MATERIAL SAFETY DATA SHEET

According to 91/155/EEC - ISO 11014-1

Date of print-out 18/09/2018 last revision date 01/10/2006
MSDS-No.: 149/SDS/2014 DARUMA AC-200 Page 1 of 4

1. Identification of the substance/preparation and of the company/undertaking

Trade name DARUMA AC-200
Manufacturer PT. SOMAGEDE
INDONESIA Komplek Griya
Inti sentosa,
Jl. Griya Agung no. 3 Sunter Agung, Jakarta 14350 - Indonesia
Telephone (62-21) 6410730 Facsimile (62-21) 6401572
In case of emergency Telephone (62-21) 6452725

2. Composition / information on ingredients

Base substances of preparation:
Acid cleaning agent
Declaration of ingredients:
Inorganic acid, glycol, nonionic surfactant

3. Hazards Identification
Special hazards for man and environment:
R 35: Causes severe burns

4. First Aid Measures

After inhalation: Remove to fresh air, give oxygen, and seek medical advice in hospital
After skin contact: Immediately rinse with copious amounts of running water (for 10 minutes). Remove contaminated
clothes. Put on a bandage with sterile gauze, see a physician.
After eye contact: Immediately flush eyes with copious amounts of running water (for 10 minutes), put on a bandage
with sterile gauze, see an oculist.
After ingestion: Rinse mouth, drink plenty of water, see a physician.

5. Fire-fighting measures
Suitable extinguishing media: In case of fire, cool endangered containers with water spray.
Extinguishing media which must not be used for safety reasons: None known
Special hazards by the product itself: Does not burn (aquaeous solution). In case of fire, after evaporation of water
and further heating, SOx can be released.
Combustion products or gases to be formed: SOx.
Additional information: Wear self-contained breathing apparatus. Do not inhale combustion gases.

6. Accidental release measures

Personal precautions: Avoid contact with skin and eyes. Ensure adequate ventilation.
Environmental precautions: Do not allow to enter drainage system, surface or ground water.
Process for cleaning and take-up: neutralize with acid-binding material (e.g. powdered limestone) caution: release of
nitrous fumes (poisoning) and carbon dioxide

7. Handling and Storage

Handling: Attention when opening containers: poisonous gases may be accumulated in the air space of containers
Ensure that workrooms are adequately ventilated. When diluting, always stir the product into standing water

A Technical Bulletin can be ordered at your local sales office.

 MATERIAL SAFETY DATA
Date ofSHEET
print-out 18/09/2018 last revision date 01/10/2006
MSDS-No.: 149/SDS/2014 DARUMA AC-200 Page 2 of 4

Storage: Keep container in a well ventilated place; keep container tightly sealed; Store only in the original container.
Do not store together with edibles or other consumable substances.

8. Exposure controls/personal protection

Additional information for system design: Ensure for good ventilation/suction.
Components with specific control parameters for workplace: The product contains sulphuric acid, CAS-No.: 7664-
93-9. The relevant German exposure-limit for working place (MAK-value) according to °TRGS 900° for this
substance is 1 mg/m3 (total aerosole). (STEL-category I)
Respiratory protection: If there is atomisation
Hand protection: Protective gloves made of PVC
Eye protection: Goggles which can be tightly
sealed Skin protection: Suitable protective clothing
General protection and hygiene measures: Keep away from food, beverages and animal food. Do not eat, drink or
smoke while working

9. Physical and chemical properties

Designation Value

Delivery state: liquid

State: -
Odor: no valuation
Color(s): Yellowish liquid
pH-value (20 °C; Conc.: 10g/l in water) less than 2
Flash point No flash point up to 100°C.
Density (20 °C) 1.17 - 1.18
Solubility (qualitative) (20 °C; Solvent: water) miscible in water

10. Stability and reactivity

Conditions to avoid: On hot surfaces SOx gases can be released
Materials to avoid: Reacts with alkalis: heat generated
Hazardous decomposition products: None if used for intended purpose. SOx may be generated

11. Toxicological information

Inhalation: Harmful by inhalation
Ingestion: Harmful if swallowed
Skin contact: The product causes corrosion on skin and mucous membranes.
Eye contact: Strong corrosive effect
Swallowing will lead to a strong caustic effect on mouth and throat and to the danger of perforation of esophagus and
stomach.

12. Ecological information

General ecological information: This product contains inorganic product. Degradability is not pertinent.
Other information on ecology: In case of discharge of acidic or alkaline products into the sewerage system the pH
must be in the range of 6-10 since higher or lower pH values may damage the sewerage system or impair biological
sewage treatment plants. Local discharge statutes have to be observed.
Waste water: harmful effect due to low pH-value

A Technical Bulletin can be ordered at your local sales office.

 MSDS-No.: 149/SDS/2014 DARUMA AC-200 Page 3 of 4

13. Disposal considerations

Waste code (EWC): The valid EWC was code numbers are source-related. The manufacturer is therefore unable to
specify EWC waste codes for the articles or products used in the various sectors. The EWC codes listed are intended as a
recommendation for users. 0601 99
Product disposal: In consultation with the responsible local authority and must be subjected to special treatment:
neutralization ;
Recommended cleaning agents: Clean the packaging with water

14. Transport information

Transport over land ADR/RID:
Class: 8 Number/Letter: 76b
1st numbering of tanks panel:
86
2nd numbering of tanks panel: 2922
Designation of goods:
2922 Ätzender flüssiger Stoff, giftig ,
n.a.g. (enthält Salpetersäure)

Transport over inland waterways

ADN/ADNR: Class: 8 Number/Letter:
76b Designation of goods:
Ätzender flüssiger Stoff, giftig ,
n.a.g. (enthält Salpetersäure)

Transport over sea IMDG:

Class: 8 UN-Nr.: 2922 PG: II
EmS: 8-15
MFAG: 760
Proper shipping name:
Corrosive liquid, toxic, n.o.s. (contains Sulphuric acid)

Transport by air ICAO/IATA:

Class: 8 UN/ID-Nr.: 2922 PG: II
Pkg-Instr. (passangerair.): 808
Pkg-Instr.(cargo air. only):
812 Proper shipping name:
Corrosive liquid, toxic, n.o.s. (contains Sulphuric acid)

15. Regulatory information

Symbols of danger: T Toxic ; C Corrosive
Hazard trigger: sulphuric acid
R-phrases:
R 35: Cause severe burns
S-phrases:
S 7/9: Keep container tightly closed and in a well-ventilated place
S 26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
S 36/37/39: Wear suitable protective clothing, gloves and eye/face protection
S 45: In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible)
VOC-portion: 0% (RiLi 1999/13/EC)
National regulations/information:
WGK = 1, slightly water-endangering product (manufacturer classification in conformity with the calculation method of
the German VwVwS of May 17, 1999).
 MSDS-No.: 149/SDS/2014 DARUMA AC-200 Page 4 of 4

16. Additional information

This information is based on our current level of knowledge and relates to the product in the state in which it is
delivered. It is intended to describe our products from the point of view of safety requirements and is not intended to
guarantee any particular properties.