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MSDS or SDS-VRLA Battery-2022

The document is a material safety data sheet for valve-regulated lead acid batteries. It provides information on product identification, hazards, composition, first aid measures, fire fighting measures, accidental release measures, handling and storage, exposure controls and personal protection, physical and chemical properties, stability and reactivity, toxicological information and ecological information. The batteries contain lead, lead oxides, sulfuric acid, a separator and ABS container. Under normal conditions of use, they do not present a hazard but can cause irritation if exposed to their contents.
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0% found this document useful (0 votes)
634 views5 pages

MSDS or SDS-VRLA Battery-2022

The document is a material safety data sheet for valve-regulated lead acid batteries. It provides information on product identification, hazards, composition, first aid measures, fire fighting measures, accidental release measures, handling and storage, exposure controls and personal protection, physical and chemical properties, stability and reactivity, toxicological information and ecological information. The batteries contain lead, lead oxides, sulfuric acid, a separator and ABS container. Under normal conditions of use, they do not present a hazard but can cause irritation if exposed to their contents.
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd
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MATERIAL SAFETY DATA SHEET

VALVE-REGULATED LEAD ACID BATTERIES


MAINTENANCE-FREE NON-SPILLABLE

Series No: 9990920160120-001


ACCORDING TO ISO 11014-2009 FORMAT
Version: 2.0
Date Issued: 01-Jan-2022
SECTION 1- CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Name: Sealed Lead Acid Battery, Valve Regulated Lead Acid Battery GEL Battery ,

BATTERIES, WET, NONSPILLABLE,electric storage, TN, TNL, TNF, TNS, TNX, TNG, TNFG,TNC,

TNFC, TNE, OPZV, TNEH, TNEP, DZM, DZF, EVF, AGM、TA、TAA、TAS Series
Product type:
TN2-500, TN2-1000 , TN6-4.0, TN6-7.0, TN12-4.5, TN12-5.5, TN12-6.5, TN12-7.0,TN12-7.2, TN12-9.0,

TN12-12, TN12-18, TN12-20, TN12-24, TN12-33, TN12-38, TN12-45, TN12-50, TN12-55, TN12-65, TN12-
75, TN12-100, TN12-150, TN12-200,TN12-250, TNG12-20,TNG12-65 , TNG12-75 , TNG12-80 , TNG12-
100 , TNG12-150 , TNG12-200 , TNX12-21W, TNX12-28W, TNX12-34W, TNX12-690W, TNL12-90L, TNL12
-100, TNL12-180, TNL12-200, TNF12-100, TNF12-150, TNF12-200,TNC2-500,TNC2-1000,TNC2-
1200,TNC12-65P,TNC12-80P,TNC12-170P,TNC12-200P, TNE12-7.0, TNE12-9.0, TNE12-15, TNE12-25,
TNE12-35B, TNE12-38,TNE12-40,TNE12-45,TNE12-52, TNE12-58, TNE12-65, TNE12-75, TNE12-85,
TNE12-90, TNE12-100, TNE12-125, TNE12-150, TNE12-170,TNE12-190,TNE12-200, TNE12-230, TNE6-
250 , TNE6-270 , TNEH12-15,TNEH12-27, TNEH12-40,TNEP12-16, TNEP12-28,TNEP12-41,TNEP12-
48,TNEP12-60,TNEP12-66, TNEP6-240, TNEP6-290, TNEP6-400, 6-DZF-12, 6-DZF-15, 6-DZF-20, 6-DZF
-28, 6-DZF-13.2,6-DZF-22.3,3-EVF-150、3-EVF-200、3-EVF-200T、3-EVF-220、4-EVF-150、4-EVF-150T
、4-EVF-155、4-EVF-180、6-EVF-35.5,6-DZF-12III,6-DZF-23L,6-EVF-36L,6-EVF-32, 6-EVF-45,6-EVF-52,6
-EVF-58,6-EVF-60A,6-EVF-71,6-EVF-80,6-EVF-100, 6-EVF-120H, 6-EVF-135,6-EVF-150,6-EVF-160B,6-
EVF-180,AGM12-100(12V100Ah)、TA36325、TA45380、TA60480、TA70580B、TA60500B、TA72650、

TAS60610、TAS75660、TAS75700、TAA60660、TAA70760、TAA105950

Name of Company:
ZHEJIANG CHANGXING TIANNENG POWER CO., LTD.
Address:No.18th, Baoqiao Road, Huaxi Industrial Zone of Changxing County, Zhejiang, China Tel: +86-572-
6058015
Fax: +86-572-6058015
E-mail: export@tiannenggroup.com
SECTION 2- HAZARDS IDENTIFICATION

Hazards identification:

The battery has passed the vibration test, pressure differential test and leakage test at 55 ℃ according to
Recommendations on the TRANSPORT OF DANGEROUS GOODS Model SPECIAL PROVISION 238. It is not
restricted to IATA DGR according to special provision A67 and is not restricted to IMDG CODE according to
special provision 238.
Lead/Lead oxides: Under normal conditions of use, lead dust, vapors, and fumes are not generated.

Address: No.18th, Baoqiao Road, Huaxi Industrial Zone of Changxing County, Zhejiang, PRC 313100 1
Telephone: +86-572-6058015 Fax:+86-572-6058015 Website: http://en.cn-tn.com
MATERIAL SAFETY DATA SHEET
VALVE-REGULATED LEAD ACID BATTERIES
MAINTENANCE-FREE NON-SPILLABLE
Hazardous exposure may occur when product is overheated, oxidized or otherwise processed ordamaged to
create dust, vapor or fumes.
Inhalation: Lead dust or fumes may cause irritation of upper respiratory tract or lungs.
Skin Contact: Lead Compounds are not readily absorbed through the skin.
Eye Contact: Lead Compounds may cause eye irritation
Sulfuric acid: Under normal conditions of use, it will not be affected. When the battery is opened and leaks,
dangerous contact may occur.
Inhalation: Acid mist may irritate the upper respiratory tract or lungs.
Skin contact: Sulfuric acid can corrode the skin.
Eye contact: Sulfuric acid can cause eye irritation.
SECTION 3- COMPOSITION / INFORMATION ON INGREDIENTS

Substance/Mixture Percent CAS No.


Lead/Lead oxides 60%~75% 7439-92-1
Sulfuric Acid 20%~30% 7664-93-9
Separator 1.5%~4% 65997-17-3
ABS Container 4%~8% 9003-56-9
SECTION 4 - FIRST AID MEASURES
Inhalation
Sulfuric Acid: Remove to fresh air immediately. Give oxygen or artificial respiration if needed. Get
immediate medical attention.
Lead/Lead oxides: Remove from exposure, gargle, wash nose and lips, consult physician
Eyes contact
Sulfuric Acid: Flush with plenty of water for at least 15 minutes, hold eyelids open. Get immediate
medical attention..
Lead/Lead oxides: Flush immediately with water for 15 minutes, consult a physician
Skin contact
Sulfuric Acid: Flush with large amounts of water for at least 15 minutes, remove any contaminated
clothing. If irritation develops seek medical attention.
Lead/Lead oxides: Wash with soap and water.
Ingestion
Sulfuric Acid: Ingestion: Do not induce vomiting. Dilute by giving large quantities of water. If available give
several glasses of milk. Do not give anything by mouth to an unconscious person. Give CPR if breathing
has stopped. Get immediate medical attention.
Lead/Lead oxides: Consult a physician immediately
SECTION 5 - FIRE FIGHTING MEASURES
Flash Point: Not Applicable
Extinguishing Media:
Use water, foam or dry powder, as appropriate to extinguish fire.
Fire Fighting Procedures:

Address: No.18th, Baoqiao Road, Huaxi Industrial Zone of Changxing County, Zhejiang, PRC 313100 2
Telephone: +86-572-6058015 Fax:+86-572-6058015 Website: http://en.cn-tn.com
MATERIAL SAFETY DATA SHEET
VALVE-REGULATED LEAD ACID BATTERIES
MAINTENANCE-FREE NON-SPILLABLE
In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus
with full-face piece operated in the pressure demand or other positive pressure mode. Fight fire from the
maximumdistance. Evacuate area.
Specific Hazards:
When involved in a fire, the battery may decompose and produce irritating fumes containing metal oxides.
And plastic may create toxic vapors, gases or fumes under fire conditions.
SECTION 6 - ACCIDENTAL RELEASE MEASURES
Personal Precautions:
Wear appropriate personal protective equipment as specified in Section 8.
Environmental Precautions:
This material may be non-hazardous in ordinary use and may be discarded in accordance with applicable
governmental regulations and take order with the demands of the environmental protection section.
Methods of Clean up:
Spill and leaks are unlikely because cells are contained in a sealed case. In the event of a battery rupture,
prevent skin contact and collect all released material in a plastic lined metal container to prevent spill from
entering drinking water supplies or streams. Any product recovery or disposal must comply with local, state,
federal,international or country Specific regulations.
SECTION 7 - HANDLING AND STORAGE

Handling: It can be used normally under the temperature of -20~40℃. All connections should be connected
accurately to avoid the possibility of a short circuit. Do not let oil and water or other contamination drop on
the top of battery while working. Use only in the well-ventilated areas. Keep away from heat, sparks and
open flames. Make available in the work area emergency shower and eyes wash. Avoid contact with skin
and eyes. Use of full- length sleeves and pants; boots or work shoes are recommended for manufacturing
operations.
Storage: Store in cool, dry, well-ventilated area and away from combustible materials, sources of ignition,
excessive heat and direct sunlight. Do not store in sealed areas.
Warning: Not for use on children under 5 years old.
SECTION 8 - EXPOSURE CONTROLS AND PERSONAL PROTECTION
Engineering control: use ventilation equipment, safety showers and eye baths
Personal protective equipment:
Respiratory: Wear government approved air purifying respirator if necessary.
Eyes: Chemical safety glasses.
Clothing: Wear appropriate protective clothing.
Hands: Wear acid-proof gloves.
Other protective measures: smoking, drinking and eating are strictly prohibited in the workplace.Wash
thoroughly after washing your hands.
SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES

General Physical Form: The battery is solid.


Odor: The battery is odorless.

Address: No.18th, Baoqiao Road, Huaxi Industrial Zone of Changxing County, Zhejiang, PRC 313100 3
Telephone: +86-572-6058015 Fax:+86-572-6058015 Website: http://en.cn-tn.com
MATERIAL SAFETY DATA SHEET
VALVE-REGULATED LEAD ACID BATTERIES
MAINTENANCE-FREE NON-SPILLABLE
Solubility in Water: Lead, lead oxide and lead sulfate are insoluble in water.
SECTION 10 - STABILITY AND REACTIVITY
Stability: Stable under normal conditions.
Conditions to Avoid: Direct sunlight, overheat, sparks and other sources of ignition.
Incompatibility: Incompatible with strong oxidizing agents, potassium, sodium.
Hazardous Polymerization: Hazardous polymerization will not occur.
SECTION 11 - TOXICOLOGICAL INFORMATION
Lead/Lead Oxides: Toxic by ingestion or inhalation. Chronic poison.
Sulfuric Acid:Contact may cause severe irritation to eyes and skin, causes burns.
Potential Chronic Health Effects:
Be slightly hazardous in case of skin contact (permeate).
Carcinogenic effects: Lead/Lead Oxides:Classified A3 (Proven for animal.) by ACGIH, 2B (Possible for
human.) by IARC. Sulfuric Acid:G1 by IARC. Mutagenic effects:Not available.
Teratogenic effects: Not available. Developmental toxicity: Not available.
Lead may be toxic to blood, kidneys, central nervous system (CNS).
Repeated or prolonged exposure to the substance can produce target organs damage.
SECTION 12 - ECOLOGICAL INFORMATION

Lead/Lead Oxides:
Eco-toxicity: Not available. BOD5 and COD: tNo available.
Products of Biodegradation: Possibly hazardous short-term degradation products are not likely. However,
long-
term degradation products may arise.
Toxicity of the Products of Biodegradation: The products of degradation are less toxic than the product itself.
Special Remarks on the Products of Biodegradation: Not available.
Sulfuric Acid:
Harmful to the environment, can cause pollution to water bodies and soil. Biodegradability and Non-
biodegradability:No available.

SECTION13 - DISPOSAL CONSIDERATIONS

Waste Disposal Method:


Spent batteries must be treated as hazardous waste and disposed of according to local state, and federal
regulations. A copy of this material safety data must be supplied to any scrap dealer or secondary smelter
withbattery. Put into dustbin, otherwise incineration, otherwise licensed landfill, or safe disposal as required
by local, state, federal, international or country specific regulations.
Empty Container Warnings:
Empty containers may contain product residue, follow MSDS and label warnings even after they have been
emptied.
SECTION 14 - TRANSPORT INFORMATION

GROUND-US DOT:
Our non-spillable lead acid batteries meet all of the following requirements found at DOT 49 CFR 173.159(d)
Address: No.18th, Baoqiao Road, Huaxi Industrial Zone of Changxing County, Zhejiang, PRC 313100 4
Telephone: +86-572-6058015 Fax:+86-572-6058015 Website: http://en.cn-tn.com
MATERIAL SAFETY DATA SHEET
VALVE-REGULATED LEAD ACID BATTERIES
MAINTENANCE-FREE NON-SPILLABLE
● When offered for transport, the batteries are protected against short circuits and securely packaged as
required by DOT 49 CFR 173.159(d) (1);
● The batteries and outer packaging are marked with the words “NONSPILLABLE” or “ NONSPILLABLE
BATTER” as required by DOT 49 CFR173.159(d) (2);
● The batteries comply with the vibration and pressure differential tests found in DOT 49 CFR 173.159(d) (3).
AIRCRAFT-ICAO-IATA:
Our non - spillable lead acid batteries also are excepted from the international hazardous materials (also
known as dangerous goods ) regulations since they comply with the following requirements:
● According to the requirements of Packing Instruction 806 in IATA (International Air Transport Association )
and ICAO ( International Civil Aviation Organization ), there should not be any electrolyte leakage after the
vibration and pressure differential tests .
● And, Special Provision A67 states Non- spillable batteries are not subject to these Instructions ( Packing
Instruction 806 ) if at the temperature of 55℃ (131°F), the electrolyte will not flow from a ruptured or
cracked case and there is no free liquid flow and if, when packaged for transport the batteries are
protected from short circuit and unintentional activation .
VESSEL IMO-IMDG:
Our non-spillable batteries are excepted from the international hazardous materials (also known as
dangerous goods) regulations since they conform to the requirements of IMDG Code Special Provision 238,
that is the batteries have passed the vibration and pressure differential performance tests, and at a
temperature of 55℃, the electrolyte will not flow from a ruptured or cracked case and there is no free liquid
flow and if, when package for transport, the terminal are protected from short circuit.
SECTION 15 - REGULATORY INFORMATION
EU regulation:According to the EU2013 / 56 / EC battery directive, VRLA batteries should carry a crossed
wheeled bin symbol with an ISO recycling symbol.

SECTION 16 - OTHER INFORMATION


The above information is believed to be correct but does not purport to be all inclusive and shall be used only
as a guide. RJS Standard Testing & Certification Center shall not be held liable for any damage resulting
from handling or from contact with the above product. See reverse side of invoice or packing slip for
additional terms and conditions of sale. License granted to make unlimited paper copies for internal use
only.

Address: No.18th, Baoqiao Road, Huaxi Industrial Zone of Changxing County, Zhejiang, PRC 313100 5
Telephone: +86-572-6058015 Fax:+86-572-6058015 Website: http://en.cn-tn.com

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