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DPP NO. # 1
* Marked Questions are having more than one correct option.
1. The volume of water that must be added to a mixture of 250 ml of 0.6 M HCl and 750 ml of
0.2 M HCl to obtain 0.25 M solution of HCl is :
(A) 750 ml (B) 100 ml (C) 200 m (D) 300 m

2. What approximate volume of 0.40 M Ba(OH)2 must be added to 50.0 mL of 0.30 M NaOH to get a solution
in which the molarity of the OH– ions is 0.50 M?
(A) 33 mL (B) 66 mL (C) 133 mL (D) 100 mL

i r
3.
Ag+, Cl–, Na+, NO3– in the solution would be
(A) [K+] = 0.0416 [Ag+] = 0.04 [Na+] = 0.002 (B) [K+] = 0.0416 [Na+] = 0.00166
S
500 ml of 0.1 M KCl , 200 ml of 0.01 M NaNO3 and 500 ml of 0.1 M AgNO3 was mixed. The molarity of K+,

[C–] = 0.04 [NO3–] = 0.042

+ + +
(C) [K ] = 0.04 [Ag ] = 0.05 [Na ] = 0.0025
[C–] = 0.05 [NO3–] = 0.0525
[NO3–] = 0.0433

t a
(D) [K+] = 0.05 [Na+] = 0.0025
[NO3–] = 0.0525

4.
(A) 13.9 (B) 15.5
u
(C) 14.5
p
Mole fraction of A in H2O is 0.2. The molality of A in H2O is :
(D) 16.8

5. G
What is the molarity of H2SO4 solution that has a density of 1.84 g/cc and contains 98% by mass of H2SO4?
(Given atomic mass of S = 32)
(A) 4.18 M (B) 8.14 M

a m (C) 18.4 M (D) 18 M

6.
1000 gm of solvent.
(A) 1000 g
p
The molality of a sulphuric acid solution is 0.2. Calculate the total weight of the solution having

u
(B) 1098.6 g (C) 980.4 g (D) 1019.6g

7.
(A) 0.46
A n
Mole fraction of C3H5(OH)3 in a solution of 36 g of water and 46 g of glycerine is :
(B) 0.36 (C) 0.20 (D) 0.40

8. Column-I Column-II
(a) 4.5 m solution of CaCO3 density 1.45 g/ml (P) mole fraction of solute is 0.2
(b) 3 M 100 ml H2SO4 mixed with 1 M 300 ml H2SO4 solution (Q) mass of the solute is 360 g
(c) 14.5 m solution of Ca (R) molarity = 4.5
(d) In 4 M 2 litre solution of NaOH, 40 gm of NaOH is added. (S) molarity = 1.5
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DPP NO. # 2
1. Mixture of volatile components A and B has total vapour pressure (in Torr) p = 254 – 119 xA where xA is mole
0 0
fraction of A in mixture. Hence p A and pB are (in Torr)
(A) 254, 119 (B) 119, 254 (C) 135, 254 (D) 119, 373

2. What is the mole ratio of benzene (PB0= 150 torr) and toluene (PT0 = 50 torr) in vapour phase if the given
solution has a vapour pressure of 120 torr?
(A) 7 : 1 (B) 7 : 3 (C) 8 : 1 (D) 7 : 8

3.
r
At 323 K, the vapour pressure in millimeters of mercury of a methanol-ethanol solution is represented by the

i
(A) 250 mm (B) 140 mm (C) 260 mm (D) 20 mm
A

S
equation p = 120 XA + 140, where XA is the mole fraction of methanol. Then the value of xlim1
pA
X A is

4.

t a
Two liquids A and B form ideal solution at 300 K. The vapour pressure of a solution containing one mole of A
and four mole of B is 560 mm of Hg. At the same temperature if one mole of B is taken out from the solution,

(A) 330, 550 (B) 200, 300

p
the vapour pressure of solution decreases by 10 mm of Hg. Vapour pressures of A and B in pure state will be:

u
(C) 400, 600 (D) 800, 1200

5.
G
The vapour pressure of two volatile liquid mixture is PT = (5.3 – 2XB) in cm of Hg ; where XB is mole fraction
of B in mixture. What are vapour pressure of pure liquids A and B ?
(A) 3.3 and 2.1 cm of Hg (B) 2.3 and 3.3 cm of Hg

6.
(C) 5.3 and 2.3 cm of Hg

a m (D) 5.3 and 3.3 cm of Hg

At 40ºC the vapour pressure in torr of methanol and ethanol solution is P = 119 x + 135 where x is the mole

u p
fraction of methanol, hence,
(A) vapour pressure of pure methanol is 119 torr
(B) vapour pressure of pure ethanol is 135 torr

7.
n
(C) vapour pressure of equimolar mixture of each is 127 torr

A
(D) mixture is completely immiscible

Solution of two volatile liquids A and B obey Raoult’s law. At a certain temperature, it is found that when the
total vapour pressure above solution is 400 mm of Hg, the mole fraction of A in vapour phase is 0.45 and in
liquid phase 0.65 then the vapour pressures of two pure liquids at the same temperature will be -
(A) 138.4 mm, 628.57 mm (B) 276.9 mm, 628.57 mm
(C) 276.9 mm, 314.28 mm (D) 138.4 mm, 314.28 mm

8. The vapour pressure of benzene and toluene at 20ºC are 75 mm of Hg and 22 mm of Hg respectively.
23.4 g of benzene and 64.4g of toluene are mixed. If two forms ideal solution, the mole fraction of benzene in
vapour phase when vapours are in equilibrium with liquid mixture, is -
(A) 0.59, 0.41 (B) 0.25, 0.75 (C) 0.5, 0.5 (D) 0.35, 0.65

9. The vapour pressure of two liquids are 15000 and 30000 in a unit. When equimolar solution of liquids is made.
Then the mole fraction of A and B in vapour phase will be :

2 1 1 2 1 1 1 3
(A) , (B) , (C) , (D) ,
3 3 3 3 2 2 4 4
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10. At 90ºC, the vapour pressure of toluene is 400 mm and that of xylene is 150 mm. The composition of liquid
mixture that will boil at 90ºC when the pressure of mixture is 0.5 atm, is -
(A) 0.8, 0.2 (B) 0.75 , 0.25 (C) 0.92 , 0.08 (D) 0.66 , 0.34

11. Mole fraction of a liquid A in an ideal mixture with another liquid b is XA. If XA is the mole fraction of
component A in the vapour in equilibrium, the total pressure of the liquid mixture is -
(PºA = vapour pressure of pure A ; PºB = vapour pressure of pure B )

X'A Pº A X A P º B X 'A Pº B X A
(A) P º A (B) (C) (D)
XA X 'A XA X 'A

1.
Revision Problem

4.48 litres of methane at N.T.P. correspond to :

i r
(A) 1.2 x 1022 molecules of methane.
(C) 3.2 gm of methane.
(B) 0.5 mole of methane.
(D) 0.1 mole of methane.
S
2.
(B) 16 (C) 8
a
5.6 litre of a gas at N.T.P. weighs equal to 8 gm. The vapour density of gas is :
(A) 32 (D) 40

t
3.
(B) 0.6NA (C) NA

u p
The number of oxygen atoms present in 14.6 g of magnesium bicarbonate [Mg(HCO3)2] is :
(A) 6NA (D) 0.5 NA

4. One mole of P4 molecules contains :

(A) 1 molecule.
(C) 1/4 × 6.022 × 1023 atoms. G
(B) 4 molecules.
(D) 24.088 × 1023 atoms.

5. What is correct for 10 g of CaCO3 ?

(A) It contains 1g-atom of carbon.
a m (B) It contains 0.3 g-atom of oxygen.

u p
(C) It contains 12 g of calcium. (D) None of these.

ANSWER KEY

A n DPP NO. # 1
1. (C) 2. (A) 3. (B) 4. (A) 5. (C) 6. (D) 7. (C)

8. (a – R ; b – S ; c – P ; d – Q,R)

DPP NO. # 2
1. (C) 2. (A) 3. (C) 4. (C) 5. (D) 6. (B) 7. (B)

8. (A) 9. (B) 10. (C) 11. (B)

Revision Problem

1. (C) 2. (B) 3. (B) 4. (D) 5. (B)

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DPP No. 03
1. The vapour pressure of ether at 20ºC is 442 mm. When 7.2 g of a solute is dissolved in 60 g ether, vapour
pressure is lowered by 32 units. If molecular weight of ether is 74 then molecular weight of solute is -
(A) 113.77 (B) 150.35 (C) 116.23 (D) 190.26

2. The vapour pressure of pure benzene at 25ºC is 639.7 mm of Hg and the vapour pressure of a solution of a
solute in C6H6 at the same temperature is 631.9 mm of Hg. Molality of solution is -
(A) 0.079 mol/kg of solvent (B) 0.256 mol/kg of solvent
(C) 0.158 mol/kg of solvent (D) 0.316 mol/kg of solvent

3.

i r
A 6% (by weight) of non-volatile solute in isopentane at 300 K has a vapour pressure of 1426 mm Hg. 20 g of
isopentane is now added to the solution. The resulting solution has a vapour pressure of 1445 mm of Hg at the
same temperature. Then :
(i) Molecular weight of solute is -
(A) 28. 32 (B) 92.81 (C) 113.30 (D) 56.65
S
(ii) Vapour pressure of isopentane at 300 K is -
(A) 1541.68 mm (B) 770.89 mm (C) 1212.46 mm

t a (D) 981.32 mm

4.
pressure to 4/5th of pure water -
(A) 130 g (B) 150 g (C) 300 g
p
Find out the weight of solute (M. wt. 60) that is required to dissolve in 180 g water to reduce the vapour

u (D) 75 g

5. G
The molality of a solution containing a non-volatile solute if the vapour pressure is 2% below the vapour
pressure of pure water, will be -
(A) 2.213 (B) 2.518

a m (C) 1.133 (D) 1.891

6.

(A) 20 gm
u p
The weight of a non-volatile solute (m. wt. 40). Which should be dissolved in 114 g octane to reduce its vapour
pressure to 80%, is -
(B) 10 gm (C) 7.5 gm (D) 5 gm

7.
n
Twenty gram of a solute are added to 100 g of water at 25ºC. The vapour pressure of pure water is

A
23.76 mm Hg, vapour pressure of solution is 22.41 mm Hg. The mass of this solute that is required in 100 g
water to reduce the vapour pressure to one-half of the pure water is -
(A) 333 g (B) 666 g (C) 166 g (D) 256 g

8. Vapour pressure of pure water is 40 mm. If a non-volatile solute is added to it vapour pressure falls by 4 mm.
Hence, molality of solution is -
(A) 6.173 molal (B) 3.0864 molal (C) 1.543 molal (D) 0.772 molal

9. The vapour pressure of pure liquid solvent A is 0.80 atm. When a non-volatile substance B is added to the
solvent, its vapour pressure drops to 0.60 atm ; mole fraction of the component B in the solution is
(A) 0.50 (B) 0.25 (C) 0.75 (D) 0.40

10. Vapour pressure of CCl4 at 25ºC is 143 mm Hg. If 0.5 gm of non-volatile solute (mol. mass 65) is dissolved in
100 ml CCl4, then the vapour pressure of the solution at 25ºC is -
[ Given : Density of CCl4 = 1.58 g/cm3 ]
(A) 141.93 mm (B) 94.39 mm (C) 199.34 mm (D) 143.99 mm
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DPP No. 04
1. Lowering of vapour pressure of 1.00 m solution of a non-volatile solute in a hypothetical solvent of molar mass
40 g at its normal boiling point, is -
(A) 29.23 torr (B) 30.4 torr (C) 35.00 torr (D) 40.00 torr

2. The vapour pressure of a liquid decreases by 10 torr when a non-volatile solute is dissolved. The mole fraction
of the solute in solution is 0.1. What would be the mole fraction of the liquid if the decrease in vapour pressure
is 20 torr, the same solute being dissolved -
(A) 0.2 (B) 0.9 (C) 0.8 (D) 0.6

3. The mole fraction of the solvent in the solution of a non-volatile solute is 0.980. The relative lowering of vapour
pressure is -
(A) 0.01 (B) 0.980 (C) 0.02 (D) 0.49

4.

i r
The vapour pressure of a solution of a non-volatile solute B in a solvent A is 95% of the vapour pressure of the
solvent at the same temperature. If the molecular weight of the solvent is 0.3 times the molecular weight of
the solute, what is the weight ratio of solvent to solute.

5.
(A) 0.15 (B) 5.7 (C) 0.2
S
(D) none of these

The vapour pressure of water at room temperature is 23.8 mm Hg. The vapour pressure of an aqueous
solution of sucrose with mole fraction 0.1 is equal to –
(A) 23.9 mm Hg (B) 24.2 mm Hg (C) 21.42 mm Hg

t a
(D) 31.44 mm Hg

6.

p
The vapour pressure of pure A is 10 torr and at the same temperature when 1 g of B is dissolved in
20 g of A, its vapour pressure is reduced to 9.0 torr. If the molecular mass of A is 200 amu, then the molecular
mass of B is –
u
7.
(A) 100 amu (B) 90 amu

G
(C) 75 amu (D) 120 amu

The vapour pressure of pure benzene C6H6 at 50ºC is 260 Torr. How many moles of nonvolatile solute per mole
of benzene are required to prepare a solution of benzene having a vapour pressure of 167.0 Torr at 50ºC ?

8.
(A) 0.305 mol (B) 0.605 mol

a m (C) 0.336 mol (D) 0.663 mol

Lowering of vapour pressure due to a solute in 1 molal aqueous solution at 100ºC is -

9.
(A) 13.44 Torr

u p
(B) 14.12 Torr (C) 312 Torr (D) 352 Torr

How many grams of sucrose must be added to 360 g of water to lower the vapour pressure by

(A) 342 g

A n
1.19 mmHg at a temperature at which pressure of pure water is 25 mm Hg ?
(B) 360 g (C) 375 g

Revision Problems
(D) 380 g

1. The atomic weight for a triatomic gas is a. The correct formula for the number of moles of gas in its w g is:

3w w a
(A) (B) (C) 3wa (D)
a 3a 3w

2. 16 g of SOx occupies 5.6 litre at S.T.P. Assuming ideal gas nature, the value of x is :
(A) 1 (B) 2 (C) 3 (D) none of these

3. Find the relative density of SO3 gas with respect to methane.

4. Vapour density of a gas is 17 then find the weight of 11.2 L. of gas at STP.

5. Compounds of boron with hydrogen are called boranes. One of these boranes has the empirical formula BH3
and a molecular weight of 28 amu. What is its molecular formula ?

6. Calculate vapour density of a sample containing 10 moles of CO2, 5 moles of SO2 & 400 g of SO3 with
respect to CH4 gas.
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7. Calculate total number of carbon atoms in a sample containing 160 g of CH4, 600 g of acetic acid, 340 g of
C3O2 & 360 g of pentane.

8. Match the following :

Column - I Column - II

(A) 49 g H2SO4 (p) 0.5 mole

(B) 20 g NaOH (q) 1.5 NA atoms

i r
(C)

(D)
11.2 L of CO2 at STP

6.023 x 1023 atoms of Oxygen

(r)

(s) S
0.5 NA molecules

2 mole of ‘O’ atom

9. Column - I

t
Column - II
a
(A)

(B)
32 gm each of O2 and S

2 gram molecule of K3[Fe(CN)6]

(p)

u p
2 moles of Fe

(q) 3 moles of ozone molecule

(C) 144 gm of oxygen atom

G (r) one mole

(D)

a m
From 168 g of iron 6.023 × 1023 atoms
of iron are removed the iron left
(s) 12 moles of carbon atoms

u p ANSWER KEY

1. (C)
A
2.
n (A) 3. (B)
DPP NO. # 1

4. (A) 5. (C) 6. (D) 7. (C)

8. (a – R ; b – S ; c – P ; d – Q,R)

DPP NO. # 2
1. (C) 2. (A) 3. (C) 4. (C) 5. (D) 6. (B) 7. (B)

8. (A) 9. (B) 10. (C) 11. (B)

Revision Problem

1. (C) 2. (B) 3. (B) 4. (D) 5. (B)

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* Marked Questions are having more than one correct option.

DPP NO. # 05
1. A complex of iron and cyanide ions is 100% ionized at 1 molal. If its elevation in boiling point is 2.08°, then
the complex is (Given: Kb = 0.52°C mol–1 kg)
(A) Fe III
4
[FeII(CN)6]3 (B) K3[FeIII(CN)6] (C) K4[FeII(CN)6] (D) none

2. 15 g of a solute in 100 g water makes a solution freeze at –1°C. 30 g of a solute in 100 g of water will give a
depression in freezing point equal to
(A) –2°C (B) 0.5°C (C) 2°C (D) 1°C
3.
(A) lowering of boiling point
(C) reduced specific heat
(B) reduced viscosity
(D) lowering of freezing point
r
In cold countries, ethylene glycol is added to water in the radiators of cars during winters. It results in

i
4. Which represents correct difference?
S
(I) (II)
t a
u p
G
(III)

(A) I, II, III (B) I, III

a m (C) II, III (D) I, II
5.
p
Boiling point- composition diagram of the liquid-vapour equilibrium for propanol-2

u
(A) and 2-methyl-propanol-1 (B) is shown a side. If a binary liquid mixture of A and

A n
B is distilled fractionally, which of the following would be correct observation?
(A) composition of the still (residue) will approach pure liquid A
(B) composition of the distillate will approach pure B
(C) composition of distillate and residue will approach pure A and B respectively.
(D) Neither of the components can be obtained in pure state.
6. 4.00 g of substance A, dissolved in 100 g H2O depressed the f. pt. of water by 0.1ºC. While 4 g of another
substance B, depressed the f. pt. by 0.2 ºC. What is the relation between molecular weights of the two
substance -
(A) MA = 4MB (B) MA = MB (C) MA = 0.5MB (D) MA = 2MB
7. An aqueous solution containing 5% by weight of urea and 10% by weight of glucose. Freezing point of
solution is [Kf for H2O is 1.86 K mol–1 kg]
(A) 3.04º C (B) –3.04º C (C) –5.96º C (D) 5.96º C

8. The freezing point of a solution prepared from 1.25 gm of non-electrolyte and 20 gm of water is 271.9 K. If molar
depression constant is 1.86 K molality-1. Then molar mass of the solute will be -
(A) 105.68 (B) 106.7 (C) 115.3 (D) 93.9
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9. Elevation in boiling point of an aqueous urea solution is 0.52º. (Kb = 0.52K kg mol-1). Hence mole fraction of
urea in this solution is -
(A) 0.982 (B) 0.0567 (C) 0.943 (D) 0.018

10. The molal freezing point constant for water is 1.86 K. molarlity–1. If 34.2 g of cane sugar (C12H22O11) are
dissolved in 1000g of water, the solution will freeze at
(A) –1.86°C (B) 1.86°C (C) –3.92°C (D) 2.42°C

11. 20 g of a binary electrolyte (mol.wt. = 100) are dissolved in 500 g of water. The freezing point of the solution
is –0.74°C, Kf = 1.86 K.molality–1. The degree of ionisation of the electrolyte is
(A) 50% (B) 75% (C) 100% (D) 0

DPP NO. 06

1. A liquid mixture having composition corresponding to point z in the figure

shown is subjected to distillation at constant pressure. Which of the following
statement is correct about the process
(A) The composition of distillate differs from the mixture
i r
(B) The boiling point goes on changing
(C) The mixture has highest vapour pressure than for any other composition.
(D) Composition of an azeotrope alters on changing the external pressure. S
2.
a
At a temperature, total pressure in Torr of a mixture of volatile components A and B is given by
P = 120 – 75 XB
t
3.
(A) 120, 75 (B) 120, 195 (C) 120, 45

u p
hence, vapour pressure of pure A and B respectively (in Torr) are:

The boiling point of 1.0 m K4[Fe(CN)6] is (Kb for water = 0.52 K kg mol–1)
(D) 75, 45

4.
(A) 100.52°C (B) 100.10°C
G
(C) 100.26°C (D) 102.6°C

For CrCl3. xNH3, elevation in boiling point of one molal solution is double than that of one molal urea solution,

(A) 4 (B) 5 m
hence x would be (complex is 100% ionized)

a (C) 6 (D) none of these

5.
p
The amount of ice that will separate out from a solution containing 25 g of ethylene glycol in 100 g of water

u
and is cooled to –10ºC, will be - [ Given : Kf for H2O = 1.86 K mol–1 kg ]
(A) 50.0 g (B) 25.0 g (C) 12.5 gm (D) 30.0 gm

6.
n
In winter, the normal temperature in Kullu valley was found to be –11ºC. Is a 28% (by mass) aqueous solution

A
of ethylene glycol suitable for a car radiator ? Kf for water = 1.86 K kg mol–1.
(A) Yes (B) No (C) can’t predict (D) None of these

7. When a solution containing w g of urea in 1 kg of water is cooled to -.372ºC, 200 g of ice is separated. If Kf
for water is 1.86 K kg mol-1, w is -
(A) 4.8 g (B) 12.0 g (C) 9.6 g (D) 6.0 g

8. Relative decrease in V. P. of an aqueous glucose dilute solution is found to be 0.018. Hence, elevation in
boiling point is : (it is given 1 molal aq. urea solution boils at 100.54ºC at 1 atm. pressure)
(A) 0.018º (B) 0.18º (C) 0.54º (D) 0.03º

9. Y g of non - volatile organic substance of molecular mass M is dissolved in 250 g benzene. Molal elevation
constant of benzene is Kb. Elevation in its boiling point is given by
M 4K b Y KbY KbY
(A) (B) (C) (D)
KbY M 4M M

10. The values of observed and calculated molecular weights of silver nitrate are 92.64 and 170 respectively. The
degree of dissociation of silver nitrate is
(A) 60% (B) 83.5% (C) 46.7% (D) 60.23%
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DPP NO. 07
1. Which of the following has been arranged in the increasing order of freezing point?
(A) 0.025 M KNO3 < 0.1 M NH2CSNH2 < 0.05 M BaCl2 < 0.1 M NaCl
(B) 0.1 M NaCl < 0.05 M BaCl2 < 0.1 M NH2 CSNH2 < 0.025 M KNO3
(C) 0.1 M NH2 CSNH2 < 0.1 M NaCl < 0.05 M BaCl2 < 0.025 M KNO3
(D) 0.025 M KNO3 < 0.05 M BaCl2 < 0.1 M NaCl < 0.1 M NH2 CSNH2
2. Equal volumes of 1.0 M KCl and 1.0 M AgNO3 are mixed. The depression of freezing point of the resulting
solution will be (Kf(H2O) = 1.86 K kg mol–1, 1 M = 1m)
(A) 3.72 K (B) 1.86 K (C) 0.93 K (D) none of these
3. The molal boiling point constant of water is 0.53ºC. When 2 mole of glucose are dissolved in 4000 gm of
water, the solution will boil at -
(A) 100.53ºC (B) 101.06ºC (C) 100.265ºC (D) 99.47ºC
4. The boiling point of an aqueous solution of a non-volatile solute is 100.15ºC. What is the freezing point of an
aqueous solution obtained by diluting the above solution with an equal volume of water ?
[Kb and Kf for water are 0.512 and 1.86 K molality-1]
(A) -0.544ºC (B) -0.512ºC (C) -0.272ºC (D) -1.86ºC
i r
5.

(A) 180 gm (B) 18 gm (C) 1.8 gm (D) 0.18 gm

S
Glucose is added to 1 litre water to such an extent that Tf/Kf becomes equal to 1/1000, the weight of
glucose added is

6.
a
At 40°C, the vapour pressures in torr, of methyl alcohol - ethy alcohol solution is represented by the equation.

t PA

u p
P = 119XA + 135 where XA is mole fraction of methyl alcohol, then the value of Lim
X A 1 X A is

7.
(A) 254 torr (B) 135 torr

G
(C) 119 torr (D) 140 torr

The amount of ice that will separate on cooling a solution containing 50g of ethylene glycol in 200g water to

8.*
–9.3°C is : [Kf = 1.86 K molality–1]
(A) 38.71 g

Select correct statement:

(B) 38.71 mg

a m (C) 42 g (D) 42 mg

u p
(A) Heats of vaporisation for a pure solvent and for a solution are similar because similar intermolecular
forces between solvent molecules must be overcome in both cases.
(B) Entropy change between solution and vapour is similar to the entropy change between pure solvent and
vapour

A n
(C) Boiling point of the solution is larger than that of the pure solvent
(D) All are correct statements

Answer Key
DPP NO. # 05
1. (B) 2. (C) 3. (D) 4. (A) 5. (C) 6. (D) 7. (B)

8. (A) 9. (D) 10. (A) 11. (D)

DPP NO. 06

1. (D) 2. (C) 3. (D) 4. (A) 5. (B) 6. (A) 7. (C)

8. (C) 9. (B) 10. (B)

DPP NO. 07

1. (B) 2. (B) 3. (C) 4. (A) 5. (D) 6. (A) 7. (A)

8.* (AC)
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Marked Questions are having more than one correct option.

DPP NO. # 08
1. Maximum freezing point will be for 1 molal solution of, assuming equal ionisation in each case :
(A) [Fe(H2O)6]Cl4 (B) [Fe(H2O)5Cl]Cl2.H2O
(C) [Fe(H2O)4Cl2]Cl.2H2O (D) [Fe(H2O)3Cl3].3H2O

2. The osmotic pressure of 1 m solution at 27°C is [CPMT 1999]

(A) 2.46 atm (B) 24.6 atm (C) 1.21 atm (D) 12.1 atm

3.

(A) 3.42 (B) 34.2 (C) 5.7 (D) 19

i r
The concentration in gms per litre of a solution of cane sugar (M = 342) which is isotonic with a solution
containing 6gms of urea (M = 60) per litre is : [Orissa PMT 1989]

4. A 0.6% solution of urea (molecular weight = 60) would be isotonic with

(A) glucose
(C) 0.6% glucose solution
(B) 0.1 M KCl
(D) 0.6% KCl solution
S [NCERT 1982]

5.

t a
0.6 g of a solute is dissolved in 0.1 litre of a solvent which develops an osmotic pressure of 1.23 atm at 27ºC.
The molecular mass of the substance is : [BHU 1990]

6.
(A) 149.5 g mole–1 (B) 120 g mole–1

u
Acetic acid dissolved in benzene shows a molecular weight of :
p
(C) 430 g mole–1 (D) None of these

[MP PET 2002]

7.
(A) 60 (B) 120 (C) 180

G
For the solution of ethanoic acid in benzene, Van't Hoff factor is :
(D) 240

8.
(A) 1 (B) 1/2

a
Which of the following is incorrect : m (C) 2 (D) None of these

u p
(A) Molecular weight of NaCl found by osmotic pressure measurements in half of the theoretical value
(B) Molecular weight of CH3COOH in benzene found by cryscopic methods is double of the theoretical values
(C) Osmotic pressure of 0.1 M glucose solution is half of that of 0.1 M NaCl solution
(D) Molecular weight of HCl found by any colligative property will be same in the aqueous solution and

9.*
n
benzene solution.

A
Which of the following aqueous solutions produce the same osmotic pressure :
(A) 0.1 M NaCl solution
[Roorkee 1999]

(B) 0.1 M glucose solution

(C) 0.6 g urea in 100 ml solution
(D) 1.0 g of a non-electrolyte solute (X) in 50 ml solution (Molar mass of X = 200)

10.* In the depression of freezing point experiment, it is found that the : [IIT 1999]
(A) Vapour pressure of the solution is less than that of pure solvent
(B) Vapour pressure of the solution is more than that of pure solvent
(C) Only solute molecules solidify at the freezing point
(D) Only solvent molecules solidify at the freezing point
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DPP NO. # 09
1. The vapour pressure of pure benzene at a certain temperature is 200 mm Hg. At the same temperture the
vapour pressure of a solution containing 2g of non-volatile non-electrolyte solid in 78g of benzene is
195 mm Hg. The molecular weight of solid is : [UPSEAT 2001]
(A) 50 (B) 70 (C) 85 (D) 78

2. Assertion (A) : An increase in surface area increases the rate of evaporation

Reason (R) : Stronger the inter-molecular attractive forces, fast is the rate of evaporation at a given temperature
[AIIMS 2002]
(A) Both A and R are true and R is a correct explanation of A
(B) Both A and R are true but R is not a correct explanation of A
(C) A is true but R is false
(D) Both A and R are false

3. At 40°C, the vapour pressure in torr of methanol and ethanol solution is P = 119 x + 135
where, x is the mol fraction of methanol. Hence :
(A) Vapour pressure of the pure methanol is 119 torr.
i r
(B) Vapour pressure of pure ethanol is 135 torr.
(C) Vapour pressure of equimolar mixture of of each is 127 mm
(D) Mixture is completely immiscible S
4.
a
Based on the given diagram, which of the following statements regarding the solutions of two miscible volatile
liquids are correct :
t
u p
G
a m
(1) Plots AD and BC show that Raoult's law is obeyed for the solution in which B is a solvent and A is the

u p
solute and as well as for that in which A is solvent and B is solute.
(2) Plot CD shows that Dalton's law of partial pressures is observed by the binary solutions of components
A and B.

A n
(3) EF + EG = EH; and AC and BD correspond to the vapour pressures of the pure solvents A and B
respectively.
Select the correct answer using the codes given below
Codes
(A) 1 and 2 (B) 2 and 3 (C) 1 and 3 (D) 1, 2 and 3

5. The rise in the boiling point of a solution containing 1.8 gram of glucose in 100g of a solvent is 0.1ºC. The
molal elevation constant of the liquid is : [CPMT 1999]
(A) 0.01 K/m (B) 0.1 K/m (C) 1 K/m (D) 10 K/m

6. Elevation in boiling point was 0.52ºC when 6 gm of a compound X was dissolved in 100 gm of water.
Molecular weight of X is ( Kb for water is 0.52) [CPMT 1989]
(A) 120 (B) 60 (C) 180 (D) 600

7. The boiling point of 0.1 molal K4[Fe(CN)6] solution will be (given Kb for water 0.52ºC kg mol–1)
[Haryana CEET 1998]
(A) 100.52°C (B) 100.104°C (C) 100.26°C (D) 102.6°C

8. An aqueous solution freezes at – 0.186ºC (kf = 1.86º; kb = 0.512º). What is the elevation in boiling point
[MP PET/PMT 1998]
0.512
(A) 0.186 (B) 0.512 (C) (D) 0.0512
1.86
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9. The freezing point of a 0.01 M aqueous glucose solution at 1 atmosphere is – 0.18ºC. To it, an addition of
equal volume of 0.002 M glucose solution will produce a solution with freezing point of nearly : [AMU 1999]
(A) – 0.036ºC (B) – 0.108ºC (C) – 0.216C (D) – 0.422ºC

10.* Which of the following aqueous soltuon are isotonic (R = 0.082 atm K–1 mol–1) [Roorkee Qualifying 1998]
(A) 0.01 M glucose (B) 0.01 M NaNO3
(C) 0.04 N HCl (D) 500 ml solution containing 0.3g urea

11.* Which is / are correct statement(s)

(A) When mixture is less volatile there is positive deviation from Raoult's law
(B) When mixture is more volatile, there is negative deviation from Raoult's law
(C) When mixture is less volatile, there is negative deviation from Raoult's law
(D) When mixture is more volatile, there is positive deviation from Raoult's law

1. Which is correct about Henry's law :

DPP NO. # 10

i r
[Kurukshetra CET 2002]
(A) The gas in contact with the liquid should behave as an ideal gas
(B) There should not be any chemical interaction between the gas and liquid.
(C) The pressure applied should be high
S
2.
(D) All of these

A solid dissolved in water if :

t a
(A) Lattice energy is greater than hydration energy
(B) Lattice energy is less than hydration energy
(C) Lattice energy is equal to hydration energy
u p
3.
(D) Dissolution is exothermic

G
Dissolution of a solute is an exothermic process when :
(A) Hydration energy > Lattice energy (B) Hydration energy < Lattice energy

4.
(C) Hydration energy = Lattice energy

a m (D) None of these

Solubility curve of Na2SO4. 10H2O in water with temperature is given as :

u p
A n
(A) Solution process is exothermic
(B) Solution process is exothermic till 34°C and endothermic after 34°C
(C) Solution process is endothermic till 34°C and exothermic there after
(D) Solution process is endothermic

5. Which one of the following plots correctly represents the variation in density of water with temperature :
[AIIMS 1985]

(A) (B) (C) (D)

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N N
6. 5 ml of N HCl, 20 ml of H2SO4 and 30 ml of HNO3 are mixed together. The normality of the resulting
2 3
solution is : [Kerala CET (Med.) 2003]
N N N 5N
(A) (B) (C) (D)
5 10 20 11

7. A 0.01M ammonia solution is 5% ionised. The concentration of OH– ions is : [KCET (Eng.)1993]
(A) 0.005 M (B) 0.0005 M (C) 0.0001 M (D) 0.05 M

8. Formation of a solution from two components can be considered as : [CBSE 999]

(i) Pure solvent  separated solvent molecules H1
(ii) Pure solute  separated solute molecules H2
(iii) Separated solvent and solute molecules  solution H3
Solution so formed will be ideal if :
(A) Hsoln = H3 – H1 – H2
(C) Hsoln = H1 + H2 – H3
(B) Hsoln = H1 + H2 + H3
(D) Hsoln = H1 – H2 – H3
i r
9. S
A solution is obtained by dissolving 12 g of urea (mol. wt. 60) in a litre of water. Another solution is obtained
by dissolving 68.4 g of cane sugar (mol. wt. 342) in a litre of water at are the same temperature. The lowering
of vapour pressure in the first solution is :
(A) Same as that of 2nd solution
(C) Double that of 2nd solution a
(B) Nearly one-fifth of the 2nd solution

t
(D) Nearly five times that of 2nd solution
[CPMT 2001]

10.*
u p
Toluene and benzene form an ideal solution over the whole range of composition. Two different solutions are

have same density (0.08 g/ml), then :

G
made, solution I is one molar and solution II is one molal with respect to toluene. Assume both solutions to

(A) Solution I will have lower freezing point than solution II

[IIT Screening Paper 1992]

solvent

a m
(B) Solution I and II have the same freezing point
(C) The depression in the freezing point of solution I will be less than that of solution II with respect to the pure

(D) The boiling point of solution I will be higher than that of solution II

11.*

u p
At 35°C, the vapour pressure of CS2 is 512 mm Hg, and acetone is 344 mm Hg. A solution of CS2 and
acetone in, which the mol fraction of CS2 is 0.25, has a total vapour pressure of 600 mm Hg. Which of the

n
following statements is/are correct :

A
(A) A mixture of 100 mL of acetone and 100 mL of has a volume of 200 mL
(B) When acetone and are mixed at 35°C, heat must be absorbed in order to produce a solution at 35°C
(C) When acetone and are mixed at 35°C, heat is released
(D) There is negative deviation from Raoult's law

ANSWER KEY
DPP NO. # 08
1. (A) 2. (B) 3. (B) 4. (A) 5. (B) 6. (B) 7. (B)
8. (D) 9.* (BCD) 10.* (AD)

DPP NO. # 09
1. (D) 2. (C) 3. (B) 4. (D) 5. (C) 6. (B) 7. (C)
8. (D) 9. (B) 10.* (A(D) 11.* (CD)

DPP NO. # 10

1. (B) 2. (B) 3. (A) 4. (C) 5. (C) 6. (D) 7. (B)

8. (B) 9. (A) 10.* (AD) 11.* (BD)