1

M Prakash Institute Chemistry

MOLE-1 Advanced MCQs

Note:
Atomic numbers: H:1, C:6, N:7, O:8, F:9, Na:11, Mg:12, Al:13, Si:14,
P:15, S:16, Cl:17, K:19, Zn:30, Br:35, Rb:37, Sn:50, I:53, Ba:56, Pb:82
Atomic Masses: H:1, He:4, Li:7, C:12, N:14, O:16, F:19, Na: 23,
Mg:24, Al:27, Si:28, P:31,S:32, Cl: 35.5, K:39, Ca:40, Fe: 56, Ti:
48, Mn:55, Cu: 63.5, Zn:65, Br:80, Rb:85, Sr: 88, Ag: 108, I:127,
Xe:131, Pt:195, Au:197, Pb:207, Bi: 209
————————————————————————————–
Note: Use ‘NA ’ = 6×1023
————————————————————————————–
1. 10 g CaCO3 on heating leaves behind a residue weighing 5.6 g,
Carbon dioxide released into the atmosphere at STP will be
(A) 2.24 L (B) 4.48 L (C) 1.12 L (D) 0.56 L
2. Law of multiple proportions is illustrated by one of the following
(A) H2 S and SO2 (B) N H3 and N O2
(C) N a2 S and N a2 O (D) BeO and BeCl2
(E) N2 O and N O
3. Two oxides of a certain metal were separately heated in a cur-
rent of hydrogen until constant weights were obtained. The water
produced in each case was carefully collected and weighted. 2 g of
each oxide gave 0.2517 g and 0.4526 g of water respectively. This
observation illustrates
(A) law of conservation of mass
(B) law of constant proportions
(C) law of multiple proportions
(D) law of reciprocal proportions
4. The mass of nitrogen per gram hydrogen in the compound hy-
drazine is exactly one and half times the mass of nitrogen in the
compound, ammonia. The fact illustrates :
(A) the law of conservation of mass
(B) the multiple valency of nitrogen
(C) the law of multiple proportions
(D) the law of definite proportions
2

5. Two samples of lead oxide were separately reduced to metallic

lead by heating in a current of hydrogen. The weight of lead from
one oxide was half the weight of lead obtained from the other oxide.
The data illustrate
(A) law of reciprocal proportions
(B) law of constant proportions
(C) law of multiple proportions
(D) law of equivalent proportions
6. One part of an element X combines with two parts of another el-
ement B. Six parts of the element C combine with four parts of the
element B. If A and C combine together, the ratio of their weights
will be governed by
(A) law of definite proportions
(B) law of multiple proportions
(C) law of reciprocal proportions
(D) law of conservation of mass
7. 12 g carbon combine with 64 g sulphur to form CS2 . 12 g carbon
also combine with 32 g oxygen to form CO2 . 10 g sulphur combine
with 10 g oxygen to form SO2 . These data illustrate the
(A) law of multiple proportions
(B) law of definite proportions
(C) law of reciprocal proportions
(D) law of gaseous volumes
8. The weight of one molecule of a compound C60 H122 is
(A) 1.30 × 10−20 g (B) 5.01 × 10−21 g
(C) 3.72 × 1023 g (D) 1.4 × 10−21 g
1
9. If we consider that 61 , in place of 12 , mass of carbon atom is
taken to be relative atomic mass unit, the mass of one mole of a
substance will
(A) increase two fold
(B) decrease twice
(C) be a function of molecular mass of the substance
(D) remain unchanged
10. Mass of a mole of electrons is :
(A) 0.20 mg (B) 0.02 mg (C) 0.55 mg (D) 1.00 mg
 3

11. There are 6.02 × 1022 molecules each of N2 , O2 and H2 which

are mixed together at 760 mm and 273 K. The mass of the mixture
of gases in grams is
(A) 3.09 (B) 4.12 (C) 6.2 (D) 7.0
12. The system that contains the maximum number of atoms is
(A) 4.25 g of N H3 (B) 8 g of O2
(C) 2 g of H2 (D) 4 g of He
13. A gaseous mixture contains oxygen and nitrogen in the ratio of
1 : 4 by weight. Therefore, the ratio of their number of molecules
is
(A) 1 : 4 (B) 1 : 8 (C) 7 : 32 (D) 3 : 16
14. A person adds 1.71 gram of sugar (C12 H22 O11 ) in order to
sweeten his tea. The number of carbon atoms added are (mol.
mass of sugar = 342)
(A) 3.6 × 1022 (B) 7.2 × 1021
(C) 0.05 (D) 6.6 × 1022
15. Common salt obtained from sea-water contains 95% NaCl by
mass. The approximate number of molecules present in 10.0 g of
the salt is :
(A) 1021 (B) 1022 (C) 1023 (D) 1024
16. Which of the following has the largest number of atoms ?
(A) 0.5 g atom of Cu (B) 0.635 g of Cu
(C) 0.25 mole of Cu (D) 6.35 × 1020 amu of Cu
17. One litre of a gas is at a pressure of 10−6 mm of Hg at 25◦ C.
How many molecules are present in the vessel ?
(A) 3.2 × 106 (B) 3.2 × 1013
(C) 3.2 × 1010 (D) 3 × 104
18. Two containers P and Q of equal volume (1 litre each) contain
6 g of O2 and SO2 respectively at 300 K. Then
(A) number of molecules in P is less than that in Q
(B) number of molecules in Q is less than that in P
(C) number of molecules in P and Q are same
(D) either (A) or (B)
19. A sample of phosphorus trichloride (P Cl3 ) contains 1.4 moles
of the substance. How many atoms are there in the sample ?
(A) 4 (B) 5.6
23
(C) 8.431 × 10 (D) 3.372 × 1024 (E) 2.409 × 1024
4

20. The number of moles of SO2 Cl2 in 13.5 g is

(A) 0.1 (B) 0.2 (C) 0.3 (D) 0.4
21. How many moles of electron weigh one kilogram ?
1
(A) 6.023 × 1023 (B) × 1031
9.108
6.023 1
(C) × 1054 (D) × 108
9.108 9.108 × 6.023
22. The total number of electrons in 18 mL of water (density 1 g
mL−1 ) is
(A) 6.02 × 1023 (B) 6.02 × 1025
(C) 6.02 × 1024 (D) 6.02 × 18 × 1025
23. The total number of protons in 10 g of calcium carbonate is
(N0 = 6.023 × 1023 )
(A) 1.5057 × 1024 (B) 2.0478 × 1024
(C) 3.0115 × 1024 (D) 4.0956 × 1024
24. The number of g-atom of oxygen in 6.02 × 1024 CO molecules
is
(A) 1 (B) 0.5 (C) 5 (D) 10
25. 280 mL of sulphur vapour at NTP weigh 3.2 g. The molecular
formula of the sulphur vapour is
(A) S (B) S2 (C) S4 (D) S8
26. A gas mixture contains 50% helium and 50% methane by vol-
ume. What is the percent by weight of methane in the mixture ?
(A) 19.97% (B) 20.05% (C) 50% (D) 80.06%
27. Which one of the following statement is incorrect ?
(A) One gram atom of carbon contains Avogadro’s number of atoms
(B) One mole of oxygen gas contains Avogadro’s number of molecules
(C) One mole of hydrogen contains Avogadro’s number of atoms
(D) One mole of electrons stands for 6.02 × 1023 electrons.
28. If a compound contains two oxygen atoms, four carbon atoms
and number of hydrogen atoms is double of carbon atoms, the den-
sity of its vapour shall be
(A) 88 (B) 44 (C) 132 (D) 72
29. The compound N a2 CO3 .xH2 O has 50% H2 O by mass. The
value of x is
(A) 4 (B) 5 (C) 6 (D) 7 (E) 8
 5

30. Which pair of species have same percentage of carbon ?

(A) CH3 COOH and C6 H12 O6
(B) CH3 COOH and C2 H5 OH
(C) HCOOCH3 and C12 H22 O11
(C) C6 H12 O6 and C12 H22 O11
Q.31. What will be the molarity of 588 grams of H3 PO4 in 3 dm3
of its aqueous solution?
A) 2.2 M B) 2.1 M C) 2.4 M D) 2 M
Q.32. Calculate percentage by weight of phosphorus in calcium
phosphate.
A) 20% B) 40% C) 0.20% D) 50%
Q.33. 1 mole of P4 molecule contains—
A) 4 atoms B) 4 × NA atoms
1
C) 4 × NA atoms D) 16 × NA atoms
Q.34. In ammonia and Hydrazine (N2 H4 ) the variable masses of
hydrogen which combine with the fixed mass of nitrogen are in a
simple ratio of—
A) 1 : 3
B) 1 : 2
C) 2 : 3
D) 2 : 5
Q.35. A student carefully placed 23 g of sodium in a reactor with
an excess quantity of chlorine gas. When the reaction is complete,
the student obtained 58 grams of common salt. How many grams
of chlorine reacted?
A) 58.5 grams B) 58 grams C) 35.5 grams D) 35 grams
Q.36. One volume of N2 combines with one volume of O2 gas to
form two volumes of nitric oxide. Calculate the volume of each re-
actant required to produce 250 mL of nitric oxide.
A) 150 mL B) 125 mL C) 250 mL D) 1250 mL
Q.37. How much volume will be occupied by 2 mole CO2 gas at
STP?
A) 4.48 L B) 448 L C) 44.8 L D) 4480 L
Q.38. Which of the following contains largest number of atoms?
A) 11 grams CO2 B) 4 grams of H2
C) 5 grams of NH3 D) 8 grams of O2
6

Q.39. Two compounds each containing only tin and oxygen had
the following composition.
- Mass % of Tin Mass % of oxygen
Compound A 78.77 21.23
Compound B 88.12 11.88
The above information is in accordance with the following—
A) Law of combining volume
B) Law of multiple proportions
C) Law of definite proportions
D) Law of conservation of mass
Q.40. The number of Cl− ions in 222g anhydrous CaCl2 is—.
A) 2NA B) 3NA C) NA D) 4NA
Q.41. What is the ppm concentration of calcium ion in 0.010 M
CaCO3 ?
A) 450ppm B) 1000ppm C) 40ppm D) 400ppm
Q.42. 16 g of SOx occupies 5.6 litre at STP. Assuming ideal gas
nature, The value of ‘x’ is—-
A) 1 B) 2 C) 3 D) None of these
Q.43. 5.6 L of a gas at STP weighs 8 grams. The vapour density
of that gas will be—
A) 32 B) 16 C) 8 D) 40
Q.44. The mass percentage of KI in water is 15%. What is the
molality of the solution?
A) 1.55 molal B) 1.92 molal C) 1.06 molal D) 2.05 molal
Q.45. An iodized salt contains 0.5% (W/W) of ‘NaI’. A person
consumes 3 g of salt everyday. The number of iodide ions going
into his body everyday is—-
A) 10−4 B) 6×10−4 C) 6×1019 D) 6×1023
Q.46. The volume of water is required to make 0.2 M solution from
16 mL of 0.5 M solution is–
(A) 40 mL (B) 16 mL (C) 50 mL (D) 24mL
Q.47. If a solution is 0.638 molal in N a2 CO3 , how many grams of
salt must be added to 250 g of water?
A) 17 grams B) 170 grams C) 1.7 grams D) 1.7 Kg
Q.48. If 500 ml of 1 M solution of glucose is mixed with 500 ml of
1 M solution of glucose final molarity of solution will be :
A) 1 M B) 0.5 M C) 2 M D) 1.5 M
 7

Q.49. What is the molarity of an ethyl alcohol (C2 H5 OH) solution

of volume 95 ml prepared by adding 50 ml of ethyl alcohol to 50ml
of water? The density of ethyl alcohol is 0.789 g/ml.
A) 9M B) 8M C) 7M D) 0.9M
Q.50. Molarity of H2 SO4 is 18 M. Its density is 1.8 g/cc , hence
molality is—-
A) 18 molal B) 100 molal C) 36 molal D) 500 molal
8