RM-1 CPP 24 Physics Chemistry 2021
RM-1 CPP 24 Physics Chemistry 2021
REGULAR
MEDICAL-2021-22
Physics
Chapterwise Practise Problems (CPP) for NEET
Chapter - Wave Optics
1. The light waves having wave equations y 1 = 7. In Youngs double slit experiment, if the widths of
10Sin(t – kx) and y2 = 5Sin(kx – t + ) interfere. the slit are in the ratio 4:9, ratio of intensity of
The ratio of maximum to the minimum intensity of maxima to intensity of minima will be (width of slit
light in the interference pattern is is directly proportional to amplitude of interfering
waves)
(1) 9 : 1 (2) 3 : 1
(1) 25 : 1 (2) 9 : 4
(3) 2 : 1 (4) 81 : 1
2. First diffraction minima due to slit of width 1.0 × 10– (3) 3 : 2 (4) 81 : 16
5cm is at 30°. Then wavelength of light used is
8. In a YDSE how many maxima can be obtained on
(1) 400Å (2) 500Å screen (excluding central maxima) on both sides of
central fringe if = 2000Å and d = 7000Å?
(3) 600Å (4) 700Å
(1) 12 (2) 6
3. When white light is incident normally on an oil film
of thickness 10–4 cm and refractive index 1.4 then (3) 18 (4) 9
the wavelength which will be seen in the reflected
system of light 9. In the far field diffraction pattern of a single slit under
polychromatic illumination, the first dark fringe of
(1) 7000Å (2) 8000Å wavelength 1 is found to be coincident with the
(3) 5600Å (4) All of these third bright fringe of 2. Which of the following is
correct?
4. For what distance is ray optics a good
approximation when a plane light wave is incident (1) 31 = 0.32 (2) 61 = 2
on a slit aperture of width 2mm having wavelength (3) 1 = 3.52 (4) 62 = 1
600nm ?
10. A light has amplitude A after coming out from
(1) 6m (2) 8m
polariser. Angle between transmission axis of
(3) 6.7m (4) 4m analyser and polariser is 60°. Light passing through
analyser has amplitude
5. What is the approximate radius of the central bright
diffraction spot of light of wavelength = 0.5µm, if
A
focal length of the lens is 20cm and radius of (1) 2A (2)
2
aperture of the lens is 5cm?
(1) 1.22µm (2) 2.30µm
3A A
(3) 4.22µm (4) 6.23µm (3) (4)
2 2
6. An unpolarized light passes through 2 polarizer. If
the intensity of the transmitted light is 20% that of 11. The diameter of the objective lens of a telescope is
the original light, what is the angle between the 5.0 m and wavelength of light is 6000Å. The limit of
transmission axes of the 2 polarizing sheets ? resolution of this telescope will be (1° = 3600)
(1)
(1)
Wave Optics Aakash Institute
12. Huygens’ principle of secondary wavelets may not
1.22 a
be used to (1) (2)
a 1.22
(1) Find the new position of a wavefront
(2) Explain Snell’s law m a
(3) (4)
1.22a 1.22m
(3) Explain laws of reflection
(4) Explain particle behaviour of light 19. A beam of unpolarised light passes through a
tourmaline crystal A and then it passes through a
13. It is found that when waves from two identical second tourmaline crystal B oriented so that its
coherent sources superpose at certain point with principal is parallel to that of A. The intensity of the
same individual intensity, then the resultant emergent light is Io. Now B is rotated by 45° about
intensity is equal to the intensity of one wave only. the ray. The emergent light have intensity
This means that phase difference between the two
waves at that point is Io Io
(1) (2)
(1) Zero (2) /3 4 2
(2)
Aakash Institute Wave Optics
24. A light of wavelength 5000Å is coming from distant illuminated by the light of wavelength 6000 Å. If slit
star. What is the limit of resolution of a telescope is illuminated by light of another wavelength angular
whose objective has a diameter of 200cm ? width decreases by 30% wavelength of light used
(1) 3.05 × 10–7rad (2) 6.6 × 10–7rad is
(1) 3500 Å (2) 4200 Å
(3) 8 × 10–7rad (4) 2.23 × 10–7rad
(3) 4700 Å (4) 6000 Å
25. A poloroid sheet and an analyzer are placed such 30. A person with normal vision can just resolve two
that their transmission axes are parallel. The poles separated by a distance of 10m. If the limit
analyzer is then rotated by 22.5°. W hat is the of resolution be 1, then the distance of the poles
intensity of the transmitted light as a fraction of from the person is
intensity of light incident on analyser ?
(1) 34 km (2) 3.4 km
(1) 0.45 (2) 0.68 (3) 34 m (4) 3.4 m
(3) 0.41 (4) 0.87 31. A ray of light is incident on the surface of a glass
26. The observed wavelength of light coming from a plate of refractive index 3 at the polarising angle.
distant galaxy is found to increase by 0.5% as The angle of refraction is
compared with that coming from a terrestrial source. (1) 60° (2) 30°
The galaxy is
(3) 45° (4) 50°
(1) Stationary with respect to earth 32. When a thin film is illuminated by a parallel beam
(2) Approaching earth with a velocity of 1.5 × of light of wavelength 6000 Å,
106 m/s 7 fringes are observed in a certain region of the
film. How many fringes will be observed in the
(3) Receding from earth with velocity of light same region of the film if light of wavelength 4200
(4) Receding from earth with a velocity equal to 1.5 Å is used?
× 106 m/s (1) 6 (2) 10
(3) 14 (4) 18
27. In young double slit experiment, D equals the
33. Young’s double slit experiment is performed with
distance of screen from slits and d is the separation
light of wavelength 5000 Å. If a glass plate of
between the slits. The distance of the nearest point
thickness 1 m and refractive index 1.5 is kept in
to the central maxima where intensity is same as
front of one of the slits, then number of fringes that
that due to a single slit, is equal to
passes through the field of view, is
D D (1) 1 (2) 2
(1) (2)
d 2d (3) 3 (4) 4
34. In YDSE, distance between two slits is 4 mm, D
D 2D = 1 m and = 12000 Å. If intensity of coherent
(3) (4)
3d d light from two slits are I0 and 16 I0 , then find
28. Consider the arrangement shown in figure. The intensity at y = 0.1 mm, on the screen
distance D is large compared to the seperation d (1) 7 I0 (2) 10 I0
between the slits. A monochromatic beam of light (3) 13 I0 (4) 16 I0
of wavelength ‘’ falls on the slit as shown. Find the
distance x at which the first order bright fringe is 35. Two polarising sheets are placed with their planes
formed parallel, so that light intensity transmitted is
maximum. Through what angle must either sheet
P
be turned so that light intensity drops to half the
x maximum value?
Incident d
O
ray (1) 30° (2) 45°
(3) 60° (4) 90°
D screen I1
D
36. The intensity ratio of the two interfering waves
D 2 D I2
(1) (2)
d d
Imax
in a Young’s experiment is 4. The ratio in
3 D D d 2
Imin
(3) (4)
2 d d resulting wave is
29. Angular width of central maximum in the (1) 4 : 1 (2) 2 : 1
Fraunhoffer’s diffraction pattern is measured. Slit is (3) 3 : 1 (4) 9 : 1
(3)
Wave Optics Aakash Institute
37. When angle of incidence on a material is 60°, the
reflected light is completely polarized. The velocity 1 1
of the refracted ray inside the material is,
(1) 3,sin1 3 (2)
3
,sin1
3
(4)
Aakash Institute Wave Optics
D2 d2 2
(1) (2) (1) (2) 2
2d 2D 1
D2 d2 2 1
(3) (4) (3) (4)
d D 1 2
48. A parallel beam of mono chromatic light of
wavelength 5000 A° is incident normally on a single 55. Light from a sodium lamp = 590 nm is diffracted by
narrow slit of width 0.001 mm. The light is focused a slit of width d = 0.30 mm. The distance from the slit
by a convex lens on a screen placed on the focal to the screen is D = 0.87 m. The width of central
plane. The first minimum will be formed for the maxima will be
angle of diffraction equal to
(1) 3.9 mm (2) 3.4 mm
(1) 30° (2) 60°
(3) 15° (4) 0° (3) 3.0 mm (4) 4 mm
49. A telescope, whose objective lens has an aperture 56. In an electron microscope if the potential is increased
of 1mm for the wavelength of light 500Å, then limit from 20 KV to 80 KV, the resolving power of the
of resolution of the telescope is: microscope will change from R to
(1) 2.1 × 10–4 rad (2) 4.1 × 10–4 rad
–4
(3) 5.1 × 10 rad (4) 6.1 × 10–4 rad R
(1) (2) 4R
50. A ray of light is incident on a glass plate at the 4
polarising angle 57°. Then (Given = tan57°)
R
(1) The reflected ray and transmitted ray both will (3) 2R (4)
be completely polarised 2
(2) The reflected ray will be completely polarised 57. A beam of light strikes a piece of glass at an angle of
and the transmitted ray will be partially incidence 60° and the refracted beam is completely
polarised plane polarised. The refractive index of the glass is
(3) The reflected ray will be partially polarised and
the transmitted ray will be completely polarised. (1) 1.5 (2) 3
(4) The reflected and transmitted both rays will be
partially polarised 3
(3) 2 (4)
51. Which of the following phenomena is not explained 2
by Huygen’s construction of wavefront. 58. A star is going away from the earth. Then it shows
(1) Refraction (2) Reflection (1) Red shift (2) Blue shift
(3) Diffraction (4) Origin of spectrum
(3) Yellow shift (4) Green shift
52. The equivalent path length in air for thickness t of
a medium of refractive index is 59. Two light sources are coherent when
(5)
Wave Optics Aakash Institute
61. Two slits are separated by a distance of 1 mm are (3) 12.5 mm (4) 6 mm
illuminated with red light of wavelength 6.5×10–7 m.
The interference fringes are observed on a screen
68. If two waves y1 3 sin t and y2 = 3cos
placed 1m from the slits. The distance between the 3
third dark fringe and the fifth bright fringe is equal to
t interfere at a point, then the amplitude of
(1) 0.65 mm (2) 1.63 mm resulting wave will be
(1) 5.8 (2) 2.7
(3) 3.25 mm (4) 4.88 mm
(3) 4.6 (4) 6.8
62. If the screen (in YDSE) is perpendicular to y-axis
(line joining the sources), i.e., x–z plane, the fringes 69. A single slit of width 12 × 10–5 cm is illuminated
will be with light of wavelength 6000 Å. Angular width of
central maxima is
(1) Hyperbolic (2) Straight
(1) 2 rad (2) 3 rad
(3) Circular (4) Parabolic
(3) 1 rad (4) 8 rad
63. Choose the correct statement
70. An ordinary light has amplitude A and angle
(1) In interference and diffraction the width of all between the axes of polariser and analyser is 60°.
maximas are equal Light emerging from the analyser has amplitude of
(6)
Aakash Institute Wave Optics
76. In Young’s double slit experiment two slit are d 78. When the light is incident at the polarizing angle on
distance apart. Interference pattern is observed on the transparent medium then the completely
screen at a distance D from the plane of slit. A polarized light is
bright is observed on the screen directly opposite (1) Refracted light
to one of the slits. The wavelength of light is
(2) Reflected light
2 2
D d (3) Refracted and reflected light
(1) (2)
2d 2D (4) Neither Reflected nor Refracted light
79. The first diffraction minimum due to a single slit
D2 d2 diffraction is at angle = 30° for a light of
(3) (4)
d D wavelenth 5000A°. The width of the slit is
77. A plate of thickness t made of a material of (1) 5 × 10–5cm (2) 1 × 10–4cm
refractive index µ is placed infront of one of the slit (3) 2.5 × 10–4cm (4) 1.25 × 10–5cm
in a double slit experiment. What should be the
minimum thickness t which will make the intensity
at the centre of fringe pattern zero.
( 1)
(1) (2) (µ – 1)
2
(3) 2 1 (4)
1
(7)
Wave Optics Aakash Institute
CPP-24 FOR
REGULAR
MEDICAL-2021-22
ANSWERS
8. (2) 9. (3) 10. (4) 11. (1) 12. (4) 13. (3) 14. (2)
15. (2) 16. (1) 17. (1) 18. (2) 19. (2) 20. (2) 21. (4)
22. (4) 23. (1) 24. (1) 25. (4) 26. (4) 27. (3) 28. (4)
29. (2) 30. (1) 31. (2) 32. (2) 33. (1) 34. (3) 35. (2)
36. (4) 37. (2) 38. (3) 39. (1) 40. (3) 41. (3) 42. (4)
43. (1) 44. (2) 45. (2) 46. (2) 47. (4) 48. (1) 49. (4)
50. (2) 51. (4) 52. (1) 53. (2) 54. (1) 55. (2) 56. (3)
57. (2) 58. (1) 59. (4) 60. (3) 61. (2) 62. (3) 63. (3)
64. (3) 65. (3) 66. (1) 67. (1) 68. (3) 69. (3) 70. (3)
71. (2) 72. (3) 73. (2) 74. (3) 75. (2) 76. (2) 77. (3)
(8)
CPP-24 FOR
REGULAR
MEDICAL-2021-22
Chemistry
Chapterwise Practise Problems (CPP) for NEET
Chapter - Aldehydes, Ketones and Carboxylic acids
1. x
CH3 CH CH CH2OH CH3 CH CH CHO
(1) (2) OH
Select the correct oxidising agent among the OH
following
(1) PCC (2) KMnO4 / OH(–) (3) (4)
(3) K2Cr2O7 / H+ (4) Conc. HNO3
2. The product of the following reaction will be 7. The product for the following reaction will be
O O
P2O5 /
CH3 C Product
OH C
OH
O O (i) NaBH4
Cyclic
(1) CH C (2) CH2 – C – H (ii) H + /H 2O Product
CH 3 CH3 C
3
H
O
O O
NO2 Product is
NO2
O
I II III IV
O
(1) IV > II > III > I (2) II > III > IV > I
(1) (2)
(3) II > IV > III > I (4) I > II > III > IV
()
5. HCN
Acetaldehyde X
H /H2 O
Y
O O
The product Y is
O
(1) Tartaric acid (2) Lactic acid (3) (4)
(3) Malonic acid (4) Adipic acid OH
O O
H2 SO5 C CH2 CH 3
10.
Major
CH 3
Reduction
14.
O O
11. In Cannizzaro’s reaction, the intermediate that will
(1) C (2) C
be the best hydride donor is - C2 H5 C2H5 CH3 H
H
H O OH
–
– O (3) (4)
O C
O– H H CH3 – CH 2
(1) OH (2) O2N
16. For the reaction
H OH
H
O
–
MnO2 A (major), A is
O–
– O–
(3) O (4) H3C
O
O
O (1) O (2)
C
Cl
(i) CH3 MgBr
12.
(ii) H( ) /H2 O
Product
(1 mol) O
OH OH
(3) (4)
Number of moles of CH3MgBr required
(1) 2 (2) 3
17. Consider the following sequence of reactions
(3) 4 (4) 5
CH3
RCO3H H3O+
(–) A B
13. The correct order of reactivity with HCN / OH
addition, among the following will be The product B in the above sequence is
O O CH3 OH
O
C H C (1) OH (2)
CH3
H C
CH 3
OH OH
O2 N MeO
NO2
OH OCH3
I II III
CH3
(1) I > II > III (2) II > I > III (3) (4)
OH OH
(3) III > I > II (4) III > II > I
(2)
Aakash Institute Aldehydes, Ketones and Carboxylic acids
18. W hich of the following will give Cannizaro’s 23. Acetone on distillation with conc.H2 SO4 gives
reaction ?
(1) Xylene (2) Phorone
(1) CH3 – CHO (2) H – CHO
CH3 (3) Mesitylene (4) Mesityl oxide
(3) CH3–CH–CHO (4) Both (2) and (3)
19. Consider the following reaction sequence 24. NO2 CHO + (C 6 H 5 – CH 2 CO) 2 O
OH
C6H5 CH2COONa
X, X will be
–
PCC OH (aq)
A B (1) C6H5 – CH = CH – COOH
The final product B is
(2) NO2 CH = CH – COOH
O O
(1) (2)
(3) NO2 CH = C – COOH
O O C6H5
(3) (4)
(4) C6H5 – CH = C – COOH
20. Consider the following sequence of reaction
O NO2
NH2–OH H2SO4
A B 25. Which of the following compounds will give aldol
(pH=4.5) condensation ?
Which of the following is incorrect regarding the (1) CH3 – CH = CH – CHO
above reaction sequence ?
(1) The product A is cyclohexanone oxime CH = CH –CHO
(2)
(2) The product B is a cyclic amide
(3) The conversion of A to B is known as Benzoin O
condensation
(3) Ph – C – Ph
(4) The conversion of A to B is known as
Beckmann rearrangement O
H3C
21. Which of the following statements is incorrect ? (4) C – CH – C – CPh3
H3C
(1) Aldehydes impart magenta color to Schiff’s
reagent 26. Which of the following compound does not give
Cannizzaro reaction ?
(2) Sterically hindered ketones do not produce
bisulfite addition product (1) C6H5COCHO (2) CHO–CHO
(3) Benzaldehyde responds to Fehling’s test
(3) CCl3CHO (4) HCHO
(4) Formic acid reduces with Tollen’s reagent
22. Which of the following is incorrect ? 27. Which of the following species acts as Nucleophile
during Benzoin condensation ?
(1) Phenyl or aryl sulfonyl chloride is known as
Hinsberg’s reagent (1) : CN
(2) Sulfonamides are produced when Hinsberg’s ••–
••O
reagent reacts with 1° or 2° amine
(2) C6H5 – C – CN
(3) 3° amines produce a sulfonamide which H
dissolves in alkali
OH
(4) Sulfonamides of 2° amines are insoluble in
alkali (3) C6H5 – C – CN
••
(3)
Aldehydes, Ketones and Carboxylic acids Aakash Institute
O O O
(i) Zn CF3COOOH
28. R – C – H + R – CH – C – OR Product 32. CH3 – CH – C – CH2 – CH3 Product
(ii) H3O+
Br CH3
aldehyde -bromoester
Product is
Product is
O
(1) - hydroxy ester
(1) CH3 – CH – O – C – O – CH2 – CH3
(2) - hydroxy ester
CH3
(3) - unsaturated ester
(4) - haloketone O
29. Which of the following reactions can take place ? (2) CH3 – CH2 – C – O – CH – CH3
CH3
R
(1) C=O + NH 2 – NH 2 O
H (3) CH3 – C – OC(CH3)3
R
basic medium
C = N – NH2
H (4) CH 3 – CH – C – CH – CH 3
R CH 3 CF3
(2) – NH 2 strong acidic medium
C = O + NH2
H 33. Which reaction is used for the preparation of -
chloroacetic acid ?
R
C = N – NH2 (1) Perkin reaction
H
(2) Stephens reaction
R
(3) C = O + NH2 – NH 2 weak acidic medium
(3) HVZ reaction
H (4) Gatlerman-koch reaction
R
C = N – NH2 (i) Mg/ether
H 34. CH2 = CH – Br X. Identify X
(ii) CO2
+
(iii) H3O
(4) All of these (1) CH3 – CH2 – COOH
30. A compound C 4 H 10 O on oxidation forms a (2) CH3CHO
compound, C 4 H 8 O which gives an oxime and a (3) HCHO
positive iodoform test. The original compound on
treatment with conc.H 2 SO 4 give C 4 H 8 . The (4) CH2 = CH – COOH
structure of compound is O
(1) CH3 – CH2 – CH2 – CH2 – OH 35. R
CH2 = CH – CH2 – OH CH2 = CH – C – H
(2) (CH3)3COH
best reagent R will be
(3) CH3 – CHOH – CH2 – CH3
(1) MnO2/CH2Cl2 (2) K2Cr2O7 / H+
(4) CH3 – CH2 – O – CH2 – CH3
(3) KMnO4 / H+ (4) OsO4/NaHSO3
COOH
36. Which of Carbonyl compound gives tertiary alcohol
OH with Grignard reagent followed by acidic hydrolysis?
31. + (CH3CO)2O Product
(1) Formaldehyde (2) Acetaldehyde
(3) Acetone (4) Methyl formate
UPAC name of product is
(1) Phenyl salicylate 37. Formic acid does not react with
(2) Ortho salicylate benzoic acid (1) Tollen’s reagent (2) Fehling Solution
(3) 2-Acetoxybenzoic acid (3) HCN (4) NaHCO3
(4) Oil of wintergreen
(4)
Aakash Institute Aldehydes, Ketones and Carboxylic acids
COOH 42. The most suitable reagent for the given conversion
COOH is
Cl O
38. (i) (ii)
R—CH2OHR—C—H
Cl (1) KMnO4 , H2SO4 (2) K2Cr2O7 , H2SO4
+ –
COOH COOH NH CrO3Cl
(3) CrO3, H2SO4 (4)
(iii) (iv)
O
Cl
NaCN
Decreasing order of Acidic strength is 43.
HCl
x , (x) is
(1) (i) > (iii) > (ii) > (iv) (2) (i) > (ii) > (iii) > (iv)
(3) (iii) > (ii) > (i) > (iv) (4) (iii) > (i) > (iv) > (ii) HO CN CN
(5)
Aldehydes, Ketones and Carboxylic acids Aakash Institute
47. When anhydrous acetaldehyde is treated with a few
drops of concentrated sulphuric acid following is
O O
formed: C C
O
(3) O (4)
(1) Paraldehyde OH
(2) Polyoxymethylene
(3) Trioxane 51. Select from the followings that can yield an
aldehyde with Grignard Reagent
(4) Paraformaldehyde
O
18
O Ph (1) R – C – Cl (2) Ester
H ,H2O
48. Products
O (3) Hydrogen cyanide (4) Carbon dioxide
(6)
Aakash Institute Aldehydes, Ketones and Carboxylic acids
73. Benzaldehyde doesn’t give positive test with 78. The compound that can not be prepared by
Rosemund’s Reduction is
(a) Tollen’s test (b) Benedict test (c) 2,4 - DNP
(1) Acetaldehyde (2) Fomaldehyde
(1) Only (b)
(3) Benzaldehyde (4) Propanal
(2) (a) and (b) only
79. Acetone reacts with Brady’s reagent to form
(3) (b) and (c) only
(1) Propanone phenylhydrazine
(4) (a), (b) and (c)
(2) Propanone semicarbazone
O
|| (3) Propanone - 2,4 - dinitrophenylhydrazine
dil. NaOH NaBH4/MeOH
74. A B ; (4) Acetone oxime
compound (B) is 80. Correct statement ragarding role of dry HCl in
hemiacetal formation is
(8)
Aakash Institute Aldehydes, Ketones and Carboxylic acids
82. Select the one that is most acidic in nature 89. W hat is the major product in the following
reaction?
(1) Formic acid (2) Benzoic acid
(3) Acetic acid (4) Phenol OH O
+
83. Rate of esterification is maximum in case of + Ph MgBr ?
(1 mole)
(1) Methanol
(2) Ethanol OH OH O
(3) Propan-2-ol (1) (2)
(4) 2-Methyl propan-2-ol Ph
O O
O
+ (3) (4)
Mg CH2 – CH2 H3O P.C.C
84. CH3 – I x y z A
Dry ether Dry ether 90. Which of the following is most acidic ?
COOH COOH
The final product A is
NO2
(1) Ethanol (2) Ethanal (1) (2)
OCH3
(3) Propanal (4) Acetone
COOH COOH
O
Anhyd. AlCl3 (3) (4)
85. +A C + HCl
NO2 OH
91. Rate of nucleophilic addition to carboxylic acid
The reactant A is derivative follow the order
(1) Benzoyl chloride (2) Phosgene (1) alkanoyl halide > amide > ester > anhydride
(3) Carbon tetrachloride (4) Both (1) and (2) (2) ester > anhydride > amide > alkanoyl halide
Pyridine (3) alkanoyl halide > anhydride > ester > amide
86. CH3COCl C2H5OH CH3COOC2H5 HCl
(4) amide > ester > anhydride > alkanoyl halide
Pyridine is used O
(1) To remove HCl H2O18
92. O–CH3 ?
H+
(2) To increase electrophilicity of carbonyl carbon
(3) To control the nucleophilic strength of alcohol Product(s) obtained is/are
(4) All of these O
Br2/P NH3 18
O H
87. CH3–COOH A B, (1) CH3O18H (2)
(large excess)
O
The product B is
(3) OH (4) Both (1) and (3)
(1) -aminoacid (2) -aminoacid
(3) Propanedioic acid (4) Glucosamine CHO
88. Most acidic among the followings is conc OH–
93. ?
COOH NO2
(1) HCOOH (2) Product(s) obtained in the given reaction is/are
–
NO2 COO
COOH
(3) (4) (1) (2)
NO2
OH NO2
CH2OH
NO2
(9)
Aldehydes, Ketones and Carboxylic acids Aakash Institute
94. Clemmensen reduction of a ketone is carried out P and B respectively are
in presence of which of the following ?
NH2
(1) H2 /Pt
(1) CH2 = CH – COOH and CH3CH
(2) Hydrazine/Glycol/KOH COOH
(3) Zn(Hg), HCl
OH NH2
(4) LiAlH4
–
(2) CH3 – CH – COOH and CH3CH
95. The compound that undergoes decarboxylation
most readily under mild condition is COOH
COOH CH 2COOH
O O NH2
(1) (2) CH3CH and CH2 = CH – COOH
(3)
COOH
COOH
COOH NH2
(3) (4)
COOH (4) CH2 = CH – COOH and CH3CH
COOH CN
96. Find the product for the reaction
one equivalent
O
C2H5OH/HCl gas
1. Ag2O, 100. CH3 – CHO (A) . Product (A) is
CH3–C–Cl + CH2N2 +
?
2. H3O (1) Acetic acid (2) Hemiacetal
O O
(1) CH 3–C–OH (2) CH3–C–NH2 (3) Acetal (4) Ketal
101. An aldehyde on reaction with NH3 forms a
(3) CH3CH2COOH (4) CH3 – C N compound which is used as an antiseptic drug. The
aldehyde is
CHO
+ (1) CH3CHO (2) CH3CH2CHO
97. H CH3 (i) Et MgBr products (3) CCl3CHO (4) HCHO
(ii) H3O+
Ph 102. How many aldol. condensation products will be
The correct relation between the products is/are obtained considering stereoisomers on reaction with
(1) Enantiomer (2) Tautomer dilute alkali ?
H prepared by
98. OH A (Major)
(1) Perkin’s reaction
Br
(2) Cannizzaro's reaction
Major product A is (3) Darzen reaction
(4) Claisen condensation
(1) Br COOH (2) Br CHO
OH
PCl5
104. A ‘A’ is
H
Br COOH
(3) (4)
O Cl Cl
(1) (2)
+
COCl Cl COCl
H /H2O H+/ B
CH3 C
pH = 9 – 10 Cl
C = O + HCN A
99.
H NH Cl
4
Q HCl P (3) Cl (4) (2) and (3)
KCN H2O
COCl
(10)
Aakash Institute Aldehydes, Ketones and Carboxylic acids
105. The correct order of acidic strength of following –
CH2OH CH2–O
compounds is
(3) (4)
–
OH COOH CH2OH CH2–O
(i) (ii) 109. Which of the following can give positive haloform
test ?
O
COOH OH
C H
Cl CH3 (1)
(iii) (iv)
O
(1) (iii) > (ii) > (i) > (iv) (2) (i) > (ii) > (iii) > (iv) C CH2–CH3
(2)
(3) (ii) > (i) > (iii) > (iv) (4) (iii) > (ii) > (iv) > (i)
16 O CH3
106. 18 D +
O O
1618
O CH 2–CH=CH–C
(3) R – C – OD + R – O – H
H
110.
18 16
(i) LiAlH4
(4) (2) and (3)
(ii) H2O
107. An organic compound A with molecular formula
C 7 H 12 gives Baeyer's test for unsaturation, but
Product
absorbs single mole of H2 to form a compound of
molecular formula C7H14(B).
Product of the reaction will be
(A) on ozonolysis gives the only compound (c)
(c) is identified as hepta – 2, 6 – dione, O
compound [A] is CH2–CH2–CH2–C
(1) 1,3–dimethylcyclopentene (1) H
(2) 1, 2–dimethylcyclopentene
(3) 1, 4–dimethylcyclobutene
O
(4) 1, 2–diethylcyclobutene
CH2–CH2–CH2–C
(2)
H
O
C
108. PCC/CH2Cl2 CH2–CH2–CH2–CH2OH
O A B C – D
PCl5 LiAlH4 1 eqv. OH , (3)
O
Product ‘D’ is
CH2–CH=CH–CH2OH
CH2OH COO
–
(4)
(1) (2)
– –
COO COO
(11)
Aldehydes, Ketones and Carboxylic acids Aakash Institute
COOH OH
O O (4)
C C
111. H OH Me OH O
V
115. What is the product of the following reactions ?
The correct order of acidic strength will be
1. HBr, Peroxide
(1) > > > V (2) > > > V 2. Mg, Ether
(3) > > > V (4) > V > > 3. CO2
Product
112. Among the following the correct order of reactivity with 4. H +/H O 2
5. SOCl2, pyridine
HCN/ OH will be
O Cl
O
O O O (1)
C
C C C H
H H H3C H H3C CH3
V
(1) > > > V (2) > > V > (2)
(3) > V > > (4) > > > V O
113. Which among the following give negative test with
O
Tollens reagent ?
(3) Cl
(1) Aldehydes (2) -hydroxy ketone
(3) But-1-yne (4) But-2-yne O
(4)
114. The major product should be
Cl
O Br O
OH O
CH3 116. H
H H
O
Select the correct sequence of reagents for this
NaOH(dil.) reaction.
(1) Et OH NaOH, KOH (aq.), H(+)/H2O
Major product
(2) Et OH / TsOH, KOH (aq.), H(+)/H2 O
O OH NaOH, H3 O
(+)
(3) KOH (aq.)
OH
C–CH3
(1) (4) Et MgBr, H3O(+), KOH (aq.)
(i) O3
117. Product
(ii) H2O2
CH3
(2) Product of above reaction is
C H
(1) Malonic acid (2) Succinic acid
O (3) Adipic acid (4) Fumaric acid
O
C
(3) CH3
(12)
Aakash Institute Aldehydes, Ketones and Carboxylic acids
O CH3
O SO3H
C Zn–Hg C
118. H Product(P) (4) CH3
HO conc. HCl O SO3H
Product (P) will be
122. Which of the following reactions involve carbanion
CH3 enolate as reactive intermediate?
(1) I. Aldol condensation
HO
II. Benzoin condensation
CH3
(2) III. Claisen condensation
IV. Fries rearrangement
CH3
(1) I, II (2) I, III
(3)
Cl (3) I, IV (4) I, II and III
CH3 CHO conc. NaOH CH2OH H O+
3 conc
123. A B
(4) H2SO4
Cl CHO COONa
CH 3 OH
(2)
CH 2 CHO (2) CH3 – CH – CH3
CH3 O O
C = CH2 (3)
(3) CH3 – C – CH2 – C – CH3
O SO3H
(4) All of these
(13)
Aldehydes, Ketones and Carboxylic acids Aakash Institute
(14)
Aakash Institute Aldehydes, Ketones and Carboxylic acids
CPP-24 FOR
REGULAR
MEDICAL-2021-22
ANSWERS
8. (1) 9. (2) 10. (1) 11. (2) 12. (3) 13. (2) 14. (2)
15. (2) 16. (3) 17. (3) 18. (4) 19. (3) 20. (3) 21. (3)
22. (3) 23. (3) 24. (3) 25. (1) 26. (3) 27. (4) 28. (2)
29. (3) 30. (3) 31. (3) 32. (2) 33. (3) 34. (4) 35. (1)
36. (3) 37. (3) 38. (1) 39. (3) 40. (1) 41. (1) 42. (4)
43. (3) 44. (1) 45. (1) 46. (2) 47. (1) 48. (4) 49. (4)
50. (3) 51. (2) 52. (1) 53. (3) 54. (1) 55. (2) 56. (3)
57. (1) 58. (1) 59. (4) 60. (3) 61. (3) 62. (1) 63. (3)
64. (4) 65. (1) 66. (4) 67. (2) 68. (2) 69. (3) 70. (1)
71. (4) 72. (2) 73. (1) 74. (2) 75. (1) 76. (3) 77. (1)
78. (2) 79. (3) 80. (4) 81. (3) 82. (1) 83. (1) 84. (3)
85. (4) 86. (1) 87. (1) 88. (3) 89. (4) 90. (2) 91. (3)
92. (2) 93. (4) 94. (3) 95. (1) 96. (3) 97. (3) 98. (2)
99. (3) 100. (2) 101. (4) 102. (1) 103. (4) 104. (1) 105. (1)
106. (1) 107. (2) 108. (1) 109. (3) 110. (4) 111. (2) 112. (2)
113. (4) 114. (3) 115. (4) 116. (2) 117. (3) 118. (3) 119. (2)
120. (3) 121. (1) 122. (2) 123. (1) 124. (3) 125. (4) 126. (1)
127. (4)
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