SAFETY DATA SHEET

MasterTop 2200 PART B

Version Revision Date: SDS Number: Date of last issue: -

1.0 29.06.2020 000000444915 Date of first issue: 29.06.2020

1. PRODUCT AND COMPANY IDENTIFICATION

Product name : MasterTop 2200 PART B

Product code : 000000000050100936

Manufacturer or supplier's details

Company : Master Builders Solutions Construction
Chemicals LLC

Address : P.O. Box: 37127, Dubai Investment Park, Phase 1

Expo Road, Dubai, United Arab Emirates

Telephone : +97148851000

Emergency telephone : ChemTel: +1-813-248-0585

Telefax : +97148851130

Recommended use of the chemical and restrictions on use

Recommended use : Product for construction chemicals

2. HAZARDS IDENTIFICATION

GHS Classification
Skin corrosion/irritation : 1B

Serious eye damage/eye irri- : 1

tation

Skin sensitization : 1

Specific target organ toxicity - : 1

repeated exposure

GHS label elements

Hazard pictograms :

Signal Word : Danger

Hazard Statements : H317 May cause an allergic skin reaction.

H372 Causes damage to organs (Lung) through prolonged or
repeated exposure if inhaled.
H314 Causes severe skin burns and eye damage.

Precautionary Statements :
Prevention:

1 / 11
SAFETY DATA SHEET

MasterTop 2200 PART B

Version Revision Date: SDS Number: Date of last issue: -

1.0 29.06.2020 000000444915 Date of first issue: 29.06.2020

P280 Wear protective gloves/ protective clothing/ eye protec-

tion/ face protection.
P270 Do not eat, drink or smoke when using this product.
P264 Wash face, hands and any exposed skin thoroughly after
handling.
P272 Contaminated work clothing should not be allowed out of
the workplace.
P260 Do not breathe dust or mist.
Response:
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water
for several minutes. Remove contact lenses, if present and
easy to do. Continue rinsing.
P310 Immediately call a POISON CENTER/ doctor/
P303 + P361 + P353 IF ON SKIN (or hair): Take off immediate-
ly all contaminated clothing. Rinse skin with water/ shower.
P304 + P340 IF INHALED: Remove person to fresh air and
keep comfortable for breathing.
P301 + P330 + P331 IF SWALLOWED: Rinse mouth. Do NOT
induce vomiting.
P362 + P364 Take off contaminated clothing and wash it before
reuse.
Storage:
P405 Store locked up.
Disposal:
P501 Dispose of contents/container to appropriate hazardous
waste collection point.

Other hazards which do not result in classification

If applicable information is provided in this section on other hazards which do not result in classi-
fication but which may contribute to the overall hazards of the substance or mixture.

3. COMPOSITION/INFORMATION ON INGREDIENTS

Chemical nature : polyamide

Fillers

Components
Chemical name CAS-No. Concentration (%
w/w)
Quartz (SiO2) 14808-60-7 < 75
2,4,6-tris(dimethylaminomethyl)phenol 90-72-2 <7
Phenol, methylstyrenated 68512-30-1 <7
2,2'-iminodiethylamine; diethylenetriamine 111-40-0 <3
triethylenetetramine 112-24-3 <3

4. FIRST AID MEASURES

General advice : Move out of dangerous area.

Consult a physician.
Show this material safety data sheet to the doctor in attend-
ance.

2 / 11
SAFETY DATA SHEET

MasterTop 2200 PART B

Version Revision Date: SDS Number: Date of last issue: -

1.0 29.06.2020 000000444915 Date of first issue: 29.06.2020

Do not leave the victim unattended.

If inhaled : If unconscious, place in recovery position and seek medical

advice.
If symptoms persist, call a physician.

In case of skin contact : Immediate medical treatment is necessary as untreated

wounds from corrosion of the skin heal slowly and with difficul-
ty.
If on skin, rinse well with water.
If on clothes, remove clothes.

In case of eye contact : Small amounts splashed into eyes can cause irreversible tis-
sue damage and blindness.
In the case of contact with eyes, rinse immediately with plenty
of water and seek medical advice.
Continue rinsing eyes during transport to hospital.
Remove contact lenses.
Protect unharmed eye.
Keep eye wide open while rinsing.
If eye irritation persists, consult a specialist.

If swallowed : Clean mouth with water and drink afterwards plenty of water.
Keep respiratory tract clear.
Do NOT induce vomiting.
Do not give milk or alcoholic beverages.
Never give anything by mouth to an unconscious person.
If symptoms persist, call a physician.
Take victim immediately to hospital.

Most important symptoms : May cause an allergic skin reaction.

and effects, both acute and Causes serious eye damage.
delayed Causes damage to organs through prolonged or repeated
exposure if inhaled.
Causes severe burns.

Notes to physician : Treat symptomatically.

5. FIRE-FIGHTING MEASURES

Unsuitable extinguishing : High volume water jet

media

Specific hazards during fire : Do not allow run-off from fire fighting to enter drains or water
fighting courses.

Specific extinguishing meth- : Collect contaminated fire extinguishing water separately. This
ods must not be discharged into drains.
Fire residues and contaminated fire extinguishing water must
be disposed of in accordance with local regulations.

Special protective equipment : Wear self-contained breathing apparatus for firefighting if nec-
for fire-fighters essary.

3 / 11
SAFETY DATA SHEET

MasterTop 2200 PART B

Version Revision Date: SDS Number: Date of last issue: -

1.0 29.06.2020 000000444915 Date of first issue: 29.06.2020

6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protec- : Use personal protective equipment.

tive equipment and emer- Avoid dust formation.
gency procedures Avoid breathing dust.

Environmental precautions : Prevent product from entering drains.

Prevent further leakage or spillage if safe to do so.
If the product contaminates rivers and lakes or drains inform
respective authorities.

Methods and materials for : Neutralize with acid.

containment and cleaning up Keep in suitable, closed containers for disposal.

7. HANDLING AND STORAGE

Advice on protection against : Avoid dust formation.

fire and explosion Provide appropriate exhaust ventilation at places where dust
is formed.

Advice on safe handling : Avoid dust formation.

Avoid inhalation of dusts.
Avoid skin contact.
Pour downwind and allow as little free fall as possible while
emptying bags into equipment.
Breathing must be protected when large quantities are de-
canted without local exhaust ventilation.

Avoid formation of respirable particles.

Do not breathe vapors/dust.
Avoid exposure - obtain special instructions before use.
Avoid contact with skin and eyes.
For personal protection see section 8.
Smoking, eating and drinking should be prohibited in the ap-
plication area.
Dispose of rinse water in accordance with local and national
regulations.
Persons susceptible to skin sensitization problems or asthma,
allergies, chronic or recurrent respiratory disease should not
be employed in any process in which this mixture is being
used.

Conditions for safe storage : Keep container tightly closed in a dry and well-ventilated
place.
Observe label precautions.
Electrical installations / working materials must comply with
the technological safety standards.

Further information on stor- : Keep only in the original container in a cool, dry, well-
age conditions ventilated place away from ignition sources, heat or flame.
Protect from direct sunlight.

Further information on stor- : No decomposition if stored and applied as directed.

age stability

4 / 11
SAFETY DATA SHEET

MasterTop 2200 PART B

Version Revision Date: SDS Number: Date of last issue: -

1.0 29.06.2020 000000444915 Date of first issue: 29.06.2020

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Ingredients with workplace control parameters

Personal protective equipment

Respiratory protection : Wear respiratory protection if ventilation is inadequate.
Combination filter for gases/vapours of organic, inorganic,
acid inorganic and alkaline compounds (e.g. EN 14387 Type
ABEK).

Hand protection

Remarks : The suitability for a specific workplace should be discussed

with the producers of the protective gloves.

Eye protection : Eye wash bottle with pure water

Tightly fitting safety goggles
Wear face-shield and protective suit for abnormal processing
problems.

Skin and body protection : Choose body protection according to the amount and concen-
tration of the dangerous substance at the work place.

Protective measures : Do not inhale dust/fumes/aerosols.

Avoid contact with the skin, eyes and clothing.
Avoid exposure - obtain special instructions before use.
Handle in accordance with good building materials hygiene
and safety practice.
Wearing of closed work clothing is recommended.

Hygiene measures : When using do not eat or drink.

When using do not smoke.
Wash hands before breaks and at the end of workday.

9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance : pasty

Color : black

Odor : characteristic

pH : approx. 11 - 12 (approx. 28 °C)

(as aqueous suspension)

Flash point : > 100 °C

Method: Flashpoint test using closed cup, determination of

flashpoint.

5 / 11
SAFETY DATA SHEET

MasterTop 2200 PART B

Version Revision Date: SDS Number: Date of last issue: -

1.0 29.06.2020 000000444915 Date of first issue: 29.06.2020

Flammability (solid, gas) : not determined

Self-ignition : not self-igniting

Bulk density : approx. 1,642 kg/m3 (25 °C)

not applicable

Solubility(ies)
Water solubility : emulsifiable

Decomposition temperature : No decomposition if stored and handled as pre-

scribed/indicated.

Explosive properties : Not explosive

Not explosive

Oxidizing properties : not fire-propagating

Self-heating substances : No data available

10. STABILITY AND REACTIVITY

Reactivity : No decomposition if stored and applied as directed.

Chemical stability : No decomposition if stored and applied as directed.

Possibility of hazardous reac- : No decomposition if stored and applied as directed.

tions

Conditions to avoid : See SDS section 7 - Handling and storage.

Incompatible materials : Strong acids

Strong bases
Strong oxidizing agents
Strong reducing agents

Hazardous decomposition : No hazardous decomposition products if stored and handled

products as prescribed/indicated.

11. TOXICOLOGICAL INFORMATION

Acute toxicity
Not classified based on available information.
Components:

Phenol, methylstyrenated:
Acute oral toxicity : LD50 (Rat): > 2.000 mg/kg
Method: Acute Oral Toxicity - Acute Toxic Class Method

Acute inhalation toxicity : LC50 (Rat): 5 mg/l

6 / 11
SAFETY DATA SHEET

MasterTop 2200 PART B

Version Revision Date: SDS Number: Date of last issue: -

1.0 29.06.2020 000000444915 Date of first issue: 29.06.2020

Exposure time: 4 h
Method: Acute Inhalation Toxicity

Acute dermal toxicity : LD50 (Rat): > 2.000 mg/kg

Method: Acute Dermal Toxicity

Skin corrosion/irritation
Causes severe burns.
Serious eye damage/eye irritation
Causes serious eye damage.
Respiratory or skin sensitization

Skin sensitization
May cause an allergic skin reaction.
Respiratory sensitization
Not classified based on available information.
Germ cell mutagenicity
Not classified based on available information.
Carcinogenicity
Not classified based on available information.
Reproductive toxicity
Not classified based on available information.
STOT-single exposure
Not classified based on available information.
STOT-repeated exposure
Causes damage to organs (Lung) through prolonged or repeated exposure if inhaled.
Aspiration toxicity
Not classified based on available information.
Components:

Phenol, methylstyrenated:
No aspiration hazard expected.

Further information

Product:
Remarks : No data available

7 / 11
SAFETY DATA SHEET

MasterTop 2200 PART B

Version Revision Date: SDS Number: Date of last issue: -

1.0 29.06.2020 000000444915 Date of first issue: 29.06.2020

12. ECOLOGICAL INFORMATION

Ecotoxicity

Product:

Ecotoxicology Assessment
Acute aquatic toxicity : This product has no known ecotoxicological effects.

Chronic aquatic toxicity : This product has no known ecotoxicological effects.

Components:

Phenol, methylstyrenated:
Toxicity to fish : LC50 (Fish): 25,8 mg/l
Exposure time: 96 h
Method: Acute toxicity for fish

Toxicity to daphnia and other : EC50 (Daphnia magna): 14 - 51 mg/l

aquatic invertebrates Exposure time: 48 h
Method: Daphnia sp., Acute Immobilisation Test.

Toxicity to algae/aquatic : EC50 ( algae): 15 mg/l

plants Exposure time: 72 h
Method: Algae, Growth Inhibition Test

Persistence and degradability

Product:
Biodegradability : Remarks: Taking into consideration the properties of several
ingredients, the product is estimated not to be readily biode-
gradable according to OECD classification.

Bioaccumulative potential

Components:

Quartz (SiO2):
Partition coefficient: n- : Remarks: The value has not been determined because the
octanol/water substance is inorganic.

Phenol, methylstyrenated:
Bioaccumulation : Remarks: The product will not be readily bioavailable due to
its consistency and insolubility in water.
No data available

Partition coefficient: n- : Remarks: insoluble

octanol/water

triethylenetetramine:
Partition coefficient: n- : log Pow: -2,65 (25 °C)

8 / 11
SAFETY DATA SHEET

MasterTop 2200 PART B

Version Revision Date: SDS Number: Date of last issue: -

1.0 29.06.2020 000000444915 Date of first issue: 29.06.2020

octanol/water Method: other (calculated)

GLP: no
Remarks: The data refers to the undissociated form of the
substance.

Mobility in soil
No data available
Other adverse effects

Product:
Additional ecological infor- : No data available
mation

13. DISPOSAL CONSIDERATIONS

Disposal methods
Waste from residues : Do not dispose of waste into sewer.
Do not contaminate ponds, waterways or ditches with chemi-
cal or used container.
Send to a licensed waste management company.

Contaminated packaging : Empty remaining contents.

Dispose of as unused product.
Do not re-use empty containers.

14. TRANSPORT INFORMATION

International Regulations

UNRTDG
UN number : UN 3263
Proper shipping name : CORROSIVE SOLID, BASIC, ORGANIC, N.O.S.
(2,4,6-TRIS(DIMETHYLAMINOMETHYL)PHENOL,
DIETHYLENETRIAMINE)
Class : 8
Packing group : II
Labels : 8
IATA-DGR
UN/ID No. : UN 3263
Proper shipping name : CORROSIVE SOLID, BASIC, ORGANIC, N.O.S.
(2,4,6-TRIS(DIMETHYLAMINOMETHYL)PHENOL,
DIETHYLENETRIAMINE)
Class : 8
Packing group : II
Labels : Corrosive
Packing instruction (cargo : 863
aircraft)
Packing instruction (passen- : 859
ger aircraft)
IMDG-Code

9 / 11
SAFETY DATA SHEET

MasterTop 2200 PART B

Version Revision Date: SDS Number: Date of last issue: -

1.0 29.06.2020 000000444915 Date of first issue: 29.06.2020

UN number : UN 3263
Proper shipping name : CORROSIVE SOLID, BASIC, ORGANIC, N.O.S.
(2,4,6-TRIS(DIMETHYLAMINOMETHYL)PHENOL,
DIETHYLENETRIAMINE)
Class : 8
Packing group : II
Labels : 8
EmS Code : F-A, S-B
Marine pollutant : no
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable for product as supplied.
Special precautions for user
The transport classification(s) provided herein are for informational purposes only, and solely
based upon the properties of the unpackaged material as it is described within this Safety Data
Sheet. Transportation classifications may vary by mode of transportation, package sizes, and var-
iations in regional or country regulations.

15. REGULATORY INFORMATION

Safety, health and environmental regulations/legislation specific for the substance or mix-
ture
If other regulatory information applies that is not already provided elsewhere in this safety data
sheet, then it is described in this subsection.

16. OTHER INFORMATION

Full text of other abbreviations

AICS - Australian Inventory of Chemical Substances; ANTT - National Agency for Transport by
Land of Brazil; ASTM - American Society for the Testing of Materials; bw - Body weight; CMR -
Carcinogen, Mutagen or Reproductive Toxicant; DIN - Standard of the German Institute for
Standardisation; DSL - Domestic Substances List (Canada); ECx - Concentration associated with
x% response; ELx - Loading rate associated with x% response; EmS - Emergency Schedule;
ENCS - Existing and New Chemical Substances (Japan); ErCx - Concentration associated with
x% growth rate response; ERG - Emergency Response Guide; GHS - Globally Harmonized Sys-
tem; GLP - Good Laboratory Practice; IARC - International Agency for Research on Cancer; IATA
- International Air Transport Association; IBC - International Code for the Construction and
Equipment of Ships carrying Dangerous Chemicals in Bulk; IC50 - Half maximal inhibitory con-
centration; ICAO - International Civil Aviation Organization; IECSC - Inventory of Existing Chemi-
cal Substances in China; IMDG - International Maritime Dangerous Goods; IMO - International
Maritime Organization; ISHL - Industrial Safety and Health Law (Japan); ISO - International Or-
ganisation for Standardization; KECI - Korea Existing Chemicals Inventory; LC50 - Lethal Con-
centration to 50 % of a test population; LD50 - Lethal Dose to 50% of a test population (Median
Lethal Dose); MARPOL - International Convention for the Prevention of Pollution from Ships;
n.o.s. - Not Otherwise Specified; Nch - Chilean Norm; NO(A)EC - No Observed (Adverse) Effect
Concentration; NO(A)EL - No Observed (Adverse) Effect Level; NOELR - No Observable Effect
Loading Rate; NOM - Official Mexican Norm; NTP - National Toxicology Program; NZIoC - New
Zealand Inventory of Chemicals; OECD - Organization for Economic Co-operation and Develop-
ment; OPPTS - Office of Chemical Safety and Pollution Prevention; PBT - Persistent, Bioaccumu-

10 / 11
SAFETY DATA SHEET

MasterTop 2200 PART B

Version Revision Date: SDS Number: Date of last issue: -

1.0 29.06.2020 000000444915 Date of first issue: 29.06.2020

lative and Toxic substance; PICCS - Philippines Inventory of Chemicals and Chemical Substanc-
es; (Q)SAR - (Quantitative) Structure Activity Relationship; REACH - Regulation (EC) No
1907/2006 of the European Parliament and of the Council concerning the Registration, Evalua-
tion, Authorisation and Restriction of Chemicals; SADT - Self-Accelerating Decomposition Tem-
perature; SDS - Safety Data Sheet; TCSI - Taiwan Chemical Substance Inventory; TDG - Trans-
portation of Dangerous Goods; TSCA - Toxic Substances Control Act (United States); UN - Unit-
ed Nations; UNRTDG - United Nations Recommendations on the Transport of Dangerous Goods;
vPvB - Very Persistent and Very Bioaccumulative; WHMIS - Workplace Hazardous Materials In-
formation System

The information provided in this Safety Data Sheet is correct to the best of our knowledge, infor-
mation and belief at the date of its publication. The information given is designed only as a guid-
ance for safe handling, use, processing, storage, transportation, disposal and release and is not
to be considered a warranty or quality specification. The information relates only to the specific
material designated and may not be valid for such material used in combination with any other
materials or in any process, unless specified in the text.

UN / EN

11 / 11