Model Question

Grade XI
Chemistry (Theory) F.M: 75
Attempt all questions
Group "A"

Circle the best alternative to the following question. [11×1=11]

1. Which of the following contains the least number of molecules?

1 1
c)n = 2, l = 1, m = 0, s = -2 d) n = 2, l = 2, m = +1, s = +2

3. Element with atomic number 19 belongs to which block of the periodic table?
a) s b) p c) d d) f
4. Which of the following contains both covalent & ionic bonds?
a) CCl4 b) CaCl2 c) NH4Cl d) NH3
5. Which of the following represents the correct order of electron affinities?
a) Cl > Br > I >F b) Cl>F>Br < I c) F > Cl>Br > I d) Cl>F>Br>I
6. The current strength required to pass 9000 coulombs of electricity through an electrolyte
for 20 minutes is
a) 7.5 Amperes b) 0.00625 Amperes c) 150 Amperes d)0.15 Amperes
7. Which of the following is amphoteric oxide?
a) ZnO b) CuO c) Na2O d) N2O5
8. Which of the following allotrope of carbon can be used in cancer and AIDS therapy?
a) Diamond b) Graphite c) Coal d) Fullerene
9. Ores are roasted to
a) Dehydrate the ore b) Remove CO2 and H2O
c) Remove Sulphur and arsenic d) Fuse the ore
10. The IUPAC name of CH3– C = CHCH3
C2H5
a) 2- ethylbutane b) 2-ethyl but -2-ene c) 3- methylpent-2-ene d) 2-ethylpent-2-ene
11. The mass of oxygen gas whose volume is 320 ml at 17°C and 2 atmospheric pressure is
a) 0.745 gm b) 0.848 gm c) 0.932 gm d) 0.52 gm
 Group "B"
Give short answer to the following questions: [8x5=40]
1. VSEPR Theory is the simplest theory to explain geometry of various covalent compounds.
i) Write the basic assumptions of this theory. [2]
ii) Predict the geometry of NH3 molecule on the basis of this theory [2]
iii) Bond angle of H2O is 104.5° whereas that of H2S is 92.5°. How do you account for this
fact? OR [1]
Electron affinity of an atom plays important role during the formation of bond.
i) Define electron affinity. [1]
ii) How does electron affinity varies in group and period. [2]
iii) How electron affinity differs from electronegativity? [2]
2. The sodium carbonate decahydrate is known as washing soda. It is manufactured by the
solvay ammonia soda process or solvay process.
i) Write the principle for manufacture of washing soda by solvay process. [2]
ii) Draw the necessary diagram. [1]
iii) Write the action of heat on decahydrated sodium carbonate. [1]
iv) Draw the lewis structure of Na2CO3. [1]
3. Write short note on Le- chatelier’s Principle. Describe how this principle can be applied
during the manufacture of sulphuric acid by contact process. [3+2]
OR
State and explain Graham’s Law of Diffusion.
A vessel of volume 100 ml contains 10% O2 and 90% unknown gas. The gases diffuse in 86
second through small hole of vessel. If pure oxygen under the same condition diffuses in
75 second. Find the molecular mass of unknown gas. [3+2]
4. H2S gas is widely used during the qualitative analysis of metal ions.
i) Write the reaction involved during the lab preparation of H2S. [1]
ii) What happens when H2S gas is passed through [2]
(a) acidified solution of CuSO4
(b) ammoniacal solution of ZnSO4
iii) The pink colour of acidified KMnO4 solution discharges to colorless when H2S gas is
passed. Write the reaction involved. [1]
iv) Why H2S exist as gas at room temperature? [1]
5. The reduction process is used for converting metal oxides into metal and it depends on
the chemical reaction or reactivity of metals.
i) Write the differences between smelting and alumino thermite process. [2]
ii) How can metal like Na and K be reduced? [1]
iii) Define acidic flux and basic flux. [2]
6. Alcohol (-OH), Aldehyde (-CHO) etc are the examples of functional group.
i) Define functional group. [1]
ii) Write the formula for first 4 successive member in homologous series and give their
IUPAC name. [2]
iii) Why boiling point of alkane decreases with increase in branching. [2]
7. Trichloromethane on heating with silver powder gives an unsaturated hydrocarbon A.
i) Write the reaction when A is treated with water in presence of 60% H 2SO4 and HgSO4
[1]
ii) What happens when A is treated with Ozone and then with Zn? [1]
iii) How can you distinguish between A and ethane? [2]
iv) What happens when A is reacted with alkaline solution of KMnO4. [1]
8. Nitric acid is widely used acid in laboratory and for various purposes. It is widely used as
strong oxidizing agent.
i) Draw the flow sheet diagram for the manufacture of nitric acid by Ostwald’s process.
[2]
ii) Write the principle involved for the manufacture of nitric acid by Ostwald’s process.
[2]
iii) Write the action of aqua regia on gold. [1]

Group "C"
Give long answer to the following questions. [3x8=24]
9. Concept of limiting reactant is very useful to calculate the mass of reactant required and
product formed.
20 gm of marble containing 90% CaCO3 is allowed to react with 50 gm of concentrated
acid containing 36.5% HCl by mass.
i) Find limiting reactant. [1]
ii) Find mass and mole of excess reagent left over unreacted. [2]
iii) Find mass of salt formed. [1]
iv) Find molecules and mass of water formed. [2]
v) Find mass of NaOH required to absorb whole of the CO2 gas produced as Na2CO3. [1]
vi) Volume of CO2 gas at 30°C and 770 mm of Hg pressure. [1]
10. Ozone is the triatomic allotrope of oxygen which is formed in the upper layer of
atmosphere (stratosphere).
i) How can be ozone prepared from oxygen? [2]
ii) Draw the structure of ozone showing that oxygen- oxygen bond length is equal. [2]
iii) How can be ozone tested? Explain with two reactions. [2]
iv) How ozone layer deplets and how can it be controlled? [2]
OR
 Michael Faraday studied the mechanism of electrolysis and put forward two laws of
electrolysis.
i) State Faraday’s first law of electrolysis. [2]
ii) Define electrochemical equivalent. [1]
iii) Balance the following reaction by oxidation-number method or ion electron method.
Cl2 + NaOH NaCl + NaClO3 + H2O [3]
iv) Differentiate between oxidation number and valency. [2]
11. Niel’s Bohr proposed new model of atom to overcome the drawbacks of Rutherford’s
atomic model on the basis of Planck’s Theory.
i) How did Bohr’s atomic model interpreted the origin of hydrogen spectra? [2]
ii) Draw the figure of various Hydrogen spectra. [2]
iii) What are the limitations of Bohr’s atomic model? [2]
iv) Explain how Bohr’s atomic model seems to be defective according Heisenberg’s
uncertainty principle and how the correction was done? [2]

THE END