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Synchro Test 15 Paper 2

The document provides instructions for a test targeting JEE Advanced 2022. It contains 4 sections, with Section I having 6 multiple choice questions worth 5 marks each. Section II has 2 groups of 3 linked comprehension questions each worth 3 marks. Section III has multiple choice questions worth 8 marks total, and Section IV has multiple choice questions worth 3 marks each with no negative marking.

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0% found this document useful (0 votes)
251 views14 pages

Synchro Test 15 Paper 2

The document provides instructions for a test targeting JEE Advanced 2022. It contains 4 sections, with Section I having 6 multiple choice questions worth 5 marks each. Section II has 2 groups of 3 linked comprehension questions each worth 3 marks. Section III has multiple choice questions worth 8 marks total, and Section IV has multiple choice questions worth 3 marks each with no negative marking.

Uploaded by

Vinita Jain
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd
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FIITJEE:

FIITJEE INTERNAL TEST


(SYNCHRO TEST-15)
PAPER – II
TARGET: JEE ADVANCE (2022)

Time: 3 Hours Maximum Marks: 237

Please read the instructions carefully.

INSTRUCTIONS

A: General :
1. Immediately fill in the particulars on this page of the Test Booklet with Blue/Black Ball
point pen.
2. Darken the appropriate bubbles with Blue/Black Ball Point Pen only.
3. Blank papers, clipboards, log tables, slide rules, calculators, cellular phones, pagers and
electronic gadgets in any form are not allowed.
4. The answer sheet, a machine-gradable Objective Response Sheet (ORS) is provided
separately.
5. Do not Tamper/mutilate the ORS or this booklet.
6. No additional sheets will be provided for rough work
7. On completion of this test, the candidate must hand over the Answer Sheet to the
Invigilator on duty in the Room/Hall. However, the candidates are allowed to take
away this Test Booklet with them.

B: Questions paper format and Marking Scheme:


1. For each question in Section I, you will be awarded 5 marks if you darken the bubble(s)
corresponding to only the correct answer(s) and zero mark if no bubble is darkened. In
−2) mark will be awarded
case of bubbling of incorrect answer, minus two (−

2. For each question in Section II, you will be awarded 3 marks if you darken the bubble
corresponding to the correct answer and zero mark if no bubble is darkened. In case of
−1) mark will be awarded.
bubbling of incorrect answer, minus one (−

3. For each question in Section III, you will be awarded 2 marks for each row in which you
have darkened the bubble(s) corresponding to the correct answer. Thus, each question in
this section carries a maximum of 8 marks. There is no negative marking for incorrect
answer(s) for this section.

4. For each question in Section IV, you will be awarded 3 marks if you have darken only the
bubble corresponding to the correct answer and zero mark if no bubbles are darkened. No
negative marks will be awarded in this section.

Enrollment No. : Batch :

Name :

Candidate’s Signature Invigilator’s Signature:

FIITJEE Ltd., Ghaziabad Centre


*D -6 & 7, RDC, Raj Nagar, Ghaziabad, 201001. Ph- 0120-2820004/5/6*Uttaranchal Plaza, 23/3, Sector 3, Vasundhara, Ghaziabad, 201012. Ph- 0120-6517311
Email: admissions.gzb@fiitjee.com www.facebook.com/fiitjeeghaziabad/ Web: www.fiitjee.com/ghaziabad/
IITJEE-2022

SECTION – I: MATHEMATICS
(Single Correct Choice Type)

This Section contains 6 MULTIPLE choice questions. Each question has 4 choices (A), (B), (C) and (D), out of which
only ONE is correct.

x x

1. If f ( x ) is non constant differentiable function, f ( x ) ∈ ( 0, π ) and x ∫ sin ( f ( t ) ) dt = ( x + 2 ) ∫ t sin ( f ( t ) ) dt, x > 0 then
0 0

3
find the value of f ' ( x ) cot ( f ( x ) ) + ∀x > 0 is:
1+ x
(A) 0 (B) 1
(C) 2 (D) 3

2. Sides of a triangle ABC are x 2 + y 2 , y 2 + z2 and z 2 + x 2 where x, y, z are non zero real numbers, then area
of triangle ABC is
1 2 2 1 2
(A)
2
x y + y 2z 2 + z 2 x 2 (B)
2
( x + y 2 + z2 )
1 1
(C) ( xy + yz + zx ) (D) ( x + y + z ) x 2 + y 2 + z2
2 2

3. Then sum of all possible products of first n natural numbers taken two at a time is
n ( n + 1)( n − 1)( n − 2 ) n ( n + 1)( n − 1)( 3n + 1)
(A) (B)
24 24
n ( n + 1)( n − 1)( 3n + 2 ) n ( n + 1)( 3n + 1)
(C) (D)
24 6

 y3 
4. (
The solution of the differential equation  2xy + x2 y +  dx + x 2 + y2 dy = 0 is
3
)

3
y y3
(A) x 2 yex − e x = c (B) x 2 yex + e x = c
3 3
y3 x y3 x
(C) x 2 y 2ex + e =c (D) xy 2e x + e =c
3 3

5. If lines 2x + 3y = 10 and 2x − 3y = 10 are tangents at the extremities of its same latus rectum to an ellipse whose
centre is origin, then the length of the latus rectum is
110 98
(A) (B)
27 27
100 120
(C) (D)
27 7

dy x 2 + y 2 + 1
6. The differential equation = represents
dx 2xy
(A) A family of circles with centre on x-axis
(B) A family of circles with centre on y-axis
(C) A family of rectangular hyperbola with centre on x-axis
(D) A family of rectangular hyperbola with centre on y-axis

Space for Rough Work

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Email: admissions.gzb@fiitjee.com www.facebook.com/fiitjeeghaziabad/ Web: www.fiitjee.com/ghaziabad/
IITJEE-2020 SYNCHRO TEST-15_PAPER-23
SECTION − II
(Linked Comprehension Type)
This section contains 2 groups of questions. Each group has 3 multiple choice questions based on a paragraph. Each
question has 4 choices (A), (B), (C) and (D) for its answer, out of which ONLY ONE is correct.

Paragraph for Question Nos. 7 to 9

Consider two sets A = {1, 2, 3, 4, 5} and B = {−2, −1, 0, 1, 2, 3, 4, 5}.

7. The number of functions f: A → B whose domain is A, such that is f is strictly increasing.


(A) 24 (B) 36
(C) 42 (D) 56

8. The number of functions f: A → B whose domain is A such that if x1 ≥ x2 then f(x1) ≥ f(x2) ∀ x1, x2 ∈ A.
(A) 216 (B) 540
(C) 792 (D) 840

9. The number of functions f: A → A whose domain is A such that f(x) is bijective


(A) 120 (B) 24
(C) 720 (D) 840

Paragraph for Question Nos. 10 to 12

Define three integrals I1, I2 and I3 as follows


π/ 2 π/2 π/ 2
x3 cos x dx
I1 = ∫ ,I2 = ∫ x 2 cosec 2 x dx and I3 = ∫ x cot x dx , then
0 3sin x − sin3x 0 0

π3
10. Let I1 = + k 2 π ln 2 , where k1, k2 ∈ Q then k1 and k2 respectively are
k1
3 8
(A) −64, (B) 64,
8 3
1 1
(C) 8, (D) −8,
3 3

11. If I2 = k1 + k2π ln 2, where k1, k2 ∈ Q, then k1, k2 respectively are


(A) 8, 2 (B) 0, 1
(C) 2, 2 (D) −2, 1

12. If I3 = k1 + k2π ln 2 where k1=, k2 ∈ Q, then k1, k2 respectively are


(A) 1, 1 (B) 0, 1
1 1
(C) 0, (D) 0,−
2 2

Space for Rough Work

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Email: admissions.gzb@fiitjee.com www.facebook.com/fiitjeeghaziabad/ Web: www.fiitjee.com/ghaziabad/
IITJEE-2022

SECTION − III

MATRIX-MATCH TYPE

This part contains TWO question. Each question has four statements (A, B, C and D) given in Column I and five
statements (p, q, r, s and t) in Column II. Any given statement in Column I can have correct matching with one or more
statement(s) given in Column II.
For Example, if for a given statement B, darken the bubbles corresponding to q and r in the ORS.

1. Match the following:

Column−
−I Column−
−II
(a) Let D, E, F are the middle points of the sides of scalene triangle ABC. (p) 0
If p = distance between circumcentres of ∆ABC & ∆DEF, q = distance (q) 1
p 3
between circumcentre and centroid of ∆DEF, then = (r)
q 2
(b) In part (A), the distance between centroids of triangles ABC & DEF = (s) 2
λ R (R = radius of circle circumscribing ∆ABC) then λ = (t) 3
(c) In ∆ ABC, median AA1 is perpendicular to side AB, and cos A + cos B
c
= ( λ1b + λ 2a ) , then λ1 + λ2 =
ab
(d) Let H is the orthocenter of ∆ABC and R1, R2, R3 R, are the radii of
circle circumscribing the triangle BHC, CHA, AHB and ABC
respectively then R1 + R2 + R3 = λR, where λ =

2. Match the following:

Column− −I Column−
−II
2 2
(a) Area of region formed by points (x, y) satisfying [x] = [y] for 0 ≤ x ≤ 4 (p) 48
is equal to (where [.] denotes greatest integer function) (q) 27
2 2
(b) The area of region formed by points (x, y) satisfying x + y ≤ 6, x + y (r) 7
2 kπ − 2 (s) 4
≤ 6y and y ≤ 8x is , then k = (t) 3
12
(c) The area in the first quadrant by the curve y = sinx and the line
 2 +1 π
( )
2y − 1 2 3− 2
= ( 6x − π ) is  −  , then k =
2 −1 π  2 k 
 
ax
(d) If the area bounded by the graph of y = xe− (a > 0) and the abscissa
1
axis is then the value of ‘a’ is equal to
9

Space for Rough Work

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IITJEE-2020 SYNCHRO TEST-15_PAPER-25
SECTION − IV

Integer Type

This part contains FIVE questions. The answer to each question is a single integer ranging from 0 to 9. The appropriate
bubbles below the respective question numbers in the ORS have to be darkened.

xk

6 5 4 3 2
1. Let p(x) = 2x + 4x + 3x + 5x + 3x + 4x + 2. Let Ik = ∫ dx ; where 0 < k < 5. Find the value of ‘k’ for which Ik
0
p(x)
is the smallest.


626 ∫ e − x sin25 x dx
2. If ∞
0
= λ . Find the sum of the digits of λ.
∫e
−x 23
sin x dx
0

2 2
3. Tangents are drawn to x + y = 16 from the point P(0, h). These tangents meet the x-axis at A and B. If the area
of triangle PAB is minimum, then [h] = (where [.] denote greatest integer function)

 x sin x ( )
a −b
x>0
4. Let a and b are real numbers, b > 0 and f is defined on [0, 1] by f ( x ) =  . If f′′ is continuous then
 0 x=0
number of integral values of a − 2b in interval [0, 10] is

x3 x 2 x4 11x 2
5. Let f ( x ) = + + x + 2; g ( x ) = − 2x 3 + − 6x then f(g(x)) has local minima at x1 and x2, find the value
3 2 4 2
of x1 + x2

Space for Rough Work

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Email: admissions.gzb@fiitjee.com www.facebook.com/fiitjeeghaziabad/ Web: www.fiitjee.com/ghaziabad/
IITJEE-2022

SECTION – II: PHYSICS


(Single Correct Choice Type)

This Section contains 6 MULTIPLE choice questions. Each question has 4 choices (A), (B), (C) and (D), out of which
only ONE is correct.

1. A large insulating thick sheet of thickness 2d carries a uniform charge per unit volume ρ. A particle of mass m,
carrying a charge q having a sign opposite to that of the sheet, is released from the surface of the sheet. The
sheet does not offer any mechanical resistance to the motion of the particle. Find the oscillation frequency ν of the
particle inside the sheet
1 qρ 1 2q ρ
(A) ν = (B) ν =
2π m ε 0 2π m ε 0
1 qρ 1 2q ρ
(C) ν= (D) ν=
4 π mε 0 4 π mε 0

2. The coil of a heater has resistance of 5Ω and is supplied from a source of internal resistance 20Ω. With what
resistance should the coil be shunted to reduce the amount of power dissipated in it to one ninth of the value
without shunt?
(A) 2Ω (B) 4Ω
(C) 1Ω (D) 3Ω

3. In a vernier calipers having 10 vsd, the least count is 0.1 mm. when the jaws are closed, zero of vernier lies to the
th
left of zero of main and 7 vsd coincides with a main scale division. When a cylinder is placed between the jaws
the main scale reading was 7.7 cm and vernier scale read 8 divisions. What is the diameter of the cylinder?
(A) 78.1 mm (B) 77.5 mm
(C) 77.8 mm (D) 78.5 mm

57
4. The mass of 27 Co :56.936296u; 57
26Fe :56.935399u are given. Two possible nuclear reactions are proposed
57
(i) 27 Co → 57 0
26 Fe + +1 e + γ (positron emission) (ii) 57
27 Co + −01 e → 26
57
Fe + γ (K-shell capture)
1
Of these two reactions. Mass of e = u and γ is neutrino.
1840
(A) (i) is possible but (ii) is not possible (B) (i) is not possible but (ii) is possible
(C) both are possible (D) None of the reactions is possible

5. A long thin walled pipe of radius R carries a current I along its length. The current density is
uniform over the circumference of the pipe. The magnetic field at the centre of the pipe due
to a quarter portion of the pipe shown, is
µoI 2 µ0 I
(A) (B)
2
4π R π2 R
2µ 0I 2
(C) (D) None
π2 R

6. A massless spring of spring constant k is vertically mounted so that bottom end is firmly attached to the ground,
and the top end free. A ball with mass m falls vertically down with speed v on the top and of the spring and gets
attached, so that the ball oscillates vertically on the spring. What equation describes the acceleration a of the ball
when it is a height y above the original position of the top end of the spring? Let down be negative, and neglect air
resistance; g is the magnitude of the acceleration of free fall.
 2k   2k 
(A) a = −  y + g (B) a = −   y + 2g
m m
 2k  k
(C) a = −  y (D) a = −   y − g
 m  m

Space for Rough Work

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Email: admissions.gzb@fiitjee.com www.facebook.com/fiitjeeghaziabad/ Web: www.fiitjee.com/ghaziabad/
IITJEE-2020 SYNCHRO TEST-15_PAPER-27
SECTION − II
(Linked Comprehension Type)
This section contains 2 groups of questions. Each group has 3 multiple choice questions based on a paragraph. Each
question has 4 choices (A), (B), (C) and (D) for its answer, out of which ONLY ONE is correct.

Paragraph for Question Nos. 7 to 9

In a Tabla, 2-Dimensional stationary transverse waves having circular symmetry are set up in the circular membrane by
tapping a finger-tip at the centre of the membrane. It is found that the wave pattern corresponds to the second overtone.

7. As we move across a diameter of the membrane, how many nodes will be encountered, excluding the nodes at
the rim of the membrane?
(A) Zero (B) 2
(C) 4 (D) 6

8. In the above question, which harmonic does the situation correspond to?
(A) third (B) second
(C) fourth (D) fifth

9. In the above situation the radius of the circular membrane is R. The circular membrane is simultaneously tapped
at two points, at the center and at a point located at a distance 4R/7 from the center. Which value of wavelength
of the standing waves set up is not possible?
4R 8R
(A) (B)
7 21
2R
(C) (D) None
7

Paragraph for Question Nos. 10 to 12

All objects referred to, in the subsequent problems lie on the principal axis

Air Air

Water
Surface 1 Surface 2

10. If light is incident on surface 1 from left, the image formed after first refraction is definitely
(A) Real for a real object (B) Virtual for a real object
(C) Real for a virtual object (D) Virtual for a virtual object

11. In above question, if the object is real, then the final image formed after two refractions
(A) Must be real (B) May be virtual or real
(C) Must be virtual (D) None of these

12. If light is incident on surface 2 from right then which of the following is true for image formed after a single
refraction
(A) Real object will result in a real image (B) Virtual object will result in a virtual image
(C) Real object will result in a virtual image (D) Virtual object will result in a real image

Space for Rough Work

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Email: admissions.gzb@fiitjee.com www.facebook.com/fiitjeeghaziabad/ Web: www.fiitjee.com/ghaziabad/
IITJEE-2022

SECTION − III

MATRIX-MATCH TYPE

This part contains TWO question. Each question has four statements (A, B, C and D) given in Column I and five
statements (p, q, r, s and t) in Column II. Any given statement in Column I can have correct matching with one or more
statement(s) given in Column II.
For Example, if for a given statement B, darken the bubbles corresponding to q and r in the ORS.

1. Some AC circuits are given below, i and V are current and supply voltage of circuit.

Column−I Column−II
(p) Current leads supply voltage
(q) Current lag behind supply voltage
(a) (r) Current and supply voltage are in same phase
(s) On increasing frequency of supply emf, current
decreases
(t) On increasing frequency of supply emf, current
increase

(b)

(c)

(d)

Space for Rough Work

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IITJEE-2020 SYNCHRO TEST-15_PAPER-29

2. Consider a system of two starts of mass m1 & m2. The only force acting on them is mutual gravitational attraction.

Column−I Column−II
m (p) 1/2
(a) COM of the stars is stationary and both move on exactly the same path. Then 1 = (q) 1
m2
(r) 2
(b) 2m1 = m2 and COM of the stars is stationary. Stars undergo orbital motion about their (s) 3
COM. Then ratio of orbital speed of star of mass m1 to that of star of mass m2 is = (t) None
(c) m1 = m2. Initially, both stars were stationary and their centres were distance d apart.
At time t = 0, one of the stars is imparted a velocity v perpendicular to line joining their
centres. Now stars start moving (in COM frame) at time t = 0 on circular paths with
v 2d
centres on their COM, then =
4Gm1
(d) m1 = m2. Both stars were stationary and their centres were distance d apart at time t =
0. Now first is imparted a velocity v perpendicular to the line joining their centres and
the second also is imparted same velocity v in opposite direction. Now stars start
v 2d
moving on circular paths (in COM frame) with centres on their COM, then =
6Gm1

Space for Rough Work

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Email: admissions.gzb@fiitjee.com www.facebook.com/fiitjeeghaziabad/ Web: www.fiitjee.com/ghaziabad/
IITJEE-2022

SECTION − IV

Integer Type

This part contains FIVE questions. The answer to each question is a single integer ranging from 0 to 9. The appropriate
bubbles below the respective question numbers in the ORS have to be darkened.

2
1. A steel wire of length 2.0 m is stretched through 0.2 mm. The cross-sectional area of the wire is 4.0 mm . Find the
elastic potential energy stored in the wire (in milli joule)
(Young’s moudlus for steel is 200 GPa)
o
2. 100 gm ice at 0 C is mixed in a thermally insulated container of water equivalent 100 g, containing 300 g water at
o o
30 C. Find the final temperature of system (in C). Given latent heat of fusion of ice is 80 cal/gm.

3. In the figure shown a small block B of mass m is released from the


top of a smooth movable wedge A of the same mass m. The height
of wedge A shown in figure is h = 100 cm. B ascends another
movable smooth wedge C of the same mass. Neglecting friction any
where if the maximum height (in cm) attained by block B on wedge C
100
is cm, then value of x is.
x
4. A particle is dropped along the axis from a height f/2 on a concave mirror of focal length f
as shown in the figure. The acceleration due to gravity is f. Find the maximum speed of
image. (Take f = 4.8 m)

5. In the circuit shown, all voltmeters and ammeter are ideal. The internal resistance of battery is 2Ω. The reading of
voltmeter and ammeter are marked in the figure. What is resistance R2 (in ohm)?

Space for Rough Work

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IITJEE-2020 SYNCHRO TEST-15_PAPER-211

SECTION – III: CHEMISTRY


(Single Correct Choice Type)

This Section contains 6 MULTIPLE choice questions. Each question has 4 choices (A), (B), (C) and (D), out of which
only ONE is correct.

4 3
1. The EMF of cell, Ag(s) |Agl(s)| KI (aq., 2.5 × 10− M)|| AgNO3 (aq., 4 × 10− M)| ag(s) is 0.591 V. What is the value
o
of pKsp for Agl at 25 C?
(A) 14 (B) 15
(C) 16 (D) None of these

2. Predict the final products of the two reactions given below

Reaction − I:

Reaction − II:

(A)

(B)

(C)

(D)

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IITJEE-2022

3. When excess KCN solution is added into aqueous solution of following metal cation, then cation which form inner
orbital complex having magnetic moment = 1.732 BM is
2+ 2+
(A) Co (aq) (B) Cr (aq)
2+ ++
(C) Ni (aq) (D) Cu (aq)

4. When 6 gm of AB (salt of weak base & strong acid) is dissolved in water and formed 10 litre solution, pH of
solution is 5. Crystalline solid AB (d = 3.2 g/cc.) has rocksalt type structure. What is the shortest distance between
cation and anion in AB (in Å)?
6 23
Given: Kb (AOH) = 10− ; NA = 6 × 10
(A) 2.5 (B) 3.53
(C) 5 (D) None of these

5. 1 mole of HI(g) filled in a one-litre bulb were allowed to react. When the reaction attained equilibrium, one-third of
HI(g) is converted to H2(g) and I2(g). If a hole is made in the bulb then the mole ratio of the gases HI, H2 & I2
effusing out at equilibrium would be respectively
4 1 1
(A) 128 : 2 : 254 (B) : :
128 2 254
1 1 1
(C) : : (D) None of these
128 2 2 127

6. Attainment of the equilibrium A ( g ) ↽


 2C ( g) + B ( g) gave the following of graph. Find the correct option(s).


2
(A) Equilibrium const. KC for above reaction is 128 M (B) At equilibrium % dissociation of A is 40%
(C) At equilibrium % dissociation of A is 30% (D) None of these

SECTION − II
(Linked Comprehension Type)
This section contains 2 groups of questions. Each group has 3 multiple choice questions based on a paragraph. Each
question has 4 choices (A), (B), (C) and (D) for its answer, out of which ONLY ONE is correct.

Paragraph for Question Nos. 7 to 9

Compound (P), C6H12O2, was found to be optically active, and was slowly oxidized to an optically active carboxylic acid
+
(q), C6H12O3, by Ag (NH3)2. Oxidation of (p) by anhydrous CrO3 gave an optically inactive compound that reacted with
Zn amalgam/HCl to give 3-methyl pentane. With aqueous H2CrO4, compound (P) was oxidized to an optically inactive
dicarboxylic acid (R) C6H10O4.

7. Structure for compound (P):


(A) HOCH2 − CH2 − C H − CH2 − CH = O (B) HOCH2 − CH2 − CH2 − CH2 − CH2 − CH = O
|
CH3

OH O O
| || ||
(C) H3C − CH − C H − C − CH3 (D) HO 2HC − CH2− C H − C − CH3
| |
CH3 CH
3

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IITJEE-2020 SYNCHRO TEST-15_PAPER-213
8. Structures for compound (Q) & (R) are respectively:
O O O
|| || ||
(A) ( Q ) = HOCH2CH2− C H − CH2 − C − OH; (R) = HO − C − CH2 − C H − CH2 − C − OH
| |
CH3 CH3

O O O
|| || ||
(B) ( Q ) = HOCH2− C H − CH2 CH2 − C − OH; (R) = HO − C − CH2 − C H − CH2 − C − OH
| |
CH3 CH3
O O O
|| || ||
(C) ( Q ) = HOCH2CH2 − CH2 − CH2CH2 − C − OH ; (R) = HO − C − CH2 − CH2 − C H − C − OH
|
CH3
O O O
|| || ||
(D) ( Q ) = HOCH2CH2− C H − CH2 − C − OH; (R) = HO − C − CH2 − CH2 −C H − C − OH
| |
CH3 CH3

9. Compound (Q) can be formed by saponification of which of the following cyclic ester?
O O

(A) H3C (B)


O O

H3C

H3C O
O
(C) (D)

O
H3C

Paragraph for Question Nos. 10 to 12


3 3
A rigid and insulated tank of 3 m volume is divided into two compartments. One compartment of volume of 1m contains
3
an ideal gas at 0.8314 MPa (Mega pascal) and 400 K and while the second compartment of volume 2 m contains the
same gas at 8.314 MPa and 1000 K. If the partition between the two compartments is ruptured.

10. For above process


(A) only q = 0 (B) only w = 0
(C) only ∆U = 0 (D) all are zero

11. What is the final temperature of the gas?


(A) 250 K (B) 333.333 K
(C) 933.333 K (D) None of these

12. What is the final pressure of the gas?


(A) 17.457 MPa (B) 5.819 MPa
(C) 5.173 MPa (D) None of these

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IITJEE-2022

SECTION − III

MATRIX-MATCH TYPE

This part contains TWO question. Each question has four statements (A, B, C and D) given in Column I and five
statements (p, q, r, s and t) in Column II. Any given statement in Column I can have correct matching with one or more
statement(s) given in Column II.
For Example, if for a given statement B, darken the bubbles corresponding to q and r in the ORS.

1. Specify the relationship(s) of the compounds in each of the following sets given in column−I with column−II:

Column−I Column−II
(a) α − D − glucopyranose and β − D − glucopyranose (p) Epimers
(b) β − D − mannopyranose and β − L − mannopyranose (q) Anomers
(c) Aldehyde form of D−glucose and α−D−glucopyranose (r) Enantiomers
(d) α−D−manopyranose and α−D−glucopyranose (s) Diastereomers
(t) Constitutional isomers

2. Match the following:

Column−I (Acidic Radical) Column−II (Characteristics)


(a) NO3 − (aq) (p) Coloured gas is evolved on adding conc. H2SO4
(b) C2O24− ( aq) (q) Acidified KMnO4 solution is decolourized
(r) Gives purple colour with sodium nitroprusside
(c) S2− ( aq) (s) Give precipitate with AgNO3 solution
(t) Evolves NH3 gas with (Zn + conc. NaOH) reagent
(d) NO 2 − ( aq )

SECTION − IV

Integer Type

This part contains FIVE questions. The answer to each question is a single integer ranging from 0 to 9. The appropriate
bubbles below the respective question numbers in the ORS have to be darkened.

1. A 60 ml sample solution of KI was electrolysed for 579 sec using a 5 amp constant current. The I2 produced,
completely reacted with 0.20 M sodium thiosulphate solution and unreacted KI solution required 30 ml of 0.04 M
1
acidic solution of KMnO4. If the original molarity of KI solution can be expressed in scientific notation as Y × 10− .
calculate the value of Y.

2. Calculate difference between oxidation state of chromium (Cr) in blue and green coloured chromium species
formed during the following given transformation.
+
H2O 2 /H
CrO24− ( aq)  on s tanding
→ Blue solution  → Green solution

3. The count rate of a 10 ml radioactive liquid is C. Some of this liquid is now discarded. The count rate of the
remaining liquid is found to be C/10 after three half-lives. Calculate volume of remaining liquid (in mL)

4. The resistance of a 0.1 M solution of acetic acid in a cell was found to be 600 Ω. What is the % degree of
ionization of CH3COOH at this concentration?
1
Given cell constant = 0.936 cm−
ΛM∞ (HCl) = 426 Scm2 mol−1 ; ΛM∞ (NaCl) = 126 Scm2mol−1 ; ΛM∞ ( CH3COONa) = 90 Scm2 mol−1

5. How many boron atoms are present in the compound (Y) formed in the following sequence of reactions.
A ℓ +NaOH o
( ) B 2 H6 +
200 C −
NaNO 2  → ( X ) gas  → [BH2 X 2 ] [BH4 ] → ( Y ) compound

Space for Rough Work

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