of mineralized bodies that can be groundwater flow. Thus, in cold climate, large and
transported along considerable distances before well-defined anomalies do not develop because
eventually emerging in springs or streams. During chemical dissolution is inefficient and drain-
dispersal, the elements can be reconcentrated in ages are poorly developed; in dry, arid climate,
vegetation, on clay minerals, or in organic matter, chemical dissolution is ineffective and dispersal
all of which are attractive sampling media in geo- by occasional flash floods does not lead to the
chemical exploration. Regarding the vegetation, formation of well-defined anomalies. By contrast,
some metals in solution can be collected by plants in tropical climate decomposition and leaching
and trees and then concentrated in the living tis- of the ore-forming elements can be so complete
sue. In some cases, the element that originates the that no traces of the metals remain in weathered
most important primary halo is not necessarily rocks or soils. Therefore, the best environment for
the one of greatest economic significance in the geochemical exploration is located in a temperate
mineralization. climate in regions of gentle topography, in which
Mobility is an indicator of how far an element abundance of water and warm temperatures leads
can go dissolved in water, broadening the signal to effective dissolution of ore minerals and the
originated from the mineral deposit. For this rea- gentle topography fosters both chemical dissolu-
son, the usefulness of the mobility of an element is tion and the development of good secondary dis-
essential in geochemical prospection. This type of persion halos (Gocht et al. 1988).
element is commonly referred to as a pathfinder.
The pathfinders are very useful in geochemical Stream Sediment Sampling
exploration since their halo is generally greater Stream sediment geochemical surveys are the cor-
than that of the element with the most economic nerstone of all types of reconnaissance exploration,
interest or because it can be identified more easily mainly in regions undergoing active weathering.
3.4 · Exploration Methods
165 3
Stream sediment sampling can be applied only if a fractions commonly include pebbles, which are
well-developed drainage system is present. In this usually depleted in trace elements.
technique, stream sediments are taken from active Panning heavy minerals to obtain concen-
stream channels and studied to find anomalous trates is also a classical method of stream sedi-
element concentrations since the sediment sample ment studies, being a very useful geochemical
from an active riverbed is considered to represent prospecting technique (e.g., panning for gold).
3 an average of its upstream watershed. Thus, the Panning refers to the process in which a sample
objective is to obtain sample(s) representative of is agitated in water to separate minerals by their
the catchment area. The relatively easy use of the specific gravity. Thus, heavy mineral panning is
method leads to a quick evaluation of regions at widely employed for searching native elements
fairly low cost. such as gold grains, platinum, diamonds, and
Small streams give maximum resolution and heavy resistant mineral grains such as magnetite,
sharpest contract, as opposed to large streams in zirconium, ilmenite, rutile, monazite, and cassit-
which any anomaly from a mineralized zone will erite. If positive results are obtained, immediately
be diluted by large amounts of stream sediment follow-up campaign is carried out to look for the
from barren areas. Sampling densities are about source of the anomaly.
one sample per two square kilometers in regional
reconnaissance programs. In more detailed inves- Soil Sampling
tigations, higher density of sampling density is Soil sample geochemistry is a powerful tool in the
usually carried out depending on the local con- exploration of anomalies found by stream sedi-
ditions and the characteristics of the target. For ment investigations. The method works very well
instance, sampling densities can range from one since weathering and leaching of buried deposits
sample over 100 km2 in reconnaissance studies can discharge anomalous concentrations of ele-
to a few samples per km2 in more specific follow- ments to soil and groundwater. The released heavy
up. In general, the values of the background and metals spread outward and originate a dispersion
anomalous element concentrations are computed halo in the soil that is much larger than the min-
statistically, and metal distributions are illustrated eral deposit itself. As a rule, the dispersion halos
in geological maps. Previously, samples are sieved in soils are smaller than those in stream sediments
to 80 mesh (0.157 mm) and the fine fraction is but larger than those in primary halos in rocks.
analyzed since it reflects better metal anomalies. Similar to stream sediment sampling, samples col-
It is important to remember that the coarser lected (. Fig. 3.33) are commonly the fine silty or
interest, background concentrations are low, delineation of mineralized felsic plutons and
enhancing anomaly contrast» (Leybourne and exhalative horizons because these plutons with
Cameron 2007). Interpretation of groundwater mineralization of copper and tungsten are com-
geochemistry in mineral exploration is easier if monly enhanced in these elements, although
data related to the local and regional hydrology invariably display a high variability inside the
is available. pluton. For instance, tin mineralization associ-
3 ated with highly evolved and altered intrusive
Rock Sampling bodies is delineated examining the geochemistry
Rock geochemical surveys seek the primary dis- of minerals such as micas.
persion halo around mineral deposits. Because
this type of halos is restricted to a small area Biogeochemical Sampling
immediately surrounding any prospective min- Biogeochemistry is a viable first-pass exploration
eral deposit, rock surveys are mainly applied to method, and it can show multi-element halos at
evaluate specific targets outlined by regional small scale, being more refined if more detailed
surveys. Although this technique has been also exploration methods are carried out in the target.
applied with relatively good results in regional Biogeochemical sampling is a relatively cheap,
reconnaissance, it becomes most effective in efficient, and environmentally passive method in
detailed campaigns (Moon 2006), being rock sam- the initial stages of mineral exploration programs
pling included in the techniques devoted to for (Reid and Hill 2010). Biogeochemical tech-
follow-up mineral exploration. It provides direct niques utilized in mineral deposit prospecting
evidence about the geochemical characteristics of are based on soil and plant relationships. In this
the rocks that cause the anomaly, helping in the sense, plants incorporate elements from soil and
geological interpretation of stream sediment and groundwater into their branches and leaves, and
soil surveys (Govett 1983). this absorption of trace elements depends on the
Geochemical exploration with rock samples or plant species, plant organs, grow stage, and soil
selected minerals is based on specific geological- type. Biogeochemical exploration with sampling
petrological models. Examples include regional and chemical analysis of plant tissues has been
sampling of granites in order to locate fertile utilized extensively in Canada and Russia and
intrusions, discrimination of prospective and more recently in Australia (Närhi et al. 2014).
barren porphyries by analyzing copper in bio- Plant samples (. Fig. 3.35) have benefits com-
tite, and identification of rare metal pegmatites pared to other sample media in terms of provid-
by muscovite analysis (Pohl 2011). On a regional ing data that represent a broad area, due to their
basis, the most successful applications deal with deep spreading root systems. Biogeochemical
.. Fig. 3.35 Biogeochem-
ical sampling of plants
(Image courtesy of Andrea
Castaño)
3.4 · Exploration Methods
169 3
exploration «relies on the fact that plant roots Gases are potentially an attractive medium
penetrate soil horizons, have access to weathered/ to sample because they can diffuse through thick
fractured bedrock and associated groundwater, overburden. Thus, a number of gases have been
and accumulate elements in their organs» (Dunn used in mineral exploration: sulfur vapors indi-
2007). Accordingly, if some plant organs include cate the presence of sulfide deposits, radon gas
excessive amounts of particular metals, they can guides to uranium deposits, and gaseous hydro-
be used as indicators of ore zones in bedrock for carbons reflect the presence of petroleum and
geochemical exploration (Brooks et al. 1995). natural gas. However, mercury has been the
Plant growing on soil is dramatically affected most successful gas studied in mineral prospect-
by the host soil composition, which leads to the ing due to mercury is the only metallic element
selection of specific flora. Thus, plants answer to that constitutes a vapor at room temperature.
elemental composition of soil in three ways: exclu- Thus, it is widely present in sulfide deposits, par-
sion, indication, and accumulation (Rajabzadeh ticularly volcanic-associated base metal depos-
et al. 2015). Biogeochemists use soil indicator its. Enrichment of carbon dioxide and depletion
plants for prospecting ore deposits. For instance, of oxygen produced by weathering of sulfide
because serpentine plants have been studied and mineral deposits have been tested recently.
ultramafic rocks are profuse on the crust of the The results are commonly inconsistent due to
Earth, plants growing on serpentinized materials the large changes in gas concentration (partial
are satisfactorily utilized in biogeochemical explo- pressure) caused by variations in environmental
ration (Freitas et al. 2004). conditions, specifically changes in pressure and
rainfall.
Gas Sampling
At present, mineral deposits susceptible to be Indicator Minerals
prospected are commonly buried deep below Indicator minerals are mineral species trans-
the surface of the Earth. However, the alteration ported as grains in clastic sediments and indi-
and oxidation of a deposit release gaseous com- cating the presence in bedrock of a specific type
ponents that can be detected at the surface using of mineralization, hydrothermal alteration, or
gas samples from soil or down drillholes. This lithology (. Fig. 3.37). The preservation and
method can identify a few different gases if they identification of these minerals is provided
are present in sufficient amount (e.g., mercury, by their physical and chemical characteris-
oxygen, CO2, and radon) (. Fig. 3.36). The char-
tics, including relatively high density. They
acteristics of these gases and their concentration are quickly recuperated at the parts per billion
can provide hints on minerals occurring at depth level from stream, alluvial, glacial, or aeolian
and, consequently, where a mineral deposit can be sediments or soils producing large exploration
present. targets. Indicator mineral methods differ from
.. Fig. 3.36 Measure-
ment of soil radon using
a soil gas probe (Image
courtesy of DURRIDGE
Company Inc.)
170 Chapter 3 · Mineral Resource Exploration
.. Fig. 3.37 Zircons
used as indicator minerals
(Image courtesy of Javier
Fernández)
traditional geochemical methods for soil, stream only a few grains, equivalent of ppb-level indica-
sediment, or till sampling in that the indicator tor mineral abundances (Averill 2001). One of
grains reflect mechanical dispersion and the the most important and typical occurrences in
individual grains are visually examined and the application of indicator mineral techniques
counted. The greatest advantage of indicator was the bloom in diamond exploration activity in
mineral methods over traditional geochemical the glaciated terrain of Canada, which originates
analysis of the heavy mineral or some other frac- drastic changes in the concepts of sampling and
tion is that the mineral grains are visible and can processing methods because indicator minerals
be studied (McClenaghan 2005). The choice of improved the knowledge of kimberlite host rock.
sample media will depend on the climate, topog- Since most of Canada has been glaciated, the gla-
raphy, and size of area to be sampled. For exam- ciers advanced, eroded, homogenized, and redis-
ple, in glaciated terrain, till is most often used tributed the components of the bedrock that they
for indicator mineral surveys due to its simple pass over. For this reason, diamonds in glacial
transport history. Stream and alluvial sediments drift are the best indicators of a bedrock source
are sampled in glaciated, temperate, tropical, of diamond. However, they are very scarce even
and arid terrains. In turn, aeolian sediments can in the highest-grade diamond-bearing rocks. For
be sampled in arid terrain where other media are example, one carat – 0.2 g – of diamond per ton
not available. of mineralization is regarded a very high-grade
Nowadays indicator minerals are used to diamond deposit. As a result, indicator minerals
detect a great number of mineral deposits such as are an indirect but very useful tool to locate bed-
diamond, gold, Ni–Cu, PGE, porphyry Cu, mas- rock sources of diamond.
sive sulfide, and tungsten deposits. The resulting
benefits of using indicator minerals are numer- Analytical Methods
ous: (1) the ability to detect halos or plumes The analytical methods applied in geochemi-
much larger than the mineralized target includ- cal exploration depend on the requirements of
ing associated alteration; (2) physical evidence exploration stages. Techniques can be grouped
of the presence of mineralization or alteration; according to the attribute being measured. Some
(3) the ability to provide information about the techniques utilize X-rays in different forms for
source that traditional geochemical methods analytical objectives, while other techniques use
cannot, including nature of the ore, alteration, the optical effects of samples. Obviously, each
and proximity to source; (4) sensitivity to detect method has a minimum detection limit and
3.4 · Exploration Methods
171 3
below the concentration cannot be calculated. expected. In developed countries, most common
Therefore, geochemical analysis has a degree of analysis is actually performed by inductively
uncertainty, being uncertainty expressed in terms coupled plasma optical emission spectrometry
of precision. The theoretical lower detection limit (ICP-OES), often in combination with inductively
is an intrinsic function of the technique, although coupled plasma mass spectrometry (ICP-MS)
the quality of the calibration and the cleanliness and X-ray fluorescence (XRF) (. Box 3.6: X-Ray
of the equipment used in sample and standard Fluorescence Analysis). The three methods require
preparation also limit detection. The goal of most numerous constraints such as highly sophisticated
analysis is the determination of the trace metal laboratories, very pure chemicals, continuous
concentrations in a sample, but currently it is still and nonfluctuating power supplies, and readily
impossible to analyze all elements simultaneously available service personnel, among others. In less
at the needed levels. sophisticated situations, relatively high quality
The differences between methods are the analysis can be carried out using atomic absorp-
costs involved, analysis detection limits, velocity tion spectrophotometry (AAS), which was the
of analysis, and the requirement to take material most commonly utilized technique in developed
into solution. The method selected will depend countries until 1980. Regarding individual miner-
upon the element being analyzed and the amount als, detailed identification is commonly provided
Box 3.6
utilizing a scanning electron microscope (SEM) or limits for certain elements can be as low as parts
an electron microprobe. per trillion level in aqueous solutions. AAS uses
The advent of sensitive, rapid throughput the absorption of light to estimate the concen-
instrumentation such as ICP-OES and ICP-MS tration of gas-phase atoms. Concentrations are
used to complement one another has revolu- commonly established using a working curve
tionized exploration geochemistry in the last after calibrating the instrument with standards
decades. ICP-OES and ICP-MS are widely used of known concentration.
because of their convenient, virtually simulta- In exploration geochemistry, it is very
neous multi-element capabilities. Plasma used important to note that absolute element con-
in these techniques permits the simultaneous tent in a sample is not always necessary or,
analysis of up to 40 elements, which means that in other words, accuracy cannot be essential.
ICP-MS and ICP-OES (. Fig. 3.39) are multi-
Deviations of ±30% from the absolute value,
element techniques. In some cases, detection for example, using international standards, are
.. Fig. 3.39 ICP-OES
instrument (Image cour-
tesy of AGQ Labs)
3.4 · Exploration Methods
173 3
endured, if the relative error remains within and further model building (Grunsky 2010). It
narrow limits. In contrast, excellent reproduc- involves the use of automatic and knowledge-
ibility of results (high precision) is needed. In based procedures for the recognition of patterns
fact, this is the most important characteristic of that can be attributed to known processes (e.g.,
any data evaluation, particularly if the contrast crystal fractionation, hydrothermal alteration, or
between background and anomalies is small. weathering).
In all geochemical programs, error control is According to Grunsky (2010), issues dealing
a fundamental aspect, and for this reason, it is with geochemical data are numerous: «(a) many
good practice to repeat at least 10% of sampling elements have a censored distribution, meaning
and/or control the data by another laboratory that values at less than the detection limit can
(Pohl 2011). The process of analysis is gener- only be reported as being less than that limit; (b)
ally done at some distance from the explora- the distribution of the data is not normal; (c) the
tion project, which means that analytical data data have missing values: not every specimen
is usually accepted and utilized without making has been analyzed for the same number of ele-
criticisms. However, while most laboratories ments; often, missing values are reported as zero,
generate good quality results, they are usually which is not the same as a specimen having a zero
looking for a business to make a profit. For this amount of an element and this can create compli-
reason, a good quality control minimizes biases, cations in statistical applications; (d) combining
confirms that laboratory assays are correct groups of data that show distinctive differences
within a defined degree of accuracy and preci- between elements where none is expected; this
sion, and detects the presence of contamination can be the result of different limits of detection,
between samples. instrumentation or poor quality control pro-
cedures; and (e) the constant sum problem for
Interpretation of Data compositional data.» These problems generate
Introduction difficulties to apply typical statistical procedures
Once the analytical data have been obtained to the data. For instance, in the case of varying
from the laboratory and the results are checked detection limits, the data need separation into
for precision and accuracy, the next question is the original groups so that appropriate adjust-
how to treat and interpret the data. A geochemi- ments can be applied to the groups of data. To
cal exploration data set consists mainly of sample avoid the problems of censored distributions, dif-
location and values of element concentration in ferent processes have been designed to estimate
many samples. Since the data are usually multi- replacement values for the objectives of statistical
element and the number of samples is large, the calculations. On the other hand, if missing values
use of statistical analysis using computer software are present, several methods can be provided to
is essential. This is because the development of impute replacement values that have complete
low-cost, rapid multi-element analytical tech- analyses.
niques has originated large geochemical databases The normal concentration of an element in
in many exploration programs, including usually non-mineralized Earth materials is referred to as
thousands of observations with as many as fifty or background, which fluctuates around a mean value.
more elements. Thus, the resulting data matrix is It is more realistically viewed as a range of values
enormous, and effective interpretation utilizing all rather than an absolute value because the distribu-
of the elements becomes cumbersome. tion of any element in any particular Earth mate-
To study these large matrices, the use of multi- rial is rarely uniform and varies considerably from
variate statistical techniques can extract geochemical one type of Earth material to another and from one
patterns related to the underlying geology, weath- location to another. The upper limit of the range of
ering, alteration, and mineralization. Modern background values is called the threshold, and uni-
methods of evaluating data, structures, and pat- element concentrations greater than the thresh-
terns are clustered under the term «data mining.» old are collectively called anomaly. Regarding
This term involves the use of multivariate data the concept of threshold, it is possible that in the
analysis and statistical methods in combination same exploration project, a lower threshold can be
with geographic information systems and signifi- applied in regional exploration, whereas a higher
cantly assists the objective of data interpretation threshold is selected to locate the best targets
174 Chapter 3 · Mineral Resource Exploration
Maximum
Positive (right) skewed
3rd quartile
Median
.. Fig. 3.42 Histogram
50
3
40
Frequency
30
20
10
4% 5% 6% 7% 8%
Grade
curve representative of a normal distribution looks evaluation, the use of geostatistical procedures
like «S.» A probability plot is a special adaption of provides quantification of the spatial variabil-
that curve when the Y axis is scaled in such a way ity of an element, for instance, by construct-
that a normal distribution plots as a straight line. In ing a semivariogram. Semivariograms measure
probability plots any deviations from normality can the average variance between sample points at
be quickly identified (. Fig. 3.43). These plots have
specific distances (lags). Usually, the variance
been applied in the splitting of univariate, polymodal increases as distance increases between any pair
geochemical populations into unimodal subpopula- of points. Thus, evaluation of the semivariogram
tions as they help in the identification of anomalies. allows assessing the spatial continuity of an ele-
Cumulative frequency diagrams and probability ment. The effectiveness of applying geostatistical
plots are better than histograms in displaying data. methods relies on adequate sampling density to
Equivalent to normal probability plots are represent the variation of the data.
quantile-quantile (Q-Q) plots. They also allow The effective use of geostatistical techniques
graphical comparison of a frequency distribution requires knowledge and experience in order
with respect to an expected frequency distribu- to model and extract information from spatial
tion (usually the normal distribution). In the data. They permit better estimates of geochemi-
Q-Q plots, the quantile values are calculated for cal trends though geostatistical techniques must
the normal frequency distribution, and then they be used with the awareness of the problems with
are plotted against the ordered observed data. The techniques of interpolation and the spatial behav-
plot will be a straight line where the frequency ior of the data (Grunsky 2010).
distribution is normally distributed, but it will be
curved or discontinuous for skewed frequency Contoured Plans and Profiles
distributions or for polymodal populations. Contour plots of both plans and sections can pro-
vide relevant information where variables are grada-
Geostatistical Techniques tional in nature, and this gradational character exists
Although geostatistics will be described in detail between control points. Contours indicate trends,
in the next chapter because this technique is directions of preferred elongation and indications if
mainly devoted to mineral resource/reserve more than one domain is needed. Since contouring
3.4 · Exploration Methods
177 3
.. Fig. 3.43 Normal prob-
ability plot
60
50
Grade (%)
40
30
1 5 10 25 50 75 90 95 99
Percent of data
some kind of interpolation criterion to construct a Normal distributions of the data are not assumed
regular grid of values that can be contoured easily. in X-Y plots, but log transformation can be used
Interpolation algorithms include inverse distance in scaling the data. The resulting plots supply bet-
weighting, nearest point, and triangulation or krig- ter visual estimate of the relationship between
ing, among others. This graphical expression of the two variables and can highlight clusters within
data is commonly used not only for geochemical the data. This can be improved by display in a
data but also in geophysical surveys. scatterplot matrix that allows to represent X-Y
plots for every variable against every other vari-
Bivariate Methods able simultaneously.
This section considers the analytical methods
used if it is necessary to take in account simulta- Correlation Coefficients
neously the variation of two variables where both Correlation is an exploratory technique used to
are measured on each element in a sample. In examine if the values of two variables are sig-
addition to providing extra information about the nificantly related. It means that the values of both
frequency distribution of a sample, these methods variables change or are not together in a consistent
generate information on the relationship between way. There is no expectation that values of one vari-
variables (Swan and Sandilands 1995). All the able can be predicted from the other or that there
techniques of bivariate statistics can be regarded is any causal relationship between them (McKillup
as ways of describing and analyzing the shape of and Dyar 2010). Quantitative correlation and cal-
the bivariate scatter. culation of simple linear correlation coefficients
178 Chapter 3 · Mineral Resource Exploration
5.5
3
Specific gravity
5.0
4.5
4.0
5 6 7 8 9 10 11
Grade
are useful tools for estimating the degree of inter- Regression Analysis
dependence between two variables. This can be of The correlation coefficient measures the strength
great importance provided that it can indicate that of the relationship between two variables. In
the variables are linked, directly or indirectly, in the contrast, regression analysis leads to express the
underlying causative geochemical process. nature of the relationship in quantitative terms.
The most common correlation coefficient used Thus, regression analysis is used to describe the
is the Pearson correlation coefficient (abbreviated functional relationship between two variables
to r). This coefficient is defined as the covariance so that the value of one can be predicted from
of the two variables divided by the product of their the other. Regression analysis is often preferred
standard deviations. As explained in a next section, to measure the linear relationship between
the concept of R-mode factor analysis is based on two variables because the nature of the bivari-
the correlation coefficients among a large number ate relationship can be more precisely defined
of variables. Correlation coefficients are dimen- in the form of equation. Regression analysis
sionless. They range between +1.0 (perfect positive is essential in geochemistry and geology since
linear relationship) and −1.0, the latter value repre- the derived equation can be used to describe
senting a perfect negative relationship (. Fig. 3.45). and aid understanding of the geological process
Real data rarely lead to perfect, whether positive or and permits predictions to be made (Swan and
negative, correlation. Like other summary statis- Sandilands 1995).
tics, the correlation coefficient can display abnor- In the case of simple linear regression, a set
mal values in the nature of the distribution. These of bivariate data, expressed graphically as X-Y
must be always rectified before any important con- plots, is fitted with a straight line, which can or
clusions are drawn from the data or if the correla- cannot pass through the origin. This line repre-
tion coefficient is used as input to other statistical sents a close relationship between the dependent
methods like factor analysis. A classic example is a variable (normally plotted on the Y axis) and the
low value of the correlation coefficient in a group of independent variable (X axis). Total deviation of
essentially random bivariate data, which increases the predicted values from the observed values is
excessively where a single outlier is introduced in estimated. Moreover, the deviations are squared
the data set. It is important to remember that lin- to remove the plus or minus effects so that the
ear correlation will only detect linear relationship method is known as «least squares.» Sometimes,
between variables. Sometimes two variables are the values of dependent and independent vari-
clearly related, but their correlation coefficient is ables are fitted with a curve, rather than a straight
near zero, since this correlation is not linear. line, and it is called polynomial regression.
3.4 · Exploration Methods
179 3
analysis techniques. The multivariate methods
a most commonly employed in studying and quan-
tifying multi-element associations in exploration
geochemical data include principal components
analysis (PCA), factor analysis (FA), cluster analy-
sis (CA), and discriminant analysis (DA). PCA
and FA are useful in studying inter-element rela-
tionships hidden in multiple uni-element data sets,
CA is utilized for studying inter-sample relation-
ships, whereas RA and DA are useful for studying
inter-element as well as inter-sample associations
(Carranza 2009). It is important to note that multi-
variate analysis requires large samples: in the same
way that two observations on a pair of variables are
sure to give a correlation coefficient of 1; multivari-
r = –1
ate data with few observations on many variables
will give misleading results.
b
Triangular Diagrams
Triangular or ternary graphs are used routinely to
display relative compositions of samples in terms
of three variables. In cases where metal abundance
differs by several orders of magnitude, multiplica-
tion of one or two of the elements by an appro-
priate factor is common practice, this resulting
in spreading of the plotted points over much of
the triangular field. This procedure leads to strong
distortion of the ratio scales in the diagrams. In
the triangular diagram, each apex represents
100% of one of the elements and the coordinates
are numbered for one element on each side in a
r = +1 clockwise direction. It is only necessary to know
the percentages of two of the three variables to
plot the point.
.. Fig. 3.45 Correlation coefficient of: a maximum nega-
tive = −1; b maximum positive = +1 Multiple Linear Regression
Multiple linear regression is a straightforward
extension of simple linear regression. Where there
Multivariate Methods is no single variable sufficiently closely related to
Multivariate statistics relate several elements to the variable being estimated, several variables can
each other and facilitate the geochemical inter- be taken together and the estimate of the derived
pretation of multi-element data. Multivariate variable will be satisfactory. For example, the sedi-
methods are important because virtually all geo- ment yield of a river can be dependent on its drain-
chemical data are inherently multivariate. Leaving age area plus other factors such as topographic
aside some methods such as triangular diagrams, relief, precipitation, and flow rate (McKillup and
multiple linear regression, or multi-element Dyar 2010).
indices, multivariate data analysis techniques
simplify the variation and data relationships in a Multi-element Indices
reduced number of dimensions or groups, which Methods exist for dealing with multi-element
can commonly be tied to specific geochemical/ data that strictly do not involve multivariate sta-
geological processes. Many specific texts, (e.g., tistics. The calculation of multi-element indices
Davis 2002), include basics of multivariate data is an example of how element associations can be
180 Chapter 3 · Mineral Resource Exploration
0.4
of principal component MFd
samples and variable MFc Nd, Sm,
scores (Chen et al. 2015) MFb Ca, La,
0.3
RD
PR
0.2
Oxide minerals
Principal component 2
0.1
0.0
-0.1
-0.2
-0.3
Dravitic tourmaline
-0.4
-0.4 -0.3 -0.2 -0.1 0.0 0.1 0.2 0.3 0.4 0.5
Principal component 1
applied to optimize features such as types of min- The linear combinations are derived from some
eralization or lithologies. Under certain circum- measure of association such as correlation or cova-
stances, some elements are deserving of greater riance matrix. Principal components are chosen
weighting in such an index because of their in such a way that the first principal component
greater importance as pathfinders for the deposit accounts for most of the variation in the data set
type sought. If detailed multivariate analysis can- and subsequent components for decreasing amount
not be achieved because of time limitation, the of variation. The interpretation of PCA results
calculation of multi-element indices provides points to geological/ geochemical interpretation
a way of combining the tendency of certain ele- on the element loadings comprising the compo-
ments to be enriched in mineralization. nents. Ideally, each principal component might be
interpreted as describing a geological process (e.g.,
Principal Components Analysis crystal fractionation, mineralization processes, or
Principal components analysis, one of the oldest weathering). . Figure 3.46 shows an example of a
% Var. expl. 36 18 15 11
relation coefficient so that distortion by outliers of the most widely used multivariate procedures
can be avoided. in Earth sciences. Discriminant analysis uses
182 Chapter 3 · Mineral Resource Exploration
.. Fig. 3.47 Graphical
representation of groups 6
using discriminant func- Sample group 1
tions 1 and 2 5 Sample group 2
Sample group 3
4
Sample group 4
3
-1
-2
-3
-4
-5
-8 -6 -4 -2 0 2 4 6 8 10
all of the analyses in a data set, being the objec- of the mineralization and must determine its
tive to maximize the distinction between two shape and continuity by studying the samples col-
or more previously defined groups. It enables lected from every drill target of the drill program.
the further allocation of samples of unknown Mining requires drilling mainly for two differ-
origin based on analyses of the same elements. ent goals: (1) production drilling, making holes
The objective is to find discriminant functions: to place explosives for blasting (the holes drilled
these are vectors in the directions of optimal for this purpose are defined as blasthole and this
separation between the groups, and they trans- topic will be covered in the exploitation chap-
form the original set of measurements on a ter), and (2) exploration drilling, to estimate the
sample into a single discriminant score. The amount and grade of a mineralization using the
discriminant function provides not only the sample collections (. Fig. 3.48). Likewise, drilling
possibility of assigning samples of unknown is a continuous process throughout the entire life
association to one of these two groups but also of the mine to supplement reserve for the mined
of measuring the degree to which each of the ore. This will increase the mine life and continue
variables contributes to the classification. mining operation. Moreover, it also upgrades the
categories of the reserves by using underground
drilling. A strategically placed underground drill-
3.4.6 Drilling ing program can even probe for new ore bodies in
the neighborhood.
Introduction Drilling is the most frequently used technol-
Where an anomaly is found, by using geophysi- ogy in mineral exploration, and it is usually the
cal and/or geochemical prospection, the mining most expensive because its expenditure can reach
company will initiate a drilling program in order up to half of the costs of total exploration. In
to test the extent of the mineralization. The den- most cases, drilling locates and defines economic
sity of drilling will be set up by the wanted level of mineralization. The first objective of drilling is
geological confidence and project economics. The to safely obtain representative samples of the
drill program searches to confirm the presence target mineralization in a cost-effective manner.
3.4 · Exploration Methods
183 3
Rock Drillability
Rock drillability is defined as the penetration
rate of a drill bit into the rock. It is a feature that
cannot be exactly defined by a single mechanical
property of the rock. For this reason, drillability
is a function of numerous rock properties such
as mineral composition, grain size, texture, and
weathering degree. Quartz is one of the common-
est minerals in rocks. Since quartz is a very hard
material, high quartz content in rock can make it
very hard to drill and will certainly cause heavy
wear, particularly on drill bits. On the other hand,
a coarse-grained structure is easier to drill and
causes less wear of the drill string than a fine-
grained structure.
Drillability is not only decisive for the wear of
tools and equipment but is, along with the drill-
ing velocity, a standard factor for the progress of
drilling works. Hoseinie et al. (2008) suggest that
the most important rock mass parameters that
affect the drilling are the following: the origin of
the rock’s formation, the Mohs hardness, the tex-
ture of the rock (shape and size of grains), poros-
ity, density, abrasiveness, rigidity, P-wave velocity,
elasticity and plasticity, UCS (point load index
.. Fig. 3.48 Preparing samples after drilling (Image
and Schmidt hammer), tensile strength, struc-
courtesy of Anglo American plc.) tural parameters of the rock mass (joints, cracks,
and bedding), and RQD.
The factors that concern the drillability of
The rock types are defined using the study of the rocks are numerous and can be classified into
samples, and portions of them are commonly two main groups: controllable and uncontrollable
chemically analyzed with the aim of further parameters. Regarding the controllable param-
characterization of rock types and to search the eters, these are bit type and diameter, rotational
existence of valuable minerals. Thus, the differ- speed, thrust, blow frequency, and flushing. Rock
ent methods of drilling are for diverse objectives properties and geological conditions are uncon-
at various phases of an exploration program. trollable parameters (Yarali and Kahraman 2011).
Studying drill core also allows for geotechnical/ The drillability of rocks depends on not only their
rock mechanics data, being logs gathered during physical properties but also on the type of drill
surface drilling. being used and drilling parameters such as rota-
There are a large number of drilling tech- tion speed, feed rate, etc. The physical properties
niques. This heading is centered on the three of rocks which have some effect on drillability are:
main types used in mineral exploration: reverse 1. Crushing strength, defined as the pressure a
circulation (RC) drilling, rotary drilling using tri- rock sustains before breaking and related to
cone roller bits, and diamond core (DC) drilling. grain hardness and strength, grain bond
Each drilling method has its own characteristics, strength, porosity, and weakness planes.
which affect the quality of the collected samples. 2. Toughness, a measure of how difficult it is to
DC drilling generates a cylinder-shaped sample of pull a rock apart and related to grain shape
the ground at an accurate depth. On the opposite, and bond, fissibility, and tenacity.
RC drilling and rotary drilling using tricone roller 3. Chip separation, this is how readily the
bits yield a crushed sample that includes cuttings cuttings are cleared from the face, and it is
from a precise depth in the drillhole. related to pore pressure and permeability.
184 Chapter 3 · Mineral Resource Exploration
4. Abrasiveness, the ability to wear downhole will be the wear. Thus, in most cases the DRI and
tools and related to grain hardness and shape BWI are inversely proportional to one another.
(Hartley 1994). However, the presence of hard minerals can pro-
duce heavy wear on the bit despite relatively good
The Norwegian Technical University has defined drillability. This is particularly the case of quartz,
two methods to evaluate the rock drillability: the which has been shown to increase wear rates
3 drilling rate index (DRI) and the bit wear index greatly. Certain sulfides in ore bodies are compar-
(BWI). The DRI describes how fast a particular atively hard, impairing drillability (Samuelsson
drill steel can penetrate. It includes measurements 2007). Other means of commonly used rock clas-
of brittleness and drilling with a small, standard sification include the Q-system; rock mass rating
rotating bit into a sample of the rock. The higher (RMR) of Bieniawski, incorporating the earlier
the DRI, the higher the penetration rate, and this rock quality designation (RQD); and the geologi-
can vary greatly from one rock type to another cal strength index (GSI).
(. Fig. 3.49). It should be noted that modern drill
bits greatly improve the penetration rates in the Selection of Drilling Method
same rock types. The BWI gives an indication of Selecting the right technique or combination
how fast the bit wears down, as determined by of techniques depends on many factors: speed,
an abrasion test. The higher the BWI, the faster cost, actual conditions (surface or underground),
.. Fig. 3.49 Relationship
between drilling rate index
and various rock types
(Samuelsson 2007)
Anortosite Granitic gneiss
Amphibolite
Mica gneiss
Diabase Phyllite
Sandstone Pegmatite
Diorite
Argillaceous schist,
Gabbro
shale clay
Monzonite
Greywacke Norite
Gneiss
Taconite Granite
10 20 30 40 50 60 70 80 90
3.4 · Exploration Methods
185 3
.. Fig. 3.50 Rock chips
and core samples (Image
courtesy of Atlas Copco)
depths of the drillholes, type of rocks, required rate and can offer three times the productivity of
sample volume and quality, logistics, environ- core drilling. Thus, significant timesaving can be
mental considerations, and finally the prefer- obtained using RC. When the ore body is located,
ence of the geologist. Moreover, each of these driller can decide to continue with RC drilling or
factors depends in turn on many parameters. switch to diamond core drilling to extract cores.
For example, drilling velocity is dependent on In so doing, RC drilling and classical core drilling
a lot of geological parameters such as jointing are perfectly combinable. The logistics of the drill-
of rock mass, rock anisotropy (e.g., orientation ing program have clear influence on the number
of schistosity), degree of interlocking of micro- of meters drilled per shift and thereof it is a time
structures, porosity and quality of cementation factor.
in clastic rock, degree of hydrothermal decom-
position, and weathering of a rock mass, among Cost Factor
others (Thuro 1997). Costs are mainly related to the time factor, except
Modern core drilling rigs carry out fast and that investment in RC rigs and equipment is
efficient core sampling of different diameters to higher compared to core drilling. For shallow
very large length. There are many items to select exploration applications, time and costs are in
the appropriate method of drilling: target, host favor of RC drilling. For deeper exploration appli-
rock, water presence, sample required, access, cations, shallow subsoil water and rocky terrain,
and politics (Hartley 1994). From a sampling core drilling is still the only practical alternative.
viewpoint, there are two types of drilling meth- Technical developments in drilling tools and rig
ods in mineral exploration: drilling methods that technology have resulted in lower drilling costs.
originate rock chips and those that generate core
samples (. Fig. 3.50). A three-key-factor selection
Confidence Factor
process can be established: the time needed, the The third variable in the equation is the confidence
cost of getting the job done, and confidence in factor. In an evaluation with positive results, a pro-
the quality of the samples brought to the surface gram of core drilling is the common way to drill for
(Gustaffson 2010). the purpose of bringing the project to a resource/
reserve status because geologists need dry and rep-
Time Factor resentative samples to carry out optimum evalu-
For any exploration drilling, the sample is the ations. Therefore, core drilling remains the only
most important goal result. RC drilling gener- viable method in these situations. The core helps
ates continuous drilling with high penetration the geologist to calculate the cost of extracting the
186 Chapter 3 · Mineral Resource Exploration
.. Fig. 3.51 Reverse
circulation drilling machine
(Image courtesy of Atlas
Copco)
Rotary Drilling
Rotary drilling using tricone bits is a noncor-
ing method, being usually utilized for drilling
through soft to medium hard rocks such as lime-
stone, chalk, or mudstone. Rotary drilling uses
different type of rotary bits although the most
typical rotary bit is probably the tricone or roller
rock bit (. Fig. 3.53) that is made with tungsten
.. Fig. 3.55 Diamond
core drilling operation
(Image courtesy of Atlas
Copco)
However, if core recovery is good, it has the ben- rig. The diamond drill bit comprises a cutting
efit of carrying undamaged rock to the surface. head using diamonds as the cutting medium. A
Therefore, diamond drilling is usually accounted variety of core bit types is available according to
to offer the best quality of sample. Most advanced the diamond cutting elements used in their con-
exploration uses a combination of diamond and struction. In softer rocks (e.g., sedimentary for-
reverse circulation drilling. In general, diamond mations), other cutting elements such as tungsten
drills are the most essential tool in the final carbide and polycrystalline diamond compacts
exploration and evaluation of mineral projects can be used. Diamonds used are fine to micro-
because the study of the drill core yields a three- fine industrial grade diamonds that are set within
dimensional geologic picture of ore and host rock a matrix of varying hardness, from brass to high-
and the samples from drill core provide samples grade steel. Other options include tungsten car-
for chemical analysis, mineral recovery tests, and bide (TC) and polycrystalline diamond composite
rock stability tests. (PDC) bits. TC core bits are utilized for drilling
Nowadays, typical drilling operation includes in non-consolidated formations and in overbur-
a truck-mounted rig and a support truck to carry den and for cleaning drillholes. PDC bits are an
items such as the rods, casing, fuel, and water alternative to TC bits and surface set diamond bits
(. Fig. 3.55). The method requires significant site
when drilling in non-consolidated and medium
preparation and rehabilitation. Diamond drilling hard rock formations (Black 2010).
machines utilized in mineral exploration com- As the drill bit advances, a cylindrical core of
monly reach depth of up to 3000 m and extraor- rock progressively fills a tube core barrel immedi-
dinarily up to 6000 m. In these situations, casing ately above the drill bit. Core barrels are classified
is installed in the upper levels to protect the walls by the length of core they contain. They are usually
from collapse. The rate of advance will depend of from 1.5 to 3.0 m in length but can be as long as
many factors (type of drill rig, type of bit, hole 6 m. It is important to note that to recover the core
diameter, the depth of drillhole, and the rock type the barrel must be removed from the hole by pull-
being drilled, among others). Drilling advance ing the entire length of drill rods to the surface,
rates of up to 10 m an hour are common. The which is a time-consuming process. For this rea-
costs can range from USD 40 to USD 90 a meter son, the wireline system is now a standard prac-
in drillholes up to 300 m long and from USD 75 to tice (. Box 3.7: Wireline System). Water is used
USD 160 a meter for length up to 1000 m. in diamond core drilling as lubricant fluid and to
The quality and continuity of the core are cru- remove crushed and ground rock fragments from
cial in the assessment of a potential mine, making the bit surface. Water can be used in combination
the core bit a key component of a core drilling with various clays or chemicals (. Fig. 3.56).
3.4 · Exploration Methods
189 3
.. Fig. 3.56 Chemical products used with water in diamond core drilling (Image courtesy of AMC)
Box 3.7
Wireline System
The Boart Longyear company time and money saved by not assembly is forced down the inside
introduced the wireline core having to remove the drill pipe in of the drill pipe using drilling mud
retrieval technology to the order to obtain a core is substan- pressure. When the core barrel
mineral exploration industry in tial. Consequently, wireline system assembly reaches the lower end
1958. By the late 1960s, it was in is designed to recover rock core of the drill stem, a locking device
almost universal use. Wireline core without removing the drill stem holds the barrel in place. The core
drilling is a special type of core from the borehole after each core barrel assembly consists of a cut-
drilling, most commonly used run (. Fig. 3.57). Besides reduced
ter head, core catcher, core barrel,
in mineral exploration. Before tripping time and decreased cost, vent or inside pressure relief, lock-
wireline drilling, the whole string wireline core drilling system has ing device, and a retrieving head.
of rods had to be pulled from the the main following advantages: (1) During coring operations, the
ground in order to recover core with improved core recovery and circulating fluid passes between
from each advance of the drill. quality, the purpose of the drilling the core barrel assembly and the
Thus, in conventional rock coring, project can be better satisfied; (2) drill collar. After the core has been
the entire drill stem and core bar- logging instruments can be low- cut, the core barrel assembly with
rel must be removed after each ered by utilizing internal flush drill its core is retrieved by lowering
core run. This is a time-consuming rod; (3) inner tube structure can an overshot through the drill pipe
operation on deep core holes, be changed in accordance with (McPhee et al. 2015), or overshot,
in addition to creating an inher- the variation of rock layer; and (4) which is designed to engage
ent risk for collapse of the rock labor intensity of the operators the upper end of the core barrel.
into the unsupported borehole. can be reduced. As the overshot is lowered over
Moreover, as the average depth To obtain a core after the the upper end of the assembly,
of hole continues to increase, the core bit is in place, the core barrel the locking devices are released,
190 Chapter 3 · Mineral Resource Exploration
Wireline
Flushing circulating
Drill rod
Reaming
shell
Core sample
Bit
.. Fig. 3.58 Head
assembly inside the
overshot (Image courtesy
of TECSO)
permitting removal of the entire drill rods sill in position within the commonly used standard core
assembly. Thus, overshots are a borehole. While the core sections diameters for wireline drilling
key component of wireline coring are being removed from the inner are AQ = 27 mm; BQ = 36.5 mm;
systems. In this method, the inner tube and placed in special core NQ = 47.6 mm; HQ = 63.5 mm;
barrel containing the rock core boxes, a replacement inner tube and PQ = 85 mm. . Figure 3.58
is rapidly brought to the surface, is lowered into the hole so that shows the head assembly and the
leaving the outer core barrel and drilling can recommence. The overshot attached.
3.4 · Exploration Methods
191 3
Core recovery is essential in diamond drill- new ore reserves and for the safety of the mines in
ing. This is a quantifiable measurement defined establishing the position of possible gas or water
as the total linear amount of physical core sample intersections.
extracted over the total linear advance in a bore-
hole, expressed as a percentage. Low core recovery Other Drilling Methods
impedes quantitative interpretation of important Other drilling methods used in mineral explora-
properties, such as ore grade and ore boundaries. tion include auger drilling and sonic core drilling,
For example, Henley and Doyle (2005) reported the latter being the most recent improvement in
an important bias in ore grade at Las Cruces drilling technology (. Box 3.8: Sonic Drilling).
(Spain) as a result of core loss. The problem was Regarding auger drilling, rock is cut and broken
related to the presence of chalcocite in the min- with a simple blade bit that is mounted on the end
eralization as a friable and unconsolidated form. of a rotating string of rods (. Fig. 3.61). The drill
Very often, core recovery of more than 90% is stem is shaped like a helical screw and is driven
stipulated with drilling contractors. Other strict rotationally into the ground. Auger drilling is a
rules must be agreed, such as careful extraction useful method for quickly and cheaply collect-
of the core and its packing in properly labelled ing geochemical samples. On the other hand,
core boxes and marking individual core runs. this method is usually utilized to take samples in
In this sense, drilling should be supervised by the reconnaissance stage of mineral exploration.
experienced geologists. Proper storage of core is Regarding the rate of penetration, it depends on
needed for the duration of the project if the pros- the type of formation being drilled but commonly
pect is rejected and for the whole life of the result- can reach depths of around 20 m. Obviously,
ing mine, if the deposit is feasible (. Fig. 3.59).
augers are not capable of penetrating hard or
Although onerous, storage is much cheaper than consolidated rock. Auger drilling uses either a
repeat drilling (Pohl 2011). handheld power auger or one mounted on a small
It is important to note that diamond core drill- vehicle. Augers are available in various sizes. Thus,
ing is also carried out in underground mining small augers mounted on trucks are often used for
development (. Fig. 3.60). Thus, underground
reconnaissance exploration projects while large
core drilling is mainly accomplished to characterize augers are utilized for construction purposes.
.. Fig. 3.60 Diamond drill underground exploration station (Canada) (Image courtesy of North American Palladium
Ltd.)
Borehole Surveying
In a drillhole, the orientation is fairly established by
its azimuth (direction) and dip (inclination). It is
common that borehole deviates away from the orig-
inal direction because of many factors (. Fig. 3.64).
Sonic Drilling
Sonic drilling is a unique technology that generates The sonic drilling method can produce almost com-
vibrational frequencies, usually between 50 and pletely undisturbed core samples from both solid and
180 Hz (cycles per second), transferring the vibrations unconsolidated materials with high percentage of core
down the drill pipe to its tungsten carbide bit while recovery rates; it is commonly greater than 90%, which
rotating the pipe at the same time. This frequency gives rise to extremely accurate estimates of mineral dis-
range falls within the lower range of sound vibrations tribution in the ore body. Sometimes, core sampling can
that the human ear is capable of hearing. Thus, the be accomplished without any drill fluids (dry coring),
term «sonic drill» has been applied to this class of although the casing is usually installed by using water or
rotary-vibratory drilling machine. Sonic drilling tech- mud to flush cuttings. Sonic drilling can collect samples
nology was first applied over 40 years ago in Canada. up to 300 mm in diameter and can drill down to 250 m
In mineral exploration, sonic drilling (. Fig. 3.62) is
in a vertical or angled hole. The environmental impact
typically used to provide continuous core samples of from sonic drilling is typically less than other drilling
softer or even harder rock formation of mineral depos- methods. Thus, having a small footprint and lack of need
its. Instead of using a diamond bit rotating at the end to introduce fluid into the hole, this is an ideal drilling
of a drill rod, the sonic drill head sends high-frequency method where contamination is potentially a problem.
vibrations throughout the length of the entire drill In soft materials, sonic drilling is a penetration
pipe and onto the bit (. Fig. 3.63).
technique that strongly reduces friction on the drill
In sonic drilling, the head contains the mechanism string and drill bit due to liquefaction, inertia effects,
necessary for rotary motion, as well as an oscillator, and a temporary reduction of porosity of the material.
which causes a high-frequency force to be superim- The entire drill string is brought to a vibration fre-
posed on the drill string. The drill bit is physically vibrat- quency of up to 200 Hz, which causes a very thin layer
ing up and down in addition to being pushed down and of soil particles directly surrounding the drill string
rotated. These three combined forces allow drilling to and bit to loose structure. Instead of the stiff mass
proceed quickly through most geological formations that requires torque and weight to penetrate, the soil
including most types of rock. The operator is able to vary behaves like a fluid powder (in an unsaturated zone) or
the frequency and drill bit weight to match the material as a slurry or paste in a saturated zone.
he/she is going through, ensuring the best penetration The liquefaction and inertia effects enable to col-
rate and most accurate sampling are obtained. lect very long and continuous samples. In addition,
the drill string stays extremely straight due to the
vertical high-frequency movement, with a diversion
.. Fig. 3.62 Sonic drilling in iron ore mining (Image .. Fig. 3.63 Sonic drill bit (Image courtesy of Sonic
courtesy of Sonic Drilling Ltd.) Drilling Ltd.)
194 Chapter 3 · Mineral Resource Exploration
of commonly a few centimeters over the full length of vibration with rotation to allow the tungsten carbide
the borehole. It makes sonic drilling an optimal tech- buttoned ring bits to cut through the harder forma-
nology for installing instrumentation and monitoring tions. Because a sonic drill bit actually impacts the
equipment. In alluvial material, vertical vibrations are rock face, if a diamond drill bit was used with the sonic
generally enough to drive down a drill string for many drilling method, it would shatter, so tungsten carbide
meters without the injection of any water or air. On bits are used instead. In order to keep the temperature
3 the contrary, liquefaction cannot take place in hard of the drill bit down and lift the cuttings, foam injec-
formations. In such cases, it is necessary to combine tion is the best solution, but water or air is possible.
problem, it is desirable to use methods to objec- three main logging forms for recording observa-
tively classify how mineralized is a sample, for tions on drill core and cuttings: prose logging,
instance, using portable XRF technology (Gazley graphical scale logging, and analytical spread-
et al. 2014). Thus, a clear, accurate, and standard- sheet logging» (Marjoribanks 2010). An interval
ized logging procedure is essential to promote is selected in prose logging, being identified by its
uniformity of data through what is commonly a downhole depth limits, and described in words.
3 long data-gathering period. It is important to note It is recommended that this type of logging must
that as geological information and concepts evolve be only utilized in a special column (e.g., com-
with time, the context is likely to request the core ments). Graphical scale log forms can include
be relogged (Sinclair and Blackwell 2002). several mapping columns along with extra col-
Although a great number of different logging umns for recording digital data, sketches, ver-
methods are utilized in the industry, «there are bal comments, etc. (. Fig. 3.65). The important
DH-01
0 to 100 0 to 500 0 to 100 0 to 500 0 to 500 0 to 400 0 to 400 0 to 400
0.0
gra-
25.0 des
mo-
re
cla-
yey
50.0
75.0
te-
mp-
orar-
ily
lost
cir-
cul-
ati-
on
100.0
125.0
is thought to be the main heat source for hydro- Historically, excavator trenching in geochemi-
thermal cells that deposited mineralization along cally anomalous areas has been the most effective
a series of northwesterly trending, structural tool for identifying near surface but non-outcrop-
conduits. The porphyry dykes are up to 30 m ping, mineralized zones. Within the main areas
wide and commonly occupy the same structural of exploration, overburden generally consists of
zones as the mineralization. The dykes are coeval 5–20 cm of vegetation and soil organics covering
with or slightly older than the mineralization. a discontinuous layer of white volcanic ash and
Mineralization is dominated by gold-silver-rich 50–125 cm of loess and/or residual soil, which cap
structures associated with a zonation model decomposed bedrock. Trenching of 22,366 m was
ranging from weak porphyry copper-molybde- performed in 84 trenches between 2010 and 2015.
num centers, outward to transitional anastomos- Where possible, trenches were excavated in areas
ing sheeted veins, and lastly to more cohesive that had previously been stripped of soil and veg-
and continuous base and precious metal veins. etation. The trenches were aligned at about 30°,
The metals of primary interest at the property which is perpendicular to the anomalous trends
are gold and silver. These metals are intimately of the main soil geochemical anomalies. All rock
associated with lead, zinc, and copper in various samples (chip sampling) collected from the prop-
forms and concentrations throughout the miner- erty were taken from excavator trenches, because
alizing system. The age of the mineralizing events there are no naturally outcropping exposures of
is now considered to be Late Cretaceous. Depth these zones. Continuous chip samples were col-
of surface oxidation ranges from 5 to 100 m below lected along one wall of the trench as close to
198 Chapter 3 · Mineral Resource Exploration
T.N.
1°59.4
Mineralized trend 20°12.5.
Gridnorth
h
nort
netic
>100 <6582
Mag
3
Annual change
>50 <100 decreasing 20’
>10 <20
0 <20
6 892 000 mN
Pro
p ery
tb
ou
nd
ary
6 890 000 mN
384 000 mN
386 000 mN
UTM ZOZE 8.NAD 83
DATE: DEC 2015
.. Fig. 3.66 Gold soil geochemical values in Klaza property (Data courtesy of Rockhaven Resources Ltd.)
the floor of the trench as slumping would allow core samples within the altered structural zones
using a geological hammer. Sample sizes averaged compared to higher values from surrounding
approximately 2 kg per linear meter sampled for unaltered wall rocks. Several of the magnetic lows
intervals containing veins and about 1.5 kg per extend outside the main areas of exploration and
linear meter sampled for intervals comprised pri- have not yet been tested by drilling or trenching.
marily of altered wall rock. . Figure 3.67 shows the first vertical derivative of
1˚59.4' 20˚12.5'
Grid north
h
nort
netic
Mag
Annual change
decreasing 20'
6892 000 mN
Airborne magnetics
first vertical derivative
Klaza property Cross-fault
380 000 mE
382 000 mE
384 000 mE
.. Fig. 3.67 First vertical derivative of the magnetic data in Klaza project (Illustration courtesy of Rockhaven
Resources)
the grid and coincides with an area of weak to hole. Five diamond drillholes totaling 308.76 m
strong gold-in-soil geochemistry (25–100 ppb) were drilled vertically, peripheral to the min-
and strong copper geochemistry (>200 ppm) as eral resource areas as water monitoring wells. In
well as porphyry style mineralization that is part general, core recovery was good, averaging 95%,
of the Kelly zone. The mineralized vein and brec- excluding the near surface portions of the holes
cia zones tested by geophysical surveys show up where core recovery was poor. Final hole depths
as resistivity lows that coincide with chargeability within the Klaza zone averaged 251.49 m, which
highs. included a maximum hole depth of 550.77 m. To
determine the deflection of each drillhole, the
kDrilling orientation was measured at various intervals
Regarding drilling program, a total of 70,099.72 m down the hole. Measurements taken and recorded
of exploration and definition drilling was done were inclination, azimuth, temperature, roll angle
between 2010 and 2015 in 295 diamond drillholes (gravity and magnetic), as well as magnetic inten-
on the property. All diamond drillholes were col- sity, magnetic dip, and gravity intensity.
lared at dips of −50°, and most of the holes had azi- As an example of the results obtained in the
muths of 30–35° (north-northeast). Drilling was main mineralized zones, the host rock of the min-
completed on section lines spaced roughly 50 m eralization in the central Klaza zone is an exten-
apart. Some of the 2015 drilling was done in part sive complex of steeply dipping veins, breccias,
for geotechnical and environmental purposes. To and sheeted veinlets. The strongest veins are typi-
monitor seasonal water levels and frost variations, cally found along dyke margins. Pyrite, arseno-
vibrating wireline piezometers were installed in pyrite, galena, and sphalerite are the main sulfide
four holes and a thermistor was installed in one minerals in this subzone. Excellent results from
200 Chapter 3 · Mineral Resource Exploration
035°
9
13 08
Looking northwest -2 4 2-
14 1-02 11 -1
09
7 - KL
2- KL L-1 4-
2
-1 Trench-10-14 K -1
KL KL
3.84 g/t Au / 43.20 g/t Ag
1.50 m
90.53 m
7.79 g/t Au / 128 g/t Ag
1.10 m
102.72 m
zone
361.80 m
Xz
l BR
PIKA
tra
Cen
402.02 m
.. Fig. 3.68 Type section depicting the geometry of the mineralized veining relative to the dyke and the gold and
silver grades values obtained in the samples (Illustration courtesy of Rockhaven Resources Ltd.)
this part of the Klaza zone were reported from an thick quaternary glacial deposits. The 45–75 Ma
interval in KL-10-07, which graded 7.10 g/t gold kimberlites of the Lac de Gras kimberlite field
and 259 g/t silver over 15.25 m, and an interval intrude both the granitoids and metagreywackes.
in KL-12-133, which graded 11.85 g/t gold and The kimberlites are mostly small pipe-like bod-
5.24 g/t silver across 6.65 m. . Figure 3.68 shows ies controlled by tectonic fissures and typically
the results of central Klaza zone. Finally, a geo- extend to depths of several 100 m below the land
technical log was carried out previous to geologi- surface. The mineralization is mostly limited to
cal logging and included determinations of core, olivine-rich resedimented volcaniclastics and pri-
rock quality designations (RQD), hardness, and mary volcaniclastics. Diamond grades from the
weathering. In 2015, fracture frequency, joint sets, kimberlites range from less than 0.05 cpt to more
and joint set roughness, shape and infill were also than 4 cpt.
recorded. Diamond exploration in the area started
with heavy mineral sampling from fluvial and
zz Ekati Diamond Project Exploration: glaciofluvial sediments, which was followed by
Courtesy of Dominion Diamond mapping of geomorphological features and field
Corporation observations. Till sampling coupled with ground
The Ekati diamond mine is located in northwest geophysics pinpointed the Point Lake kimberlite
Canada, 200 km south of the Arctic Circle. Cold pipe, which was later investigated by core drill-
winter conditions are predominant in the region ing and confirmed as diamondiferous kimberlite.
for most of the year. The area is a wildlife habi- Approximately 15,000 till samples were taken
tat, where human activities are limited to hunting during the project exploration phase. They were
and fishing. The geology of the Ekati project area also used to search for airborne geophysical
consists mainly of Archean granitoids, intruded anomalies. The extent and chemistry of the indi-
by metagreywackes and transected by Proterozoic cator minerals dispersion trains were evaluated to
mafic dykes. Bedrock is overlain by less than 5 m pinpoint drill targets.
3.5 · Case Studies
201 3
kIndicator Mineral
Kimberlite indicator mineral (KIM) composi- a Fox kimberlite - total magnetic intensity
tions were outstanding in the exploration pro-
8000
gram leading to the development of the Ekati 7000
mine. Discovery of the first kimberlite at Point 6000
Northing (m)
Lake was followed by the identification of over 5000
150 kimberlite bodies within the Ekati areas. The 4000
use of KIM geochemistry was adopted to priori- 3000
tize likely high-grade phases for follow-up bulk Fox 380 MSL 2000
sampling and/or diamond drilling programs. 1000
4000
kGeophysical Surveys
3000
The Ekati area was explored using helicopter- 2000
borne total field magnetic (TFM), electromagnetic Fox 380 MSL
1000
(EM), and very low-frequency electromagnetic
(VLF) surveys. Final exploration sweeps were car- (ohm-m)
Easting (m)
ried out using an improved airborne EM system
with tighter line spacing, reduced sensor height, c Fox kimberlite - vertical gravity gradient
and airborne gravity gradiometer (. Fig. 3.69).
40
The ground geophysical surveys were used to 20
gather more precise kimberlite/non-kimberlite 0
Northing (m)
ity of the drill targets and all of the pipes with -60
-80
reported mineral resource estimates. A small core Fox 380 MSL -100
hole seismic survey was designed in the Koala -120
pipe, this searching for detailed spatial informa-
Gdd (Eo)
tion of the kimberlite body. The data proved that Easting (m)
the borehole seismic technique could augment
drillhole pierce points with seismically deter-
mined pipe wall contacts. .. Fig. 3.69 Fox kimberlite airborne geophysical response;
the Fox kimberlite has a weak and normal magnetization a,
a strong conductive response b, and a very strong gravity
kDrilling
response c (Illustration courtesy of Dominion Diamond
Drilling lasted from 1991 until 31 July 2016 and Corporation)
included 1389 core holes (254,490 m), 111 sonic
drillholes (2596 m), and 513 RC holes (106,547 m).
Core drilling using synthetic diamond-tipped also used for gathering geotechnical and hydro-
tools and/or carbide bits contributed to define the geological data. . Figure 3.70 shows the location
pipe contacts, wall-rock conditions, and internal of the drillholes. Forty kimberlite occurrences
geology. Prior to 1995, the diameter of drillholes were subsequently tested for diamond content
ranged from 27 to 71 cm; from 1995 to 2008, the using reverse circulation (RC) drilling and/or
holes’ diameter was standardized to between 31 surface bulk samples.
and 45 cm. In order to obtain larger samples, Sonic drilling was used to core both soil
drillholes’ diameters for the 2015 and 2016 pro- and bedrock in Ekati. The primary objective of
grams ranged from 45 to 61 cm. Core drilling was sonic drilling was to characterize the nature and
202 Chapter 3 · Mineral Resource Exploration
7210000
7210000
N
(with insets)
Sable Legend
kimberlites
Currently mined kimberlite
7200000
7200000
3 Pigeon
Depleted kimberlite
Resource kimberlite
DD holes
RC holes
7190000
7190000
Sonic holes
Lakes
Panda Jay
Mine lease boundaries
Buffer zone
Koala north
7180000
7180000
Core zone
Koala
7170000
7170000
Fox
7160000
7160000
Misery ne
Misery
Misery sw ext Date: 31-07-16 Datum: NAD 1983
Misery s
Drafted by: Projection: UTM 12N
Lynx
Mineral Services
7150000
AN MS GROUP BUSINESS
km
0 5 10 20
.. Fig. 3.70 Map showing location of all drillholes with or indicator dispersion targets were drilled, with a total
insets for pipes with reported mineral resources for the of 150 kimberlites discovered (Illustration courtesy of
Ekati project area; approximately 350 geophysical and/ Dominion Diamond Corporation)
variation of the soil layers to determine the depth and the tool for conductivity induction and natu-
to bedrock. In addition, recovered soil was logged ral gamma readings, were used on all RC holes.
and geotechnical laboratory testing was performed Oriented core was used for geotechnical
on selected samples. After reaching the final depth investigation of the wall rocks but not in kimber-
of investigation at each borehole location, in situ lite. The following geotechnical parameters were
hydraulic conductivity testing was carried out. determined for all core drillholes: (a) percent-
Since core recovery was largely a function age core recovery, (b) rock quality designation
of the hardness of the kimberlite, recoveries of (RQD), (c) fracture frequency, (d) point load
95–100% for both core and RC drillholes were strength index, and (e) joint condition and water.
common within wall rock. In kimberlite, the core Digital geological and geotechnical logging
recoveries were as low as 20% and as high as 95% was completed and the core photographed before
but were more typically in the 75–85% range. For being stored in appropriate building. Color pho-
RC drillholes, kimberlite recoveries ranged from tographs were taken of delineation drill core and
50% to over 100% in cases of in holes sloughing. used to verify significant contacts and litholo-
All core and RC drillhole collars were surveyed gies as well as provide a permanent record of the
with GPS instruments prior to and after drilling drill core. Geological logging used digital logging
in order to ensure that the drillhole collar loca- forms for both wall-rock lithology, kimberlite/
tion error is minimal. For core holes, downhole wall-rock contacts, and internal kimberlite lithol-
surveys were done with industry standard instru- ogy. Kimberlite cores were examined macro-
ments. Three tools, including the tool for gyro- scopically and using a binocular microscope to
scopic deviation surveying, the three arm caliper, determine concentration of macrocrystic olivine,
3.5 · Case Studies
203 3
matrix composition, abundance and type of coun- followed up with ground prospecting/sampling.
try rock xenoliths, approximate abundance of Second, areas with mineralization of interest were
indicator minerals, rock fabric, color, and altera- then flown again at the local scale with a tighter
tion. Samples were taken from core holes for line spacing to define areas with better potential
determination of dry bulk density and moisture for thick and continuous mineralized envelopes.
content of host rock and kimberlite. In the opinion These prioritized areas were then surveyed with
of the responsible QPs, the quantity and quality of ground-based TDEM technology to allow high-
the lithological, geotechnical, density, collar, and resolution delineation of the sub- outcropping
downhole survey data collected in the drill pro- parts of conductors. This information was used
grams were sufficient to support mineral resource to quickly plan trenching and drilling for efficient
and mineral reserve estimation. sampling of the mineralization.
With graphite being significantly more con-
zz Matawinie Graphite Project Exploration: ductive than host rocks, the first step in the explo-
Courtesy of Nouveau Monde Mining ration stage was to carry out an airborne time
Enterprises Inc. domain electromagnetic (TDEM) survey. Thus,
The Matawinie project is spread over an area of a regional heliborne magnetic and TDEM survey
approximately 70 km by 50 km, being the center was carried out over an area of 55 km × 72 km
of the most important block (Tony Block) posi- at a 1 km line spacing. Several anomalies were
tioned approximately 120 km north of the city of detected and ten local areas were selected for
Montréal (Canada). The Matawinie property lies detailed surveying using the same configuration,
in the southwestern portion of the Grenville geo- but at a 100 m line spacing. The surveys were
logical province. The belt hosts the only currently successful in outlining several large-size conduc-
producing crystalline flake graphite mine in tors (. Fig. 3.71). In order to assess the multiple
kGeophysical Surveys
Given the contrasted physical properties of the TDEM response (nT/s)
graphite mineralization sought after, geophysics 49 86 124 162 199 237 274 312 350 387 425 462
was the key component of the exploration program Residual total magnetic intensity (nT)
-706-268 -183 -127 -81 -46-10 25 54 82113 157 212 282 383 5911527
and in particular time domain electromagnetic
techniques (TDEM). The exploration strategy
was twofold. First, it implied large regional air- .. Fig. 3.71 Local areas flown with heliborne MAG-TDEM
borne surveys with a wide line spacing to detect (Illustration courtesy of Nouveau Monde Mining Enter-
pluri-kilometric conductors, which were then prises Inc.)
204 Chapter 3 · Mineral Resource Exploration
resulting targets in an efficient manner, a quick using EM methods. Some poorer, more subtle,
prospection campaign was deployed. It was sup- conductors were also outlined. Furthermore, the
ported by the use of a very small EM device with chargeability model highlighted some areas where
a penetration capability estimated at 1 m. This disseminated graphite and/or sulfides may occur
effort resulted in the collection of 35 grab samples in addition of the conductive occurrences. In addi-
grading between 5% and 17% graphitic carbon. tion, the 2-D section models of the IP data were
3 Based on these preliminary results and the poten- especially useful for drillhole planning.
tial size of the conductors estimated from the Magnetic data was also gathered in an effort
airborne surveys, several areas were selected for to try to discriminate weakly magnetic conduc-
further assessment. tors, likely relating to low sulfide graphite occur-
In order to get an accurate image of the sub- rences, from strongly magnetic conductors for
outcropping portion of the conductors, a ground which higher sulfide concentration may occur
TDEM system was used. The system has a lim- (. Fig. 3.72). In one instance where a drillhole
ited penetration depth estimated in the order of had intersected a graphite-rich horizon at a depth
10–15 m but offers high spatial resolution, being much greater than expected (85 m instead of
the unit equipped with an integrated GPS. The about 20 m), a borehole Mise-À-La-Masse survey
survey was carried out along existing roads and (MALM) was carried out with a 12.5 m spacing
trails, along the 100 m spaced network of lines to verify which of the sub-outcropping conduc-
cut for other geophysical techniques, and finally tors this deep intersection was connected to. The
along a local 20 m spaced set of lines specifically MALM survey proved that the deep graphite
designed for this instrument. The overall results occurrence was connected to shallow conductive
obtained with this system proved very useful to units further to the northwest rather than nearby,
map the sub-outcropping conductors. This type indicating some local discontinuities.
of high-spatial-resolution information enables a The 2014 and 2015 ground TDEM surveys
significant gain for understanding the geometry delineated wide conductive areas over each of
of ore bodies close to surface. It served as a guide the targeted mineralized zones. As a result, four
for strategically locating exploratory trenches and trenches were excavated in 2014 and five in 2015
drillholes, especially in this geological area that (. Fig. 3.73). Trenches were oriented roughly per-
underwent strong deformation. Everywhere a pendicular to the foliation of the paragneiss units
trench was dug or a hole drilled based on these and mineralized horizons with the exception of
results, graphite and/or sulfide mineralization was one trench, which was at about 45° to the foliation
found and could explain the anomalies. The over- because of terrain constraints. In 2014, the trench-
burden encountered in the drillholes of the area ing program aimed at sampling only mineralized
varied from 0.4 to 5.5 m, with an average of 3.5 m. material along the trenches in order to determine
Other classic geophysical techniques were used the potential of the mineralization, while in 2015
to better define the conductors. A horizontal loop channel sampling usually started 2 or 4 m (1–2 sam-
EM (HLEM) survey was performed every 25 m ple lengths) outside the visible mineralized area and
with a 100 m cable using three frequencies. With was collected in a continuous manner as to prevent
its estimated penetration depth of 50 m, the infor- any sample bias. Trenches were approximately 1.5 m
mation provided by this survey was especially use- in width and varied from 0 to 4 m in depth. In some
ful at locating conductors with significant vertical instances, large boulders, the accumulation of water
extensions and those with their top located deeper and prohibitive depth prevented the excavation and/
than the penetration depth of the previous system. or sampling of portions of the planned trenches.
It also enabled some estimation of the dip, conduc-
tance, and depth to top of conductors. A resistivity/ kDrilling
induced polarization (IP) survey was also carried Drilling on the Tony Block targeted wide conduc-
out at a 12.5 m station spacing (for increased reso- tors on each of the main conductive areas out-
lution) with ten receiving dipoles using the pole- lined by the 2015 ground TDEM survey. A total
dipole configuration (for increased penetration of 70 holes were drilled for a total of 10,479 m.
depth). The conductors identified with this elec- As an example, the drilling on the southeast zone
trical method conformed well with those detected of the south deposit consisted of nine holes for a
3.5 · Case Studies
205 3
.. Fig. 3.72 Ground
magnetic survey results
(Illustration courtesy of
Nouveau Monde Mining
Enterprises Inc.)
total of 1552 m drilled. Mineralization was inter- 3.18% to 3.61% Cg. The drilling on the southwest
cepted 13 times by drilling here resulting in the zone of the south deposit consisted of 22 holes
interpretation that the southeast zone is com- for a total of 2617 m drilled. Mineralization was
posed of two main mineralized horizons (S1 and intercepted 57 times by drilling here resulting
S2). From Section S2600 to Section S2900 (300 m in the interpretation that the southwest zone is
length), the mineralized horizon ranges from 116 composed of two main mineralized horizons (S1
to 159 m true width, with grade varying from and S2). The highlight of southwest zone is a first
206 Chapter 3 · Mineral Resource Exploration
graphitic horizon (S1) about 29 m thick. It is fol- a 0.5–0.7 kg sample was collected from the follow-
lowed by a mainly barren interval between 24 and ing 0.5 m below the topsoil. Samples were placed
62 m thick and finally a second graphitic horizon in a plastic bag and tagged. A brief description that
(S2) around 40–50 m thick, with both graphitic included color of the sample, percentage of gravel,
horizons varying from 2.79% to 5.29% Cg. sand, and silt was carried out. All field information
was controlled by the geologist in charge of the soil
3 zz Coringa Gold Project Exploration: Courtesy survey and digitized into the data base before send-
of Anfield Gold Corp. ing the sample to the laboratory for gold analysis.
The Coringa gold project is located in north cen- In trench sampling, a start point was located with
tral Brazil in the mining friendly state of Para, a handheld GPS, and azimuth and trench length
65 km south of Novo Progresso. The area occurs was estimated with a compass and tape. Trenches
in the southeastern part of the Tapajós mineral were hand dug to a depth of 1 m. In these trenches,
province where past production is estimated at 30 approximately 2–3 kg chip-channel samples were
million ounces of gold. The claims are underlain collected at 1–1.5 m intervals. Finally, a stream
by Proterozoic granites and rhyolitic volcanics, sediment sampling program was also carried out,
and the main structural trends are northwest and being collected a total of 756 samples.
north-northwest. The Coringa shear-vein system
(high-grade gold mineralization is hosted in a kDrilling
series of narrow quartz-sulfide veins that range in In drilling program, four drilling phases have been
thickness from 0.15 to 4 m) is coincident with the completed on targets identified at the project site
north-northwest trend (345°) and dips 70–90° to for a total of 24,093 m of HQ core in 160 explo-
the northeast. The main shear is 7 km long and five ration holes. In the first phase of drilling, 1774 m
zones of vein mineralization occur along it. Many in 22 holes was carried out for early stage explo-
other mineralized structures are also present. ration, being drilled under the main artisanal
workings («garimpos») (. Fig. 3.74). The second
Verifying the drill hole interval Marking the core for splitting
the aim was further defining of the resources in . Table 3.5 summarizes the drillholes completed
several blocks. Regarding the third phase, drilling within each phase of drilling.
was 1979 m in 15 holes; the main objective was to The sampling procedure in holes (. Fig. 3.75)
define the resource in one block and test two of includes the continuous sampling of the core at
the IP targets. Finally, the fourth phase of drilling intervals of approximately 0.5 m (mineralized
covered 15,308 m in 79 holes), being the goal to zones) to 1 m (non-mineralized zones). In this
test the continuity of the Mae de Leite structure at process, a cutting/splitting guide line is marked
depth and along strike as well as the continuity of on the core by the geologist to ensure that the
the Meio zone along strike to the north and south. mineralized structure is equally divided, each box
208 Chapter 3 · Mineral Resource Exploration
is photographed to provide a visual record of the geochemical anomalies from the short RC explo-
core, and then one-half of the core is returned to ration holes carried out by SQM while looking for
the core box, while the other half is placed in the industrial minerals, known reported or inferred
numbered and tagged sample bag. lineaments forming structural corridors and
other geological information.
zz Atacama Copper Project Exploration: The initial target selection was reviewed again
3 Courtesy of Arena Minerals Inc. once the company acquired regional airborne
Atacama copper property consists of approximately magnetic and radiometric data that had been
920 km2 (92,000 hectares) in Chile’s Antofagasta flown as part of a multi-client survey in 1999
Region, approximately 40 km northeast from the (. Fig. 3.76). The reinterpretation of this database
city of Antofagasta. The property has been almost led to the identification of an additional 23 targets
exclusively explored and exploited for industrial that had not been selected during the initial selec-
minerals, primarily iodine and/or nitrates. These tion process. The remaining 17 of the reinterpreted
industrial minerals are found within overburden magnetic/radiometric targets correspond with
covered areas and generally within 20 m from previously selected ASTER/geochemical targets.
surface. As a result, the exploration activities All alteration zones or mineralized outcrops
within the property focused on shallow explora- were systematically sampled, and a preliminary
tion methods, ranging from trenching to short geological map was made of all areas of interest.
RC drilling in more recent years, which targeted A total of 1450 rock chip samples were collected
sedimentary layers within the overburden. Most during this phase of exploration, and several areas
of the Cu porphyry deposits of the region belong with potential for both copper porphyry and epi-
to the Paleocene-Early Eocene world-class Cu-Mo thermal gold mineralization were identified for
porphyry belt which extends from southern Peru additional ground follow-up surveys. Based on
to northern Chile for a distance of over 1300 km. the results of the initial fieldwork, five areas were
Mineralization is associated with a complex of selected for ground magnetics coverage: Cerro
granodioritic to quartz-monzonite stocks with Barco, Cerrillos, Quebrada Honda, La Paloma, and
accompanying Paleocene dykes dated at 57 mil- Paciencia. A total of 3647 line km of surveying was
lion of years. completed by this survey. Following the ground
A basic outline of the exploration program in geophysics, additional mapping and in some cases
place is as follows: (1) data compilation; (2) desk- multispectral analysis were done on selected alter-
top analysis and target selection; (3) initial ground ation areas to get a better definition of the targets
work and prospecting; (4) prospect generation and define trenching and drilling targets.
and selection; (5) follow-up ground work, includ- The ground magnetic surveys were con-
ing additional geology, geochemistry, and ground ducted on north-south lines with a line spacing
geophysics; and (6) drill program design, RC of 100 m. Readings were carried out with an
drilling in two phases: 2 km grid drilling followed approximate station spacing of approximately
by 1 km grid infill based on results. Thus, the 0.5–1.5 m. A checkpoint was measured twice
exploration program during 2013–2014 started daily with all the magnetometers. Repeatability
with an initial phase of target selection using of the corrected magnetic readings was within
satellite imagery (ASTER) to identify exposed 1 nT, and the GPS UTM coordinate repeatability
alteration zones and main structural features and was within 2 m of the average value. In summary,
trends. This work was combined with regional several large anomalies that may be indicative
geological and geochemical data to provide a of large hydrothermal alteration systems were
selection of priority targets for field follow-up observed, being the magnetic data effectively
with prospecting and sampling. Twenty-nine tar- mapping lithology.
get areas were selected of which 11 have exposed Regarding the exploration results and inter-
alteration of various compositions read from the pretation, the comparison between the smoothed
ASTER images. The other targets that do not have analytical signal data and what is known of the
surface alteration detectable by ASTER imaging local geology from either the regional map sheets
lie under cover or have only small outcrop expres- or the arena mapping allowed for a definition of a
sions (less than the 25 m pixel limit). These areas set of characteristics for the different lithologies,
were selected based on their copper-molybdenum subject to variations caused by things like burial
3.5 · Case Studies
209 3
400000 425000 450000 475000
N
7500000
7500000
1999 airborne
magnetic survey
7475000
7475000
7450000
7450000
Concession boundary
7425000
7425000
Airborne magnetic
7400000
7400000
survey location
July 13, 2015
Concession
1:550,000
0 5 km
Basemap: airborne magnetics TMI
.. Fig. 3.76 Airborne magnetic survey location (Illustration courtesy of Arena Minerals Inc.)
depth and well-known magnetic characteristics of than granites. In several locations, the lithologies
igneous and sedimentary rocks. Typically, mafic were revised based on magnetic characteristics
intrusives are more magnetic than mafic and where the regional mapping indicated lithologies
intermediate volcanics that have been subject to (e.g., Cretaceous granites) that are not consistent
oxidation, and in turn, these are more magnetic with high magnetic gradients measured in the
210 Chapter 3 · Mineral Resource Exploration
.. Fig. 3.77 Crustiform
quartz from Paciencia
prospect (Image courtesy
of Arena Minerals Inc.)
new survey and where the geological map sheet zinc (up to 0.15%), and silver (up to 154 g/t). The
shows Holocene cover and an absence of outcrop. next stage of work on this target should comprise
Pampa Paciencia prospect results, as an exam- of trenching, sampling, and mapping of the two
ple of the exploration program, are the following. vein areas prior to exploration RC drilling.
The Pampa Paciencia prospect is located approxi-
mately 10 km north and northeast of the Sierra zz Preston Uranium Project Exploration:
Gorda and Spence mines, respectively. The detailed Courtesy of Skyharbour Resources Ltd.
magnetic survey has allowed the interpretation to The Preston uranium property is located in north-
refine the position of the faults and to recognize western Saskatchewan, Canada. The property
that most of the lithologies are fault-bounded in comprises 121,148 ha and is approximately 32 km
a broadly north-south elongation direction. Two long in a northerly direction. Outcrop exposure
distinct mineralized areas, approximately 2 km is limited, generally 5%. Vegetation, weather
apart, have been discovered within altered dioritic conditions, and seasons are typical of northern
and granodioritic intrusive rocks. The mineraliza- Saskatchewan. The Preston uranium project is
tion consists of quartz vein outcrops and subcrops located 30 km southwest of the southwest margin
of angular quartz fields that align with east-west to of the Athabasca Basin, which is interpreted to
west-northwest lineaments. The quartz vein mate- have been filled over a 200 Ma period in four major
rial exhibits well-developed crustiform-colloform depositional sequences coalescing into a single
textures (. Fig. 3.77) and is associated with gold,
basin. No significant zones of uranium mineraliza-
silver, and base metals anomalies. tion have been identified on the property to date
The epithermal quartz field consists of a 500- to but the Athabasca Basin arguably hosts the world’s
800-m-long area of quartz float concentrated along largest and richest known uranium deposits.
a west-northwest axis immediately south of a large
granodiorite outcrop. Several quartz chip samples kAirborne Geophysical Surveys
taken from this area originated anomalous values A 5162 line km combined versatile time domain
of gold up to 6.82 g/t of gold. Seventeen other sam- electromagnetic (VTEMplus) and aeromagnetic
ples from this zone also generated anomalous val- survey was completed over six blocks of the
ues ranging from 0.5 to 3.85 g/t of gold. The second Preston property. The survey areas were flown at
area of interest is located 2 km southwest of the epi- 200–300 m line spacings with tie lines at 1000 m.
thermal quartz field, consisting of veins with asso- Over 300 km of conductor segments, some
ciated quartz-amethyst. Anomalous gold values approaching 10 km in length, occur in the com-
from chip sampling range from 0.3 to 2.07 g/t and bined eastern blocks of the Preston VTEM cover-
are associated locally with anomalous base metal age. Basement aeromagnetic trends in the furthest
values in copper (up to 0.12%), lead (up to 0.41%), western block are oriented northwest-southeast,
3.5 · Case Studies
211 3
while those of the eastern blocks are E-NE which Geological traversing and mapping and sampling
is similar to the dominant basement strike ori- of the various rock types were aided by ground
entation at Fission’s Patterson Lake South high- radiometric surveying. Areas with high topogra-
grade uranium discovery area. Cross-cutting phy were chosen for geological mapping traverses
structural features and flexures affecting the con- based on coinciding airborne radiometric anoma-
ductor traces were identified to be of particular lies and strong EM conductors. Geological outcrop
interest as prospective follow-up targets. and structural mapping was completed at a scale
A Goldak high-resolution radiometric survey of 1:5000 in selected areas. The dominant lithology
was flown to locate uranium boulder trains, in situ was moderately to steeply dipping, northeast trend-
uranium mineralization and alteration associated ing, weakly to moderately foliated granite. Further
with uranium mineralization. The airborne radio- to the northeast, to the extent of the Preston ten-
metric, magnetic, and VLF-EM survey was flown ure boundary, diorite-to-gabbro and granite-to-
over one large block extending up to 60 km east- granodiorite outcrops are mapped along the same
west and up to 36 km north-south flown at 50 m intermediate airborne magnetic northeast trend.
above surface. A total of 8273 line-km on 200 m Radioactive pegmatites (>2000 cps) intrude gran-
line spacing was flown on lines at 155°/335°. ite to granodiorite to the northeast.
The airborne radiometric spectrometer coverage
mapped a significant number of enhanced radio- kWater, Sediment, and Soil Sampling
active locations that were classified into contri- Lake-bottom water and sediment sampling were
butions from uranium, thorium, and potassium regularly collected together at the same site.
sources. Interpretation of the radiometric data Samples of lake sediment were collected using a
identified areas with elevated uranium counts that tubular steel instrumentation, fitted with a butter-
can be correlated along and between multiple lines fly valve that opens an impact with the sediment
potentially indicating the presence of radioactive and closes as the sample is retrieved, and trapped
boulder trains or in situ uranium mineralization. the containing sediment. The sampler is designed
These radiometric features, particularly when so that once retrieved, it can be inverted and the
coincident with prospective EM conductors, were contained sediment poured into a sample bag.
given high priority for follow-up ground work. Sample control was by GPS with sub 5 m accuracy.
Geological outcrop mapping and identifica- Thematic plotting was completed for As, Au, Co,
tion of boulders and/or boulder terrains were Cu, Li, Mo, Pb, U, Th, Y, and Zn and assessed for
completed over geochemical survey grids (at spatial associations with known geological, radon,
200 m line spacing) and on prospecting traverses and geophysical features. Statistics for select ele-
while ground truthing geophysical anomalies. ments of interest are tabulated in . Table 3.6. For
the uranium lake-bottom sediment results, a total three different tree species have differing back-
of 7 out of 260 samples collected in 2013 are above ground values on an element by element basis,
the 99th percentile. This cluster of samples is also so it is critical that plots showing biogeochemical
strongly anomalous in Co, Cu, Nb, Y, and Zn. results be levelled to account for these differences.
Regional soil sampling grids were completed,
for the most part, between 200 and 400 m line kIn Situ Radon-in-Soil
3 spacing and 100–200 m sample spacing orthogo- In situ radon-in-soil measurements were taken
nal to EM conductors and/or radiometric anoma- adjacent to the site of soil sample (hole). A hand-
lies. Over 700 B-horizon samples were collected operated auger was used to drill a hole approxi-
with sampling generally avoiding muskeg. The soil mately 2.5 cm in diameter to a depth of approxi-
profile comprises 0–15 cm of moss or pine needles mately 65 cm. Net radon results are given in counts
covering a thin 0.1–1 cm organic humus layer, then per minute (cpm). Radon-in-soil analysis was com-
into a generally beige- to white-colored uncon- pleted at a total of 181 sample sites, most of which
solidated pebbly sand. The B-horizon selected for have corresponding soil sampling completed for
sampling was identified in the field as an abrupt ICP analysis. Values for radon ranged between 0
transition from the above beige or white sand to a and 26 counts per minute. In most areas, the spac-
brown or orange sand typically occurring between ing and sample density were too low to establish
15 and 85 cm depth. Thematic plotting was com- significant anomalies when viewing the radon-in-
pleted for Ag, As, Au, Ce, Co, Cu, Li, Mo, Pb, U, Th, soil data alone. Other samples such as lake-bottom
Y, and Zn and assessed for spatial associations with water samples were also collected and measured.
known geological, radon, and geophysical features.
Uranium anomalies in soils are generally limited kGround Gravity Surveys
to one or two adjacent station anomalies. Two of The targets for land-based gravity surveying were
the most significant multi-station soil anomalies selected based on favorable geology and structure,
in the north-west to north central fin area are spa- coincident geochemical survey (lake sediment,
tially associated with mapped granitoid outcrops radon-in-water, radon-in-soil, and/or biogeochem),
with significant topographic relief. The highest U and airborne geophysical survey results from the
value for 2013 came from the west central portion 2013 exploration program. Prioritization was given
of the Swoosh target, adjacent to the projected to discrete sub-kilometric ovoid gravity lows poten-
map extension of pelitic sediments. This sample tially associated with desilicification, clay alteration,
returned 7.90 ppm U with >95th percentile values and other alteration typically found in uranium
for Cu and Y and greater than 80th percentile As deposits. The 2014 ground-based gravity survey
and Pb and positive Pb isotope systematics. consisted of gravity stations collected on survey
lines spaced at 400 m with a station spacing of 50 m.
kBiogeochemical Sampling A horizontal loop electromagnetic survey (HLEM)
Regional biogeochemical sampling was completed was later carried out. The targets were selected for
on geochemical survey grids in conjunction with HLEM surveying to more accurately define air-
soil sampling. Black spruce was selected as the borne VTEM conductors of interest refined by the
preferred vegetation medium due to its proven geological, geochemical, and gravity results.
ability to concentrate many elements and wide-
spread availability in both well-drained and poorly kDrilling
drained areas. Previous studies also identified Jack Finally, two diamond drilling programs were
pine as a suitable biogeochemical medium. These carried out in 2014 and 2015. The drill core was
species was selected as a secondary target vegeta- descriptively logged by the geologist on site for
tion type, due to its widespread distribution in the lithology, alteration, mineralization structure,
property area. Thus, twigs with attached needles and other geological attributes with the pertinent
were collected from around the circumference of data entered into a database. Handheld spectrom-
an individual tree within 20 m of each soil sampling eters were used to measure the radioactivity of the
site. Numerous field parameters were collected drill core and aided in the selection of zones for
including tree height, twig length and diameter, sampling. The core was sampled based on radio-
soil moisture conditions, slope, aspect, and any activity, alteration, and structure of the core with
other factors that would affect sample quality. The sample intervals typically 0.5–1 m in length.
3.5 · Case Studies
213 3
zz Ilovica-Shtuka Gold-Copper Project soil geochemistry sampling was approximately
Exploration: Courtesy of Euromax 5000 m2. The soil sampling targeted the subsoil
Resources horizon, which is generally at a depth of 20–30 cm
The Ilovica property is located in the southeast of (the «B» horizon of the soil profile), as this unit
Macedonia, about 16 km to the border with Bulgaria. generally contains the accumulated minerals. The
Ilovica is a porphyry copper-gold deposit, situated in soil surveys were completed by initially removing
a northwest-southeast striking Cenozoic magmatic the humus topsoil layer with a spade, before taking
arc that covers large areas of central Romania, Serbia, a 2–3 kg sample of the subsoil. The remainder of
Macedonia, southern Bulgaria, northern Greece, and the soil was restored to the sampling location and
eastern Turkey. It is more or less 1.5 km in diameter, rehabilitation of disturbed areas was performed.
being associated with a badly exposed dacite-grano- Results of soil sampling over the property
diorite plug and emplaced along the northeastern indicate significant copper anomalies (>200 ppm
border of the northwest-southeast elongate Strumica copper) to the northwest, southwest, and south
graben. The exact location of the deposit is controlled of the mineralized intrusive (. Fig. 3.78). These
by major north-south crosscutting faults and minor anomalies are believed to represent down slope
northwest-southeast faulting, parallel to the faulted dispersion of the copper from the central area
border of the graben. Alteration related to tertiary of mineralization. In contrast, significant gold
magmatic activity at Ilovica is variably present over (>0.10 ppm) and to a lesser extent molybdenum
an area of approximately 8 km2. Pervasive alteration (>20 ppm) show less down slope dispersion and
is largely confined to a roughly 1.5 km2 area in and more accurately delineate the underlying miner-
adjacent to the main intrusive complex. Smaller alization.
areas of pervasive and structurally-controlled altera-
tion extend somewhat asymmetrically to the south kGeophysical Surveys
and east of the intrusive complex. A total magnetic intensity survey was carried out
Regarding the mineralization, the main sul- and 24 east-west lines spaced 100 m apart were
fide mineral at Ilovica is chalcopyrite followed by surveyed with readings taken every 10 m. The aim
pyrite and secondary copper sulfides such as chal- of the survey was to outline the lateral and ver-
cocite, covellite, and bornite. Molybdenite, galena, tical extension of stockwork zones with second-
and sphalerite are present in minor amounts, ary magnetite enrichment intersected in several
and occasional traces of sulfosalt minerals such drillholes. Magnetic susceptibility measurements
as tetrahedrite-tennantite and tellurides of gold were taken at an average interval of about 10 cm
and silver are observed. High-temperature oxide on core from these holes using an electromagnetic
mineralization, such as magnetite, dominates at inductance bridge. A high amplitude magnetic
depth associated with pyrrhotite and chalcopyr- anomaly was outlined; the magnetic susceptibility
rhotite in what is interpreted as the core of the measurements demonstrated that the only mag-
system. A variety of iron hydroxide group miner- netic rocks in the area are the secondary mag-
als are largely developed within the oxidation and netite enrichment stockwork zones that are the
cementation zones. Very occasionally gold nug- source of the magnetic anomaly. The magnetic
gets are observed at the base of the oxidation zone. models indicated that the magnetic stockwork
zone trends north-northeast along an 800 m strike
kField Mapping, Rock Chip Sampling, and length and is approximately 300 m wide, though
Soil Geochemistry Survey inherent ambiguities in the interpretation process
Detailed geological mapping was completed on may have underestimated the width of the body.
1:2000 and 1:5000 scales and comprised observa- A high-resolution pole-dipole array survey was
tions with respect to petrology, style of alteration, carried out using dipole lengths of 300 and 150 m
and mineralization. Rock chip samples were col- and n spacings of 0.5, 1, 1.5, 2, 2.5, 3, 3.5, 4, 4.5, 5,
lected from the outcrops which were identified as and 5.5 for the array with dipole length of 300 m and
having potential to host mineralization. n = 1, 2, 3, 4, 5, 6, and 7 for the 150 m dipole length.
In total, three phases of soil sampling have The IP or resistivity survey identified a number of
been undertaken on the property, resulting in intense IP anomalies, interpreted to be related to
a total of 540 sampling points arranged on a sulfide and magnetite mineralization previously
100 m × 100 m grid. The total area covered by the intersected in drillholes (. Fig. 3.79). The resistivity
214 Chapter 3 · Mineral Resource Exploration
4596000
Legend
Drillhole
ILOVITZA 06
ILOVITZA 11
Au_soil
3 Au
Au in soil >0.216ppm
Au in soil 0.108–0.216ppm
Au in soil 0.054–0.108ppm
Au in soil 0.027–0.054ppm
Cu_soil
Cu
Cu in soil >384ppm
4595000
Cu in soil 192–384ppm
Cu in soil 96–192ppm
Cu in soil 48–96ppm
Mo_soil
Mo
Mo in soil >40ppm
Mo in soil 20–40ppm
Mo in soil 10–20ppm
Mo in soil 5–10ppm
.. Fig. 3.78 Excerpt of the soil geochemistry anomalies map (Illustration courtesy of Euromax Resources)
4594600 4594600 40
20
4594400 4594400
10
4594200 4594200 8
6
4594000 4594000
4
4593800 4593800 2
0
4593600 4593600
7652700 7653000 7653300 7653600 7653900 7654200 7654500 7654800 7655100
.. Fig. 3.79 2D IP Inversion model on level 350 m from surface (Illustration courtesy of Euromax Resources)
3.5 · Case Studies
215 3
models revealed the presence of linear, almost ver- area of low resistivity correlates with low-grade
tical low resistivity features, interpreted as fault copper and gold in the Ilovica block model, and
zones. The most prominent IP anomaly coincided in fact, grade appears to increase as the higher
spatially with the magnetic stockwork zone defined resistivity zone is intersected.
previously by the magnetic survey and tested by
several drillholes. The high IP intervals correlated kDrilling
with high total sulfide values of up to 3–5%, though A total of 130 holes have been drilled over 10
while the copper mineralization in drillholes coin- campaigns (42,032 m): 20 were drilled for geo-
cides with high sulfide concentrations, it was not technical investigation, 15 were carried out for
possible to distinguish between anomalies related hydrogeological investigation, and 95 were drilled
to a barren pyrite halo and IP anomalies associated for mineral resource determination. The drill-
with porphyry copper mineralization. holes are generally vertical or steeply dipping,
Several IP anomalies form a discontinuous with 95 of the drillholes being vertical and the
annular zone around the interpreted core of the remainder being between 55° and 75°. The drill
system, probably related to the pyrite halo. The locations are illustrated in . Fig. 3.80. All of the
resistivity model indicates the presence of near to holes were drilled using rotary diamond coring
horizontal low resistivity layers to the west of the techniques. Drillholes were collared with PQ
core of the system interpreted to reflect the pres- diameter (85 mm core) and then advanced with
ence of intensive stockwork zones with copper HQ (61.1 mm core) and then occasionally NQ
mineralization. A further observation is that the (45.1 mm core) diameters. A wireline system was
70
0 0
55
IC1577GT02
BHIL114GT
4595500
4595500
EOIC1243
EOIC1121 EOIC1232 EOIC 1235 EOIC1247
BHIL 113G3
IC1574GT01IC1591 IC1583 IC1579
EOIC1015
EOIC1019 EOIC1016 EOIC1238 EOIC1250
IC15103HG11A IC15100GT06 EOIC1240
IC15115HG4
IC1594 IC1586 IC1582 PDIC0607IC1573
45 500
0 PDIC0606
IC15110HG1EOIC1360IC1520MIC1590 IC1542M EOIC1237 EOIC1358
IC15101HG2 EOIC1120 EOIC1242 IC1584
IC1578 IC15107GT08
EOIC1124 IC1572
IC1587 EOIC1364IC1588 EOIC1370 EOIC1366
85
IC1593
0
IC1581GT03EOIC1126 EOIC1122
IC15116HG6 IC1576
IC1596 IC1597 IC1562M EOIC1367
EOIC1365 EOIC1362
EOIC0811
0
60 EOIC0813 IC1595PDIC0608
EOIC1014 EOIC1368
IC1585 IC15112HG5 IC1580
IC1589GR04
4595000
4595000
PDIC0504
0
EOIC1229
150
N
W E
S
Meters Legend
0 50 100 200 300 400 500 Drill hole location
0
70
0
80
900 Z
800 Z
Cu depleted
3 oxide zone
Supergene
600 Z enriched Cu
zone
400 Z
Primary Cu
mineralization
Cu (%)
0
200 Z 0 – 0.1
0.1 – 0.2
0.2 – 0.3
0.3 – 0.4
0.4 – 0.5
> 0.5
0Z
7653600 E
7653700 E
7653800 E
7653900 E
7654300 E
7654400 E
7654500 E
7654000 E
7654100 E
7654200 E
z
x
.. Fig. 3.81 Typical section with copper assays (%) (Illustration courtesy of Euromax Resources)
used to hoist the core tube to surface to allow the deeper holes show up to five degrees variance
drill core to be extracted. from design for both dip and azimuth. The cross
Logging included observations relating to section presented in . Fig. 3.81 illustrates the
project lies within the Indian Peak volcanic field, True thickness of the mineralized zones reaches
which is a broad tertiary volcanic field that strad- up to 150 m wide with the strike length of the
dles the Utah-Nevada border and contains several vein systems extending up to several kilometers.
nested, collapsed calderas and resurgent dome
features that formed as part of a major Oligocene- kSampling
Miocene «ignimbrite flare-up cycle.» The oldest The work program collected 2409 rock chip sam-
rocks in the region consist of Proterozoic through ples, 2964 soil samples, and 323 stream sediment
lower Mesozoic sedimentary sequence that samples. The majority of the samples were col-
became folded and thrust-faulted eastward during lected on a reconnaissance basis from both outcrop
the Cretaceous Sevier orogeny and were subse- and float material. Sampling was also conducted
quently overlain by tertiary sedimentary deposits. within the target areas where outcropping min-
Gold mineralization at Gold Springs is hosted eralization was sampled perpendicular to struc-
by complex sheeted veins, breccias, and stock- tural trends where possible. Grab samples were
work vein systems (. Fig. 3.82) that are laterally
collected to help define background geochemical
extensive and locally form resistant ledges and levels within the various rock units and to evaluate
ribs that protrude up to 10 m above the surround- metallic ion distribution and chemical zonation in
ing ground surface and surrounding areas of areas of new exploration. Select s amples were also
mineralized wall rock. The veins contain quartz, collected from mine dumps and vein exposures to
adularia, and bladed calcite with minor sulfides determine if there were any specific geochemical
(<2%) and represent a low sulfidation, epith- signatures and to characterize the ability of the
ermal gold-silver vein system. Gold and silver system to contain high-grade gold values.
mineralization are hosted in quartz and quartz- Rock chip results ranged from <5 ppb gold to a
calcite veins, breccias, and stockwork/sheeted high of 145.68 g/t gold. Silver shows some correla-
vein zones surrounding the main vein systems. tion with gold and values ranged from <0.1 ppm to a
218 Chapter 3 · Mineral Resource Exploration
high of 252.9 ppm. Gold geochemistry from the soil models for the ZTEM and magnetic inversions
samples ranged from <0.5 ppb to a high of 1.3 g/t provided a 3-D conductivity model of the earth
while silver ranges from <0.1 to 11.6 ppm. Results that honors the ZTEM and magnetic data to a
from the stream sediment sampling show a varia- specified level of fit. The modeling correctly con-
tion in gold values from a low of <5 ppb to a high of sidered 3-D topographic effects which can signifi-
1.28 g/t. Preliminary analysis of some of the down- cantly influence the data. The inversion modeling
3 hole geochemical data suggests that there are at least was unconstrained by geologic and physical prop-
two different signatures for the various target areas. erty information. The primary outcome of these
Moderately anomalous arsenic and local molybde- studies was the development of a clear correlation
num values are associated with gold mineralization with the location of surface gold mineralization
with a surrounding zone that shows a relative deple- and gold intersected in drillholes particularly with
tion in calcium, potassium, and sodium. the margins of the high resistivity features. This
Then, a detailed follow-up sampling and map- correlation can be seen in the «depth-slice» pre-
ping were conducted on several of the target areas. sentation of the data (. Fig. 3.83). Where the high
This work included detailed structural analysis and resistivity is shallow, a strong correlation between
channel sampling as well as detailed vein sampling the margins of the high resistivity and gold inter-
in the main trenches. In addition, a series of chan- sected in drillholes exists. Where the high resis-
nel sample lines were completed over the exposed tivity is deeper, gold mineralization is found both
vein zones. These channel sample lines generally at the margins and over the top of the resistivity
consist of a series of 2 m long, continuous chip- features. This correlation is interpreted as relating
channel samples across outcropping exposures of to the heat source for the «hot spring» style min-
the various vein-stockwork zones. eralization seen at Gold Springs.
kGeophysics kDrilling
A 470 line-km ZTEM and aeromagnetic heli- The last exploration work in 2014 focused on com-
copter survey was completed. Previous ground pleting a 38-hole RC and 4-hole core drill program.
surveys revealed a positive correlation between The four core holes were completed to collect mate-
the known epithermal gold systems and buried rial for metallurgical testing and to start to collect
subvertically dipping high resistivity features. geotechnical data for rock quality designation
The ZTEM results correlated very well with (RQD), fracture analysis, and lithologic and altera-
known geology, in particular the presence of all tion data. On the other hand, downhole surveys are
the known epithermal centers. The helicopter- conducted using a gyro deviation survey instru-
borne geophysical survey in Gold Springs project ment at or near the termination of the hole. These
included a Z-axis Tipper electromagnetic (ZTEM) surveys provide detailed downhole data on the azi-
system and a cesium magnetometer. Ancillary muth and dip of the hole over the length of the hole.
equipment included a GPS navigation system and The 2012–2014 drilling programs were con-
a radar altimeter. The survey was flown in an east ducted by wet reverse circulation drilling method.
to west (N 90° E azimuth) direction, with a flight Emphasis was placed on quality control and the
line spacing of 200 m. Tie lines were flown in a proper handling and numbering of all samples.
north to south (N 0° E azimuth) direction, with a The reverse circulation drill cuttings are collected
flight line spacing of 1900 m. as they come out of the drillhole from an industry
TD (total divergence) imaging converts the standard rotary wet splitter provided by the drill-
ZTEM tipper crossover data into peak responses ing company, which delivers the material to three
which assists their interpretation in plan. TD low collection points. Samples are collected on 1.52 m
(conductive) areas signify areas with sulfides or intervals. Every 20 samples, standards and blanks
possibly conductive clays, and the TD high (resis- are inserted into the numbering sequence of the
tive) areas represent resistive rocks which show drill cuttings. The material from the second sample
an excellent correlation with known gold occur- point is retained as a duplicate sample for future
rences as would be expected in the low sulfidation testing if needed. The material from the third sam-
environment. Subsequent to the 2-D inversion, a ple point is geologically logged on site and put into
3-D inversion of both the ZTEM conductivity data chip trays that are labeled with sample numbers and
and the magnetics was carried out. The resulting footage intervals from which the sample was taken.
3.6 · Questions
219 3
Gray eagle
M+|+| 220,000 AuEq Oz Iris
Horseshoe Ext.
Fluorite
Miracle Pope
Ridge North
jumbo
Red light North
jennie
Tin can
Declaration Jumbo
Charlie ross
Surface outcropping gold mineralization Jumbo
M+|+| 634,000 AuEq Oz
Silica hill Ext.
Potential buried gold targets
Silica hill Gem
Thor vein
N
Pinyon North
and Pinyon South
Sharks belly
not shown on map
0 500 1000
Meters
Midnight
.. Fig. 3.83 ZTEM high resistivity and correlation with outcropping gold-bearing rocks in the Gold Springs project
area (Illustration courtesy of TriMetals Mining Inc.).
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