Spreadsheet Calculates Critical Flow
Spreadsheet Calculates Critical Flow
Engineering Practice
Spreadsheet Calculates
Critical Flow
Sunil Kumar
Worley Engineering
This method encompasses awide
range of isentropic and frictional
factors, and subcritical flow
hen handling gas, we usu- ate between choking and non-choking that have not been widely publicized.
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NOMENCLATURE Critical flow
conditions
A = Internal cross-section area of u, = Velocity at inlet tls of the pipe P2,V2,U2
pipe, m2 (start of Row), m s P 1•V1, U1
D = Inner dia. of pipe, mm U2 = Velocity at outlet tip of the pipe,
d = Infinitesimal differential operator, m/s Maximum
dimensionless Us = Velocity of sound in gas medium length 100 m
ft = Moody friction factor, m/s Ambient
dimensionless Vo = Specific volume at upstream stag- pressure PA
F = Frictional head losses, m2/s2 nation point, m3/kg
K = Resistance coefficient, v, = Specific volume at inlet-tip of the
dimensionless pipe (start of flow), m3/kg FIGURE 1. Consider a small diameter
= Length of flow pipe, m pipe between an inexhaustible high-pres-
V2 = Specific volume at outlet tip of the sure source and a large ambient receiver.
m = Slope defined in Equation (19), pipe, m3/ kg
dimensionless It is possible that the flow from the pipe
W: Mass flowrate (critical), kg/h will approach the speed of sound
M1 = Mach Number at inlet tip of the
pipe (start of flow), dimensionless X
= Value of subcritical (t.P/PoJsuB
dimensionless '
M2 = Mach Number at outlet tip of the
pipe, dimensionless y = Equation 18), dimension ess
Value of Y correspondinr, to x (see
Po = Stagnation upstream pressure, (7)
kPaa YcR = Critical exkansion factor,
dimension ess
When dealing with adiabatic expan-
P1 = Pressure at inlet tip of the pipe sions, the fundamental PV relation-
(start of flow), kPaa t,. =
Finite change operator,
ship is Equation (8). Solve Equation
P2 = Pressure at outlet tip of the pipe, dimensionless
kPaa (t.P/Po)cR = Overall critical differential (8) for V, and write that into Equation
PA = Ambient pressure, kPaa pressure ratio, dimensionless (7) to get Equation (9).
r = (P 1/ Po)cR = Overall critical -y = Ratio of specific heat at constant
pressure ratio, dimensionless pressure to specific heat at pyr =P1V{ =constant (8)
uo = 0 =Stagnation upstream constant volume at upstream
velocity, m/ s conditions, dimensionless
2A: [[ p½ }P+2J du + f(tr dl) = o
• Node 0 is within a stagnant up- and transforms simultaneously into W P, P{YV1 "• u l, D . (9)
stream system, kinetic energy (t:..u2 I 2) as the flow
• Node 1 is the starting point of flow tends to stay isentropic. However, the Consistent with Figure 1, P 1 and V 1
• Node 2 is the discharge tip of pipe entropy in fact increases because of ·are constants. They are the upstream
into the ambient atmosphere, which velocity-induced friction. Equation (1) conditions. Taking the constants out
is at a low pressure is a fundamental energy balance [5) of integration, we get Equation (10).
In real situations, any expanding flow applicable over a fraction of pipe
emanates from an inexhaustible source length, 6.1: 2A
2
w2pfrv
1
?(p,Yr'rLP+2"•J u
du+ J(rr dl) = 0
P, 1, D
such as a vessel, or a large-bore pipe. As- Vt.P + t.u2 + t.F' = 0 (1) 1 1 (10)
sume that the u pstream pressure Po is 2
both constant and stagnant. At the Equ~tion (2) is an expression from Integration gives us Equation (11).
source conditions (Node 0), the assump- Reference [6). 2 (11)
tion of no-flow is reasonably valid. 2A ( y )
w2pYrv y+ 1 X
At the upstream tip of the pipe, the t.F = (rr ~) u; (2) 1 1
flow starts abruptly with some initial
velocity u 1 . The pressure Po has Plug Equation (2) into Equation (1). [p27 _p7]+2ln(~:)+fr(l~-li)
1
o
dropped to P1 as a result of an in-
crease in kinetic energy. As the flow Vt.P+ t,.u2 +(frt.l )u2 = 0 We can factor out P1 raised to the
2 D 2 (3)
progresses down the pipe, the thermo- (-y+1 1-y) power. from the first section
dynamic changes and frictional losses, In differential form, as the deltas of the equation. After doing some nec-
will further tend to drop the pressure shrink to infinitesimals, we arrive at essary algebra, Equation (11) trans-
until the critical pressure P2 is Equation (4). forms into Equation (12).
reached at the downstream tip of pipe (4)
(Node 2). The pressure P2 represents
the critical pressure at the tip, rather
VdP +udu+(fr~)u; = 0 ;P1A y
W Vi(Y+ 1) P1
2
[(P2)7 -l]+21n(u2)+frl~ l =)O
U1
2
than the actual downstr eam ambient Now, divide through Equation (4) by
pressure. We now have a criterion for u2 !2. The Mach Number and the resistance
evaluating critical flow. · coefficient (K) have been defined in Ref-
(5)
• If PA < Critical P2 , choking exists erence [5]. Use the definitions as in
• IfPA > Critical P2, there is no choking Equations (13) and (14). Substitute into
Substitute: u2 = (W2V2 IA 2) for flow Equation (12) and get Equation (15).
Energy balance in a constant cross-sectional pipe, to (13)
We next develop equations correlating get Equation (6).
P 1 and P2 . In an adiabatic flow
process, there is no heat transfer, and
2
2A dP
w2 v
+2du
u
+(t:r dl)
D
=O (6)
(14)
the shaft work is generally zero. As
Integrate Equation (6) between
the flow expands in the direction of de-
creasing pressure, enth alpy (the total inlet (Node 1) and the outlet (Node 2) 2 [ (PJ
r(y+l) P2 2'.:!:! ] +2ln u2 +K - 0
(uJ (15)
r -1
energy, the product V~) decreases conditions of pipe.
CHEMICAL ENGINEERING WWW.CHE.COM OCTOBER 2002 63
TABLE 1. LIMITING CRITICAL VALUES
K 'Y =1.2 'Y =1.3 'Y =1.4 'Y =1.5 'Y =1.6
( AP/P0 )c11 YcR ( AP/Po)c11 YcR ( AP/Po)c11 YcR ( AP/P0 ) c11 YcR ( AP/Po)c11 YcR
1 0.62 0.52 0.64 0.51 0.66 0.50 0.68 0.50 0.70 0.49
2 0.64 0.54 0.67 0.53 0.69 0.53 0.71 0.52 0.73 0.51
3 0.68 0.58 0.70 0.56 0.73 0.55 0.75 0.54 0.78 0.53
4 0.7 1 0.60 0.74 0.58 0.76 0.57 0.78 0.55 0.80 0.54
5 0.74 0.61 0.76 0.59 0.78 0.58 0.81 0.56 0.82 0.54
6 0.75 0.62 0.78 0.60 0.80 0.58 0.82 0.56 0.84 0.55
7 0.77 0.62 0.79 0.60 0.81 0.58 0.84 0.56 0.85 0.54
8 0.78 0.63 0.80 0.61 0.83 0.59 0.85 0.56 0.86 0.54
9 0.79 0.63 0.81 0.61 0.84 0.59 0.85 0.56 0.88 0.54
10 0.80 0.63 0.82 0.61 0.85 0.59 0.86 0.56 0.88 0.54
20 0.86 0.64 0.88 0.61 0.89 0.58 0.91 0.55 0.93 0.52
30 0.88 0.64 0.90 0.60 0.92 0.56 0.93 0.53 0.94 0.50
40 0.90 0.63 0.92 0.59 0.94 0.55 0.94 0.52 0.96 0.48
50 0.92 0.63 0.93 0.59 0.94 0.55 0.95 0.52 0.96 0.47
60 0.92 0.62 0.94 0.58 0.95 0.54 0.95 0.51 0.97 0.46
70 0.92 0.62 0.94 0.58 0.95 0.54 0.96 0.50 0.97 0.46 '
80 0.93 0.62 0.94 0.57 0.96 0.53 0.96 0.49 0.97 0.45
90 0.93 0.62 0.94 0.57 0.96 0.53 0.96 0.49 0.97 0.45
100 0.94 0.61 0.95 0.57 0.96 0.52 I 0.97 0.48 0.98 0.44
Columns 2, 4, 6, 8 and 10 show the variation between (APIP0 ) CR, 'f and K.
Columns 3, 5, 7, 9 and 11 show variation between YcR, 'I and K.
We can remove pressures and veloc- the pipe's endpoint. This is equiva-
TABLE 2. PROBLEM SETUP
ities by using thermodynamic ratios. lent to the line's flow velocity. Now
Input item Value
The math is rather involved, so it is estimate flowrate based on pipe di-
condensed in a box on p. 65. Substi- Upstream pressure, P0 6,600 kPaa
ameter. This approach assumes adi-
tute the critical ratios from Equations Downstream discharge
abatic expansion. Use Equation (45) pressure, PA 200 kPaa
(43) and (44) into Equation (15) to ar- • Or, preferably, use the isothermal Upstream specific
rive at Equation (16). correlation [5], which is conserva- volume, V0 1/58 kg/ml
2 [
{y+l}Mf 2 l
Mf(y+l) (2+{y - l}Mr) - +
~· ] (16)
tive, and usually gives a flowrate
20-30% higher than the adiabatic
calculation
• If the flow happens to be subcritical,
lsentropic coefficient, "I 1.55
linner dia. of pipe, D
Length of pipe
Number of e lbows
49.2 mm
100 m
4
21n /2+(y- l)Mf +K =O (as determined by the preceding two Resistance coefficient K
(y+l)Mr steps) use the modified Darcy for- (as estimated for above 45
mula with appropriate YCR. Skip to 49-mm pipe data)
Useful critical ratio the last part of this article for fur-
Equation (16) represents the flow sta- ther discussion ginally higher. The reason for the de-
tus during endpoint choking between Equations (16) and (17) are computer- viation in results is attributed to the
Node 1 and Node 2, and as such, it is ized in the spreadsheet that was limitation of maximum 'Y = 1.4 in the
able to provide a solution for part of promised at the beginning of this article. Crane method, whereas, for the ac-
the critical flow problem. This equa• It is provided as a download at tual gas 'Y = 1.55.
tion is a complex function of two vari- www.che.com/CEEXTRA. In addition to the spreadsheet pro-
ables, M 1 and K. For applications, en- The derivation of Y CR is shown in vided, we pi;esent Table 1 for a large
gineers are happier correlating the box on p. 66. The estimation of range of conditions so that readers can
between Node O and Node 2. We need YCR can be accomplished with the fol- verify the accuracy of the program after
more manipulation to have a solution lowing calculation steps. downloading. Table 1 indicates a wide
that estimates (Pzl Po)CR· • Estimate K for the pipes, and 'Y at variation in the critical values with re-
There is a way to estimate the pres- Node 0 spect to 'Y and K. Crane publishes a sim-
sure ratio between Node 1 and Node 2. • Determiner using the Excel spread- ilar table in Crane A-22 [4]. Figure 2
Multiply Equation (32) by Equation sheet method, as described shows the variation between
(44) and thus come up with a correla- • Substitute r into Equation (52) to (t.P IPo)cR, 'Y and K. Figure 3 shows
tion for (Pzl Po)cR: Equation (17). determine the value of YCR variation between YCR, 'Y and K. Both of
the charts indicate a reasonable varia-
r-(p
- R
2) _
-
[o.5(y +l)Mr]½
r(r+1)
Putting the results to work
We present an example for doing
tion with respect to isentropic factor.
Here is the example. Estimate the ma-
o CR [1 +0.5(y- l)Mrj2(r-1) (17) choked-flow calculations. Equation (17) terial loss for a tube-mpture incident in
.is used to determine the maximum a double-tube gas heater. The gas heater
The simultaneous solution of Equa- critical (choked) flow as well as to esti- is receiving gas from a 102-mm main
tions (16) and (17) eliminates M and mate the critical expansion factor. gas-line via a 49-mm branch line. The
yields a value for r, the critical pres- We solved the example by two length of branch line is approximately
sure ratio. We can now determine criti- methods, the Crane plot-correlation, 100 m. The upstream conditions of gas
cal flow in either of the following ways: and the spreadsheet. The flowrates and other relevant data are in Table 2.
• Determine the velocity of sound at from Crane plot-correlation are mar- The estimate ofK =45 comes out of the
64 CHEMICAL ENGINEERING WWW.CHE.COM OCTOBER 2002
Engineering Practice
- y 1.2
- y 1.3
- y 1.4
- y 1.5
- y 1.6
FIGURE 2. The critical pressure difference is influenced by 'I, FIGURE 3. The critical expansion factor is influenced by 'I,
especially at modest resistance coefficients especially at low resistance coefficients
I Number to the general isentropic flow Apply Equation (26) to the pipe inlet (Figure tion (21 ).
correlations. But it is necessary, so here 1). The subscripts are O and 1.
are the steps. 2 2
2
(27) M , = l ,,c,,v,
u¾ (35)
The Mach Number in a flow is defined as _r_ (PoVo) +uo =_r_ (P1 V1) +!2. ,,
a ratio between actual-velocity of gas to the
r- 1 2 r- 1 2
There are two velocities: uo = 0 and (u 1)2
(36)
velocity of sound, at the fluid conditions
prevailing at that particular point. [5]. = 'IM12P1V1 (from Equation ((20]). Plug
The velocity of sound in a gas medium is: these into Equation (26).
(37)
u, =ffe (20)
-Y- (PoV,o) = - Y (PV ')Mf-P1-
1 1) + - V1 (28) Rearrange Equation (37). Equation (38)
Thus, the Mach Number is: r -1 r-1 2 shows the velocity ratio.
Rearrange and simplify.
M=.j; V (21)
u,_
[f2+(r - l)M?}Mrl
_ P1V1 2
There is no motion at a point. Eliminate (29) Uz - 1 {2+(r - 1)Mr}M~
friction from Equation (1) and rewrite as PoVo - 2+ (r - 1
)Mr (38)
Equation (22). In thermodynamic text· From Equation (8), the fundamental adia- Other ratios, such as V1/V2 and P2/P1
books, this is the fundamental energy bal- batic equation, P1Vl'Y = PoV o-Y [5] can be can be worked out with some basic thermo-
ance for frictionless isentropic flow. written in the form o Equation (30). dynamic knowledge [5]:
2 (22) In pipe flow:
Vt,.P+ 0.5t!.u = 0 V1 = (Po)f
Integrate from general Point 1 to general V0 P1 (30) {u/ V) = constant (39)
Point 2: Substituting the above into Equation (29):
v, _ [{2+(r - l)Mn Mrl (40)
2
I
2
JVdp + 0.5Judu = O
I
(23)
(
P1
Po
)7-_2+(r- 1)Mr
2 (31) ½ - ~ {2+(r - 1)Mr}M~
The isentropic process has a well-known In adiabatic flow:
rela tionship [7]. Solve for P,/Po: PVY= constant (41)
fVdp = _L
l y- 1
(P2Vz - P,V1) (24) P
p~ 2
II
= 2+(r - 1)Mr
l*' (32)
f)_ _ [{2+(r - l)M~}Mrl
P, - {2+(r - 1)Mr}M~
r
2
(42)
Substitute Equa tion (24) into Equation Between Node 1 and Node 2
(23); integrate the seco nd term, and write Apply Equation (26) at the pipe end. The If the flow is choked, then there is sonic
Equatio n (25). subscripts are 1 and 2 flow at the pipe outlet. In short, M2= 1. This
25 r u2 r ) u2 creates special ca ses of Equation (38), (40 )
r~/P2½- P1V1) +(uJ _uJ) =o 1 1 r - / P1V1)+-f =r -l (P2½ +; (33) a nd (42) a s follows:
D
nee the critical pressure ratio is known,
the mass flowrate at choking can be
estimated.
rearranging the terms yields Equation (47).
W = 0.1265D2 x
,--
[ ____ ] _ _ _ (47)
I complex equations where a trial-and-
error method is required. Equations
(16) a nd (17) are non-linear and simul-
Adiabatic approach: Po x(l [P2J2J taneous equations with two unknown
variables: M1 and r. Therefore, in order
The gas velocity at the endpoint of the pipe ' 2Vo{K +
is the same as the velocity of sound at end
21n[P2~0J} -
/ 11
Po to determine the value of r, both equa·
lions must be solved simultaneously, to
point conditions. If we know the inner di- Substitute the pressure ratio consistent eliminate M 1•
l
ameter of the pipe, it is possible to trans- with Equation (17); defined as P2/Po = r
form the end point conditions to upstream Here are the steps inside the Excel
spreadsheet method. We have appended
conditions. This is the adiabatic approach, 2
and we use appropriate units and the criti- W = 0 1265D2 P.o[ I- r ] the program in www.che.com/CEEXTRA
cal pressure ratio to develop this correla- with three notational changes. While
·
1 [
N o{K + 21n[frl} (48) working in Excel, the M 1 has been re-
tion , Equation (45).
placed with M, -y with g, and P2/Po with r.
y+ I Equation (49) is Darcy formula [ I], 1. Define Names K, g (for -y) and M (for
0.089D2 r(Yvo)rr (45)
0.1265D 2YcR✓(pw:2 )
W = M 1) in separate cells that refer to their
W= (49) respective values. Note: Use Name/De-
Isothermal approach: fine command on Insert menu.
However, the use of isothermal Row equa- 2. Print the following formula in a cell
Substitute P2/Po = rand rearrange Equa- which refers to the Left hand side of
tion is more conservative, and yields about tion (49).
30% more Row than does the adiabatic Equation (16) and returns the value to
method. In addition, as discussed in the main zero via "Goal seek" command as ex-
W = 0.1265D2YCRt o~r) plained below.
body of the article, the Row stays somewhere (50)
between isothermal and isentropic. There- =2/(M"2*(g+ 1))*(((g+ 1)*
Equation (48) equals Equation (50).
fore it is reasonable to use the isothermal M"2/(2+(g- 1)*M"2))"((g+ 1)/2)-1)
Solve for YCR· +2*LN(SQRT((2+(g- 1)*
equation for the estimation of mass Rowrate.
The mass Rowrate for expanding Row is K( 1- r 2 ) M"2)/((g+ 1)*M"2)))+K
given by the following formula [5], which we YcR = (51) 3. Print the following formula in a cell that
call Equation (46). The usage of this expan- 1{ K+ 21n[fr])(1- r) refers to the right hand side of Equation
sion factor is limited for Rows only through
We can cancel the term ( 1-r) from the nu- (17) a nd returns the value of P2/Po.
constant-cross-section (diameter) pipes.
merator and denominator. We get Equa- =((g+ 1)*M"2/ 2)"(g/ 2)/(1 +(g- 1)*
tion (52) for critical expansion factor. M"2/2)"(g*(g+ 1)/ (2*(g-1)))
2
W- [ A Po ] ( ~) (46) K(l+r) 4. Use "Goal seek" command (from
- ~ K +2/n[¾ ] Po
YCR = 1 { K+ 21,{fr])
(52) Tools menu) to calculate M, by having
the M-value to change so as to set the
Converting this equation to convenient value of the left hand side of Equation
(metric) units, substituting for area and den· NOTE: For flows through an orifice, the ex- (1 6) to zero.
sity (a s defined in the nomenclature), and pansion factor is provided in (2). • 5. Print the solved values for rand M.
6. Further, the value of YCR can be deter-
mined by a simple formu la inserted in
Crane book [6]. The Moody Friction Fac- "I and K. We achieve a less-conserva- spreadsheet (or done on a desk calcu-
tor is 0.02 for 100,000 mm of pipe to- tive and more-precise flowrate. Also, lator). The spreadsheet formula for
gether with 4 standard elbows and exit the Excel model is a lot quicker . YCR or the right -hand side of Equa-
and entrance losses. Solution by Crane method: By tion (52) is as follows:
Solution via Excel spreadsheet using the plot-correlation as given in
=SQRT(K*( 1+r)/ (2*(K+2*LN(l / r)))). O
Solve Equations (16) and (17) simulta- Refer ence [4], (y = 1.4, and K = 45) we
neously: get the following critical values after
r = (P2 ! P0)cR = 0.048 interpolation between K =40 and K = Subcritical flow
Hand calculation: (t:J> / Po)cR = 0.952 100: Graphical methods can give a clue how
From Par t 6 of spreadsheet : (t:J> I Po)cR = 0.885 to deal with subcritical flow. The sub-
YcR = 0.68 YcR = 0.72 critical values for Y can be determined
Critical pressure, P2 = r X P0 = 0.048 The critical pressure, P2 = 759 kPaa by linearly interpolating between (Y =
X 6,600 = 317 kPaa Since P2 > PA, the pipe will choke. 1, t:J> I P0 = 0) and (YCR, [t:J> I Pol CR). If
Since P2 > PA, the pipe will choke. Therefore, for flow estimation, t:J> will Y and [t:J> I PolCR are plotted on y and x
Therefore, for flow estimation, t:J> will be (6,600 - 759) = 5,841 kPa axis respectively, a linear equation to
be (6,600 - 317) = 6,283 kPa. Use Equation (49) with these data . determine intermediate values for Y
Using Equation (49), critical mass Critical mass flow, W = 19,130 kg/h can be written as Equation (18).
flow, W = 18,724 kg/h The plot-based correlation presents
Note that we alternatively can use limitations, as the data wer e outside
(18)
Equation (48) to estimate the critical the graphed range. K had to be ex-
mass flow, by applying the calcu- trapolated and only "I= 1.3 and 1.4 are Solve for slope:
lated value of r directly. Th e for - plotted. The extrapolation process, 1- YcR
mula-based correlation provides an and referring the values from plots,
opportunity to input actual values of are both time consuming. m = ( ll?jpJCR (19)
Solved via spreadsheet. The prob- (M'IPo)cR = 0.952). Interpolating linearly between
lem is the same one as above with one Subcritical Y= 0.816 (Y=l , M' IP0 = 0) and (YcR = 0.72,
change. The downstream pressure is Use Equation (49) for flow. M' I Po)cR = 0.545), or read directly
3,000 kPaa and not 200 kPaa, which is W = 17,028 kg/h Reference [4),
a significant difference. Solved by Crane method: Subcritical Y = 0.82
By using the plot-correlation in Refer- Using Equation (49) for flowrate.
r = (P2 1P0 )cR = 0.048
ence [4), (y =1.4, and K =45) we get the The mass flow, W = 17,104 kg/h. This
(M'IPo)cR = 0.952
following critical values after interpo- is a close check. Obviously, the graph-
YcR = 0.68
lation between K =40 and K =100: ical correlation deviates less in sub-
The critical pressure, P2 = 317 kPaa (M'IPo)cR = 0.885 critical applications. •
Since P2 < PA, the pipe will not YCR = 0.72 Edited by Peter M. Silverberg
choke. Therefore, M' will be (6,600 - The critical pressure, P2 = 759 kPaa
3,000) kPaa. = 3,600 kPa Since P2 < PA, the pipe will not Author
Sub-critical (M' I P o)suB = 3,60016,600 choke. Therefore, M' will be (6,600 - Sunil Kumar is senior
= 0.545 3,000) kPaa = 3,600 kPa process engineer at Worley
Engineering (250 St. Georges
Interpolate linearly between (Y=l, Subcritical (M' IPo)suB = Terrace, Perth, Western
M' IP0 = 0) and (YcR = 0.68, 3,60016,600 = 0.545 Australia 6000; Phone: 61-
8-92788111; Fax: 62-21-
5746709; Email: sunil.kumar
References 4. Crane Co., op cit., p. A-22, . @worley.com.au). He has 12
5. Smith, J . M., and Van Ness, H. C., '!Intl"O- years process design experi-
1. Crane Co., "Flow of Fluids," Publication ence for a variety of offshore
410M, p. 1- 9, Equation 1-11, Joliet, m., duction to Chemical Engineering Thermody-
namics," 4th ed., Sec. 7.2 and 7.3, McGraw- oil and gas r,roduction plat-
March 1988. forms, petro eum refineries,
Hill, New York.
2. Miller, R. W., "Flow Measurement Engineer- petrochemical plants and gas processing
ing Handbook," 2nd ed., Equation 13.14, Mc- 6. Crane Co., op cu., Section 3, Equations 3-14, 3-15. plants. Before Worley, he was employed by
Graw-Hill, New York. 7. Coulson, J. M., and Richardson, J. F., Bechtel. He has a M.Tech. in chemical engi-
3. Kern, R., How to Size Piping as Gas Expands "Chemical Engineering," Vol. 1, 3rd ed., p. neering from Harcourt Butler Technological Jn.
at Flow Conditions, Chem. Eng., Oct. 13, 1975. 30, Equation 2. 71, Per~amon International stitute. He is a member of the Institute of Engi-
Library, Butterwort Hememann. neers (Australia).
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CHEMICAL ENGINEERING WWW.CHE.COM OCTOBER 2002 67
Engineering Practice