Sah 1957
Sah 1957
Summary--For certain p-n junctions, it has been observed that It has been pointed out by Shockley and Read4 that
the measured current-voltage characteristics deviate from the ideal generation of the current carriers in the space charge
case of the diffusion model. It is the purpose of this paper to show region or the transition layer of a p-n junction may be
that the current due to generation and recombination of carriers from
generation-recombination centers in the space charge region of a extremely high. The essential features of the reverse
p-n junction accounts for the observed characteristics. This phe- characteristics of a silicon p-n junction can be under-
nomenon dominates in semiconductors with large energy gap, low stood in terms of this phenomenon by using a model of
lifetimes, and low resistivity. This model not only accounts for the single energy level uniformly distributed Shockley-
nonsaturable reverse current, but also predicts an apparent Read-Hall recombination centers. Pell and Roe,' and
exp (qV/nkT) dependence of the forward current in a p-n junction.
The relative importance of the diffusion current outside the space Kleinknecht and Seiler' have independently used this
charge layer and the recombination current inside the space charge model to account for the reverse characteristics of sili-
layer also explains the increase of the emitter efficiency of silicon con p-n junctions.
transistors with emitter current. A correlation of the theory with ex- Shockley has suggested that the recombination of the
periment indicates that the energy level of the centers is a few kT carriers may also dominate in the space charge region
from the intrinsic Fermi level.
when a p-n junction is biased in the forward direction.'
I. INTRODUCTION However, the importance of this effect on the p-n j unc-
r HE VOLTAGE current characteristics of p-n tion and junction transistor characteristics has not been
junctions have been studied by many authors. realized until recently.7
The ideal theory of a p-n junction of Shockley In this paper, we present a physical theory of p-n
accounts for the electrical characteristics of a ger- junctions taking into account the recombination and
manium p-n junction quite well at room temperatures.' generation of the carriers in the space charge region or
However, it is generally observed that at room tem- the transition region.
peratures the measured electrical characteristics of sili- II. SHOCKLEY-READ-HALL RECOMBINATION STATISTICS
con p-n junctions deviate considerably from that predi-
cated by the ideal theory. For example, Shockley's ideal A brief derivation is given in this section for the
theory predicts a saturation current for the p-n junction steady-state recombination statistics of electrons and
under large reverse bias and a simple dependence of the holes in semiconductors to illustrate the method and
forward current on the applied bias through the Boltz- physical principle involved. For a complete and detailed
mann's factor of the full applied voltage when the for- treatment of this subject, the reader is referred to
ward bias is several kT/q. Usually, at room temperature Shockley anid Read.4
the current in a silicon p-n junction does not saturate at The recombination and generation of electrons and
large reverse bias and increases much slower than the holes in semiconductors may take place at some type of
Boltzmann's factor to the full applied voltage under recombination-generation centers or traps. These sites
forward bias. Discrepancy has also been observed by may be crystal lattice dislocations, impurity atoms lo-
many workers between the ideal theory for p-n junction cated interstitially or substitutionally in the crystal
transistors and the observed characteristics of silicon lattice, or surface defects. Recombination may also oc-
p-n junction transistors. In particular, the ideal theory
predicts a nearly unity value for the transistor current 4 W. Shockley and W. T. Read, Jr., "Statistics of recombinations
amplification factor, alpha, at low emitter current of holes and electrons," Phys. Rev., vol. 87, pp. 835-842; Septemnber,
1952.
densities, while the observed alpha usually becomes very R. N. Hall, "Germanium rectifier characteristics," Phys. Rev.,
small at low emitter current densities.2'3 vol. 83, p. 228; July, 1951.
R. N. Hall, "Electron-hole recombination in germanium," Phys.
Rev., vol. 87, p. 387; July, 1952.
5 E. M. Pell and G. M. Roe, "Reverse current and carrier life-
*Original manuscript received by the IRE, March 23, 1957; time as a function of temperature in germanium junction diodes,"
revised manuscript received, May 13, 1957. J. Appi. Phys., vol. 26, pp. 658-665; June, 1955.
8 H. Kleinknecht
t Shockley Semiconductor Lab., Mountain View, Calif. and K. Seiler, "Einkristalle und pn Schicht-
1 W. Shockley, "The theory of p-n junctions in semiconductors kristalle aus Silizium," Z. Physik, vol. 139, pp. 599-618; December
and p-n junction transistors," Bell Sys. Tech. J., vol. 28, pp. 435- 20, 1954.
489; July, 1949. 7 R. N. Noyce, C. T. Sah, and W. Shockley, "Carrier generation
2 J. L. Moll, et al., "P-N-P-N transistor switches," PROC. IRE, and recombination in the space charge region of a p-n junction,'
vol. 44, pp. 1174-1182; September, 1956. Bull. Amer. Phys. Soc. II, vol. 1, H9, p. 382; December 27, 1956.
8 M. Tanenbaum and D. E. Thomas, "Diffused emitter and base C. T. Sah, and W. Shockley, 'Interpretation of silicon p-n junc-
silicon transistors," BeU Sys. Tech. J., vol. 35, pp. 1-22; January, tion current-voltage characteristics," Bull. Amer. Phys. Soc. II, vol.
1956. 1, H1O, p. 382; December 27, 1956.
1957 Sah, Noyce and Shockley: Carrier Generation and Recombination in P-N Junctions 1229
cur directly with the emission of light or by the three (or TABLE I
more) particle process (Auger process) with the third SYMBOLS
carrier carrying away the energy. The radiative process n = density of electrons in the conduction band = ni exp (F,,-Ei) /k T
is rather improbable. At present, there is no sufficient p = density of holes in the valence band =ni exp (Ei - F5)/kT
information about the Auger process in semiconductors. E,= energy of the highest valence band level
E= energy of the lowest conduction band level
Thus, these processes will not be considered. E,=intrinsic Fermi level =-q
Under steady-state conditions, a single energy level Et= energy level of the recombination-generation centers or traps
recombination center is characterized by three numbers: eg=(Et-Ei)/kT+ln V/rpO/7nO
I =electrostatic potential =-E,q
the capture cross section for electrons, the capture 'D=diffusion or built-in voltage in a p-n junction
cross section for holes, and the energy involved in these on= quasi-Fermi electrostatic potential or imref for electrons
transitions. The cross sections are inversely proportional 4,=quasi-Fermi electrostatic potential or imref for holes=- F/q
to the lifetimes of electrons and holes respectively, and n=-density of electrons or holes in an intrinsic specimen
N0 =effective density of levels for conduction band
the transition energy may be measured from one of the N= effective density of levels for valence band
edges of the energy gap of the semiconductor.8 Nt=density of the recombination-generation centers or traps
ftp=fraction of traps occupied by holes
There are four basic processes involved in the carrier ft = fraction of traps occupied by electrons=1 -ftp
n,=density of electrons in the conduction band when the Fermi
generation and recombination through the traps.4 If a level falls at Et=ni exp (Et-Ei)/kT
trap is occupied by a hole, an electron may drop into the pt= density of holes in the valence band when the Fermi level falls
trap from the conduction band and recombine with the at Et = ni exp (Ei-Et)/k T
mrO=lifetime for electrons injected into highly p-type specimen
hole, or the trap may emit the hole to the valence band. tro=lifetime for holes injected into highly n-type specimen
If the trap is initially filled with an electron, the trapped q = magnitude of electronic charge
k = Boltzmann constant
electron may be emitted to the conduction band or a T= absolute temperature
valence band hole may move into the trap and recom- U0. = net electron capture rate
Uc,,= net hole capture rate
bine with the trapped electron. These four processes are U= steady-state electron or hole recombination rate
illustrated in Fig. 1. The direction of the arrow indicates Jr=recombination-generation current density in the space charge
layer
CONDUCTION BAND JD -diffusion current density outside the space charge layer
E
cEI where a is a proportionality factor which includes the
trap density, the total number of empty electronic states
in the conduction band and the probability of electron
emission from the traps. The expression for a can be
t
D- obtained by a detailed balance argument for the system
under the thermal equilibrium condition. Under this
condition, the electron emission rate must be equal to
the electron capture rate, i.e., (1) and (2) are equal.
Thus, if the occupancy of the traps is expressed in terms
of a quasi-Fermi level4 (or imref) for traps Ft, then the
v imref for electrons, Fn, must fall at Ft at thermal equi-
librium. Assuming that the semiconductor is nonde-
(a) (b) (c) generate, and using9
VALENCE BAND
Fig. 1-The basic processes of carrier generation and recombination ft = (1 + exp (Et -Ft)kT)-
through traps, (a) electron capture, (b) electron emission, (c) hole
capture, (d) hole emission.
then from equating (1) and (2) we obtain
the direction of transition for either a conduction or a
valence band electron as the case may be. a = ni/rnO (3)
Consider the electron capture process indicated by The net capture rate for electrons by the traps under
Fig. l(a). The rate that the electron in the conduction nonequilibrium conditions can then be written as
band will drop into an empty trap is
nfepl/rno. (1) Ucn = (nft, - nift)/7.o. (4)
(See Table I for the meaning of the symbols.) An entirely similar treatment can be carried out for
The electron emission rate indicated by Fig. l(b) can holes leading to the following equation for the net rate
be written as of capture for holes under nonequilibrium conditions.
aftI (2)
Usp = (pft - piftp)/rpo. (5)
The steady-state recombination statistics involving centers
8
with more than one energy level has also been considered by the
authors. (To be published.) I Electron spin degeneracy is included in E,.
1230 PROCEEDINGS OF THE IRE September
The rate of recombination for nonequilibrium but EC E @c ss ED
steady-state conditions is obtained by requiring that the
net rate of capture of electrons be equal to that of holes.
I ~~~~~~~~~~~IIc
Fn
This condition leads to El [3 ° ° Elt Et 2 a E
U = Ucn
-
Ucp
- (pn -
n2)/[(n + nl)Tlo + (p + pl)rnOj (6) Ev .1
+
ni
4\/TpoTrno
sinh qk
2kT
(4p - q5n)
(20)
cosh /Et-Ei + ln
cosh q +T _p 2 _
In - 1 + exp L2-q (p-,)i /TpO
L\T 2 /rnOJ L_2kT (4 J \kT n
Using a linear potential variation across the junction, The notations are identical to those used by Shockley
the electric field can be written as and Read,4 and are listed in Table I.
E = ('D- V)/W (16) The recombination rate given above is sketched for
where 'D is the built-in voltage. several limiting conditions in Fig. 3.
1232 PROCEEDINGS OF THE IRE September
log I
4
Fig. 3-Variation of the recombination rate in the p-n junction transi-
tion region; (a) forward bias (Op-4,0)q/2kT>>1, (Et-EO)/kT
+j ln r,o/r.ol, (b) reverse bias(4,%-41,)q/2kT>»1, (Et-E,)/kT +3
3-3
+* In rpo/,r.o , (c) small bias (O,,-0)q/2kT-1, (E,-E,)
Ik Ti In rps/raoI=4.
±2 rno-
) (23)
tial I as a function of position in the p-n junction. This
is a difficult problem involving the solution of simul- This approximation slightly overestimates the genera-
taneous nonlinear differential equations.' In this treat- tion current since the generation rate drops exponen-
ment, we shall follow a self-consistent approach given tially to zero near the edges of the space charge layer.
in Appendix I. It is convenient to consider three regions The result obtained above indicates that the traps are
of the applied bias, the large reverse-bias region, the most effective as generation centers if they are located at
small bias region, and the large forward-bias region. the intrinsic Fermi level when the lifetimes of the car-
riers are equal. In general, the traps are most effective
Large Reverse-Bias, - q(k 4>)/kT>»1 if (El-Ei)/kT+(1/2)ln rpo/rno=O. The above result
For this case, the potential energy diagram for holes also shows that the generation current cannot saturate.
is shown in Fig. 4 together with the current distribution For the linear-graded junction this current is propor-
in the p-n junction. The hole current J, shown in the tional to ij power of the applied voltage and for a step
lower part of Fig. 4 can be deduced from the recombina- junction it is proportional to a power of the applied
tion-generation rate and (21). Under large reverse-bias, voltage since the space charge layer width varies ac-
the first term in the denominator of (20) is small com- cordingly.
pared with the second term, since 4O.-4O, is several Although it was shown that the shapes of the imrefs
kT/q inside the space charge layer. Thus, the recombi- have negligible effect on the calculation of the genera-
nation rate is approximately constant over the entire tion-recombination rate, it is instructive to deduce the
transition region as illustrated in Fig. 3(b). The hole shapes of the imrefs. From the relation between the hole
current then is proportional to the distance and de- current and the imref for holes,
creases monotonically. The total recombination-gen- Jp = - qniwp exp Rop- 4)q/kT]d4p/dx, (24)
eration current for this case is then
it can be concluded that in the transition region, the in-
Jra9 =
qUW, (22) crease of the slope of 4, must be slower than the decrease
1957 Sah, Noyce and Shockley: Carrier Generation and Recombination in P-N Junctions 1233
rentcan be written as
qni
V/TPOTnO
W 2 sinh
(TD -
(4Op 4,)q/2kT
4)p
-
+ 4n)q/kT
(27)
where
rZ2 dz
f(b) = 2 + 2bz 1
-Et - E
* cosh + (1/2) In (TpO/nrfo)
Ji_ SMALL EMITTER BIAS acteristics we shall use the linear-graded junction ap-
proximation. The trap level Et-Ei and lifetimes are
obtained by matching the theoretical formula and the ex-
J2 perimental data at three points. It is most convenient
to use two points at relatively small applied bias where
the current from the space charge layer is dominant and
'i
one point at large forward bias where the diffusion cur-
rent dominates. We choose these points to be at applied
bias of 0=qV/kT= -4.6, 4.6, and +18.3. The last point
corresponds to the built-in voltage at room temper-
0
LARGE EMITTER BIAS ature. The currents at these voltages are 2.96X 10-10,
3.75X10-9, and l.OX10-4 amperes respectively from
Figs. 11 and 12.
10
J
Using (27) for the first two points and the formula for
n diffusion current given in Appendix IV we obtain the
following results:
p
IaI
rpo = 1.2 X 10-8 sec,
-nu . I I I
(a)
X. i
io_4 X0 _3 o1-Z lo-l
E -1,r 10
-N
(b) (b)
Fig. 13-(a) Experimental forward characteristics of silicon p-n Fig. 15-Geometry for separating surface and bulk currents; (a) large
junctions. (b) Experimental reverse characteristics of silicon p-n junction area to circumference ratio geometry; (b) small junction
junctions. area to circumference ratio geometry.
1957 Sah, NVoyce and Shockiey: Carrier Generation and Recombination in P-N Junctions 1239
p-n junctions. The recombination of the carriers in the Thus, for a forward current of J= 2 amp/cm2, W= 10-6
space charge layer also explains the variation of the cur- cm and ,up = 500 for Si, the maximum drop of the qutasi-
rent amplification factor of a silicon transistor at low Fermi potential for holes is
emitter current density.
APPENDIX I sinh qSOp/2kT = 0.4 exp - [¢() 2kT]
VARIATION OF THE QUASI-FERMI LEVELS IN THE
SPACE CHARGE LAYER The exponential factor on the right-hand side cannot be
The hole current can be written as more than 1. This is easily seen from Fig. 5 if the refer-
ence potential is at (2) [0,(x) +kn(x) ].==o as was implied
Jp = - qipp(d4p/dx). (32) in (36). In addition, a current less than J should be used
Substituting the expression for p from (19) into (32) as shown in Fig. 5. Thus the upper limit of the drop of
the following differential equation can be obtained. the quasi-Fermi level in the space charge layer is about
(kT/q) and is indeed very small.
d
- exlp-
q
(4o-I
q /d1\ q_ p- 4-')
-(-Iexp-(4 For the large reverse-bias case, 01 > 5, the situation is
ax kT kT dx- kT quite different. Eq. (37) can be approximated by
=--Jr_ . (33)
qMpni sinh 2-
2(W)1,T
The solution of this equation is
exp [() + V( )] 2kT}
exp (qOp/kT) = C- .exp (T
\k T J)dx
/qApnj
(34)
ni, 8e1201
To calculate the variation of the quasi-Fermi potential qp 012 (39)
variation across the space charge layer we use the linear
approximation for the hole current density Jp, and for Thus, for J= 10-6 amp/cm2, W= 10-4 cm and 01= 100,
the electrostatic potential variation. Thus, for-2 W the drop of the quasi-Fermi potential is
x<2W
Jp = J(1 -2x/W) (35) sinh (q5p/2 kT) =
exp [80.7 -
44(P ) q/2kT].
and
' = ('D - 6b) X/W, (36) By successive approximation it can be shown that the
drop of the quasi-Fermi potential for holes is approxi-
where "D is the built-in voltage, &k is the applied volt- mately equal to the applied voltage as indicated in
age and W is the space charge layer width. By the evalu- Fig. 4.
ation of the integral of (34) with these approximations, For small bias, 0, is equal to the built-in voltage. For
the following relation is obtained for the quasi-Fermi 01 20, J= 10-8 amp/cm2, and W= 10-5 cm the drop of
=
potentials for holes at the edges of the space charge the quasi-Fermi potential for holes is approximately
layer.
sinh &tpq/2kT = exp (-12.5 - &kq/kT).
exp kT[ (2 (L)
Thus the drop is appreciable only when the reverse-bias
is greater than about 12.5kT/q.
*sinh qk
2kTL /WP
(2 P
2)2
APPENDIX II
= (JW/qpni) [inh(01/2) - exp (-1/2)]] /1 (37) AVALANCHE MULTIPLICATION OF THE GENERATED
CARRIERS IN THE SPACE CHARGE LAYER
where 01= (ID-- &)q/k T. Suppose that the p-n junction shown in Fig. 16 is
For forward bias, 01 is small and (37) reduces to biased in the reverse direction. Hole current density per
unit area Jf(x) flows toward the left, and electron current
exp [ 2 + P 2 2kT density per unit area Jn(x) flows toward the right. There
is also a net steady-state generation of the hole-electron
sinh(2P ) - 2)]) = JW/2qivni. (38) pairs in the space charge region of U per unit volume per
unit time from the Shockley-Read-Hall generation-
1240 PROCEEDINGS OF THE IRE Septemnber
The solutions are
(x) + dJp (x) IX(X)
_Of Jn(x) = eJ(a-0()dz
J0(X) -_ _ J,x)+dJ,(X) \ N-TYPE f (pJ + qU)eJ (-dzdx + J,no (45)-
.N q It dx
hole
-4-- q LI dx
electron
and
dJ0(x) =
aJ0(x)dx + 3J,(x)dx + qUdx, (40) where M is the current multiplication factor given by
where the first term on the right comes from the multi-
/ W \-1
M I )x
plication of the electron current going into dx from the
side x, and the second term comes from the electrons
Eq. (48) indicates that for =,B the generated current
a
produced by holes going into dx from the side x+dx. in the space charge layer, fqUdx, acts as if it is injected
Similarly, the change of the hole current in dx per unit
into the layer as far as avalanche multiplication is con-
area is
cerned.
-dJp(x) =
aJ0(x)dx + IJp(x)dx + qUdx, (41)
APPENDIX II I
and the sum of the two incremental currents satisfies the ACTIVATION ENERGY OF THE TRAPS
condition that the total current is space constant,
namely The thermal activation energy of the traps is obtained
from the slope of a plot of the log of the reverse current
J = J,(x) + Jn(x) = independent of position. (42) as a function of the reciprocal of temperature at a con-
stant reverse-bias.
To solve the two simultaneous differential equations Consider the range of -6 > 5 where is the normalized
we use the following boundary conditions. At x = 0, applied bias ('p-0-n)q/kT. The function f(b) for this
J= J,o and at x = W, J, = Jpo. Substituting (42) into case can be approximated by (log 2b)/b and the recom-
(40) and (41) the electron and the hole current satisfies bination-generation current can be written as
the following equations:
log [Jrg/Jo(kT) 5/2]
dJn(x)/dx = (a -
$)Jn(x) + 3J + qU (43) _
-log ni
log (E -E -1 (49)
and (t In
6(kT) III cosh +
dJp(x)/dx (a O)Jp(x) aJ qU. (44) L kT 2 rn
.pN-
p+ N- Po-
+ p+ Po -X Si 0.25 0.57
qE(0)/kT (1/A/2Lo)
= We shall give again a list indicating the limiting
values of current density and voltage for this range.
qE( oo)/kT = (1/V2Lo) 2p(O)/bN.
Jnxin Vmin
Thus the electric field varies about a factor of 10 at least. amp/cm2 volt
The gradient of the electric field can be obtained by dif- 27 0.34
ferentiating (55). At x = oo, dE/dx is zero and at x = 0 43 0.75
.I
the electric field is about
ACKNOWLEDGMENT
(q/kT)(dE/dx) = I/2LM2 The authors wish to acknowledge the helpful discus-
at the lowest injection limit. This corresponds to about sions with their colleagues at the Shockley Semicon-
25 v/cm for a 1-microsecond lifetime material at room ductor Laboratory. The diffused silicon materials were
temperature. The quantity (Keo/q)dEdx can now be prepared by D. Grunwald, and some of the data were
compared with p-n+N from (53). Using the values taken by Dr. S. M. Fok and M. Asemissen.
given above we obtain (Note added in proof: The forward characteristics of
germanium p-n junctions at low temperatures have re-
p - n + N>>7.6 X 1010 cm-3, cently been investigated independently by M. Bernard
using the same model. "Mesures in fonction de Ia tem-
which is usually satisfied since N is of the order of IO'l perature du Courant," J. Electronics, vol. 2, pp. 579-
cm-3 for silicon of a few ohm-cm resistivity. 596; May, 1957.)