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Analytical Chemistry Activity

1. The document provides examples of chemistry problems involving concentrations expressed in different units like ppm, % by volume, and mole fractions. 2. It also gives practice problems interconverting between concentration terms such as molarity, molality, and mole fractions. 3. The last section provides sample chemistry problems involving stoichiometry, titration, percent composition, empirical formulas, and vapor pressure depression.

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Agyao Yam Faith
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210 views4 pages

Analytical Chemistry Activity

1. The document provides examples of chemistry problems involving concentrations expressed in different units like ppm, % by volume, and mole fractions. 2. It also gives practice problems interconverting between concentration terms such as molarity, molality, and mole fractions. 3. The last section provides sample chemistry problems involving stoichiometry, titration, percent composition, empirical formulas, and vapor pressure depression.

Uploaded by

Agyao Yam Faith
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as DOCX, PDF, TXT or read online on Scribd
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Analytical Chemistry

Name: IBUOS, JAMES VINCENT S. Date:


Course & Year: BSED-2 SCIENCE Subject: Analytical Chemistry

C. SEAT WORK
1.Expressing Concentrations in Parts by mass, Parts by volume, and Mole fraction.

a) Find the concentration of calcium (in ppm) in a 3.50-g pill that contains 40.5 mg of Ca.

Given:
Mass of solution=3.50 g
Mass of calcium=40.5 mg

Find: % by mass of calcium in ppm


mass of solute
Formula: ppm= ×1.0 ×106
mass of solution
Solution:
g
40.5 mgCa × 3
10 mg
× 106=1.16 × 104 ppm Ca
3.5 g

b) The label on a 0.750-L bottle of Italian chianti indicates “11.5% alcohol by volume” How many
liters of alcohol does the wine contain?

Given:
Alcohol by volume=11.5%
Bottle of Italian Chianti=0.750 L

Find: The Number of liters of alcohol in a wine


Solution:
11.5 L alcohol
0.750 L chianti × =0.0862 L alcohol
100 L ch ianti

c) A sample of rubbing alcohol contains 142 g of isopropyl alcohol (C 3 H 7 OH ¿ and 58.0 g of water.
What are the mole fractions of alcohol and water?

Given:
Water (solvent)=58.0 g
Isopropyl alcohol=142 g

Find: Find for the mole of fraction in water and alcohol


Solution:
mole
moles of ethelyne glycol=142 g =2.36 mol C 3 H 8 O
60.09 g
2.39 mol C3 H 8 O
2.39 mol C3 H 8 O 2 +3.22 mol H 2 O
¿ 0.423 C2 H 6 O 2

mole
moles of water=38.0 g =3.22 mol H 2 O
18.02 g
3.22 mol H 2 O
2.39 mol C3 H 8 O 2 +3.22 mol H 2 O
¿ 0.577 H 2 O
2. Interconverting Concentration Terms

a) Given:
Solution by mass=30.0%
Density of mass=1.11g/mL

Find: Mass of solvent and Calculate its molality


Solution:
g of H 2 O=100 g solution−30.0 g H 2 O 2=70.0 g H 2 O
mol H 2 O
30.0 g H 2 O2 =0.882mol H 2 O2
34.02 g H 2 O2
Calculate its Molality
Formula:
no .of moles solute
molality =
Kilogram solvent
Solution:
0.882 mol H 2 O2
Molality= =12.6 m H 2 O2
1 kg
70.0 g × 3
10 g

b) Given:
Moles of solute fraction=70.0 g
Mass percent=0.882 mol H2O2

Find: Mole fractions of H 2 O2


Formula:
moles solut e
mole fraction solute=
moles solution
moles solute
mole fraction solvent=
moles solution

Solution:

1mol H 2 O
70.0 g H 2 O× =3.88 mol H 2 O
18.02 g H 2 O
0.882 mol H 2 O 2
X H 2 O 2= =0.185
3.88mol H 2 O+0.882 mol H 2 O 2

c) Solution
1 mL
volume ( mL ) of solution=100.0 g × =90.1 mL
1.11 g
mol H 2 O2 0.882mol H 2 O2
molarity= = =9.79 M H 2 O2
L soln 1 L soln
90.1 mL× 3
10 mL
Evaluation
1.) What mass of CO is required to react with 25.13 g of Fe2O3 according to the equation
Fe2O3+3CO⟶2Fe+3CO2?

Given:

Find:
Formula:

Solution:
1 mol of Fe2 O3 3 mol of Co 28.01 g CO
25.13 of Fe2 O3 × × × =13.22 g
159.69 g of Fe2 O 3 1 mol of Fe 2 O3 1 mol of CO

2.) A 20.00-mL sample of aqueous oxalic acid, H2C2O4, was titrated with a 0.09113-M solution of
potassium permanganate, KMnO4.

Given:

Find:
Formula:

Solution:
5 H 2 C 2 O 4+ 2¿
0.02324 L ×0.09113 mol ¿ ¿

3) What is the percent of chloride ion in a sample if 1.1324 g of the sample produces 1.0881 g of
AgCl when treated with excess Ag+ ?

Given:

Find:
Formula:

Solution:
g AgCl → moles AgCl →moles Cl−1 → g → %
g
MW AgCl=143.32
mol
g
MW Cl−1=35.45
mol
1 mol AgCl 1mol Cl−1 35.4 g 100
1.0881 g × × × × =23.76 %
143.32 g 1 mol AgCl 1 mol Cl −1
1.324 g
4) A 0.00215-g sample of polystyrene, a polymer composed of carbon and hydrogen, produced
0.00726 g of CO2 and 0.00148 g of H2O in a combustion analysis. What is the empirical formula
for polystyrene?

Given:

Find:
Formula:

Solution:
y
C x H y ( s ) +O 2 ( g ) → x CO 2 ( g ) +
H O ( g)
2 2
1 mol CO2 1 mol C
0.00726 × ×
43.99 g 1 mol CO 2=1.64 ×10−4 mol H
1.64 ×10−4 mol H
=1 so CH
1.65 ×10−4 mol C

5) A solution contains 5.00 g of urea, CO(NH2)2 (a nonvolatile solute) and 0.100 kg of water. If the
vapor pressure of pure water at 25 °C is 23.7 torr, what is the vapor pressure of the solution
assuming ideal behavior?

Solution:

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