DESIGN, INSTALLATION, OPERATION AND

MAINTENANCE MANUAL

FOR

PRE-ENGINEERED AUTOMATIC INDIRECT

CARBON DIOXIDE
EXTINGUISHER UNITS
Models: IHP-500, IHP-1000 and IHP-2000 (With Dimensional Restrictions)

April 2007
P/N 800024
FM File

Firetrace USA LLC.

15690 N. 83rd Way, Suite B
Scottsdale, AZ 85260 USA

Telephone: 480-607-1218
Fax: 480-315-1316
Website: www.firetrace.com
Email: firetrace@firetrace.com

FM REV 3 Page 1 Rev 01 4/10/08

 TABLE OF CONTENTS
1.0 FORWARD ........................................................................................................4
1.1 General...........................................................................................................4
1.2 Safety Precautions........................................................................................4
2.0 INTRODUCTION...............................................................................................6
2.1 Carbon Dioxide Extinguishing Agent...........................................................6
2.1.1 Cleanliness.............................................................................................6
2.1.2 Physical Properties of Carbon Dioxide................................................6
2.1.3 Fill Density..............................................................................................7
3.0 SYSTEM DESCRIPTION .................................................................................9
3.1 General...........................................................................................................9
3.1.1 Operating Pressure .............................................................................10
3.1.2 Operating Temperature Range Limitations:......................................10
3.2 Component Descriptions ............................................................................10
3.2.1 CO2 Cylinder Valve Assemblies.........................................................10
3.2.2 Cylinder Mounting Bracket..................................................................12
3.2.3 Firetrace Flexible Detector/Actuation Tubing....................................12
3.2.4 Discharge Nozzle ................................................................................12
3.2.5 Pressure Switch...................................................................................12
3.2.6 Recharge Adapters, CO2 Cylinder .....................................................13
3.2.7 Cylinder N2 Recharge Adapter...........................................................13
3.2.8 CO2 Warning Nameplate ....................................................................13
4.0 SYSTEM DESIGN AND LIMITATIONS FOR TOTAL FLOODING ............14
4.1 General.........................................................................................................14
4.2 Design Procedure........................................................................................14
4.3 Hazard Enclosure Volume Limitations ......................................................15
4.4 General Specifications................................................................................15
4.4.1 Discharge Time:...................................................................................15
4.4.2 Storage and Operating Temperature Range: ...................................15
4.4.3 System Operating Pressure: ..............................................................15
4.5 Minimum Design Concentrations...............................................................15
4.6 Openings and Ventilation Shutdown .........................................................17
4.7 CO2 Design Concentration Flooding Factors............................................17
4.8 Maximum Protected Volume ......................................................................18
4.8.1 Example Calculations..........................................................................19
4.9 Nozzle and Discharge Tubing Requirements...........................................19
4.9.1 Discharge Nozzle Limitations.............................................................19
4.9.2 Discharge Piping & Fitting Specifications..........................................20
4.9.3 Maximum Piping and Fitting Limitations............................................20
4.10 Firetrace Detector Tubing...........................................................................20
5.0 INSTALLATION INSTRUCTIONS.................................................................22
5.1 CO2 Cylinder/Valve and Bracket Assemblies ...........................................22
5.2 Discharge Piping and Nozzles ...................................................................22
5.3 Firetrace Detection Tubing .........................................................................23
5.4 Pressurization of Firetrace Detection Tubing ...........................................23
6.0 SERVICE, MAINTENANCE, & FILLING INSTRUCTIONS.........................25

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 6.1 General.........................................................................................................25
6.2 Periodic Service and Maintenance............................................................25
6.3 Periodic Service and Maintenance Procedures .......................................25
6.3.1 Weekly/Monthly: Performed by Owner or End User .......................26
6.3.2 Semi-Annual Inspection ......................................................................26
6.3.3 Five Year Inspection............................................................................26
6.4 Post Fire Maintenance................................................................................26
6.4.1 CO2 Cylinder Valve..............................................................................26
6.5 CO2 Cylinder Retest....................................................................................27
6.6 Filling Procedures........................................................................................28
APPENDIX A...............................................................................................................29
APPENDIX B...............................................................................................................37

FM REV 3 Page 3 Rev 01 4/10/08

1.0 FORWARD

1.1 General

This manual is written for the fire protection professional that designs, installs, and
maintains Firetrace Pre-engineered Automatic High Pressure Carbon Dioxide (CO2)
Extinguisher Units.

Firetrace CO2 automatic high-pressure extinguisher units are to be designed, installed,

inspected, tested, maintained, and recharged by qualified trained personnel in
accordance with the following:

• All instructions, limitations, etc. contained in this manual P/N 800024

• All information contained on the agent cylinder nameplate(s).
• NFPA-12, Standard on Carbon Dioxide Extinguishing Systems 2005 Edition.
• FM Approval*
• Local Authority having jurisdiction.

* FM approval for flammable liquid hazards only

1.2 Safety Precautions

Safety precautions are essential when any electrical or mechanical equipment is

involved. These precautions should be followed when handling, servicing, and
recharging Firetrace CO2 automatic high-pressure extinguisher unit cylinders and
equipment. If safety precautions are overlooked or ignored, personal injury or property
damage may occur.

The following symbols are used throughout this manual. Always heed these precautions.
They are essential to the safe use of the equipment described in this manual.

DANGER:
This danger symbol identifies immediate hazards and provides specific
instructions or procedures, which if not correctly followed WILL result in
severe personal injury or death.

WARNING:
This warning symbol identifies specific instructions or procedures, which, if
not correctly followed, COULD result in severe personal injury of death.

CAUTION:
This caution symbol identifies specific instructions or procedures, which, if
not correctly followed, COULD result in minor personal injury or equipment or
property damage.

FM REV 3 Page 4 Rev 01 4/10/08

The following safety precautions should always be followed:

WARNING
Pressurized (charged) cylinders are extremely hazardous and if not handled
properly are capable of causing bodily injury, death or property damage.

1. Read and understand this manual and the other documents referenced herein.
2. The valve discharge outlet safety cap and filling port cap MUST be installed on the
cylinder valve at all times and only removed when connected into the discharge
tubing, or when performing testing, or salvaging operations in accordance with the
procedures contained in this manual.
3. Wear safety glasses when working with pressurized cylinders and charging
equipment. It is recommended to wear leather gloves to avoid any cryogenic burns if
CO2 is accidentally discharged on or near the skin.
4. Make sure that the ball valve (attached to the cylinder valve) is closed (lever is in
“OFF” position), the detection tubing has been removed from the cylinder valve; and
the safety caps installed, before removing the cylinder from the installation, and
before performing any charging, leak tests or salvage operations.
5. Follow all of the safety procedures included on the cylinder nameplate and in this
manual.
6. Never assume that a cylinder is empty. Treat all cylinders as if they are fully
charged.

Any questions concerning the information contained in this manual should be

addressed to:

Firetrace USA LLC.

15690 N 83rd Way, Suite B
Scottsdale, AZ 85260 USA

Telephone: 480-607-1218
Fax: 480-315-1316
Email: firetrace@firetrace.com

The following web site should be visited for frequent technical announcements

www.firetrace.com

FM REV 3 Page 5 Rev 01 4/10/08

2.0 INTRODUCTION

The following Firetrace High Pressure CO2 Automatic Fire Extinguisher Units are
approved with FM Approvals:
IHP 500
IHP 1000
IHP 2000 (With restrictions. See 4.3 Hazard Enclosure Volume Limitations)

These units are designed for total flooding using CO2, in accordance with NFPA-12,
Standard on Carbon Dioxide Extinguishing Systems. 2005 Edition

The Firetrace Pre-Engineered Automatic High Pressure Units have been tested to limits
established by FM in compliance with the requirements detailed in this manual.

Each installed pre-engineered unit is equipped with its’ own detection and its own
discharge tubing and nozzles. The pre-engineered concept minimizes the amount of
engineering involved in the units design. When the discharge tubing and nozzles are
installed within the limitations stated in this manual, no hydraulic calculations are
required to determine pressure drop, agent flow or discharge time.

The hazard being protected can be any size, shape or volume, provided that the hazard
being protected is within the limitations described in this Manual. Each extinguisher unit,
when installed, is a self-contained unit, meaning that it is equipped with its own
automatic (non-electric) detection system, which when actuated, automatically releases
the suppression agent into the hazard area.

Local authorities having jurisdiction should be consulted as to the acceptability for

particular hazards and requirements covering installation.

2.1 Carbon Dioxide Extinguishing Agent

The extinguishing agent used in Firetrace pre-engineered automatic high-pressure

extinguisher units is Carbon Dioxide, more commonly known as CO2. CO2 is a colorless,
odorless, electrically nonconductive inert gas that is an extremely effective fire
suppression agent.

2.1.1 Cleanliness

CO2 is clean and leaves no residue, thereby minimizing any after fire clean up, along
with keeping expensive downtime to a minimum. Most materials such as steel,
aluminum, stainless steel, brass, as well as plastics, rubber and electronic components
are not affected by exposure to CO2. This agent is also environmentally friendly, having
an ozone depletion potential (ODP) of 0.00.

2.1.2 Physical Properties of Carbon Dioxide

Chemical Name: Carbon Dioxide

Molecular Weight 44.01

FM REV 3 Page 6 Rev 01 4/10/08

Boiling Point (oF) @ 14.7psia -109.3
o
Freezing Point ( F) -69.9
Critical Temperature (oF) 87.9
Critical Pressure (psia) 1071
Critical Density (lbm/ft3) 29.2
Specific Heat, Liquid (BTU/Lb-oF) @ 2oF 0.489
Specific Heat, Vapor (BTU/Lb-oF) @ Constant
Pressure (1 ATM) @ 77oF
Heat of Vaporization (BTU/lb) @ Boiling Point
Thermal Conductivity (BTU/hr ft oF) of Liquid @ 77oF
Viscosity, Liquid (lb/ft hr) @ 77oF
Vapor Pressure (psig) @ 70oF 838
Ozone Depletion Potential 0.00

2.1.3 Fill Density

Each Firetrace CO2 storage cylinder has been designed for a maximum fill density as
shown in Table 3.1. It is important that these values not be exceeded.

Fill density and temperature significantly affect the pressure in the storage cylinder. At
elevated temperatures the rate of increase in pressure is very sensitive to fill density
(see Figure 2.1). If the maximum fill density is exceeded; the pressure will increase
rapidly with temperature increase so as to present a hazard to personnel and property.
Adherence to the limits on fill density and pressurization levels will prevent excessively
high pressures from occurring if the storage cylinder is exposed to elevated temperature.
This will also minimize the possibility of an inadvertent discharge of agent through the
cylinder pressure relief device, where provided. It is recommended to not mount the
cylinder in direct sunlight as this would create elevated cylinder temperatures.

FM REV 3 Page 7 Rev 01 4/10/08

 Pressure VS. Temperature
For Carbon Dioxide Cylinders

160

140 o
130 F

120
Temperature

100

80

Service Pressure
60

Test Pressure
40
68% Fill Density
20

0
0 300 600 900 1200 1500 1800 2100 2400 2700 3000 3300

Pressure (PSIA)
Figure 2.1: Pressure vs. Temperature of CO2

FM REV 3 Page 8 Rev 01 4/10/08

3.0 SYSTEM DESCRIPTION

3.1 General

The Firetrace CO2 Automatic High Pressure units are FM Approved in 3 sizes, namely:

IHP-500 Charged with 5.0 Lbs. of CO2

IHP-1000 Charged with 10.0 Lbs. of CO2
IHP-2000 Charged with 20.0 Lbs. of CO2

These units are designed for use in Total Flooding applications where the hazard is not
occupiable by a human being. A lock-out valve shall be provided on all systems except
where dimensional constraints prevent personnel from entering the protected space.

The Firetrace CO2 units can be used, but are not limited, to protect the following:

• Electrical and electronic cabinets.

• Telecommunication areas.
• Data Processing areas and cabinets.
• Other high value assets.
• Laboratory fume /exhaust cabinets
• Pump enclosures
• UPS units
• Flammable Chemicals storage cabinets
• Generator Enclosures
• Transformer Cabinets
• Computer/Data Storage Cabinets
• CNC & VMC Machining centers
• Many other applications

CO2 is a gaseous fire-extinguishing agent that is effective for use on:

• Class A –
⇒ Surface type fires
⇒ Deep seated fires
• Class B – Flammable liquid fires
• Class C – Electrical equipment fires

CO2 should not be used where the following materials may be present.
• Pyrotechnic chemicals containing their own oxygen supply.
• Reactive metals such as lithium, sodium, potassium, magnesium, titanium,
zirconium, uranium and plutonium.
• Metal hydrides.
• Chemicals capable of undergoing auto thermal decomposition, such as
certain organic peroxides and hydrazine.

For hazards beyond the scope described above, it is recommended that the designer
consult with Firetrace, NFPA-12, and the local authority having jurisdiction, as to the
suitability on the use of CO2 for a particular hazard, for personnel exposure effects from
the design concentration, and for installation requirements.

FM REV 3 Page 9 Rev 01 4/10/08

Firetrace CO2 Automatic High Pressure Extinguisher Units consist of the following major
components:

• CO2 Cylinder/Valve assembly.

• Cylinder Mounting Bracket.
• Firetrace detector/actuation tubing and fittings (no substitute).
• Discharge nozzles.
• Discharge Port Adapter
• Pressure switch
• Discharge tubing and fittings (furnished by others).

Once installed, the Firetrace Automatic High Pressure Unit becomes a self-contained,
self-actuating unit that does not require an external source of power or electricity.

The unit utilizes unique Firetrace flexible tubing that is attached to the cylinder valve.
This tubing is pressurized with dry nitrogen to maintain the cylinder valve in the closed
position. The tubing is temperature sensitive, and acts as a continuous linear thermal
detector that ruptures upon direct flame impingement. Once the detector tubing is
ruptured, the cylinder valve automatically opens, allowing the CO2 agent to flow through
the discharge tubing, distributing the extinguishing agent through the nozzle(s) onto the
protected area. Upon actuation, the pressure switch can be used to indicate discharge,
shutdown ventilation, close all openings, shut-off electrical power, etc. as may be
required.

3.1.1 Operating Pressure

The CO2 cylinder is stored as a liquefied gas under its own pressure; 838psig @ 70oF.

3.1.2 Operating Temperature Range Limitations:

The ambient operating temperature range for all unit components is:
0oF to +130oF (-17.8oC to +54.4oC).

3.2 Component Descriptions

3.2.1 CO2 Cylinder Valve Assemblies

CO2 is stored in DOT/TC aluminum cylinders as a liquefied compressed gas, under its
own pressure; 838psig @ 70oF (5,778 KPa @ 21oC). The cylinder/valve assemblies are
FM Approved in 3 sizes, namely:

5 LB size filled with 5.0 LBS (2.27 Kg) of CO2

10 LB size; filled with 10.0 LBS (4.54 Kg) of CO2
20 LB size; filled with 20.0 LBS (9.07 Kg) of CO2

Each cylinder is equipped with a brass valve and a quarter turn ball valve that interfaces
with the Firetrace detector tubing. The ball valve must be kept closed at all times when
the cylinder is not in service.

In addition, the CO2 Cylinder valves are equipped with a pressure relief (rupture disc)
device in compliance with DOT/TC requirements.

FM REV 3 Page 10 Rev 01 4/10/08

Each valve is also equipped with (1) discharge outlet port and (1) filling port. Each port
is provided with a safety cap that must be installed whenever a cylinder is not in service.
These caps are safety devices designed to prevent uncontrolled discharge of the
cylinder in the event that the valve is accidentally actuated.

WARNING
The safety caps must be installed on the valve discharge port and filling port
at all times, except when connected into the units discharge tubing or when
filling. Failure to follow these instructions could result in personal injury,
death or property damage.

Table 3.1 describes the 5, 10 and 20 LB cylinder assemblies. Each cylinder is equipped
with a straight siphon tube and can only be mounted in a vertical (upright) position.

Table 3.1: CO2 Cylinder / Valve Assemblies

Nom Assy Outside Overall Internal CO2 Fill

Size Part Dia. Height Volume Agent Density
No. in. cm in. Cm in3 cm3 lb. kg %
5 110050 5.25 12.70 20.0 50.67 205 3359 5.0 2.27 68
10 110100 6.89 17.50 22.4 55.32 408 6717 10.0 4.54 68
20 110200 8.00 20.32 29.0 72.14 816 13340 20.0 9.07 68

Table 3.2 describes the DOT/TC Specifications used for the manufacture of the CO2
cylinders.

Table 3.2: DOT/TC Cylinder Specifications

Cylinder
Nominal DOT TC Service Test Pressure
Size Spec Spec Pressure DOT TC
psig psig psig
5 3AL1800 3ALM124 1800 3000 2700
10 3AL1800 3ALM124 1800 3000 2700
20 3AL1800 3ALM124 1800 3000 2700

The Firetrace CO2 Units are designed for an operating temperature range of 0oF to
+130oF. Table 3.3 shows the cylinder, pressure-temperature relationship based on a
maximum fill density of 68%; and a charged pressure of 838 psig at 70oF

Table 3.3: Cylinder Pressure-Temperature Relationship

FM REV 3 Page 11 Rev 01 4/10/08

 Cylinder Pressure
Temperature Pressure
o o
F C psig kPa
32 0.00 505 3,481
40 4.44 567 3,909
50 10.00 652 4,495
60 15.56 747 5,150
70 21.11 852 5,874
80 26.67 975 6,722
90 32.22 1205 8,308
100 37.78 1465 10,100
110 43.33 1725 11,893
120 48.89 1995 13,755
130 54.44 2265 15,616
140 60.00 2545 17,547
150 65.56 2825 19,477

3.2.2 Cylinder Mounting Bracket

A wall mounted painted steel bracket is used to mount the 5, 10, and 20lb cylinder/valve
assemblies in a vertical (upright) position. Each bracket is equipped with an interlocking
steel strap that is secured with a metallic pin.

3.2.3 Firetrace Flexible Detector/Actuation Tubing

The Firetrace tubing is used as a combination linear heat detector and unit activation
device to cause actuation of the CO2 agent cylinder. The tubing is installed throughout
the hazard volume, with one end connected to the CO2 cylinder valve. The tubing is
pressurized with nitrogen to 195 psig while maintaining the ball valve in the “OFF”
position. An optional pressure gauge or pressure switch can be connected to the other
end of the detector tube to monitor tubing pressure and/or signal unit actuation etc. The
detector tubing is heat sensitive and in a fire situation is designed to rupture at any point
along the tube. The rupture of the tube releases the nitrogen pressure causing the CO2
cylinder valve to actuate, resulting in complete discharge of the CO2 agent through the
nozzles.

3.2.4 Discharge Nozzle

Discharge nozzles are used to distribute CO2 agent uniformly throughout the hazard
area. One size nozzle is available for use with all IHP models, and must be used within
the limitations described in this Manual

3.2.5 Pressure Switch

A pressure switch is available as an optional item. This switch can be connected at the
end of the line of the Firetrace detector tubing to monitor unit pressure, unit actuation
and or to energize or de-energize electrically operated equipment. Firetrace
recommends that all units use a pressure switch coupled with some device to alert
personnel in the event of discharge.

FM REV 3 Page 12 Rev 01 4/10/08

3.2.6 Recharge Adapters, CO2 Cylinder
The recharge adapter is connected to the filling port located on the cylinder valve during
the cylinder recharging procedure. The adapter is used for refilling the cylinder with CO2.

3.2.7 Cylinder N2 Recharge Adapter

The recharge adapter is connected to the Firetrace tubing, and the other end of the
tubing is attached to the ball valve, located on the cylinder valve, during the charging
procedure. The adapter is used to apply nitrogen pressure to the detection tubing, and
to keep the valve piston seated.

3.2.8 CO2 Warning Nameplate

The Warning Plate is required to warn personnel not to enter the hazard area during or
after discharge. Warning signs shall be provided in a conspicuous location, at the
entrance to the protected areas, or in the case of cabinet protection on the front face of
the cabinet. Signs must be in accordance with NFPA 12, Section 4.3.

FM REV 3 Page 13 Rev 01 4/10/08

4.0 SYSTEM DESIGN AND LIMITATIONS FOR TOTAL FLOODING

4.1 General
The Firetrace series of CO2 Pre-Engineered Automatic High Pressure Extinguisher
units were tested and limits established by Firetrace and Factory Mutual. These units
were subjected to numerous performance tests, in order to verify their suitability and to
establish design limitations for:

• Hazard volume
• Nozzle placement
• Discharge time and flow rates
• Design concentrations & design factors
• Detector tubing placement

The pre-engineered automatic unit concept minimizes the amount of engineering

required when evaluating a design for a specific application. So long as the discharge
piping, tubing, and nozzles are installed within the limits prescribed in this manual, no
calculations are required for pressure drop, flow rates or discharge time. When the
additional limitations of hazard volume, design concentration, agent quantity, detector
arrangement, etc., are also met, the unit installation can be understood to comply with
the design requirements, NFPA-12, and FM Approval.

4.2 Design Procedure

The following procedures should be used to design a Firetrace CO2 pre-engineered

IHP automatic extinguisher unit. In addition, the applicable requirements specified in
NFPA-12 should be followed.

a. Conduct a survey and analysis of the hazard to be protected

b. Determine the height, length, and width of the enclosure. Calculate the
volume. All of these parameters must be within the dimensional limits specified
in this manual. (See Section 4.3, Table 4.1).
c. Determine the anticipated minimum and maximum ambient temperatures
expected within the enclosure to be protected.
d. Determine the minimum design concentration required for the hazard. (See
Section 4.5 and Table 4.3).
e. Determine the integrity of the enclosure. Are there any openings that must be
closed at the time of agent discharge? (See Section 4.6).
f. Calculate the quantity of CO2 agent required, with the proper design
concentration, to protect the enclosed space. (Refer to Section 4.7 and Example
4.8.1).
g. Determine the cylinder size required, based on the hazard volume limitations,
enclosure size, and quantity of CO2 agent required.
h. Determine the location of the CO2 cylinder.
i. Determine the location and quantity of nozzles required, based on the size and
configuration of the enclosure. (See Section 4.9 and Table 4.6).
j. Determine the routing and quantity of discharge pipe (tubing) required. The
discharge pipe (tubing) and fitting limitations must not be exceeded. (See
Section 4.9 and Table 4.6).

FM REV 3 Page 14 Rev 01 4/10/08

 k. Determine the arrangement and placement of the Firetrace detector tubing.
(See Section 4.10).
l. Determine any auxiliary equipment requirements, such as pressure switch(s) to
sound alarms, shut-down ventilation, shut-off electrical power, etc..
m. Prepare system drawings, bill of materials list, etc; following Section 4.4 of
NFPA-12 2005 Edition.

4.3 Hazard Enclosure Volume Limitations

The maximum volume for each size unit is shown in Table 4.1. The protected
enclosure can be any size or shape provided that the volume does not exceed the
limitations shown in Table 4.1 with the exception of the IHP-2000 as noted below.

Table 4.1: Enclosure Size Limitations

CO2 Volume
Model (Lbs) 3
(Ft )
IHP-0500 5.0 70
IHP-1000 10.0 140
IHP-2000 20.0 300*
* At least one dimension (l, w, h) must not exceed 2 feet
Volumes are based on 34% Design Concentration

4.4 General Specifications

4.4.1 Discharge Time:

Surface fires: The design concentration must be achieved within 1 minute from start
of discharge.

4.4.2 Storage and Operating Temperature Range:

The Firetrace CO2 units and equipment are designed to be stored and operated at an
ambient temperature range of 0oF to +130oF. (-17.8oC to +54.4oC).

4.4.3 System Operating Pressure:

The normal operating pressure for the unit is 838 psig at 70oF.

4.5 Minimum Design Concentrations

The minimum design concentrations to be used with Firetrace CO2 units shall not be
less than 34%. For class B hazards, proper consideration must be given to the
material involved in the hazard, the design concentration should then be given a safety
factor (SF) of 20%, as specified in NFPA-12, Year 2005 edition.

FM REV 3 Page 15 Rev 01 4/10/08

 Table 4.2: Minimum Safety Factor

Minimum
Hazard Type
Safety Factor
Class B Flammable Liquids 20%

Table 4.3 lists CO2 minimum design concentrations that must be used with Firetrace
CO2 units for Class A hazards and the various Class B fuels shown.

Consult Firetrace website, or contact Firetrace if the hazard you desire to protect is not
listed.

Table 4.3: Minimum Carbon Dioxide Concentrations for Extinguishment

Theoretical Minimum
Minimum CO2 Design CO2
Material Concentration Concentration
% %
(a)
Class A (surface fires)
Including plastic materials typically 34 34
found in electrical/electronic equip.
(b)
Class B fuels
Acetylene 55 66
Acetone 27 34
Aviation Gas Grades 115/145 30 36
Benzol, Benzene 31 37
Butadiene 34 41
Butane 28 34
Butane-I 31 37
Carbon Disulfide 60 72
Carbon Monoxide 53 64
Coal or Natural Gas 31 37
Cyclopropane 31 37
Diethyl Ether 33 40
Dimethyl Ether 33 40
Dowtherm 38 46
Ethane 33 40
Ethyl Alcohol 36 43
Ethyl Ether 38 46
Ethylene 41 49
Ethylene Dichloride 21 34
Ethylene Oxide 44 53
Gasoline 28 34
Hexane 29 35
Higher Paraffin Hydrocarbons
28 34
CnH2m + 2m - 5
Hydrogen 62 75

FM REV 3 Page 16 Rev 01 4/10/08

 Hydrogen Sulfide 30 36
Isobutane 30 36
Isobutylene 26 34
Isobutyl Formate 26 34
JP-4 30 36
Kerosene 28 34
Methane 25 34
Methyl Acetate 29 35
Methyl Alcohol 33 40
Methyl Butene - I 30 36
Methyl Ethyl Ketone 33 40
Methyl Formate 32 39
Pentane 29 35
Propane 30 36
Propylene 30 36
Quench, Lube Oils 28 34
Note: The theoretical minimum extinguishing concentrations in air for the materials in the table were obtained
from a compilation of Bureau of Mines, Limits of Flammability of Gases and Vapors (Bulletins 503 and 627)

For all materials not given in Table 4.3, the minimum theoretical carbon dioxide
concentration shall be obtained from some recognized source or determined by test.

4.6 Openings and Ventilation Shutdown

Provisions must be made to provide means to close all openings in the hazard
enclosure and shut-off ventilation at the time of discharge.

4.7 CO2 Design Concentration Flooding Factors

The total flooding quantity of CO2 agent needed to protect an enclosure containing a
material requiring a 34% design concentration can be found in Table 4.4.

To find the total quantity of CO2 required, multiply the hazard volume by the Volume
Factor found in Table 4.4

If the design concentration is greater than 34%, the basic quantity calculated from Table
4.4 shall be multiplied by the corresponding conversion factor found in Figure 4.1.

CAUTION
This table should only be used for materials requiring a 34% CO2
Design Concentration. And for environments where the temperature
range is between 0-130 o F

FM REV 3 Page 17 Rev 01 4/10/08

 Table 4.4: Flooding Factors for 34% Concentration.

(C)
(A) (B)
Calculated
Volume of Space Volume Factor
Quantity (LB)
(Ft3) Ft3/lb CO2 lb CO2/Ft3 (Not Less Than)
Up to 140 14 0.072 ---
141-500 15 0.067 10
501-1600 16 0.063 35
1601-4500 18 0.056 100
4501-50,000 20 0.050 250
Over 50,000 22 0.046 2500

4
Conversion Factor

1
30 40 50 60 70 80
M in im u m D e s ig n C O 2 C o n c e n tra tio n (% )

Figure 4.1: Conversion Factor for Design Concentrations Greater than 34%.

4.8 Maximum Protected Volume

The maximum volume that can be protected by the Firetrace CO2 units is dependent
on the minimum design concentration. The maximum volumes calculated from Table
4.4 for concentrations of 34% for Firetrace CO2 systems are listed below.

Table 4.5: Maximum Protected Volume for IHP Systems

Model Volume (ft3)

IHP 0500 Up to 70
IHP 1000 71 to 140
IHP 2000 141-300

FM REV 3 Page 18 Rev 01 4/10/08

4.8.1 Example Calculations

The requirements given in Sections 4.1 through 4.8 describe the procedures to be used
to design and size a Firetrace IHP CO2 unit.

The following example provides guidelines, following procedures 4.2.a, through 4.2.e., in
order to determine the quantity of CO2 agent required and cylinder size for a total
flooding application.

Example:
Given:
• Hazard – Small cabinet storing Ethyl Alcohol.
• Class B hazard
• Enclosure size: 4’ wide x 4’ long x 6’ high. One (1) access door equipped
with self closing apparatus
• Minimum anticipated ambient temperature: 50oF
• Maximum anticipated ambient temperature: 90oF

Procedure:
a. Determine min. design concentration required (Refer to Table 4.2)
Use 43% min. design concentration for Ethyl Alcohol.

b. Calculate hazard volume (V).

V = 4’ x 4’ x 6’ =96 Ft3

c. Calculate quantity (Q) of CO2 required first using volume factor for 34%
concentration (Refer to Table 4.4)
volume of 96 Ft3 shows that a Volume Factor 0.072 Lb CO2/Ft3

Q = 96 Ft3 x 0.072 Lb CO2/Ft3 = 6.912 Lbs. of CO2 is required. Because this is

based on a 34% concentration, it must be multiplied by the conversion factor,
which can be found in Figure 4.1. For a design concentration of 43%, the
conversion factor is 1.25.
Qtotal = 6.912 x 1.25= 8.64 Lbs (This then requires the use of a IHP-1000 with
10 Lbs of CO2)

4.9 Nozzle and Discharge Tubing Requirements

4.9.1 Discharge Nozzle Limitations

One size nozzle P/N 510010 is to be used with all Firetrace IHP CO2 extinguisher units
in total flooding applications.

Placement of nozzles shall be such that discharge of CO2 will not splash flammable
liquids or create dust clouds that could extend the fire.

More than one nozzle can be used to protect a particular hazard, as long as the
“Equivalent Length of Pipe” for Firetrace IHP CO2 systems is not exceeded. Refer to
section 4.9.3 for information regarding the “Equivalent Length of Pipe”.

FM REV 3 Page 19 Rev 01 4/10/08

4.9.2 Discharge Piping & Fitting Specifications

All Firetrace IHP Units shall use steel piping for the distribution system. The following
piping and fittings shall be used.

Piping Specifications:
Material: Black or Galvanized steel pipe
Type: ASTM A 53 seamless or electric welded, Grade A or B
Size: ½ Pipe
Note: For other options consult NFPA 12 2005 Edition Section 4.7

Pipe Fitting Specifications:

Material: Malleable or ductile iron fittings
Type: Class 300

4.9.3 Maximum Piping and Fitting Limitations

The maximum “Equivalent Length of Piping” shall not exceed 24ft. The “Equivalent
Length of Piping” includes individual lengths of pipe and all pipe fittings. Table 4.6
includes the equivalent lengths of ½ inch threaded pipe fittings that need to be
considered when determining the total “Equivalent Length of Piping”.

Table 4.6: Equivalent length in feet of threaded pipe fittings.

Elbow 90 o
Elbow Elbow Long Union
Pipe Tee Side
Std. Std. Radius Coupling
Size
45o 90 o & Tee
Thru Flow
1/2 0.8 1.7 1.0 3.4 0.4

4.10 Firetrace Detector Tubing

For the Indirect CO2 units, the Firetrace tube is used as a combination heat detector and
unit activation device to cause actuation of the CO2 agent cylinder.

The detector tubing is heat sensitive and in a fire situation is designed to rupture at any
point along the tube upon direct flame impingement.

Location and spacing of the tubing is critical to the response time in the event of a fire.
The tubing should be placed above the hazard areas being protected. The drawing in
Appendix A provides general guidelines for placement of the detector tubing along with
the maximum spacing and height limitations. Depending on the configuration of specific
hazards, the guidelines may, or may not, be applicable. The maximum length of tubing
that can be used for any IHP unit is 120 feet. The maximum height that is allowed
between layers is 3.28 feet. The maximum distance between passes is 21.12 inches.

FM REV 3 Page 20 Rev 01 4/10/08

NOTE: It is recommended that the tubing not be placed horizontally adjacent to
potential fire sources as this may significantly delay response time.

FM REV 3 Page 21 Rev 01 4/10/08

5.0 INSTALLATION INSTRUCTIONS

This section provides installation instructions covering components and limitations

described in Sections 3 and 4 of this manual.

All components should be installed to facilitate proper inspection, testing, recharging,

and any other required service or maintenance as may be necessary. Equipment must
not be subjected to severe weather conditions or mechanical, chemical, or other
damage, which could render the equipment inoperative. The equipment must be
installed in accordance with instructions in this manual and NFPA 12.

WARNING
CO2 cylinder/valve assemblies must be handled, installed, and serviced in
accordance with the instruction contained in this manual and on the cylinder
nameplate. Failure to follow these instructions could result in severe injury,
property damage or death.

5.1 CO2 Cylinder/Valve and Bracket Assemblies

The CO2 cylinders should be located as close as possible to the protected enclosure. In
some cases the cylinder can be mounted inside the protected enclosure. The
assemblies shall be located in a readily accessible location to allow for ease of
inspection service and maintenance. The cylinders shall be located in an environment
protected from the weather and where the temperature range is between 0oF and +
130oF.

Cylinder and bracket must be mounted in the vertical plane with the cylinder valve facing
up.

Mount the cylinder where it will not be subject to accidental damage or movement.
Suitable protection must be installed where necessary to prevent damage or movement.

CAUTION
Make sure that the ball valve, located on the cylinder valve, is maintained in
the “OFF” position, and the discharge port safety caps are in place. Failure to
follow these instructions will result in actuation and discharge of the cylinder
contents.

1. Securely mount the cylinder bracket to structural support using 2 or more

mounting holes.

2. Secure cylinder in place using the bracket strap.

5.2 Discharge Piping and Nozzles

1. Locate the nozzle(s) following the guidelines and limitations described in Section
4.9.

FM REV 3 Page 22 Rev 01 4/10/08

 2. Determine the routing of the discharge piping following the guidelines and
limitations described in Section 4.9

3. Remove the safety cap from the valve discharge port as required. Attach female
connection fittings (Firetrace P/N 200201) onto discharge port.

4. Install the necessary piping and fittings between the cylinder and nozzle(s).
Secure piping with appropriate size piping clamps as required.

5.3 Firetrace Detection Tubing

CAUTION
1. Do not kink, bend, or crush Firetrace tubing in order to prevent leakage,
which could result in accidental unit discharge.
2. Do not install tubing in a hazardous environment where the maximum
ambient temperature exceeds 176oF (80oC)
3. Do not place the tubing on a surface where the temperature of the
surface exceeds 140oF (60oC)
4. Maximum length of detector tubing shall not exceed 120 Feet.

1. Follow guidelines as outlined in section 4.10 and the drawing in Appendix A for
the tubing placement.

2. Secure detection tubing using Mounting Tabs at 1.5 ft. intervals.

3. Use appropriate rubber/plastic grommets when detection tubing is routed through

sharp holes in order to prevent damage to the tubing.

4. Connect the end of line adapter and spring top unit to the detection tubing as
shown in Appendix A.

5. When installing tubing to the cylinder valve make sure that the detection tubing is
pushed through the top of the ball valve inlet all the way through to the shoulder
and then tighten the spring top unit to a torque of 4-6 Nm.

6. Ensure the detection tubing is pushed through the end of line adapter all the way
through to the shoulder. Then tighten the spring top unit to the end of line
adapter to a torque of 4-6 Nm.

7. The detector tubing is now ready to be pressurized with nitrogen. (See section
5.4 for pressurization procedure)

5.4 Pressurization of Firetrace Detection Tubing

1. Attach the filling adapter (P/N 600023) to the detector-tubing end of line adapter.

2. Using a regulated dry nitrogen supply, pressurize the detection tubing with dry
nitrogen through the filling adapter to 195 psig. It is recommended to have a
portable dry nitrogen cylinder for on site use.

FM REV 3 Page 23 Rev 01 4/10/08

 3. Remove the filling adapter and attach calibrated test pressure gauge & 0-ring to
verify that the tubing is pressurized to at least 195 psig at 70oF.

4. With gauge still attached to the end of line adapter, test for leakage.
• Apply soapy water solution to the cylinder valve connection, end of line
adapter connection, and the pressure gauge connection. Observe for bubble
leaks.
• Wait 30 minutes, then observe pressure gauge. Any decrease in pressure is
an indication of a leak.
• In the event of a leak go back to Section 5.3 and repeat steps 4, 5, & 6.
• If no leaks are observed proceed to step 5 of Section 5.4

5. If an optional pressure switch is to be installed in the EOL adapter, remove

pressure gauge and install the washer and pressure switch using wiring
instructions located on the device. Check pressure switch connection for bubble
leaks using soapy water solution.

6. After confirming that there is no leakage within the detector tubing, SLOWLY
rotate the ball valve lever counter clockwise to the “ON” position.

CAUTION
If the ball valve lever is opened abruptly this may result in activation of the
cylinder valve and unit discharge.

7. Tamper proof the unit by choosing one of the options below

a. Option #1 Remove the ball valve lever completely. Follow directions for
removal of lever listed in Appendix A.
b. Option #2 Attach tamper seal around the ball valve lever to secure it in
the “ON” position, which is the set/ready position also shown in Appendix
A.

8. Ensure appropriate electrical connections to the optional EOL pressure switch,

which can be used to annunciate unit discharge, shut down ventilation, etc., as
may be required by the end user or the AHJ. (All electrical connections are to be
in accordance to NFPA 70 National Electric Code)

9. Attach the warning nameplate(s) (Firetrace P/N 800031) to the appropriate

locations.

10. Unit is now fully armed and ready for use.

FM REV 3 Page 24 Rev 01 4/10/08

6.0 SERVICE, MAINTENANCE, & FILLING INSTRUCTIONS

WARNING
1. CO2 cylinder/valve assemblies must be handled, installed, inspected
and serviced only by qualified and trained personnel in accordance
with the instructions contained in this manual, the cylinder nameplate,
NFPA-12, and any other regulations and codes that may apply.
2. Before performing maintenance or refilling procedures refer to the
material safety data sheets in the appendix at the back of this manual.

6.1 General

A regular program of systematic maintenance must be established for continuous,

proper operation of all CO2 units, and to avoid violating the warranty. A periodic
maintenance schedule must be followed and an inspection log maintained for ready
reference. As a minimum, the log must record: (1) inspection interval, (2) inspection
procedure performed, (3) maintenance performed, if any, as a result of inspection, and
(4) name of inspector performing task.

6.2 Periodic Service and Maintenance

Perform service and maintenance of the CO2 unit in accordance with the schedule
shown in Table 6.2

Table 6.2: Periodic service and maintenance schedule.

Reference
Schedule Requirement Paragraph

Weekly Visually inspect unit components 6.3.1

Monthly Visually inspect unit components. 6.3.1

Semi-Anually Check CO2 cylinder weight. 6.3.2

Check nozzles for obstruction.

Every 5 Years Perform external visual inspection of CO2 6.3.3

Cylinders.

6.3 Periodic Service and Maintenance Procedures

FM REV 3 Page 25 Rev 01 4/10/08

6.3.1 Weekly/Monthly: Performed by Owner or End User

1. Make a general visual inspection of the CO2 cylinder and equipment for
damaged or missing parts.
2. Ensure access to hazard areas, discharge nozzles, and cylinders are
unobstructed and that there are not obstructions to the operation of the
equipment or distribution of CO2 agent.
3. Inspect detection tubing in hazard area for abrasion, distortion, cuts, or
dirt accumulation, and that there are no obstructions preventing tubing
from sensing a fire should one occur.
4. Verify that there have been no changes in the size of the enclosure and
that no new ventilation has been added.

6.3.2 Semi-Annual Inspection

1. Check CO2 cylinder for weight.

2. Remove cylinder from the installation as follows:
• Close ball valve, by turning ball valve lever clockwise to the
“OFF” position.
• Disconnect detector tubing at the ball valve. Note: There will
be a loss of nitrogen pressure out of the tubing.
• Disconnect piping and fittings from the cylinder valve discharge
port.
• Immediately install safety cap onto the valve discharge port.
• Remove cylinder from bracket
3. Weigh cylinder. Compare measured weight with weight found on the
cylinder nameplate. If the container shows a loss in agent quantity of
more than 10 percent, the cylinder shall be refilled or replaced.
4. Remove nozzle(s) and inspect for obstructions. Reinstall nozzles.
5. Reinstall cylinder and re-pressurize detector tubing with nitrogen following
the applicable procedures outlined in Section 5.0.

6.3.3 Five Year Inspection

CO2 cylinders continuously in service without discharging shall be given a

complete external visual inspection in place, every 5 years or more
frequently if required.

6.4 Post Fire Maintenance

In the event of a unit discharge the following procedures shall be performed.

6.4.1 CO2 Cylinder Valve

FM REV 3 Page 26 Rev 01 4/10/08

 Remove the cylinder assembly from the installation following procedures detailed
in Section 6.3.2, Step 2. Inspect and service the CO2 cylinder valve as
follows:

WARNING
Prior to removal of the valve from the cylinder, verify that all
pressure has been released. To relieve any remaining pressure
loosen but do not remove the valve safety caps. Then open the
ball valve to the “ON” position and allow any residual pressure to
leak out past the plugs.

1 Only after verifying that the cylinder has been depressurized, remove
valve from cylinder.
2 Perform a visual inspection of the valve to verify that no damage occurred
due to the fire. If integrity of the valve looks compromised, contact
Firetrace. The valve should not be serviced by anyone other than a
Firetrace Technician.
3 Change the cylinder/valve o-ring. Discharge of CO2 causes the o-ring to
undergo vacuum decompression; failure to change the o-ring will result in
leaks around the cylinder/valve connection.
3. Re-seat the piston in the valve by following the procedure in Section 6.6,
Step 2.

6.5 CO2 Cylinder Retest

Firetrace CO2 cylinders are built to DOT-3AL specifications and therefore fall under DOT
regulations for retest prior to refill.

DOT-3AL cylinders used exclusively in CO2 service are required to be retested and re-
stamped prior to recharge and shipment if the last retest date has expired.

Firetrace CO2 (DOT-3AL) containers requiring retest must be hydrostatically tested in

accordance with DOT CFR Title 49, Section 173.34(e). This periodic retest must be
performed by an authorized retester having a current identification number issued by the
Associated Administrator for Hazardous Material Safety of DOT, and must include an
internal and external examination in accordance with CGA pamphlet C-6, C-6.1, C-6.2,
or C-6.3, as applicable. The test procedures are described in CGA pamphlet C-1.
Because volumetric expansion of the container must be measured, only the water jacket
volumetric expansion method or the direct expansion methods are acceptable.

As an alternate option, CO2 agent containers may be given a complete external visual
inspection, as detailed in Section 173.34(e)(13), in lieu of hydrostatic test. The visual
inspection shall only be made by competent persons. A person who performs the visual
examination specified in 173.34(e)(13) is not required to have a re-tester’s identification
number.

FM REV 3 Page 27 Rev 01 4/10/08

Retest can be performed by either of the following methods:

First Subsequent Special Marking

Retest Method Retest Retest Due (Yrs)
Due (Yrs)

Full hydrostatic test

Retest Date
including determination of 5 5
Month/Year
cylinder expansion.

External visual inspection

per paragraph Retest Date
173.34(e)(13) and CGA 5 5 followed by “E”
pamphlet C-6, Section 3.

6.6 Filling Procedures

1. Weigh and record cylinder empty weight with valve and the 2 safety caps
installed.
2. Remove the safety cap from the discharge port and visually check that the
piston is seated inside of the valve. Replace safety cap. (If piston is not seated,
apply 195 psi of Nitrogen pressure through the ball valve. You will be able to
hear the piston change positions. Return ball valve to “OFF” position and
remove hose connection).
3. Remove safety cap from filling port and attach Firetrace CO2 filling adapter (P/N
60024) to filling port
4. Attach CO2 supply line to filling adapter. (CO2 is to be pumped)
5. Place the cylinder, with supply line hooked up, on scale and zero the scale.
Open the supply of CO2 from bulk tank to fill the cylinder to the required weight.
6. Close supply of CO2 while maintaining all connections.
7. Disconnect CO2 recharge adapter and immediately attach discharge port cap to
valve.

CAUTION
Any hissing or discharge coming from vent valve indicates that
the piston is not seating properly or has opened. If this occurs,
repeat Step 10 and verify that the cylinder valve piston remains
closed.

8. Verify weight by checking it against what is printed on the label.

9. Leak test the cylinder.
10. Cylinder is now ready to be transported to the installation site.

Note: All reasonable efforts must be made to prevent emitting any CO2 to
the environment during filling or servicing of Firetrace units.

FM REV 3 Page 28 Rev 01 4/10/08

 APPENDIX A

COMPONENT DESCRIPTION DRAWINGS

INSTALLATION DRAWINGS

FM REV 3 Page 29 Rev 01 4/10/08

 Parts List
5, 10, & 20 LB.
PRE-ENGINEERED
AUTOMATIC INDIRECT
CO2 EXTINGUISHER UNIT
7
MODELS 950504 5 LB. CO2 IHP 1
951004 10 LB. CO2 IHP
952004 20 LB. CO2 IHP

5
ITE PART NO. DESCRIPTION SYSTEM
M
1 310201 IHP Valve All Systems
2 110050 5 Lb. Cylinder 5 LB
6
2 110100 10 Lb. Cylinder 10 LB 3
2 110200 20 Lb. Cylinder 20 LB
5 1
3 600008 Siphon Tube /8”x13 /4” 5 LB
5 1
3 600005 Siphon Tube /8”x15 /4” 10 LB
5 1 2
3 600006 Siphon Tube /8”x21 /2” 20 LB 4
4 111201 5 Lb. Heavy Duty Bracket 5 LB
4 111010 10 Lb. Heavy Duty Bracket 10 LB
4 111020 20 Lb. Heavy Duty Bracket 20 LB
5 310310 Discharge Port Safety Cap All Systems
8
6 310305 Collar O-Ring All Systems
7 200160 Spring Top Support Unit All Systems
8 600053 Pull Pin All Systems
9 600007 Nameplate: CO2 All Systems
* 600125 Label: IHP CO2 FM Approval All Systems
* 800100 Warranty/Registration Card All Systems
* 200201 Discharge Port Adapter All Systems
* PART NOT PICTURED
9

FM REV 3 Page 30 Rev 01 4/10/08

 Discharge Line Parts List
ITEM NUMBER PART NUMBER DESCRIPTION
* 200201 IHP Discharge Port Adapter
3 510010 Small Total Flood Nozzle
4 500024 Total Flooding Nozzle
1 510015 IHP Wide Dispersion Nozzle
2 510016 IHP Narrow Dispersion Nozzle
* 201802 2’ Hydraulic Discharge Hose With Elbows
* 201804 4’ Hydraulic Discharge Hose With Elbows
* 201806 6’ Hydraulic Discharge Hose With Elbows
* 201808 8’ Hydraulic Discharge Hose With Elbows
* PART NOT PICTURED

2
1

FM REV 3 Page 31 Rev 01 4/10/08

 Detection Line Parts List
ITEM NUMBER PART NUMBER DESCRIPTION
* 200005 Firetrace Detection/Actuation Tubing (by the foot)
* 200125 Tube Union With Spring Tops
1 200126 Tube Tee With Spring Tops
* 200136 Bulkhead With Spring Tops
4 200155 Tube Elbow With Spring Tops
* 200160 Spring Top
* 200158 Tube Union Slip On Fitting
2 200157 Tube Tee Slip On Fitting
5 200178 Tube Elbow Slip On Fitting
* 200179 Tube to Threads Union Slip On Fitting
* 200177 Tube to Threads Tee Slip On Fitting
* 200159 Tube to Threads Elbow Slip On Fitting
* 200133 Tube Plug
3 600064 Manual Release With CO2 Gauge and Spring Top
* 200168 End Of Line Adapter With Spring Top
* 200169 In Line Adapter With Spring Tops
* 310303 Plug With O-Ring For End Of Line Adapter
* 400029 CO2 195 psi Pressure Gauge
* 400004 Pressure Switch With Washer for End Of Line Adapter
* 600090 Audible Alarm (Battery Operated)
* 200171 Mounting Tabs (Qty. 12)
* 200150 Rubber Grommets (Qty. 2)
* 200151 Plastic Grommets (Qty. 2)
* PART NOT PICTURED

3
2
1

FM REV 3 Page 32 Rev 01 4/10/08

 Firetrace Indirect High Pressure (IHP) Valve
P/N 310201

FM REV 3 Page 33 Rev 01 4/10/08

 Firetrace IHP System Overview

NOZZLE
NOZZLE

SPRING TOP SUPPORT

UNIT

INDIRECT HIGH
PRESSURE VALVE

HIGH PRESSURE
DISCHARGE PORT
ADAPTER TUBING CLIPS

FILLING ADAPTER
(REMOVE AFTER PRESSURIZING LINE)

FIRETRACE DETECTION
END OF THE
TUBING
LINE ADAPTER

SPRING TOP SUPPORT

UNIT

OPTIONAL MANUAL RELEASE

*NOTE: Manual Release can be

used in place of an End of Line Adapter, BRACKET
or can be added at any point along tube by
adding a "T" fitting

End of Line Adapter may also incorporate

an optional Pressure Gauge or
a Pressure Switch

FM REV 3 Page 34 Rev 01 4/10/08

 Firetrace Tubing Placement Diagram

Side View Overhead View

FM REV 3 Page 35 Rev 01 4/10/08

 Ball Valve
Lever

Plastic Tie
4” Long
18 LB Tensile Strength

Option #1 Option #2
1. Check to see that the ball valve 1. Remove the ON/OFF faceplate.
lever is set to the “ON” position. 2. Unscrew the ball valve lever
2. Remove the ON/OFF faceplate. from the assembly.
3. Pull the tie through the hole in 3. Pull the lever off of the ball valve
the ball valve lever. assembly.
4. Wrap the tie around the ball 4. Keep the items in a bag and
valve assembly. secure them to the unit.
5. Firmly pull on the tie to tighten
and secure the lever.
6. If desired, cut off the excess tie.

FM REV 3 Page 36 Rev 01 4/10/08

 APPENDIX B

Material Safety Data Sheet

FM REV 3 Page 37 Rev 01 4/10/08

Product: Carbon Dioxide P-4574-J Date: July 2007

Praxair Material Safety Data Sheet

1. Chemical Product and Company Identification

Product Name: Carbon dioxide Trade Names: Carbon Dioxide, Medipure® Carbon Dioxide
(MSDS No. P-4574-J)
Chemical Name: Carbon dioxide Synonyms: Carbonic anhydride, carbonic acid gas, refrigerant
gas R744
Chemical Family: Acid anhydride Product Grades: Industrial; 3.0; 4.0 anaerobic, instrument,
laser; 4.5, 5.0, 5.5 LaserStar™; 4.8 research, supercritical fluid
chromatography, semiconductor process gas; 5.0 supercritical
fluid extraction
Telephone: Emergencies: 1-800-645-4633* Company Name: Praxair, Inc.
CHEMTREC: 1-800-424-9300* 39 Old Ridgebury Road
Routine: 1-800-PRAXAIR Danbury, CT 06810-5113
* Call emergency numbers 24 hours a day only for spills, leaks, fire, exposure, or accidents
involving this product. For routine information, contact your supplier, Praxair sales
representative, or call 1-800-PRAXAIR (1-800-772-9247).

2. Hazards Identification

EMERGENCY OVERVIEW
CAUTION! High-pressure liquid and gas.
Can cause rapid suffocation.
Can increase respiration and heart rate.
May cause nervous system damage.
May cause frostbite.
May cause dizziness and drowsiness.
Self-contained breathing apparatus may be required by rescue workers.
This product is a colorless, odorless gas at normal temperature and pressure.
The gas is slightly acidic and may be felt to have a slight, pungent odor and
biting taste.
OSHA REGULATORY STATUS: This material is considered hazardous by the OSHA Hazard
Communications Standard (29 CFR 1910.1200).
POTENTIAL HEALTH EFFECTS:
Effects of a Single (Acute) Overexposure
Inhalation. Carbon dioxide gas is an asphyxiant with effects due to lack of oxygen. It is
also physiologically active, affecting circulation and breathing. Moderate concentrations
may cause headache, drowsiness, dizziness, stinging of the nose and throat, excitation,

Copyright © 1980, 1985,1986, 1989, 1991-1993, 1997, 1999, 2004, 2007, Page 1 of 12
Praxair Technology, Inc.
All rights reserved.
A vertical line in the left margin indicates revised or new material.
Product: Carbon Dioxide P-4574-J Date: July 2007

rapid breathing and heart rate, excess salivation, vomiting, and unconsciousness. Lack
of oxygen can kill.
Skin Contact. No harm expected from vapor. Cold gas, or liquid or solid carbon dioxide
may cause severe frostbite.
Swallowing. An unlikely route of exposure. This product is a gas at normal temperature
and pressure.
Eye Contact. No harm expected from vapor. Cold gas, or liquid or solid carbon dioxide
may cause severe frostbite.
Effects of Repeated (Chronic) Overexposure. No harm expected.
Other Effects of Overexposure. Damage to retinal or ganglion cells and central nervous
system may occur.
Medical Conditions Aggravated by Overexposure. The toxicology and the physical and
chemical properties of carbon dioxide suggest that overexposure is unlikely to aggravate
existing medical conditions.
CARCINOGENICITY: Carbon dioxide is not listed by NTP, OSHA, or IARC.
POTENTIAL ENVIRONMENTAL EFFECTS: None known. For further information, see section
12, Ecological Information.

3. Composition/Information on Ingredients
This section covers materials of manufacture only. See sections 8, 10, 11, and 16 for
information on by-products generated during use in welding and cutting.
See section 16 for important information about mixtures.

COMPONENT CAS NUMBER CONCENTRATION

Carbon dioxide 124-38-9 >99%*
*The symbol > means “greater than.”

4. First Aid Measures

INHALATION: Immediately remove to fresh air. If not breathing, give artificial respiration. If
breathing is difficult, qualified personnel may give oxygen. Call a physician.
SKIN CONTACT: For exposure to cold vapor or solid, immediately warm frostbite area with
warm water not to exceed 105°F (41°C). In case of massive exposure, remove contaminated
clothing while showering with warm water. Call a physician.
SWALLOWING: An unlikely route of exposure. This product is a gas at normal temperature
and pressure.
EYE CONTACT: For exposure to cold vapor or solid, immediately flush eyes thoroughly with
warm water for at least 15 minutes. Hold the eyelids open and away from the eyeballs to
ensure that all surfaces are flushed thoroughly. See a physician, preferably an ophthalmologist,
immediately.
NOTES TO PHYSICIAN: There is no specific antidote. Treatment of overexposure should be
directed at the control of symptoms and the clinical condition of the patient.

Page 2 of 12
Product: Carbon Dioxide P-4574-J Date: July 2007

5. Fire Fighting Measures

FLAMMABLE PROPERTIES: Nonflammable
SUITABLE EXTINGUISHING MEDIA: Carbon dioxide cannot catch fire. Use media
appropriate for surrounding fire.
PRODUCTS OF COMBUSTION: Not applicable.
PROTECTION OF FIREFIGHTERS: CAUTION! High-pressure gas liquid and gas.
Evacuate all personnel from danger area. Immediately deluge cylinders with water from
maximum distance until cool; then move them away from fire area if without risk. Self-contained
breathing apparatus may be required by rescue workers. On-site fire brigades must comply
with OSHA 29 CFR 1910.156.
Specific Physical and Chemical Hazards. Heat of fire can build pressure in cylinder and
cause it to rupture. No part of cylinder should be subjected to a temperature higher than 125°F
(52°C). Carbon dioxide cylinders are equipped with a pressure relief device. (Exceptions may
exist where authorized by DOT.)
Protective Equipment and Precautions for Firefighters. Firefighters should wear personal
protective equipment and fire-fighting turnout gear as appropriate for surrounding fire.

6. Accidental Release Measures

STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED:
CAUTION! High-pressure liquid and gas.
Personal Precautions. Carbon dioxide is an asphyxiant. Lack of oxygen can kill. Evacuate all
personnel from danger area. Use self-contained breathing apparatus where needed. Shut off
leak if you can do so without risk. Ventilate area or move cylinder to a well-ventilated area.
Test for sufficient oxygen, especially in confined spaces, before allowing reentry.
Environmental Precautions. Prevent waste from contaminating the surrounding environment.
Keep personnel away. Discard any product, residue, disposable container, or liner in an
environmentally acceptable manner, in full compliance with federal, state, and local regulations.
If necessary, call your local supplier for assistance.

7. Handling and Storage

PRECAUTIONS TO BE TAKEN IN HANDLING: Avoid breathing gas. Do not get liquid in eyes,
on skin, or clothing. Protect cylinders from damage. Use a suitable hand truck to move
cylinders; do not drag, roll, slide, or drop. Never attempt to lift a cylinder by its cap; the cap is
intended solely to protect the valve. Never insert an object (e.g., wrench, screwdriver, pry
bar) into cap openings; doing so may damage the valve and cause a leak. Use an adjustable
strap wrench to remove over-tight or rusted caps. Open valve slowly. If valve is hard to open,
discontinue use and contact your supplier. Keep cylinder upright when in use. Never apply
flame or localized heat directly to any part of the cylinder. High temperatures may damage
the cylinder and could cause the pressure relief device to fail prematurely, venting the cylinder
contents. For other precautions in using carbon dioxide, see section 16.
PRECAUTIONS TO BE TAKEN IN STORAGE: Gas can cause rapid suffocation due to
oxygen deficiency. Store and use with adequate ventilation. Store only where temperature
will not exceed 125°F (52°C). Carbon dioxide is heavier than air. It tends to accumulate near

Page 3 of 12
Product: Carbon Dioxide P-4574-J Date: July 2007

the floor of an enclosed space, displacing air and pushing it upward. This creates an oxygen-
deficient atmosphere near the floor. Ventilate space before entry. Verify sufficient oxygen
concentration. Close cylinder valve after each use; keep closed even when empty. Prevent
reverse flow. Reverse flow into cylinder may cause rupture. Use a check valve or other
protective device in any line or piping from the cylinder. Do not strike an arc on the cylinder.
The defect produced by an arc burn could lead to cylinder rupture. Do not ground the cylinder
or allow it to become part of an electrical circuit. Firmly secure cylinders upright to keep
them from falling or being knocked over. Screw valve protection cap firmly in place by hand.
Store full and empty cylinders separately. Use a first-in, first-out inventory system to prevent
storing full cylinders for long periods.
RECOMMENDED PUBLICATIONS: For further information on storage, handling, and use, see
Praxair publications P-14-153, Guidelines for Handling Gas Cylinders and Containers; P-15-
073, Safety Precautions for Carbon Dioxide; and P-3499, Safety Precautions and Emergency
Response Planning. Obtain from your local supplier.

8. Exposure Controls/Personal Protection

See section 16 for important information on by-products generated during use
in welding and cutting.

COMPONENT OSHA PEL ACGIH TLV-TWA (2007)

Carbon dioxide 5,000 ppm 5,000 ppm, 30,000 ppm 15 min STEL
TLV-TWAs should be used as a guide in the control of health hazards and not as fine lines
between safe and dangerous concentrations.
IDLH = 40,000 ppm
ENGINEERING CONTROLS:
Local Exhaust. Use a local exhaust system, if necessary, to keep the concentration of carbon
dioxide below all applicable exposure limits in the worker’s breathing zone.
Mechanical (General). Under certain conditions, general exhaust ventilation may be
acceptable to keep carbon dioxide below the exposure limits.
Special. None
Other. None
PERSONAL PROTECTIVE EQUIPMENT:
Skin Protection. Wear insulated neoprene gloves for cylinder handling; welding gloves for
welding. Metatarsal shoes for cylinder handling. Select in accordance with OSHA 29 CFR
1910.132 and 1910.133. See section 16 for requirements when using carbon dioxide or carbon
dioxide mixtures in welding and cutting. Regardless of protective equipment, never touch live
electrical parts.
Eye/Face Protection. Select in accordance with OSHA 29 CFR 1910.133. See section 16 for
requirements when using carbon dioxide or carbon dioxide mixtures in welding and cutting.
Respiratory Protection. None required under normal use. An air-supplied respirator must be
used in confined spaces. Respiratory protection must conform to OSHA rules as specified in 29
CFR 1910.134. Select per OSHA 29 CFR 1910.134 and ANSI Z88.2.

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Product: Carbon Dioxide P-4574-J Date: July 2007

9. Physical and Chemical Properties

APPEARANCE: Colorless gas
ODOR: Odorless. It is felt by some to have a slight,
pungent odor and biting taste.
ODOR THRESHOLD: Not applicable.
PHYSICAL STATE: Gas at normal temperature and pressure
pH: 3.7 (for carbonic acid)
SUBLIMATION POINT at 1 atm: -109.3°F (-78.5°C)
BOILING POINT at 1 atm: Not applicable.
FLASH POINT (test method): Not applicable.
EVAPORATION RATE (Butyl Acetate = 1): High
FLAMMABILITY: Nonflammable
FLAMMABLE LIMITS IN AIR, % by volume: LOWER: Not UPPER: Not
applicable. applicable.
VAPOR PRESSURE at 68°F (20°C): 838 psig (5778 kPa)
LIQUID DENSITY (saturated) at 70°F (21.1°C) 47.6 lb/ft3 (762 kg/m3)
and 1 atm:
SPECIFIC GRAVITY (H2O = 1) at 19.4°F (-7°C): 1.22
SPECIFIC GRAVITY (Air = 1) at 70°F (21.1°C)
and 1 atm: 1.52
SOLUBILITY IN WATER vol/vol at 68°F (20°C): 0.90
PARTITION COEFFICIENT: n-octanol/water: Not available.
AUTOIGNITION TEMPERATURE: Not applicable.
DECOMPOSITION TEMPERATURE: Not available.
PERCENT VOLATILES BY VOLUME: 100
MOLECULAR WEIGHT: 44.01
MOLECULAR FORMULA: CO2

10. Stability and Reactivity

CHEMICAL STABILITY: Unstable Stable
CONDITIONS TO AVOID: Contact with incompatible materials, exposure to electrical
discharges, and/or high temperatures as stated below.
INCOMPATIBLE MATERIALS: Alkali metals, alkaline earth metals, metal acetylides,
chromium, titanium above 1022°F (550°C), uranium above 1382°F (750°C), magnesium above
1427°F (775°C)
HAZARDOUS DECOMPOSITION PRODUCTS: Electrical discharges and high temperatures
decompose carbon dioxide into carbon monoxide and oxygen.
POSSIBILITY OF HAZARDOUS REACTIONS: May Occur Will Not Occur
Decomposition into toxic, flammable, and/or oxidizing materials under above-stated conditions.

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Product: Carbon Dioxide P-4574-J Date: July 2007

11. Toxicological Information

ACUTE DOSE EFFECTS: LCLo = 90,000 ppm, 5 min., human
The welding process may generate hazardous fumes and gases. (See sections 10 and 16.)
Carbon dioxide is an asphyxiant. It initially stimulates respiration and then causes respiratory
depression. High concentrations result in narcosis. Symptoms in humans are as follows:

EFFECT: CONCENTRATION:

Breathing rate increases slightly. 1%

Breathing rate increases to 50% above normal level. Prolonged 2%

exposure can cause headache, tiredness.

Breathing increases to twice normal rate and becomes labored. Weak 3%

narcotic effect. Impaired hearing, headache, increased blood pressure
and pulse rate.

Breathing increases to approximately four times normal rate, symptoms 4 - 5%

of intoxication become evident, and slight choking may be felt.

Characteristic sharp odor noticeable. Very labored breathing, 5 - 10%

headache, visual impairment, and ringing in the ears. Judgment may
be impaired, followed within minutes by loss of consciousness.

Unconsciousness occurs more rapidly above 10% level. Prolonged 10 - 100%

exposure to high concentrations may eventually result in death from
asphyxiation.
REPRODUCTIVE EFFECTS: A single study has shown an increase in heart defects in rats
exposed to 6% carbon dioxide in air for 24 hours at different times during gestation. There is no
evidence that carbon dioxide is teratogenic in humans.

12. Ecological Information

ECOTOXICITY: No known effects.
OTHER ADVERSE EFFECTS: No adverse ecological effects expected. Carbon dioxide does
not contain any Class I or Class II ozone-depleting chemicals.

13. Disposal Considerations

WASTE DISPOSAL METHOD: Do not attempt to dispose of residual or unused quantities.
Return cylinder to supplier.

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Product: Carbon Dioxide P-4574-J Date: July 2007

14. Transport Information

DOT/IMO SHIPPING NAME: Carbon dioxide
HAZARD PACKING IDENTIFICATION PRODUCT
CLASS: 2.2 GROUP/Zone: NA* NUMBER: UN1013 RQ: None
SHIPPING LABEL(s): NONFLAMMABLE GAS
PLACARD (when required): NONFLAMMABLE GAS
*NA = Not applicable.
SPECIAL SHIPPING INFORMATION: Cylinders should be transported in a secure position, in a
well-ventilated vehicle. Cylinders transported in an enclosed, nonventilated compartment of a
vehicle can present serious safety hazards.
Shipment of compressed gas cylinders that have been filled without the owner’s consent is a
violation of federal law [49 CFR 173.301(b)].
MARINE POLLUTANTS: Carbon dioxide is not listed as a marine pollutant by DOT.

15. Regulatory Information

The following selected regulatory requirements may apply to this product. Not all such
requirements are identified. Users of this product are solely responsible for compliance with all
applicable federal, state, and local regulations.
U.S. FEDERAL REGULATIONS:
EPA (ENVIRONMENTAL PROTECTION AGENCY)
CERCLA: COMPREHENSIVE ENVIRONMENTAL RESPONSE, COMPENSATION,
AND LIABILITY ACT OF 1980 (40 CFR Parts 117 and 302):
Reportable Quantity (RQ): None
SARA: SUPERFUND AMENDMENT AND REAUTHORIZATION ACT:
SECTIONS 302/304: Require emergency planning based on Threshold Planning
Quantity (TPQ) and release reporting based on Reportable Quantities (RQ) of
Extremely Hazardous Substances (EHS) (40 CFR Part 355):
TPQ: None
EHS RQ (40 CFR 355): None
SECTIONS 311/312: Require submission of MSDSs and reporting of chemical
inventories with identification of EPA hazard categories. The hazard categories for
this product are as follows:
IMMEDIATE: Yes PRESSURE: Yes
DELAYED: No REACTIVITY: No
FIRE: No
SECTION 313: Requires submission of annual reports of release of toxic chemicals
that appear in 40 CFR Part 372.
Carbon dioxide is not subject to reporting under Section 313.
40 CFR 68: RISK MANAGEMENT PROGRAM FOR CHEMICAL ACCIDENTAL
RELEASE PREVENTION: Requires development and implementation of risk
management programs at facilities that manufacture, use, store, or otherwise handle
regulated substances in quantities that exceed specified thresholds.
Carbon dioxide is not listed as a regulated substance.

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Product: Carbon Dioxide P-4574-J Date: July 2007

TSCA: TOXIC SUBSTANCES CONTROL ACT: Carbon dioxide is listed on the TSCA
inventory.
OSHA: OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION:
29 CFR 1910.119: PROCESS SAFETY MANAGEMENT OF HIGHLY HAZARDOUS
CHEMICALS: Requires facilities to develop a process safety management program
based on Threshold Quantities (TQ) of highly hazardous chemicals.
Carbon dioxide is not listed in Appendix A as a highly hazardous chemical.
STATE REGULATIONS:
CALIFORNIA: Carbon dioxide is not listed by California under the SAFE DRINKING
WATER AND TOXIC ENFORCEMENT ACT OF 1986 (Proposition 65).
PENNSYLVANIA: Carbon dioxide is subject to the PENNSYLVANIA WORKER AND
COMMUNITY RIGHT-TO-KNOW ACT (35 P.S. Sections 7301-7320).

16. Other Information

Be sure to read and understand all labels and instructions supplied with all containers of this
product.
ADDITIONAL SAFETY AND HEALTH HAZARDS: Using carbon dioxide or mixtures containing
carbon dioxide in welding and cutting may create additional hazards.
Read and understand the manufacturer’s instructions and the precautionary labels on the
products used in welding and cutting. Ask your welding products supplier for a copy of Praxair’s
free safety booklets, P-2035, Precautions and Safe Practices for Gas Welding, Cutting, and
Heating, and P-52-529, Precautions and Safe Practices for Electric Welding and Cutting, and for
other manufacturers’ safety publications. For a detailed treatment, get ANSI Z49.1, Safety in
Welding, Cutting, and Allied Processes, published by the American Welding Society (AWS), or
see OSHA’s Web site at http://www.osha-slc.gov/SLTC/weldingcuttingbrazing/. Order AWS
documents from Global Engineering Documents, 15 Inverness Way East, Englewood, CO
80112-5710, http://global.ihs.com/.
FUMES AND GASES can be dangerous to your health and may cause serious lung
disease.
• Keep your head out of fumes. Do not breathe fumes and gases. Use enough
ventilation, local exhaust, or both to keep fumes and gases from your breathing
zone and the general area. Short-term overexposure to fumes may cause
dizziness; nausea; and dryness or irritation of the nose, throat, and eyes; or may
cause other similar discomfort.
Fumes and gases cannot be classified simply. The amount and type depend on the metal
being worked and the process, procedure, equipment, and supplies used. Possible
dangerous materials may be found in fluxes, electrodes, and other materials. Get an MSDS
for every material you use.
Contaminants in the air may add to the hazard of fumes and gases. One such contaminant,
chlorinated hydrocarbon vapors from cleaning and degreasing activities, poses a special
risk.
• Do not use electric arcs in the presence of chlorinated hydrocarbon vapors—
highly toxic phosgene may be produced.
Metal coatings such as paint, plating, or galvanizing may generate harmful fumes when
heated. Residues from cleaning materials may also be harmful.

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Product: Carbon Dioxide P-4574-J Date: July 2007

• Avoid arc operations on parts with phosphate residues (anti-rust, cleaning

preparations)—highly toxic phosphine may be produced.
To find the quantity and content of fumes and gases, you can take air samples. By
analyzing these samples, you can find out what respiratory protection you need. One
recommended sampling method is to take air from inside the worker’s helmet or from the
worker’s breathing zone. See AWS F1.1, Methods for Sampling and Analyzing Gases for
Welding and Allied Processes, available from the American Welding Society, 550 N.W. Le
Jeune Rd., Miami, FL 33126.
NOTES TO PHYSICIAN:
Acute: Gases, fumes, and dusts may cause irritation to the eyes, lungs, nose, and
throat. Some toxic gases associated with welding and related processes may cause
pulmonary edema, asphyxiation, and death. Acute overexposure may include signs and
symptoms such as watery eyes, nose and throat irritation, headache, dizziness, difficulty
breathing, frequent coughing, or chest pains.
Chronic: Protracted inhalation of air contaminants may lead to their accumulation in the
lungs, a condition that may be seen as dense areas on chest x-rays. The severity of
change is proportional to the length of exposure. The changes seen are not necessarily
associated with symptoms or signs of reduced lung function or disease. In addition, the
changes on x-rays may be caused by non-work-related factors such as smoking, etc.
PROTECTIVE CLOTHING AND EQUIPMENT FOR WELDING OPERATIONS:
PROTECTIVE GLOVES: Wear welding gloves.
EYE PROTECTION: Wear a helmet or use a face shield with a filter lens. Select lens
per ANSI Z49.1. Provide protective screens and flash goggles if needed to protect
others; select per OSHA 29 CFR 1910.133.
OTHER PROTECTIVE EQUIPMENT: Wear hand, head, and body protection. (See ANSI
Z49.1.) Worn as needed, these help prevent injury from radiation, sparks, and electrical shock.
Minimum protection includes welder’s gloves and a face shield. For added protection consider
arm protectors, aprons, hats, shoulder protection, and dark, substantial clothing.
OTHER HAZARDOUS CONDITIONS OF HANDLING, STORAGE, AND USE: High-pressure
liquid and gas. Use piping and equipment adequately designed to withstand pressures to be
encountered. Prevent reverse flow. Reverse flow into cylinder may cause rupture. Use a
check valve or other protective device in any line or piping from the cylinder. Do not strike an
arc on the cylinder. The defect produced by an arc burn could lead to cylinder rupture. Never
work on a pressurized system. If there is a leak, close the cylinder valve. Blow the system
down in a safe and environmentally sound manner in compliance with all federal, state, and
local laws; then repair the leak. Never place a compressed gas cylinder where it may
become part of an electrical circuit. When using compressed gases in and around electric
welding applications, never ground the cylinders. Grounding exposes the cylinders to damage
by the electric welding arc.
Mixtures. When you mix two or more gases or liquefied gases, you can create additional,
unexpected hazards. Obtain and evaluate the safety information for each component before
you produce the mixture. Consult an industrial hygienist or other trained person when you
evaluate the end product. Remember, gases and liquids have properties that can cause serious
injury or death.

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Product: Carbon Dioxide P-4574-J Date: July 2007

HAZARD RATING SYSTEMS:

NFPA RATINGS: HMIS RATINGS:
HEALTH =1 HEALTH =1
FLAMMABILITY =0 FLAMMABILITY =0
INSTABILITY =0 PHYSICAL HAZARD = 3
SPECIAL = SA (CGA recommends this to designate Simple Asphyxiant.)
STANDARD VALVE CONNECTIONS FOR U.S. AND CANADA:
THREADED: CGA-320
PIN-INDEXED YOKE: CGA-940 (medical use)
ULTRA-HIGH-INTEGRITY CONNECTION: CGA-716
Use the proper CGA connections. DO NOT USE ADAPTERS. Additional limited-standard
connections may apply. See CGA pamphlet V-1 listed below.
Ask your supplier about free Praxair safety literature as referred to in this MSDS and on the
label for this product. Further information can be found in the following materials published by
the Compressed Gas Association, Inc. (CGA), 4221 Walney Road, 5th Floor, Chantilly, VA
20151-2923, Telephone (703) 788-2700, http://www.cganet.com/Publication.asp.
AV-1 Safe Handling and Storage of Compressed Gases
AV-7 Characteristics and Safe Handling of Carbon Dioxide
G-6 Carbon Dioxide
G-6.1 Standard for Low Pressure Carbon Dioxide Systems at Customer Sites
G-6.2 Commodity Specification for Carbon Dioxide
P-1 Safe Handling of Compressed Gases in Containers
SB-2 Oxygen-Deficient Atmospheres
V-1 Compressed Gas Cylinder Valve Inlet and Outlet Connections
— Handbook of Compressed Gases, Fourth Edition

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Product: Carbon Dioxide P-4574-J Date: July 2007

Praxair asks users of this product to study this MSDS and become aware of product hazards
and safety information. To promote safe use of this product, a user should (1) notify employees,
agents, and contractors of the information in this MSDS and of any other known product
hazards and safety information, (2) furnish this information to each purchaser of the product,
and (3) ask each purchaser to notify its employees and customers of the product hazards and
safety information.

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Product: Carbon Dioxide P-4574-J Date: July 2007

The opinions expressed herein are those of qualified experts within Praxair, Inc. We
believe that the information contained herein is current as of the date of this Material
Safety Data Sheet. Since the use of this information and the conditions of use of the
product are not within the control of Praxair, Inc., it is the user’s obligation to
determine the conditions of safe use of the product.

Praxair MSDSs are furnished on sale or delivery by Praxair or the independent distributors and suppliers
who package and sell our products. To obtain current MSDSs for these products, contact your Praxair
sales representative or local distributor or supplier, or download from www.praxair.com. If you have
questions regarding Praxair MSDSs, would like the form number and date of the latest MSDS, or would
like the names of the Praxair suppliers in your area, phone or write the Praxair Call Center (Phone: 1-
800-PRAXAIR; Address: Praxair Call Center, Praxair, Inc., PO Box 44, Tonawanda, NY 14151-0044).
Praxair, the Flowing Airstream design, LaserStar, and Medipure are trademarks
or registered trademarks of Praxair Technology, Inc. in the United States and/or other countries.

Praxair, Inc.
39 Old Ridgebury Road
Danbury, CT 06810-5113

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