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Advanced Level Problem Solving-2210

JEE 2022 | Chemistry
Solid State, Liquid Solution, Electrochemistry, Chemical Kinetics, Coordination
Compounds, Metallurgy, Stereochemistry, Aromatic Compounds,
Environmental Chemistry & Practical’s involved in Chemistry
*Mark questions are more than one options correct type

1. Carbon cannot be used in the reduction of Al2 O3 because :

(A) It is non-metal
(B) The heat of formation of CO 2 is more than that of Al2 O3
(C) Pure carbon is not easily available
(D) The heat of formation of Al2 O3 is too high
2. Which of the following reaction is known as ‘clock reaction’ ?
(A) 2I (aq)  H2O2 ( )  2H (aq) 
 I2 (aq)  2H2O( )
I2 (aq)  2S2O32 (aq) 
 S4O62 (aq)  2I (aq)
(B) Na 2S2O3 (aq)  2HCl(aq) 
 2NaCl(aq)  H2O( )  SO2 (g)
(C) Na 2S2O3 (aq)  2HCl(aq) 
 2NaCl(aq)  H2O( )  SO2 (g)  S(s)
(D) 2I (aq)  Cl2 (aq) 
 I2 (aq)  2Cl (aq)
Cl2 (aq)  Na 2S2O3  H2O 
 Na 2SO4  2HCl  S(s)
3. Which of the following metal has high maximum prescribed concentration in drinking water ?
(A) Al (B) Cu (C) Zn (D) Mn
4. Given E0  0.34V
Cu 2 /Cu

E0  1.36V
Cl2 / Cl

E0  1.08V
Br2 / Br 

E0  0.54V
I2 / I

Column I Column II
2 
(A) Cu  2Cl  Cu  Cl2 (p) Can produce electricity in the galvanic cell
(B) Cl2  Cu  Cu 2  2Cl (q) Can be made to occur in electrolysis cell
(C) 2I   starch solution + chlorine water (r) Appearance of brown color
(D) 2Br   CCl4  chlorine water (s) Appearance of violet color

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5. Which of the following statement(s) is (are) correct?

(A) A plot of log K p versus 1/T is linear.
(B) A plot of log [X] versus time is linear for a first order reaction, X  P .
(C) A plot of log P versus 1/T is linear at constant volume.
(D) A plot of P versus 1/V is linear at constant temperature.
6. Identify diastereomers in the following :

(A) (B)

(C) (D)

*7. Which of the following is correct ?

Titration Indicator
(A) Weak acid - Strong alkali Phenolphthalein
(B) Strong acid - Weak base Methyl orange
(C) Strong acid - Strong base Methyl orange
(D) Weak acid - Weak base Phenolphthalein
8. The reduction of an oxide by aluminium is called :
(A) Baeyer's process
(B) Goldschmidt's aluminothermite process
(C) Hall's process
(D) Van Arkel process
9. Which of the following compound is obtained when acetone and benzaldehyde is mixed in the presence
of aqueous sodium hydroxide ?

(A)

(B)

(C)

(D)

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10. Which of the following has been used both as an agricultural insecticide and as a pharmaceutical
treatment for lice ?

(A) (B)

(C) (D)

11. The E0cell  1.18V for

Zn  s  | Zn 2 1M  || Cu 2 1M  | Cu s 

Determine the value of x if when excess granulated zinc is added to 1MCu 2 solution the Cu 2 
eq.

 2.303RT 
becomes 10 x M  T  298K,  0.059  . (Give your answer in multiple of 10)
 F 
12. A solution of A   and B   with 30 mole percent of A is in equilibrium with its vapour which
contains 60 mole percent of A. Assuming ideality of the solution and its vapour calculate the ratio of
vapour pressure of pure A to that of pure B. (Report your answer as ratio  2)
13. Which of following compound is achiral ?

(A)

(B)

(C)

(D) All of these

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14. Match the Column-I and Column-II

Column-I (Compound) Column-II (Nature)

(A) (p) cis-compound

(B) (q) trans-compound

(C) (r) Optically active

(D) (s) Optically inactive

15. Match the column :

Column-I Column-II
NO2
(A) (P) Group attached with phenyl ring is  M

N Rate of electrophilic aromatic substitution is less than

(B) (Q)
benzene ring

CH3
Group attached with phenyl ring will show (H)
(C) (R)
(Hyperconjugation)

Group attached with phenyl ring will show (H) effect

(S)
(Hyperconjugation)

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16. Consider the following metallurgical processes :

(I) Heating impure metal with CO and distilling the resulting volatile carbonyl (b.p. 43°C) and
finally decomposition at 150C  200C to get the pure metal
(II) Heating the sulphide ore in air until a part is converted to oxide and then further heating in the
absence of air to let the oxide react with unchanged metal sulphide
(III) Electrolysis of the molten electrolyte containing approximately equal amounts of the metal
chloride and NaCl to obtained the metal
The processes used for obtaining magnesium, nickel and copper are respectively:
(A) (I), (II) and (III) (B) (II), (III) and (I)
(C) (III), (I) and (II) (D) (II), (I) and (III)
17. Sodium thiosulphate reacts with hydrochloric acid and produces a colloidal solution of sulphur, which
makes the solution translucent. The ionic form of the reaction is written as
S2O32 (aq)  2H (aq) 
 H2O( )  SO2 (g)  S(s)
The structure of S2O32 ion is described as follows :

The two sulphur atoms are marked here as (1) and (2). Which of the sulphur atoms is precipitated as
colloidal sulphur ?
(A) Only s atom marked as 1 (B) Only s atom marked as 2
(C) Both s atoms marked as 1 and 2 (D) Can’t be predicted
18. Lead in drinking water can damage kidney, liver, reproductive system etc. The prescribed upper limit
concentration of lead in drinking water is about :
(A) 50 ppm (B) 5 ppb (C) 50 ppb (D) 0.05 ppb

19. Match the following :

Column I Column II
1
(A) Work concentration cell (p) H2  O2  H2O  electrical energy
2
(B) Spontaneous cell reaction (q) E 0cell  0

(C) Non-working Daniel cell (r) E cell  0

(D) Working fuel cell (s) Galvanic cell
For working of concentration cell, concentration of
(t) cation in anodic compartment should be less then
the cathodic compartment
20. Which of the following is related with green chemistry ?
(A) 3CH4  2O3 
 3CH2  O  3H2O
(B) ClONO2  HCl 
 Cl2  HNO3
(C) NO  O3 
 NO2  O2
2CH2  CH2  O2 
Pd(II)/Cu(II)
(D) in water
2CH3CHO (90%)

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21. Which of the following pairs can be resolved ?

(A) (B)

(C) (D)

22. Which is increasing order of pH of NaCl, FeCl3 and Na 2 CO3 solutions at 25°C ?
(A) Na 2 CO3  NaCl  FeCl3 (B) NaCl  FeCl3  Na 2 CO3
(C) FeCl3  NaCl  Na 2 CO3 (D) Na 2 CO3  FeCl3  NaCl

23. Blister copper is refined by stirring molten impure metal with green logs of wood because such a wood
liberates hydrocarbon gases (like CH 4 ) . This process X is called ........ and the metal contains impurities
of Y is :
(A) X = cupellation, Y  CuO 2 (B) X = polling, Y  Cu 2 O
(C) X = polling, Y  CuO (D) X = cupellation, Y  CuO
24. Which of the following is NOT matched correctly ?
(A) Preparation of dibenzylidene acetone – Claisen-Schmidt reaction
(B) Preparation of p-Nitroacetanilide – Aromatic-electrophilic substitution reaction
(C) Preparation of p-Aminoazobenzene – Rearrangement reaction of diazoamino benzene
(D) Preparation of phenyl-azo-  - naphthol – Aromatic-nucleophilic substitution reaction
25. In the acid base titration  H3PO4  0.1M   NaOH  0.1M  e.m.f. of the solution is measured by
coupling this electrode with suitable reference electrode. When alkali is added pH solution is in
accordance with equation
E cell  E cell
0
 0.059 pH
For H3PO4 Ka1  103 ;Ka 2  108 ;Ka 3  1013
What is the cell emf at the IInd end point of the titration if E 0cell at this stage is 1.3805 V.
26. 25 ml of FeC 2 O 4 dissolved in 186 gm of water calculate depression in freezing point. If 10 ml of same
FeC 2 O 4 titrated with 30 ml of 0.4 M KMnO 4 in acidic medium : ( k f for H 2 O  1.86 , Assume 100%
ionization of FeC 2 O 4 )
27. Which of the following have plane of symmetry ?

(A) (B)

(C) (D) All of these

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28. Match the Column-I and Column-II :

Column-I (Molecule) Column-II (Stereoisomers)

(A) (p) 2

(B) (q) 0

(C) (r) 4

(D) (s) 8

29. Match the column :

Column-I Column-II

(A) (P) Tropylium ion

 CrO 3 in CH3COOH 
?

(B)  Ph3C 
? (Q) Benzaldehyde

(C)  n - Pr Br  ZnCl2 
? (R) Two types of products

AlCl
(D) C6 H6  CO  HCl 
3
? (S) Aromatic product obtained

30. Arrange the following in increasing order of CFSE.

(A) [Ni(CN)4 ]2  [Ni(CN)6 ]4  [NiCl4 ]2
(B) [Ni(CN)4 ]2  [Ni(CN)6 ]4  [NiCl4 ]2
(C) [Ni(CN)6 ]4  [Ni(CN)4 ]2  [NiCl4 ]2
(D) [Ni(CN)6 ]4  [NiCl4 ]2  [Ni(CN)4 ]2

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31. When alumina is heated with carbon in nitrogen atmosphere, the products are :
(A) Al  CO (B) Al  CO 2 (C) Al  CO  CO 2 (D) AlN  CO
32. What is the charges of colloids formed when ?
(i) FeCl3 is added to excess of hot water and
(ii) FeCl3 is added to NaOH solution, respectively.
(A) Positively charged in both cases
(B) Positively charged and negatively charged
(C) Negatively charged and positively charged
(D) Negatively charged in both cases
33. The maximum limit of nitrate in drinking water is 50 ppm. Excess nitrate in drinking water can cause :
(A) Laxative effect (B) Blue-baby syndrome
(C) Melanoma (D) Harmful effect to bones
34. Match the following :
Column I Column II
(A) Molten PbCl 2 Using inert electrode (p) Metal of salt will reduced
Sodium chloride solution using inert
(B) (q) H2O  2e  H2  g   2OH
electrode
Silver nitrate solution with silver
(C) (r) Solution become basic after electrolysis
electrode
Sodium nitrate solution using inert
(D) (s) Solution become neutral after electrolysis
electrode
(t) Solution become acidic after electrolysis
35. Match the column :
Column I Column II

(A) 0.1MAl2 SO4 3 (p) Solution with highest boiling point

(B) 0.1M AlPO 4 (q) Van’t Hoff factor is greater than 1

(C) 0.1M urea (r) Solution with lowest osmotic pressure

(D) 0.1M MgCl 2 (s) Solution with lowest freezing point

36. Match the column :

Column-I Column-II

(A) (p) Geometrical isomers

(B) (q) Structural isomer

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(C) (r) Number of Geometrical isomer of first

compound is even number

(s) Number of Geometrical isomer of second
compound is even number
37. Which of the following is NOT correct for O3 ?
(A) Ozone is a green house gas
(B) Ozone is an important component of photochemical smog
(C) It absorb harmful ultraviolet radiations
(D) It is thermodynamically most stable form of oxygen
*38. The process(es) by which lighter earthy particles are freed from the heavier particles using water is/are:
(A) Gravity separation (B) Levigation
(C) Hydraulic washing (D) Leaching
*39. Which of the following is NOT correct ?
(A) Chloroxylenol – Bayer’s test
(B) Dibenzal acetone – Ferric chloride test
(C) Aniline yellow – Carbyl amine test
(D) Alitame – Sodium hydrogen carbonate test
40. Which of the following is NOT correct for organic toxins used as pesticides ?
(A) Most of the organic toxins are water insoluble and non-biodegradable
(B) These are high persistent toxins
(C) These causes serious metabolic and physiological disorders in higher animals
(D) These are less persistent or more biodegradable
41. The e.m.f. of a cell corresponding to the reaction
Zn  2H  aq   Zn 2  0.1M   H2  g 1atm 
Is 0.26 volt at 25°C. Calculate the pH of the solution at the hydrogen electrode.
42. In 103 Litre sample of hard water CaSO 4 and MgSO 4 is present. If elevation in Boiling point is
0.000052°C. Calculate the degree of Hardness of hard water. ( K b for H 2 O  0.52 )
43. How many chiral center (excluding N centres) are there in morphine ?

(A) 4 (B) 5 (C) 6 (D) More than 6

44. How many of the following are optically active?

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(a) (b) (c)

(d) (e) (f)

(g) (h)

45. Match the following :

Column-I Column-II

(A) CO2  is evolved from NaHCO 3 by the reaction of (P)

Compounds gives yellow oily liquid on reaction with

(B) (Q)
NaNO 2  HCl

Compounds evolve a colourless gas on reaction with

(C) (R)
active metals

AlCl
(D) C6 H6  CO  HCl 
3
? (S)

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46. Give the correct order of initials T or F for following statements. Use T if statement is true and F if it is
false:
(i) Every mineral is an ore but every ore is not a mineral
(ii) Slag is product formed during extraction of metal by combination of flux and impurities
(iii) Highly pure semi conductor can be obtained by zone refining
(iv) Carnallite is an ore of magnesium and sodium
(A) TTTF (B) FTTF
(C) FTTT (D) TFTF
47. Which of the following is used to check the presence of Na  during purification of albumin by dialysis?
(A) Silver nitrate
(B) Uranyl zinc acetate
(C) Cellophane paper
(D) None of these
48. Which of the following is persistent organic pollutants ?
(A) DDT (B) Organo phosphates
(C) Carbamates (D) NaClO3

49. Match the following :

Column I Column II
(Quantities) (Factors on which dependency exist)
(A) Molar conductance (p) Temperature
(B) Emf of a cell in operation (q) Concentration of species involved
(C) Electrode potential (r) Nature of substance involved
(D) Standard reduction potential (s) No. of electrons lost or gained in the reaction
(t) Is on additive property

50. Match Column I with Column II and select the correct answer using the code given below the lists :

Column I Column II

r Anion-anion contact present, cation lies in

(A) For Ionic solid  0.51 (p)
r octahedral void

r Anion-anion contact missing, cation lies in

(B) For Ionic solid  0.414 (q)
r tetrahedral void

r Anion-anion contact missing, cation lies in

(C) For Ionic  0.4 (r)
r cubical void

r Anion-anion contact missing, cation lies in

(D) For Ionic solid  0.9 (s)
r octahedral voids

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51. Match the column :

Column-I Column-II

(A) (p) Structural isomer

(B) (q) Identical

(C) (r) Enantiomers

(D) (s) Diastereomers

52. The geometry of [Ni(CO) 4 ] and [Ni(PPh 3 ) 2 Cl2 ] are

(A) both square planar (B) tetrahedral and square planar
(C) both tetrahedral (D) square planar and tetrahedral
*53. Which of the following are true for electrolytic extraction of aluminium ?
(A) Cathode material contains graphite
(B) Anode material contains graphite
(C) Cathode reacts away forming CO 2
(D) Anode reacts away forming CO 2
54. Which of the following is NOT correctly matched ?
Compound Test to distinguish
(A) Hexylamine & Aniline - Azo dye test
(B) Methanol & Ethanol - Iodoform test
(C) Phenol & Benzoic acid - Phthalein dye test
(D) Benzaldehyde & Acetone - Fehling’s test

55. Which of the following is NOT correct for herbicides ?

(A) These are toxic to mammals but are not as persistent as organo-chlorides
(B) These decompose in a few months
(C) Some herbicides cause birth defects
(D) These are not toxic to mammals
56. For the cells in opposition,
Zn  s  | ZnCl2  sol  | AgCl  s  | Ag | AgCl  s  | ZnCl 2  sol  | Zn  s 
C1  0.02 M C 2  0.5M
RT
Find out the emf (in millivolt) of the resultant cell? (Take log 2  0.3, at 298K  0.060 )
F
(give your answer in multiple of 10)
57. The vapour pressure of fluorobenzene at t°C is given by the equation
1250
log p  mmHg   7.0 
t  220
Calculate the boiling point of the liquid in °C if the external (applied) pressure is 5.26% more than
required for normal boiling point (log 2 = 0.3). Express your answer  t  10 

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58. What is the absolute configuration of the following molecules? (NS = the molecules has no center)
Note : For the purpose of this question only, the order of stereocenters is not specified ; i.e., R, S = S, R.

(I)

(II)

(III)

(IV)

I II III IV
(A) R R, S R NS
(B) R R, R S R, R
(C) R R, S NS NS
(D) R R, S R R, S
59. The following compounds may exist as two or more stereoisomers. These may be classified as
enantiomeric pairs or meso compounds.

(a) (b)

(c) (d)

(e) C(CH3CHCl)4 (f)

(g) (h)

Answer the following question about the above structures.

(1) Total number of stereoisomers
(2) Number of enantiomeric pairs
(3) Number of meso compounds

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60. Match the following :

Column-I Column-II

Compounds which on reaction with neutral FeCl3 gives

(A) (P)
violet/blue colour are

Compounds which on reaction with

(B) (Q)
gives para red dye

Compounds which do not give yellow ppt. on reaction with O

(C) (R) ||
NaOI Ph  CH 2  C  CH 2 CH3

(D) Compound which have maximum resonance energy (S)

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61. When ZnS and PbS minerals are present together, then NaCN is added to separate them in the froth
floatation process as a depressant, because :
(A) Pb(CN) 2 is precipitated while no effect on ZnS
(B) ZnS forms soluble complex Na 2  Zn (CN) 4 
(C) PbS forms soluble complex Na 2  Pb(CN)4 
(D) They cannot be separated by adding NaCN
2
62. Which of the following is NOT correct for the following equilibrium reaction between  Co(H 2 O)6 

and Cl ions ?

(A) At room temperature, the equilibrium mixture is blue due to CoCl24
(B) In a freezing mixture, the colour of the mixture turns pink due to Co(H2O)62
2
(C)  value of  Co(H 2 O)6  is higher than the  value of [CoCl4 ]2
(D) On increasing temperature paramagnetic character decreases
63. Which of the following is NOT pesticide ?
(A) DDT (B) Aldrin (C) Dieldrin (D) Sodium arsenite
64. 100 ml, 0.05M CuSO 4 solution is electrolysed by using current of 0.965 Å for 100 min. Find the pH of
solution at the end of electrolysis.
65. Column-I and Column-II contains four entries each. Entries of Column-I are to be matched with some
entries of Column-II. One or more than one entries of Column-I may have the matching with the same
entries of Column-II.
Column I (Bravais Lattice(s)) Column II [Crystal system]
(A) Primitive, face centered, body centered, end centered (p) Cubic
(B) Primitive, face centered, body centered (q) Orthorthombic
(C) Primitive, body centered (r) Hexagonal
(D) Primitive only (s) Tetragonal
66. How many of the following pairs are diastereomers?

(1)

(2)

(3)

(4)

(5)

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(6)

(7)

(8)

(9)

*67. Which of the following reaction in the blast furnace is/are endothermic ?
(A) C(s)  O2 (g) CO2 (g)
(B) CO2 (g)  C(s) 2CO(g)
(C) CaCO3 (g) CaO(s)  CO2 (g)
(D) Fe2O3 (s)  3CO(g) 2Fe(l)  3CO2 (g)
68. Which of the following compound do not produce red colouration in Lassaigne’s test ?
(A) Alitame (B) Bithional (C) Penicillin (D) Methyl orange
69. Which of the following decrease environmental pollution ?
(A) use of liquefied carbondioxide with a suitable detergent in dry cleaning of clothes
(B) use of hydrogen peroxide for the bleaching clothes in the process of laundry
(C) use of powder of kernel of tamarind seeds to make municipal and industrial waste water clean
(D) use of malathion to keep insects away
70. The conductivity of a solution may be taken to be directly proportional to the total concentration of the
charge carries (ions) present in it in many cases. Using the above fact find the percent decrease in
conductivity (k) of a solution of a weak monoacidic base BOH when its 0.1 M solution is diluted to
double its original volume. ( K b  105 for BOH) (take 50  7.07 ) (Mark the answer to nearest
integer). (give your answer in multiple of 10)
71. 1g of arsenic dissolved in 86 g of benzene brings down the freezing point to 5.31°C from 5.50°C. If K f
C
of benzene is 4.9 , the atomicity of the molecule is : (Atomic mass of As = 75)
m
C6 H6  3Cl2  C6H6Cl6 (Gamexene)
hv
72.
How many meso isomers are possible for C6 H 6 Cl6
73. A compound was synthesized by a student, but its structure was not identified. However, his
wonderfully helpful instructor told him that it was a meso compound with 5 carbons and 2 stereogenic
centers. Which of the following structures should the student consider as possibilities for his compound?

(A) I, II, IV (B) II, IV (C) I, III, V (D) II, IV, V

74. Oxidation number of Fe in violet coloured complex Na 4 [Fe(CN)5 (NOS)] is :
(A) 0 (B) 2 (C) 3 (D) 4

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75. Which of the following is NOT correct for methyl orange indicator ?
(A) Methyl orange is weak Arrhenius base
(B) The unionised form of methyl orange is yellow in colour
(C) The quinonoid form of methyl orange is deeper in colour and thus is responsible for the colour
change at the end point
(D) It can be prepared by diazotisation of p-amino benzene sulphonic acid followed by coupling
with N, N-dimethyl aniline

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76. Leaching of Ag 2S is carried out by heating it with a dilute solution of :

(A) NaCN only (B) HC1
(C) NaOH (D) NaCN in presence of O 2
77. Which of the following is NOT correct ?
(A) Milk is a stable emulsion
(B) Dettol forms an emulsion in water
(C) The stability of an oil and water emulsion is increased by the addition of soap solution
(D) When an oil soluble dye is added to the emulsion, if the background becomes coloured the
emulsion is oil in water type
78. Which of the following is correctly matched ?

(A) Only (a) (B) (a) and (b) only

(C) (b) and (c) only (D) (a), (b) and (c)
79. Small spherical ball of silver metal used in jewellery having diameter 0.1 cm, which is obtained by the
electrolytic deposition. It total number of balls in jewellery is 10,000, then calculate the applied amount
of electricity in coulombs, which is used on the deposition on electrodes.
It is assumed that 3.5% electricity consumed as wastage during electrolysis. [Give your answer in
multiple of 10 4 ] [Density of Ag = 10.5]
80. Match the column :
Column I Column II

(A) 74% occupancy of space (p) Cubic close packing of identical spheres

(B) Coordination number = 6 (q) Hexagonal close packing of identical spheres

(C) 68% occupancy of space (r) Body centred cubic packing of identical spheres

(D) Coordination number = 12 (s) Simple cubic packing of identical spheres.

*81. Which of the following are isostructural ?

(A) [Ni (CO) 4 ] and XeF4 (B) [Fe (CO)5 ] and S(CH 2 )F4
(C) [Cu (NH3 )4 ]2 and XeF4 (D) [NiCl4 ]2 and CCl3F
82. Which of the following is NOT correct ?
(A) It is 2000 times more sweet than cane sugar
(B) On complete hydrolysis it produce alanine
(C) It is more stable than aspartame
(D) It contain glycosidic linkage

VMC | Chemistry 18 ALPS-2210| JEE-2022

 Vidyamandir Classes: Innovating for Your Success

83. Total number of stereoisomers for the following molecule are:

84. Which of the following is an organo-phosphate pesticide ?

(A) DDT (B) Aldrin (C) Malathion (D) Dieldrin

85. 3 ampere current was passed through an aqueous solution of an unknown salt of Pd n  for 1 hour. 2.977
g of Pd was deposited at cathode. Find n. (Atomic weight of Pd = 106.4)
86. N A spheres of radius ‘R’ are melted in X  N A smaller spheres, so that when fcc lattice is generated
from smaller spheres the edge length is formed to be 25/6 R Find X.
87. The binaphthol (Bnp) is :

(A) An optically active compound having chiral centre

(B) An optically inactive compound
(C) A meso compound
(D) An optically active compound without chiral centre
88. Which of the following molecules is/are chiral ?

(A) I and II (B) III and IV

(C) II, IV and VI (D) I, II, III and VI
89. A complex of certain metal has the magnetic moment of 4.91 BM whereas another complex of the same
metal with same oxidation state has zero magnetic moment. The metal ion could be :
(A) Co2 (B) Mn 2  (C) Fe2 (D) Fe3
90. Griss - Ilosvay test is used for detection of :
(A) NO2 (B) SO32 (C) S2 (D) CH3COO

VMC | Chemistry 19 ALPS-2210| JEE-2022