Sodium Hydroxide Solution 30 - 54 MX EN
Sodium Hydroxide Solution 30 - 54 MX EN
Olin Corporation (OCAP) encourages and expects you to read and understand the entire (M)SDS, as
there is important information throughout the document. We expect you to follow the precautions iden-
tif ied in this document unless your use conditions would necessitate other appropriate methods or
actions.
GHS Classification
Corrosive to metals : Category 1
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SAFETY DATA SHEET
Precautionary statements :
Prevention:
P234 Keep only in original container.
P264 Wash skin thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P280 Wear protective gloves/ protective clothing/ eye protection/
f ace protection.
Response:
P301 + P312 + P330 IF SWALLOWED: Call a POISON
CENTER or doctor/ physician if you feel unwell. Rinse mouth.
P301 + P330 + P331 IF SWALLOWED: Rinse mouth. Do NOT
induce vomiting.
P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately
all contaminated clothing. Rinse skin with water.
P304 + P340 + P310 IF INHALED: Remove victim to fresh air
and keep at rest in a position comfortable for breathing. Imme-
diately call a POISON CENTER or doctor/ physician.
P305 + P351 + P338 + P310 IF IN EYES: Rinse cautiously with
water f or several minutes. Remove contact lenses, if present
and easy to do. Continue rinsing. Immediately call a POISON
CENTER or doctor/ physician.
P363 Wash contaminated clothing before reuse.
P390 Absorb spillage to prevent material damage.
Storage:
P405 Store locked up.
Disposal:
P501 Dispose of contents/ container to an approved waste dis-
posal plant.
Other hazards
None known.
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SAFETY DATA SHEET
Suitable extinguishing media : This material does not burn. If exposed to fire from another
source, use suitable extinguishing agent for that fire.
Unsuitable extinguishing : Do not use water.
media
Specific hazards during fire- : Product reacts with water. Reaction may produce heat and/or
f ighting gases.
This reaction may be violent.
Violent steam generation or eruption may occur upon applica-
tion of direct water stream to hot liquids.
Specific extinguishing meth- : Keep people away. Isolate fire and deny unnecessary entry.
ods Water is not recommended, but may be applied in large quan-
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SAFETY DATA SHEET
Environmental precautions : Prevent f rom entering into soil, ditches, sewers, waterways
and/or groundwater. See Section 12, Ecological Information.
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SAFETY DATA SHEET
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SAFETY DATA SHEET
Colour : Colorless
Odour : Odorless
pH : 14
Method: Literature
Pour point :
Sof tening point
Boiling point/boiling range : Method: ASTM D1120
Solubility(ies)
Water solubility : completely miscible
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SAFETY DATA SHEET
Viscosity
Viscosity, dynamic : No data available
Explosive properties : No
Oxidizing properties : No
Note: These are the Reference Points for these Physical Properties listed above, unless otherwise
noted in their respective Physical Property value information: Boiling Point at 760 mmHg; Evaporation
Rate Butyl Acetate = 1; Relative Vapor Density Air = 1; and Relative Density Water = 1.
NOTE: The physical data presented above are typical values and should not be construed as a speci-
f ication.
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SAFETY DATA SHEET
Acute toxicity
Product:
Acute inhalation toxicity : Remarks: Mist may cause severe irritation of upper respiratory
tract (nose and throat).
Remarks: As product:
The LC50 has not been determined.
Acute dermal toxicity : Remarks: Prolonged skin contact is unlikely to result in ab-
sorption of harmful amounts.
Components:
Sodium hydroxide:
Acute oral toxicity : LD50 (Rabbit): 336 mg/kg
Method: Estimated.
Acute inhalation toxicity : Remarks: The LC50 has not been determined.
Acute dermal toxicity : Remarks: The dermal LD50 has not been determined.
Skin corrosion/irritation
Product:
Remarks : Due to the pH of the material, it is assumed that exposure will
cause skin burns.
Brief contact may cause severe skin burns. Symptoms may
include pain, severe local redness and tissue damage.
Components:
Sodium hydroxide:
Result : Causes severe burns.
Remarks : Brief contact may cause severe skin burns. Symptoms may
include pain, severe local redness and tissue damage.
Product:
Remarks : Due to the pH of the material, it is assumed that exposure
may cause severe irritation with corneal injury which may re-
sult in permanent impairment of vision, even blindness.
Mist may cause eye irritation.
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SAFETY DATA SHEET
Components:
Sodium hydroxide:
Result : Corrosive
Remarks : May cause severe irritation with corneal injury which may re-
sult in permanent impairment of vision, even blindness. Chem-
ical burns may occur.
Dust may irritate eyes.
Product:
Remarks : For skin sensitization:
No relevant data found.
Components:
Sodium hydroxide:
Assessment : Does not cause skin sensitisation.
Remarks : Did not cause allergic skin reactions when tested in humans.
Product:
Genotoxicity in vitro : Remarks: For the major component(s):
In vitro genetic toxicity studies were negative.
Components:
Sodium hydroxide:
Genotoxicity in vitro : Remarks: In vitro genetic toxicity studies were negative.
Carcinogenicity
Product:
Remarks : No relevant data found.
Components:
Sodium hydroxide:
Remarks : No relevant data found.
Reproductive toxicity
Product:
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SAFETY DATA SHEET
Components:
Sodium hydroxide:
Assessment : Available data are inadequate to determine single exposure
specific target organ toxicity.
Components:
Sodium hydroxide:
Remarks : Based on available data, repeated exposures are not antici-
pated to cause additional significant adverse effects.
Aspiration toxicity
Product:
Aspiration into the lungs may occur during ingestion or vomiting, causing tissue damage or lung
injury.
Components:
Sodium hydroxide:
Aspiration into the lungs may occur during ingestion or vomiting, causing tissue damage or lung
injury.
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SAFETY DATA SHEET
Ecotoxicity
Components:
Sodium hydroxide:
Toxicity to fish : Remarks: May increase pH of aquatic systems to > pH 10
which may be toxic to aquatic organisms.
Components:
Sodium hydroxide:
Biodegradability : Remarks: Biodegradability is not applicable to inorganic sub-
stances.
Bioaccumulative potential
Components:
Sodium hydroxide:
Partition coefficient: n- : Remarks: No bioconcentration is expected because of the
octanol/water relatively high water solubility.
Mobility in soil
Components:
Sodium hydroxide:
Distribution among environ- : Koc: 14
mental compartments Method: Estimated.
Remarks: Potential for mobility in soil is very high (Koc be-
tween 0 and 50).
Sodium hydroxide:
Results of PBT and vPvB : This substance is not considered to be persistent, bioaccumu-
assessment lating and toxic (PBT). This substance is not considered to be
very persistent and very bioaccumulating (vPvB).
Disposal methods
Waste f rom residues : AS YOUR SUPPLIER, WE HAVE NO CONTROL OVER THE
MANAGEMENT PRACTICES OR MANUFACTURING
PROCESSES OF PARTIES HANDLING OR USING THIS
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SAFETY DATA SHEET
MATERIAL.
THE INFORMATION PRESENTED HERE PERTAINS ONLY
TO THE PRODUCT AS SHIPPED IN ITS INTENDED
CONDITION AS DESCRIBED IN MSDS SECTION: Composi-
tion Inf ormation.
All disposal practices must be in compliance with all Federal,
State/Provincial and local laws and regulations.
Regulations may vary in different locations.
Waste characterizations and compliance with applicable laws
are the responsibility solely of the waste generator.
DO NOT DUMP INTO ANY SEWERS, ON THE GROUND,
OR INTO ANY BODY OF WATER.
Empty containers should be recycled or otherwise disposed of
by an approved waste management facility.Waste characteri-
zations and compliance with applicable laws are the responsi-
bility solely of the waste generator.Do not re-use containers
f or any purpose.
International Regulations
UNRTDG
UN number : UN 1824
Proper shipping name : SODIUM HYDROXIDE SOLUTION
Class : 8
Packing group : II
Labels : 8
IATA-DGR
UN/ID No. : UN 1824
Proper shipping name : Sodium hydroxide solution
Class : 8
Packing group : II
Labels : Corrosive
Packing instruction (cargo : 855
aircraf t)
Packing instruction (passen- : 851
ger aircraf t)
IMDG-Code
UN number : UN 1824
Proper shipping name : SODIUM HYDROXIDE SOLUTION
Class : 8
Packing group : II
Labels : 8
EmS Code : F-A, S-B
Marine pollutant : no
Remarks : Stowage category AAlkalis
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable for product as supplied.
National Regulations
NOM-002-SCT
UN number : UN 1824
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SAFETY DATA SHEET
Safety, health and environmental regulations/legislation specific for the substance or mix-
ture
Federal Law f or the control of chemical precursors, : Not applicable
essential chemical products and machinery for produc-
ing capsules, tablets and pills.
International Regulations
Montreal Protocol (Ozone Depleting Substances) : Not applicable
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SAFETY DATA SHEET
Further information
NFPA 704:
Flammability
0
Health Instability
3 1
Special hazard
AICS - Australian Inventory of Chemical Substances; ANTT - National Agency for Transport by
Land of Brazil; ASTM - American Society for the Testing of Materials; bw - Body weight; CMR -
Carcinogen, Mutagen or Reproductive Toxicant; DIN - Standard of the German Institute for
Standardisation; DSL - Domestic Substances List (Canada); ECx - Concentration associated with
x% response; ELx - Loading rate associated with x% response; EmS - Emergency Schedule;
ENCS - Existing and New Chemical Substances (Japan); ErCx - Concentration associated with
x% growth rate response; ERG - Emergency Response Guide; GHS - Globally Harmonized Sys-
tem; GLP - Good Laboratory Practice; IARC - International Agency for Research on Cancer; IATA
- International Air Transport Association; IBC - International Code for the Construction and
Equipment of Ships carrying Dangerous Chemicals in Bulk; IC50 - Half maximal inhibitory con-
centration; ICAO - International Civil Aviation Organization; IECSC - Inventory of Existing Chemi-
cal Substances in China; IMDG - International Maritime Dangerous Goods; IMO - International
Maritime Organization; ISHL - Industrial Safety and Health Law (Japan); ISO - International Or-
ganisation for Standardization; KECI - Korea Existing Chemicals Inventory; LC50 - Lethal Con-
centration to 50 % of a test population; LD50 - Lethal Dose to 50% of a test population (Median
Lethal Dose); MARPOL - International Convention for the Prevention of Pollution from Ships;
n.o.s. - Not Otherwise Specified; Nch - Chilean Norm; NO(A)EC - No Observed (Adverse) Effect
Concentration; NO(A)EL - No Observed (Adverse) Effect Level; NOELR - No Observable Effect
Loading Rate; NOM - Official Mexican Norm; NTP - National Toxicology Program; NZIoC - New
Zealand Inventory of Chemicals; OECD - Organization for Economic Co-operation and Develop-
ment; OPPTS - Office of Chemical Safety and Pollution Prevention; PBT - Persistent, Bioaccumu-
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SAFETY DATA SHEET
lative and Toxic substance; PICCS - Philippines Inventory of Chemicals and Chemical Substanc-
es; (Q)SAR - (Quantitative) Structure Activity Relationship; REACH - Regulation (EC) No
1907/2006 of the European Parliament and of the Council concerning the Registration, Evalua-
tion, Authorisation and Restriction of Chemicals; SADT - Self-Accelerating Decomposition Tem-
perature; SDS - Saf ety Data Sheet; TCSI - Taiwan Chemical Substance Inventory; TDG - Trans-
portation of Dangerous Goods; TSCA - Toxic Substances Control Act (United States); UN - Unit-
ed Nations; UNRTDG - United Nations Recommendations on the Transport of Dangerous Goods;
vPvB - Very Persistent and Very Bioaccumulative; WHMIS - Workplace Hazardous Materials In-
f ormation System
Olin Corporation (OCAP) urges each customer or recipient of this (M)SDS to study it caref ully
and consult appropriate expertise, as necessary or appropriate, to become aware of and under-
stand the data contained in this (M)SDS and any hazards associated with the product. The in-
formation herein is provided in good faith and believed to be accurate as of the effective date
shown above. However, no warranty, express or implied, is giv en.Regulatory requirements are
subject to change and may differ between various locations. It is the buyer's/user's responsibility
to ensure that his activities comply with all f ederal, state, provincial or local laws. The information
presented here pertains only to the product as shipped. Since conditions for use of the product
are not under the control of the manufacturer, it is the buyer's/user's duty to determine the condi-
tions necessary for the saf e use of this product. Due to the prolif eration of sources for information
such as manufacturer-specific (M)SDSs, we are not and cannot be responsible for (M)SDSs ob-
tained from any source other than ourselves. If you have obtained an (M)SDS f rom another
source or if you are not sure that the (M)SDS you have is current, please contact us for the most
current version.
MX / EN
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