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Alcohols Phenols&ether

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Alcohols Phenols&ether

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ALevhols, Prowl auc ethos, Sours pal RUe Bydaocorbor, id es SS : Akiphotichyswocarton Agonotce Aytincoson He zeplated b OH soup OH ROH aleobwk a *8 phenol a or 7 OH mat treet aptathed- 5 ZS, bomosie aheobn L cay ena RH > H & Aeplated-h ORC obboKy % otHs) ie ik ¢ Ya oaglons 4 oop ) podoetie ossificadiow anh. B- on munrber o Olt ce } ° 2 Monotey die —_ | ditycue o ie 2 w Bundt j vcd feo) > ear EEE -» GQHoeHK ey Ett ee oe ethouk cH,-0HK co a cslycoo2 ] a Wen etol Con (Vorewwe Om oad oe or le iM pesorctno® op 2 ou On . ceaeeok oJ P Fomet chs Phemod | Monohy dace abeotok Compound. Contaunin Cops OH bon: he abc. oScotol 2 7 Benz ye 50H re pie 20H pop U2 attached | 6, gli obehioh fe oye 4 Sp3 conbon. ne 4 OH group le oe vite oe hom next eu k-cH-OH ee ff © puomoty CHye ch -CH oH sad l bon secondty nl yon (ol se omni on Textior p a : pet ~ compount. contain aii pape =i — Nin abcobok f seen = OH group axtouked oH perpen fe , Corte. Cx: oloubbe dorkon &% azo ma htt Jeon de te to winylte ang ov com cpp sCH-OH coy phouck ‘ ethers dgnncctitcot Mixed grin ee seem nrop | Umegef Mee attarhed to 0 ore yap SOP a gporont game CH,0CH3 M Ks CH,OC HS mell.nrg toe) ue ote | Oe pein engme Pemapre: Nomenclature op 00 CH, -CH,-CH,-OH CHx-CH-CHs | CH= CH CHLOH Ou Common. on Peopyl aleokne Tropeepygly |p on-Buty® abeobot name ae sob PAC Propan-l-ok Propan-2-08 bichon Nome Pe CHy- CH-CH,-CHs CH,-cH-CH, OH CH: ‘i OH arto ccbposaied tok piitye abcolul ! . Common, set Buty? robuey ob a-mettye popan2-O upac Butan-2-0& 2anethay? (nope ie Ethers Cals OGHS CH;0%2He | Ggnccochs / hem tamamon 9 Deedee ORS ety meth? | Mette ‘aid 00 mn e i ethane tho 4 Tupac » Etkony ethane paethoxs mel Bo. ak 3 : Stusctune h Pumttoonal Abeohast Phewve ot eee a am se jae wes SN OM | Re u-G wearH a, Wes ang inte Sp A proton’ 13 pi . nest — Bonk eo us (ham 7-0 bond im mactiione - pelshedaaLangfe (lots? phew Cla6pm) Bowe angle is due ba nepubvionds AUS tam ametiiar) entts then { unshared eertrone © ore eer A at a aut ch ora as tie beh Preparation 4 okcokols |. Eepne atleenne ” i. © by auth coctabgteok Teli polation ; CHycH cH, +H? Hs cHy-ch-tHs Birding be diy opaaneon nhkeovs ube mechansm seapt- protonation df ablene tappin Coukocatiory Lun attarle of H0* Ay ele tro] RO+tHt Ht ts os \ if ~ WNeset yt wlo- Ha ee +H: : H A pcalton W\ Se uw H Es l =o ( = \ @ ate hes ° ° - ot w @ As gala 2 £ , Hyoleo, go¥ld e, 2sep pibotane CBMs), {yd ge PORT ou. a CH. —cH=cH,+ ee cota a a ee ; ee “cH CH) 3H -(H a (CH, -CH CHL) Bl sengnsyet “anh pects Propan-| + BCOH)s 2,0 Jotemor teste! a } ee (Beer, cp cHOk Bud 3 ch,cHeC he Wala BCHCH CH 2, Pom cantony’compounnt Y ptdebyde eee C0! cna sual 9cO™ cs pcook! O byrectutiond, pudehyde onde HIP" ® Addition g 4 idaogen ae A, Cmoleute. NHI Nastent oygtne Aayderg eusstsrn Rectuclton T s eo ere cee [Finelcnitect ee NoBH4. LAL Ke Lith Ne, Pa, pk Sool bio uy Pr e Ay bide albumin ecto+H, Pe ypc, OH pep NeBHts p bak —- Pol aa cucuott, A> CHCl Su x , oie cope tt, EE cu _—cH-Ct. es 2 Ascelag ch > fabeoho! ; b vctone 3° ve. @ Byseduction. s conkonybee. quick and esters ° p- COOH Gane PCHOH Tic ADM, Os am ex pensive » ent EUs fot f % PoP O demic pion He fa ' RCOOK 5? pcoor Zabel 10K 4 OM Gy Hs0H aM cuye-O OH + Ho GELC2OR) aaa 3 ut Ettiyl ethauoate He OH 3. daLquord 2engouk SO x Famaldclyle hol any olter abt oF : d [ceforne fs ateohot u u ee H,. Wo D Ba gon a Pes ie pr p-ck? admgr pat Otani pea OF ays e! S P ateleobet | . ‘ = c-OMyx > p-cop + PMgr Cea x pc Or + MgO , ' a ood | Preparation. howls O Fxom Aoboorencs 6231 by & | O} + Naor => 300 alm o eet Soduum o Ph an oH @ Fxonben e wetplinit HE, © E Be aud ONG Co tg Haon> (OT ad One ‘rookie phew: _ ud dena OH @ Eaorn cumons pe che foo K Fe oO © or cumene °° phewwe Acerone Cumeme ; aul tes xed C So PRCT 0s hy dtsoperore ‘Acetone rypodact . atiee pepored tn tn Soage phyptcol panpertiet Boulter 0 Unk: Cee aT vordmnstt HET yy ; ew seed Tn eanching T sungave 0202-1 Yau forces © eer Hobo orns Sobubilety 4 Akhiok aud Phenols are golutle On walt > form H-bond Woe. water > Solubility) Soeg ay lage pore chow cob goatlon ° Vesgatile compotenol i rebephuke 08, uuncteoplile Prctonoked ohio fr on CAO be beok en + boncl beter ois Koken * Bouol bebe => B 1 Anas peo- ¢ © p-Bu —p-b-4- 7 a | at cw 28H 2 Ba Hite ez 5 teolne inettg Teens BOE and Phot 1, act obiey oaanlnl ace. head ; Saunaee © ablcoxde © Reattion withomotal patel Rous Cpl OK + aN | > Rom | Gps +H Now Yo caches, mel phewoxide m DCO Na —72CHs0NO. +H coda vnettdXce u,? 2 COOH PNo —aeyona +H. Co oli pheno xtde phewk algo 2e0nk with, ogNa0H H Na Ol + NaOH > ui +4H,° i Nee bose godine aene Gama > NewtrolinlPe, ction > Alobok darot gow phovtwk and Phenwl > pBeovsteot aud CGnre 2 anes 6B: ee — BH + oPrk Bose Aus Saat — conpurgnk one cord Oo. tuarealir O Acéoli alrobol Auictit matere 6 albne -» Pol fol oaltey o-H bond » Election seleoving Feat poup CHa, CHS) > Tneendes ebecteon densi by A ah onorg gen uv aise On pobatty decreases — Pelee | RyCH OK > ScH-OH > Bb xe-0H Rrra Rp chee. det, 1° , “ apne yf 7s plc aal ane £5 auigtéc toon Hy0 p-or tH-O-H Ota 40H. ease | Aud Conpugate ait Or os + alate, is better H*LOU0e —> Stronger thon abcolot 5 Ror fs better Ht auepter than OM Teen Aydenride : “"pboside te anonge 2° Dbase oluo vecanee pumehatect L022, ae _a baat CHa, Ate? ane Te & 4 — so bode bi fo nae on otarbed SD> CLE ret ding at 08 elatoe a Pherwk & mete artdit than water and alberto Reogon O Bonizotion j Oo poew = RO EHt & = ol “ne " auielet = pea 0H & attached sou is attached to High elertro negative ope iC nt cbestioncaptive Cache bm > é density onoryaen T > € densi ay on nga 4 + pobaaity o 0-H bone + > Pohanly ob O-H wove T > Ionization L L > ToulgationT tt Ear grength > petlic BREN @ Stability peiclic Emerg gteonlitiy Antone “ Abtoxide CP-0") phowoxide ion (Cr?) ee + ve chasge Bee ye he Atyonance effet on oxygen 20K" i pads 2 ae ceanility, ¥ ee a acy nesonomee tn Phomoxcde oe oO H ea 6) > cee ten ce bowl becaus® Substituted Pheu? Etectron woth daawing Eletiou donating ee ELEC! > Ede drow pulled away 7 Ekertion pustied tower pm mga ge ite oresatave chaage > obiltty? = "¢ d stab bites puisie eBongee aie soma : ok e vag eg Paget 7h @ asteaijientio cbigds plurtiok anol Prema goatt te aie aot at ande ROH + Bee u ot © ut pons QOOlO => a ott — picook d Ls penta) > H, Ho xonnove Hog fh ea endl 7 Pyuaone ew ma 2 : co) rarad orchefe FOP > Dlr pxetybabor Cee cots oF oy ut 0 =? {Tt (Cc we CCH COD os L is cucoot cauk eas ct nepal Reaution bavelves Ueavaze of 6-0 bonel.. 1. Reartion with Anygobangen Mobioer . ROH+RX > Rx+H,o° (ucag #28 2 ROH ca0buble) | zoe seagank (ON Nigdbons nth) pee tmmis ct bee? )7 H $04 ee eee rs pete cle tna > c—c~u anhydeovs Kw (aaa 4,03 sce, 443k cus cH +H,0 CH,CH,OHK Cone Hy S04 a Beit Pama® are hob 2 am ashes 7 CUs-CH- Cl,“ gaole A Ou é cH3 207: H3P% CHy-c — = om ch +H,° 4 i -c-OK Bike a Ce cen Ca ag : : i clos, De a ad amb pacck tonatect abertol: @ kK + Fast, CUs- ss aH tS, chs 0 ee ° Céty onontinm 0 Step2 > Formatiowd, eae 2 re) v : —CH, eaaauene ei A ye eartwocatibu 1 Hs * etione «patie wre top te step & & s Etnene te somove to Aue tn ale fe @ oeidatin. ees =o » outolatiow Ce eonoge & C-H ovals 40 fom 7 BS deogrsaline ors of diy Pager Seno aud O-H . Also called ctehy dt oxedisn rl 0 oe a “donut ROK — RCHO RoR Paco —RCOOM ebtro cBaomate) 3 pee Chrystie milan C0, ith pyitine +Hee- -CH,OH PCE CH,-CHeCH-CHO CHy -CHscH ssobuaateg folertok p-cH-k chuomsiX™ »_¢ -p! ou yee wedione CH-CH, a 3 on “to Pee ee eG aa prdehy de -cH-OH ray a > ae Tk My in Cus 3 abeohok 2 ateodo! [cetone dog vy drelio Um at Guna : ‘i K 's cea easel cH, doch, tHe congution. * BE E We *teone ene - peartinnedh plows 1 Eke cle phe pap matic sos LEY « phew ex Bibl ROME @0-H ©o-# a nas i nctinated EAS cs tee 3 ° 0, p2treteng uaael J ne ALANS conc: HN [up eno & , Craale) ys NOL a @ “or NU, ou ~T, Nae Coane ant nga seen, ° 06 SoH vol ol ce Oey 1 : Oo a e° wera (vine notes (Taterrnateout A 3 Haloganation ae wu ar : and Low pobark cty Brontne wafer ee al & : on Br. co “6 el o-teompphour® Fiemein BA oD r when? 24,6 pinto ae cha a pial) 2 Tn Phowk, ptesiuate toke place bx 08 ence Letts on pase Ce OD hecauke % Aight, ote canny se? GO" FP qttached & ae ag a Ol®, CO cooH & NQok, Si? Oar ES hyde era ey Lenpxac GS cand) » Phonoske rst ee ar CO. | eg tebatiom ome cro] c. 6 s, ice ee HeALtINe than Phew clio Reb en, -Teemann 408 E ® Leim tt nao, aio ae or 4 cuts [ o ase ea oes @ readin uith 2 use rare He et fi Ayeerth © oxidation o He Benge Nay oO O oO} Hse¢ nf Benzogutnone Some. com mexcrably Cnporbank byl Ih mettanok alec kmown0’ 1200: ps ce 7 bestuctive disdain 5 2no7 0a, CO +2H, Seino aan _ 843-64 » coboulers anid * B.P2 33 Fle « Lighhy pottonous > Te dow o smodl wantity i lanclnc pn ca aaa + Sok un paw eh elie pice ee ide - 2. Ethanol 2 4 MOM, 2.C, HOH. t20O- 1 + Few ZT tation peiger. Cols + omacapbte comaadion - Cs és sefeased aleotoe ts made nf ie ba aishenlcong . Commesical ee oper suciprhot (£09 a 2, co e i he Mean by me en ct nal Pp by oading Me é js cio ney ee Gee CES pseposotioe be es bg aed ouch, ¥ 4ak | soe ae ee io an Cy Hs OCr HS piety eA% De +3 MecPuovntim Step? + Paotonotlong alcohol | ch,—cH,— 0-H tHE cncHg oer Step>> Attack i. cH, - CH 0 Step3> Lose B. 6 cH, Hoo a Fann. this method? eee alcotnk on. pent onoiecl ATC" a oa See Hot CH, cH Hs +H,o CH,-CH- o- pote Hy- CH 9 —— i ~CH, 6 u,cH-0- CHE Ht H® Gow) * abenhol tN El aad gyQ eens "evens. L BUNe itléamion tise antgnméical cleo con t pepated . symmstaical awl tiga meBOO, ut Alege alide * p noi RX + nie apdiaancavnase fo fm Oe 2 & pelo Nes p-O-Na yy muchooph eGte) cu u 7 ON = Zz Pau ose as ae dens oe ek Ce 3 CHa & ree ©, 8 odinum BE dahicle > Mme ne No oP cH! cHs suse ange putorides a tnation by BAM: ou 1G No emo ons phowk physical “ yaliol EPS. naauck ofipele. momen, © 86 ponct tn etkes & pp Bowlin aint CBP) i Laaity o thew BP choca n> onbecul Mm penta Oca i smiled. eae adteame 4 Se Sokubbity > mye sone We @ w-vond: ed pie ue ith Ageale ps a. RULE Lond nya g tay > HE HOR? HY tC ° CR OH * pus to promodion pasta Fe weonons ont pu osteyprorggen bow Alley aon paeeet aa epee af one &, “the R porp On s TRe suo sa rear’ aliege foude —® akg een us pore me mMebawsm 4 Steel 7 ae cH, + ae is cHsee cH, ae Step 2 > Nucbonphiee’ S ‘i zoe hye -o8 cages fT bye 2-H) CHACH OH te cht + Be » I beén sa etek ape onan om dsplate o” se pegioups cue pase / tft Lane obese group tank fom DT- Step?" phen RT Tigh Tompson . peaction at “gh vetiaaml ence with ont poate mebacede ANE costed ethryeio ipdide ast aa ee Py Cc ewer chs ee ou cise tho . ser 2 When one BP group ie bettas “hobide ts ferned : ong @ 4) & oye SINt oneckawdn i Hs ales St $e si CH,- 28 Cu, FHT OCHS —GHCHy +E won cus GH e Cs Epa cH a duet ; oP Hy - Fast CH ait + PCat me si i chs ots case3 Aniioke Gree tat aos One CH, oT ear fey onxes® act Crt oxontunn 10" o> + Bond been o- Cs i ten an Pe i, eck amc p 2 0 pouble Youd B 5. elecbte “ie subg tudor a ike et BS ee oil cated |) : ols RonF go aS © Halogenotow sl ocr oc, Bay m “ eM, (0 + [O Ethanole i [eto ad cae p- tromoomsle Comianer) Chnafot) ® Faiedal wpe CH. CH é 7 rn ADU, CH. @ cg tinea Oy” a) CH, egiation 3% wae, a (o + cH, cok anlydrors AO Bs coc, Ms (eo) + 12 es wel a oul 4 metry nldaabion. ee ees Oe CMs ae Se, at oJ “tno; es L of NO, 4 Nd% ausole NCERT Tufext Atueshow ULL Classify ‘CLOW if “6 nt ana x @ Chy- en HOH at a 4 ( =cu-cH,oH © He =cH-cHO © CHCl CMs @ cry ch CH aot G gor Oey SCH yon bs © ALcobv£ ©, D> Pusmary © AewkoL @auk@ 2 secon y © ALcohvl O > Tertiary (L229 LTaentifg allylic caleotuk in above exarnples rane Abeobol @ tO Wyle 13> Name the polbowing conpouuclt awning to to DOPAC vowe Syste - b 2 u a 3 © Euy—eu,- € tu ceH- CH-Chy cute cH, a 3-chdaormne ya Cte yl ettegt) Pi eutan-t-0F oma GHZ OH ® ch eu, — buen cH, cs ou Ug - Show how are Che bvllowum, alot ols popated ty Ae atllon, 4 a surtable Crtguond Reagent On metthanal @ CH, —cH-CH- OH. Sie u Mg I ~en =CH-CHO io CHaScu-Mgt * ee a CHT CH C25 a Oe [pore* CH -CH-CHOK cH,OR uy ccs cus { GhOMy Be cHoH. Host @ ok AY toe a | US Wate gructure 4 poate b fottowwns scaclinn. eee © cy,-cecw, ee > ~ ¢-008, . 0) oy ve 5 Noble —cu CHO Nak cu-cyH A cHy -ocl cute > -cy- cH CH? @ cH Hs . would expec 6 > Geve BAUCAE op the poduls Soe i © Hee (20h, Buy Ost. o 8 98 zal cuce CHAE ne , ace ct ad O2- Methyl btan-2 ne ye “o£: Cs, =cy- CHa +Hee AS cH ec Hs ee, cH-c 2H cHy- C~ Poy tH, 150%, — CH ihn tM du re ie ct, d= tec, + HR” cape cH ths OH We Pail otis a pee dl ae Lemnblliyl cyclhokexowol skool chy OK By ut oe A? jemetiyeigenenens D putantof ut ach che Ch chook ~~? cael CHC och ei CH= CHM re oe is formeck ue Le R20 gutermedcate omootation be give £e 2 seartionsee Williamson’ eae ae " te aS -S-methyl pons enciane starting, fom ice se potted ho ans cu -eycon eH -cw, NO, ve NG, cu CH Gn ONG: A a cs < hated gnes a PBS. : a oA, io 3 CH;CH, Bs chy cher “ba ona. aaa car CHO Cots { Us Cts dM, cb, tNo @° 43 Lit > bhi, of Hee folowing bs ann opproprcote ; se & seartkamk fot Ake peporation a, (- mnethnny-F mnitin ben gene. anh Why ae a ® (CJ +t NO, Nop . Ans is an appeoptate set greatants $rt tte preparation aft mnethiony + ee eae : ecause alleyk Aatde wundl ote wucleopbiha tetechion Aeadilg « hes donot Seb & nab approphiate Sees aie | uncler pus cetulion oO @ +CH,oNa cH. NG a O + CH, BS aad. (e) 4+Na NO, Bs - Noy dict the poo 4 -CHyr HOA aed Lee cH, CHO s cH, oc pls GoM t04 fone er oO (ol Coca (ols: + Cone HNO ce potbowreeg goartton UD + Pre Ocy-cH ut —o GUs a Cc Hy), IH. (o> CCHS)C L+G Ht? 2

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