EMERGE 2024

ISOMERISM
STRUCTURAL ISOMERISM 06D

Marking Scheme : Single Correct (+3,-1) M M: 93 Time : 1 hr

1. Which of the following pairs of structures do not represent isomers ?

O
O
(a) and (b) and (c) and (d) and
O O OH O O

2. How many isomers of C5H11OH will be primary alcohols

(a) 2 (b) 3 (c) 4 (d) 5
3. Number of structural isomers possible from molecular formula C4H9Cl
(a) 3 (b) 4 (c) 5 (d) 6
4. In which of the following, functional group isomerism is possible ?
(a) Alcohols (b) Aldehydes (c) Alkyl halides (d) Cyanides
5. Number of only cyclic structural isomers possible from molecular formula C4H6 is
(a) 3 (b) 4 (c) 5 (d) 6
6. Total number of structural isomers possible from molecular formula C4H10O is.
(a) 4 (b) 5 (c) 6 (d) 7
7. In which of the following functional group isomerism not possible ?
(a) carbooxylic acid (b) aldehyde (c) ether (d) alkylhalide
8. Total number of structural isomers possible from molecular formula C8H18 that contain seven carbons in
the parent chain are?
(a) 3 (b) 4 (c) 5 (d) 6
9. Which of the following is correctiy matched?

(a) and : Chain Isomer (b) and : Positional Isomer

Cl Br OCH3 CH2OH

(c) and : Identical (d) and : Metamer

Br Cl

10. Tolal number of structural isomers possible from molecular formula C7H16 that contain five carbons in
the parent chains are ?
(a) 3 (b) 4 (c) 5 (d) 6

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11. Among the following. which is not structural isomers of the others ?

(a) (b) (c) (d)

12. Which of the following pairs of compoundsis not a pair of constitutional isomers?

O
(a) CH3 O CH CH2 and CH3CH 2CH (b) and CH3CH CHCH 2CH3
O O
(c) CH3C OH and HO CH 2CH (d) CH3CHCH(CH 3)2 and (CH3)2CHCH(CH 3)2

CH 3
13. Name the compound, that is not isomer with diethyl ether
(a) n-propylmethyl ether (b) Butane-1-ol (c) 2-methylpropane-2-ol (d) Butanone
14. C7H9N has how many isomeric forms that contain a benzene ring?
(a) 4 (b) 5 (c) 6 (d) 7
15. Which of the following compounds will show metamerism:
(a) CH3COOC 2H5 (b) C2H5 S C 2H5 (c) CH3 O CH3 (d) CH3 O C2H5
16. Only two isomers of monochloro product is possible of
(a) n-butane (b) 2,4-dimethyl pentane (c) Benzene (d) 1-methyl propane
17. Number of isomers of molecular formula C2H2Br2 are
(a) 1 (b) 2 (c) 3 (d) 0
18. How many alcohols are structural isomers with the formula:C5H11OH?
(a) 5 (b) 6 (c) 7 (d) 8
19. The number of isomers from the molecular formula C7H8O having phenyl ring is:
(a) 2 (b) 3 (c) 4 (d) 5
20. How many isomers are possible for C3H7Br?
(a) 1 (b) 2 (c) 3 (d) 4
21. The number of possible alkynes with molecular formula C5H8 is
(a) 2 (b) 3 (c) 4 (d) 5
22. Total number of alcohols possible (structurally different) for molecular formula C4H10O are:
(a) 3 (b) 4 (c) 5 (d) 6
23. Which of the following pairs of molecules are NOT structural isomers?

CH3 O OH
CH 3
(a) , (b) ,
H 3C
H 3C CH3 H 3C CH3

CH3 O
HO
(c) , H 3C C C CH 3 (d) H 3C ,
OH
OCH3

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24. The total number of possible isomeric structures for trimethyl benzene are:
(a) 2 (b) 3 (c) 4 (d) 6

CH3 H

25. (i) (ii) CH3(CH 2)3CHCH 3 (iii) H C CH2CH 2CH2 C H

CH 3 H CH 3

(iv) (v) CH3CH 2CH(CH 3)CH 2CH2CH 3

The relationship between (ii) & (iv) is

(a) chain isomer (b) positional isomer (c) Functional group isomer (d) metamer
26. Correct Isomeric relationship between given is:
Cl & Br
F
(a) Stereoisomer (b) Positional isomer
Br (c) Functional isomer (d) Identical
F Cl

27. Which of following alcohol will not undergo oxidation?

OH OH
(a) (b) OH (c) (d)
OH

28. Functional isomers of CH3 C OH are:

(a) 2 (b) 3 (c) 4 (d) 5

29. C7H9N has how many isomeric forms that contain a benzene ring
(a) 4 (b) 5 (c) 6 (d) 7
30. The number of isomers from the molecular formula C9H12 having phenyl ring is
(a) 9 (b) 8 (c) 7 (d) 5
31. The number of isomers from the molecular formula C9H12O having phenol is
(a) 25 (b) 24 (c) 23 (d) 21

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All students are advised to solve DPPs within allowed time only.
All discussions are scheduled in every 4th doubt discussion class
–MKA Sir (Guruji)

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