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Chapter 7 Overall Material Balance

The document describes the process of producing phosphoric acid from phosphate rock at the Technological Institute of the Philippines. It involves grinding the rock, mixing it with sulfuric acid in a CSTR reactor, filtering out the gypsum byproduct, and recycling a portion of the gypsum-containing stream back into the process. The streams and mass balances at each stage of processing are provided.

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47 views18 pages

Chapter 7 Overall Material Balance

The document describes the process of producing phosphoric acid from phosphate rock at the Technological Institute of the Philippines. It involves grinding the rock, mixing it with sulfuric acid in a CSTR reactor, filtering out the gypsum byproduct, and recycling a portion of the gypsum-containing stream back into the process. The streams and mass balances at each stage of processing are provided.

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216435964
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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Technological Institute of the Philippines

OVERALL
MATERIAL
BALANCE

1
Technological Institute of the Philippines

BALL MILLER
EQUIPMENT CODE V-101
OBJECTIVE To reduce the size of Phosphate rock
OPERATING PARAMETERS
Quantity (kg/hr) 4932.65
Pressure (atm) 1
Temperature (K) 298.15

Mass In:

Component Stream 41 Wt. Fraction Mass (kg/hr)


CaF2 0.20 885.64
Ca3(PO4)2 0.75 3331.89
SiO2 0.05 215.12
H2O 0.00 0.00
Total 1.00 4432.65

Component Stream
Wt. Fraction Mass (kg/hr)
42
CaF2 0.00 0.00
Ca3(PO4)2 0.00 0.00
SiO2 0.00 0.00
H2O 1.00 500.00
Total 1.00 500.00

2
Technological Institute of the Philippines

Mass Out:

Component Stream
Wt. Fraction Mass (Kg/hr)
42
CaF2 0.18 885.64
Ca3(PO4)2 0.68 3331.89
SiO2 0.04 215.12
H2O 0.10 500.00
Total 1.00 4932.65

3
Technological Institute of the Philippines

CSTR REACTOR
EQUIPMENT CODE R-104
To mix the Phosphate Slurry and Sulfuric Acid to
OBJECTIVE
produce Phophoric Acid and Gypsum
OPERATING PARAMETERS
Quantity (kg/hr) 4432.65
Pressure (atm) 1
Temperature (K) 298.15

4
Technological Institute of the Philippines

Mass In:
Components Stream 40 Wt. Fraction Mass (kg/hr)
Ca3(PO4)2 0.180 885.636
CaF2 0.675 3331.890
SiO2 0.044 215.122
H2O 0.101 500.000
Mass Total per Stream 1.000 4932.648

Components 43 Wt. Fraction Mass (kg/hr)


H2O 0.060 191.219
H2SO4 0.940 2995.767
Mass Total per Stream 1.000 3186.986

Components 44 Wt. Fraction Mass (kg/hr)


O2 0.210 21.000
N2 0.790 79.000
Mass Total per Stream 1.000 100.00
Mass Out:
Components Stream 39 Wt. Fraction Mass (kg/hr)
H2O 0.160 1120.922
O2 0.028 21.000
N2 0.104 79.000
HF 0.027 20.471
H2SiF6 0.681 515.392
Mass Total per Stream 1.000 757.324

Components Stream 45 Wt. Fraction Mass (kg/hr)


Ca3(PO4) 0.235 1749.242
H3PO4 0.134 1000.00
H2O 0.020 147.793
H2SO4 0.052 390.752
CaSO4.2H2O 0.353 2935.416
CaSO4 0.205 1532.026

5
Technological Institute of the Philippines

Mass Total per Stream 1.000 4932.648

PUMP

6
Technological Institute of the Philippines

EQUIPMENT CODE P-102


To increase pressure of the stream before entering
OBJECTIVE
the filter
OPERATING PARAMETERS
Quantity (kg/hr) 7455.23
Pressure (atm) 1
Temperature (K) 343.15

Mass In:
Components Stream 45 Wt. Fraction Mass (kg/hr)
Ca3(PO4) 0.235 1749.242
H3PO4 0.134 1000.000
H2O 0.020 147.793
H2SO4 0.052 390.752
CaSO4.2H2O 0.353 2635.416
CaSO4 0.205 1532.026
Total 1.000 7455.230

Mass Out:
Components Stream 47 Wt. Fraction Mass (kg/hr)
Ca3(PO4) 0.235 1749.242
H3PO4 0.134 1000.000
H2O 0.020 147.793
H2SO4 0.052 390.752
CaSO4.2H2O 0.353 2635.416
CaSO4 0.205 1532.026
Total 1.000 7455.230

FAN FILTER

7
Technological Institute of the Philippines

EQUIPMENT CODE FF-102


OBJECTIVE To separate phosphoric acid to gypsum
OPERATING PARAMETERS
Quantity (kg/hr) 7455.23
Pressure (atm) 1
Temperature (K) 343.15

Mass In:
Components Stream 47 Wt. Fraction Mass (kg/hr)
Ca3(PO4)2 0.235 1749.242
H3PO4 0.134 1000.000
H2O 0.020 147.793
H2SO4 0.052 390.752
CaSO4.2H2O 0.353 2635.416
CaSO4 0.205 1532.026
Total 1.000 7455.230

8
Technological Institute of the Philippines

Components Stream 48 Wt. Fraction Mass (kg/hr)


H2O 1 1378.99128
Total 1.000 1378.99128

Mass Out:

Components Stream 50 Wt. Fraction Mass (kg/hr)


H3PO4 0.40 1000
H2O 0.60 1500
Total 1.000 2500

Components Stream 49 Wt. Fraction Mass (kg/hr)


H2O 0.06 24.5675
H2SO4 0.94 384.8909
Total 1.00 409.4584
Components Stream 51 Wt. Fraction Mass (kg/hr)
Ca3(PO4)2 0.295 1749.2424
H2O 0.0004 2.2169
H2SO4 0.00099 5.8613
CaSO4.2H2O 0.445 2635.4165
CaSo4 0.2586 1532.0257
Total 1.000 5924.7627

MIXER
EQUIPMENT CODE MIX-101
OBJECTIVE To mix recycle stream with sulfuric acid
OPERATING PARAMETERS
Quantity (kg/hr) 2777.53
Pressure (atm) 1

9
Technological Institute of the Philippines

Temperature (K) 345.15

Mass In:
Components Stream 46 Wt. Fraction Mass (kg/hr)
H2SO4 0.94 2610.88
H2O 0.06 166.65
Total 1.00 2777.53

Components Stream 49 Wt. Fraction Mass (kg/hr)


H2SO4 0.94 384.89
H2O 0.06 24.57
Total 1.00 409.46

Mass Out:
Components Stream 43 Wt. Fraction Mass (kg/hr)
H2SO4 0.94 2995.77
H2O 0.06 191.22
Total 1.00 3186.99

10
Technological Institute of the Philippines

PUMP
EQUIPMENT CODE P-103
OBJECTIVE To increase the pressure before entering evaporators
OPERATING PARAMETERS
Quantity (kg/hr) 2500
Pressure (atm) 1

11
Technological Institute of the Philippines

Temperature (K) 298.15

Mass In:
Components Stream 50 Wt. Fraction Mass (kg/hr)
H3PO4 0.4 1000
H2O 0.6 1500
Total 1 2500

Mass Out:
Components Stream 52 Wt. Fraction Mass (kg/hr)
H3PO4 0.4 1000
H2O 0.6 1500
Total 1 2500

EVAPORATORS
EQUIPMENT CODE E-101
To remove water to produce concentrated
OBJECTIVE
phosphoric acid
OPERATING PARAMETERS
Quantity (kg/hr) 2500

12
Technological Institute of the Philippines

Pressure (atm) 2
Temperature (K) 345.15

Mass In:
Components Stream 52 Wt. Fraction Mass (kg/hr)
H3PO4 0.4 1000
H2O 0.6 1500
Total 1 2500

Mass Out:
Components Stream 55 Wt. Fraction Mass (kg/hr)
H3PO4 0 0
H2O 1 441.1765
Total 1 441.1765

13
Technological Institute of the Philippines

Components Stream 56 Wt. Fraction Mass (kg/hr)


H3PO4 0.4857 1000
H2O 0.5143 1058.8235
Total 1 2058.8235

EVAPORATORS
EQUIPMENT CODE E-102
To remove water to produce concentrated
OBJECTIVE
phosphoric acid
OPERATING PARAMETERS
Quantity (kg/hr) 2058.8235

14
Technological Institute of the Philippines

Pressure (atm) 1.79


Temperature (K) 379.15

Mass In:
Components Stream 56 Wt. Fraction Mass (kg/hr)
H3PO4 0.4857 1000
H2O 0.5143 1058.8235
Total 1 2058.8235

Mass Out:
Components Stream 57 Wt. Fraction Mass (kg/hr)
H3PO4 0 0
H2O 1 441.1765
Total 1 441.1765

Components Stream 58 Wt. Fraction Mass (kg/hr)


H3PO4 0.6182 1000
H2O 0.3818 617.6471

15
Technological Institute of the Philippines

Total 1 1617.6471

EVAPORATORS
EQUIPMENT CODE E-103
To remove water to produce concentrated
OBJECTIVE
phosphoric acid
OPERATING PARAMETERS
Quantity (kg/hr) 1617.6471
Pressure (atm) 1.25

16
Technological Institute of the Philippines

Temperature (K) 363.15

Mass In:
Components Stream 58 Wt. Fraction Mass (kg/hr)
H3PO4 0.6182 1000
H2O 0.3818 617.6471
Total 1 1617.6471

Mass Out:
Components Stream 59 Wt. Fraction Mass (kg/hr)
H3PO4 0 0
H2O 1 441.1765
Total 1 441.1765

17
Technological Institute of the Philippines

Components Stream 60 Wt. Fraction Mass (kg/hr)


H3PO4 0.85 1000
H2O 0.15 176.4706
Total 1 1176.4706

18

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