Safety data sheet

According to 1907/2006/EC (REACH), 2015/830/EU

HYDRU Disinfectant

SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING

1.1 Product identifier: HYDRU Disinfectant
1.2 Relevant identified uses of the substance or mixture and uses advised against:
Relevant uses: Detergent
Uses advised against: All uses not specified in this section or in section 7.3
1.3 Details of the supplier of the safety data sheet:
HydrUStent, S.A.
AVEPARK - Parque de Ciência e Tecnologia (Sala 213)
Zona Industrial da Gandra,
4805-017 Guimarães

1.4 Emergency telephone number: C.I.A.V. 800 250 250

SECTION 2: HAZARDS IDENTIFICATION

2.1 Classification of the substance or mixture:
CLP Regulation (EC) No 1272/2008:
The product is not classified as hazardous according to CLP Regulation (EC) No 1272/2008.
2.2 Label elements:
CLP Regulation (EC) No 1272/2008:
None
2.3 Other hazards:
Product fails to meet PBT/vPvB criteria

SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS **

3.1 Substance:
Non-applicable
3.2 Mixture:
Chemical description: Mixture of substances
Components:
In accordance with Annex II of Regulation (EC) No 1907/2006 (point 3), the product contains:
Identification Chemical name/Classification Concentration
CAS: 7173-51-5 Didecyldimethylammonium chloride⁽¹⁾ ATP CLP00
EC: 230-525-2
0,2 - <1 %
Index: 612-131-00-6
Regulation 1272/2008 Acute Tox. 4: H302; Skin Corr. 1B: H314 - Danger
REACH: 01-2119945987-15-
XXXX

⁽¹⁾ Voluntarily-listed substance failing to meet any of the criteria set out in Regulation (EU) No. 2015/830

To obtain more information on the hazards of the substances consult sections 11, 12 and 16.

** Changes with regards to the previous version

SECTION 4: FIRST AID MEASURES

4.1 Description of first aid measures:
The symptoms resulting from intoxication can appear after exposure, therefore, in case of doubt, seek medical attention for
direct exposure to the chemical product or persistent discomfort, showing the SDS of this product.
By inhalation:
This product does not contain substances classified as hazardous for inhalation, however, in case of symptoms of intoxication
remove the person affected from the exposure area and provide with fresh air. Seek medical attention if the symptoms get worse
or persist.

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 Safety data sheet
According to 1907/2006/EC (REACH), 2015/830/EU

HYDRU Disinfectant

SECTION 4: FIRST AID MEASURES (continued)

By skin contact:
This product is not classified as hazardous when in contact with the skin.

By eye contact:
Rinse eyes thoroughly with water for at least 15 minutes. If the injured person uses contact lenses, these should be removed
unless they are stuck to the eyes, in which case removal could cause further damage. In all cases, after cleaning, a doctor should
be consulted as quickly as possible with the SDS for the product.
By ingestion/aspiration:
Do not induce vomiting, but if it does happen keep the head down to avoid aspiration. Keep the person affected at rest. Rinse
out the mouth and throat, as they may have been affected during ingestion.
4.2 Most important symptoms and effects, both acute and delayed:
Acute and delayed effects are indicated in sections 2 and 11.
4.3 Indication of any immediate medical attention and special treatment needed:
Non-applicable

SECTION 5: FIREFIGHTING MEASURES

5.1 Extinguishing media:
Product is non-flammable under normal conditions of storage, handling and use. In the case of combustion as a result of
improper handling, storage or use preferably use polyvalent powder extinguishers (ABC powder), in accordance with the
Regulation on fire protection systems. IT IS NOT RECOMMENDED to use full jet water as an extinguishing agent.
5.2 Special hazards arising from the substance or mixture:
As a result of combustion or thermal decomposition reactive sub-products are created that can become highly toxic and,
consequently, can present a serious health risk.
5.3 Advice for firefighters:
Depending on the magnitude of the fire it may be necessary to use full protective clothing and self-contained breathing apparatus
(SCBA). Minimum emergency facilities and equipment should be available (fire blankets, portable first aid kit,...) in accordance
with Directive 89/654/EC.
Additional provisions:
Act in accordance with the Internal Emergency Plan and the Information Sheets on actions to take after an accident or other
emergencies. Eliminate all sources of ignition. In case of fire, cool the storage containers and tanks for products susceptible to
combustion, explosion or BLEVE as a result of high temperatures. Avoid spillage of the products used to extinguish the fire into an
aqueous medium.

SECTION 6: ACCIDENTAL RELEASE MEASURES

6.1 Personal precautions, protective equipment and emergency procedures:
Isolate leaks provided that there is no additional risk for the people performing this task. Personal protection equipment must be
used against potential contact with the spilt product (See section 8). Evacuate the area and keep out those who do not have
protection.
6.2 Environmental precautions:
This product is not classified as hazardous to the environment. Keep product away from drains, surface and ground water.
6.3 Methods and material for containment and cleaning up:
It is recommended:
Absorb the spillage using sand or inert absorbent and move it to a safe place. Do not absorb in sawdust or other combustible
absorbents. For any concern related to disposal consult section 13.
6.4 Reference to other sections:
See sections 8 and 13.

SECTION 7: HANDLING AND STORAGE

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 Safety data sheet
According to 1907/2006/EC (REACH), 2015/830/EU

HYDRU Disinfectant

SECTION 7: HANDLING AND STORAGE (continued)

7.1 Precautions for safe handling:
A.- Precautions for safe manipulation
Comply with the current legislation concerning the prevention of industrial risks. Keep containers hermetically sealed. Control
spills and residues, destroying them with safe methods (section 6). Avoid leakages from the container. Maintain order and
cleanliness where dangerous products are used.
B.- Technical recommendations for the prevention of fires and explosions
Product is non-flammable under normal conditions of storage, handling and use. It is recommended to transfer at slow speeds
to avoid the generation of electrostatic charges that can affect flammable products. Consult section 10 for information on
conditions and materials that should be avoided.
C.- Technical recommendations to prevent ergonomic and toxicological risks
Do not eat or drink during the process, washing hands afterwards with suitable cleaning products.
D.- Technical recommendations to prevent environmental risks
It is recommended to have absorbent material available at close proximity to the product (See subsection 6.3)
7.2 Conditions for safe storage, including any incompatibilities:
A.- Technical measures for storage
Minimum Temp.: 5 ºC
Maximum Temp.: 30 ºC
Maximum time: 12 Months
B.- General conditions for storage
Avoid sources of heat, radiation, static electricity and contact with food. For additional information see subsection 10.5
7.3 Specific end use(s):
Except for the instructions already specified it is not necessary to provide any special recommendation regarding the uses of this
product.

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION

8.1 Control parameters:
Substances whose occupational exposure limits have to be monitored in the workplace
There are no occupational exposure limits for the substances contained in the product
DNEL (Workers):
Short exposure Long exposure

Identification Systemic Local Systemic Local

Didecyldimethylammonium chloride Oral Non-applicable Non-applicable Non-applicable Non-applicable
CAS: 7173-51-5 Dermal Non-applicable Non-applicable 8,6 mg/kg Non-applicable
EC: 230-525-2 Inhalation Non-applicable Non-applicable 18,2 mg/m³ Non-applicable

DNEL (General population):

Non-applicable
PNEC:
Identification
Didecyldimethylammonium chloride STP 0,595 mg/L Fresh water 0,002 mg/L
CAS: 7173-51-5 Soil 1,4 mg/kg Marine water 0,0002 mg/L
EC: 230-525-2 Intermittent 0,00029 mg/L Sediment (Fresh water) 2,82 mg/kg
Oral Non-applicable Sediment (Marine water) 0,28 mg/kg
8.2 Exposure controls:
A.- General security and hygiene measures in the work place

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 Safety data sheet
According to 1907/2006/EC (REACH), 2015/830/EU

HYDRU Disinfectant

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES

9.1 Information on basic physical and chemical properties:
For complete information see the product datasheet.
Appearance:
Physical state at 20 ºC: Liquid
Appearance: Characteristic
Colour: Not available
Odour: Characteristic
Odour threshold: Non-applicable *
Volatility:
Boiling point at atmospheric pressure: 82 - 100 ºC
Vapour pressure at 20 ºC: 2351 Pa
Vapour pressure at 50 ºC: 12384,64 Pa (12,38 kPa)
Evaporation rate at 20 ºC: Non-applicable *
Product description:
Density at 20 ºC: 1030,9 kg/m³
Relative density at 20 ºC: 1,031
Dynamic viscosity at 20 ºC: Non-applicable *
Kinematic viscosity at 20 ºC: Non-applicable *
Kinematic viscosity at 40 ºC: Non-applicable *
Concentration: Non-applicable *
pH: Non-applicable *
Vapour density at 20 ºC: Non-applicable *
Partition coefficient n-octanol/water 20 ºC: Non-applicable *
Solubility in water at 20 ºC: Non-applicable *
Solubility properties: Non-applicable *
Decomposition temperature: Non-applicable *
Melting point/freezing point: Non-applicable *
Explosive properties: Non-applicable *
Oxidising properties: Non-applicable *
Flammability:
Flash Point: Non Flammable (>60 ºC)
Flammability (solid, gas): Non-applicable *
Autoignition temperature: 399 ºC
Lower flammability limit: Non-applicable *
Upper flammability limit: Non-applicable *
Explosive:
Lower explosive limit: Non-applicable *
Upper explosive limit: Non-applicable *
9.2 Other information:
Surface tension at 20 ºC: Non-applicable *
Refraction index: Non-applicable *
*Not relevant due to the nature of the product, not providing information property of its hazards.

SECTION 10: STABILITY AND REACTIVITY

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 Safety data sheet
According to 1907/2006/EC (REACH), 2015/830/EU

HYDRU Disinfectant

SECTION 10: STABILITY AND REACTIVITY (continued)

10.1 Reactivity:
No hazardous reactions are expected because the product is stable under recommended storage conditions. See section 7.
10.2 Chemical stability:
Chemically stable under the conditions of storage, handling and use.
10.3 Possibility of hazardous reactions:
Under the specified conditions, hazardous reactions that lead to excessive temperatures or pressure are not expected.
10.4 Conditions to avoid:
Applicable for handling and storage at room temperature:
Shock and friction Contact with air Increase in temperature Sunlight Humidity
Not applicable Not applicable Not applicable Not applicable Not applicable

10.5 Incompatible materials:

Acids Water Oxidising materials Combustible materials Others
Avoid strong acids Not applicable Precaution Not applicable Avoid alkalis or strong bases

10.6 Hazardous decomposition products:

See subsection 10.3, 10.4 and 10.5 to find out the specific decomposition products. Depending on the decomposition conditions,
complex mixtures of chemical substances can be released: carbon dioxide (CO2), carbon monoxide and other organic
compounds.

SECTION 11: TOXICOLOGICAL INFORMATION **

11.1 Information on toxicological effects:

The experimental information related to the toxicological properties of the product itself is not available

Dangerous health implications:

In case of exposure that is repetitive, prolonged or at concentrations higher than the recommended occupational exposure limits,
adverse effects on health may result, depending on the means of exposure:
A- Ingestion (acute effect):

- Acute toxicity : Based on available data, the classification criteria are not met, however, it contains substances classified
as dangerous for consumption. For more information see section 3.
- Corrosivity/Irritability: Based on available data, the classification criteria are not met. However, it does contain substances
classified as dangerous for this effect. For more information see section 3.
B- Inhalation (acute effect):

- Acute toxicity : Based on available data, the classification criteria are not met, as it does not contain substances classified
as dangerous for inhalation. For more information see section 3.
- Corrosivity/Irritability: Based on available data, the classification criteria are not met. However, it does contain substances
classified as dangerous for this effect. For more information see section 3.
C- Contact with the skin and the eyes (acute effect):

- Contact with the skin: Based on available data, the classification criteria are not met. However, it contains substances
classified as dangerous for skin contact. For more information see section 3.
- Contact with the eyes: Based on available data, the classification criteria are not met. However, it does contain substances
classified as dangerous for this effect. For more information see section 3.
D- CMR effects (carcinogenicity, mutagenicity and toxicity to reproduction):

- Carcinogenicity: Based on available data, the classification criteria are not met, as it does not contain substances classified
as dangerous for the effects mentioned. For more information see section 3.
IARC: Propan-2-ol (3)
- Mutagenicity: Based on available data, the classification criteria are not met, as it does not contain substances classified as
dangerous for this effect. For more information see section 3.
- Reproductive toxicity: Based on available data, the classification criteria are not met, as it does not contain substances
classified as dangerous for this effect. For more information see section 3.
E- Sensitizing effects:

** Changes with regards to the previous version

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 Safety data sheet
According to 1907/2006/EC (REACH), 2015/830/EU

HYDRU Disinfectant

SECTION 11: TOXICOLOGICAL INFORMATION ** (continued)

- Respiratory: Based on available data, the classification criteria are not met, as it does not contain substances classified as
dangerous with sensitising effects. For more information see section 3.
- Cutaneous: Based on available data, the classification criteria are not met, as it does not contain substances classified as
dangerous for this effect. For more information see section 3.
F- Specific target organ toxicity (STOT) - single exposure:

Based on available data, the classification criteria are not met, as it does not contain substances classified as dangerous for
this effect. For more information see section 3.
G- Specific target organ toxicity (STOT)-repeated exposure:

- Specific target organ toxicity (STOT)-repeated exposure: Based on available data, the classification criteria are not met, as
it does not contain substances classified as dangerous for this effect. For more information see section 3.
- Skin: Based on available data, the classification criteria are not met, as it does not contain substances classified as
dangerous for this effect. For more information see section 3.
H- Aspiration hazard:

Based on available data, the classification criteria are not met, as it does not contain substances classified as dangerous for
this effect. For more information see section 3.
Other information:

Non-applicable

Specific toxicology information on the substances:

Identification Acute toxicity Genus

Didecyldimethylammonium chloride LD50 oral 500 mg/kg Rat
CAS: 7173-51-5 LD50 dermal Non-applicable
EC: 230-525-2 LC50 inhalation Non-applicable

** Changes with regards to the previous version

SECTION 12: ECOLOGICAL INFORMATION **

The experimental information related to the eco-toxicological properties of the product itself is not available
12.1 Toxicity:
Not available
12.2 Persistence and degradability:
Identification Degradability Biodegradability
Didecyldimethylammonium chloride BOD5 Non-applicable Concentration 100 mg/L
CAS: 7173-51-5 COD Non-applicable Period 28 days
EC: 230-525-2 BOD5/COD Non-applicable % Biodegradable 0%
12.3 Bioaccumulative potential:
Identification Bioaccumulation potential
Didecyldimethylammonium chloride BCF 81
CAS: 7173-51-5 Pow Log 4.66
EC: 230-525-2 Potential Moderate
12.4 Mobility in soil:
Identification Absorption/desorption Volatility
Didecyldimethylammonium chloride Koc 440000 Henry Non-applicable
CAS: 7173-51-5 Conclusion Immobile Dry soil Non-applicable
EC: 230-525-2 Surface tension Non-applicable Moist soil Non-applicable
12.5 Results of PBT and vPvB assessment:
Product fails to meet PBT/vPvB criteria
12.6 Other adverse effects:
Not described

** Changes with regards to the previous version

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 Safety data sheet
According to 1907/2006/EC (REACH), 2015/830/EU

HYDRU Disinfectant

SECTION 13: DISPOSAL CONSIDERATIONS

13.1 Waste treatment methods:
Waste class (Regulation (EU) No
Code Description
1357/2014)
20 01 30 detergents other than those mentioned in 20 01 29 Non dangerous

Type of waste (Regulation (EU) No 1357/2014):

Non-applicable
Waste management (disposal and evaluation):
Consult the authorized waste service manager on the assessment and disposal operations in accordance with Annex 1 and Annex
2 (Directive 2008/98/EC). As under 15 01 (2014/955/EC) of the code and in case the container has been in direct contact with
the product, it will be processed the same way as the actual product. Otherwise, it will be processed as non-dangerous residue.
We do not recommended disposal down the drain. See paragraph 6.2.
Regulations related to waste management:
In accordance with Annex II of Regulation (EC) No 1907/2006 (REACH) the community or state provisions related to waste
management are stated
Community legislation: Directive 2008/98/EC, 2014/955/EU, Regulation (EU) No 1357/2014

SECTION 14: TRANSPORT INFORMATION

Transport of dangerous goods by land:
With regard to ADR 2019 and RID 2019:
14.1 UN number: Non-applicable
14.2 UN proper shipping name: Non-applicable
14.3 Transport hazard class(es): Non-applicable
Labels: Non-applicable
14.4 Packing group: Non-applicable
14.5 Environmental hazards: No
14.6 Special precautions for user
Special regulations: Non-applicable
Tunnel restriction code: Non-applicable
Physico-Chemical properties: see section 9
Limited quantities: Non-applicable
14.7 Transport in bulk according Non-applicable
to Annex II of Marpol and
the IBC Code:
Transport of dangerous goods by sea:
With regard to IMDG 38-16:
14.1 UN number: Non-applicable
14.2 UN proper shipping name: Non-applicable
14.3 Transport hazard class(es): Non-applicable
Labels: Non-applicable
14.4 Packing group: Non-applicable
14.5 Environmental hazards: No
14.6 Special precautions for user
Special regulations: Non-applicable
EmS Codes:
Physico-Chemical properties: see section 9
Limited quantities: Non-applicable
Segregation group: Non-applicable
14.7 Transport in bulk according Non-applicable
to Annex II of Marpol and
the IBC Code:
Transport of dangerous goods by air:
With regard to IATA/ICAO 2019:

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 Safety data sheet
According to 1907/2006/EC (REACH), 2015/830/EU

HYDRU Disinfectant

SECTION 14: TRANSPORT INFORMATION (continued)

14.1 UN number: Non-applicable

14.2 UN proper shipping name: Non-applicable
14.3 Transport hazard class(es): Non-applicable
Labels: Non-applicable
14.4 Packing group: Non-applicable
14.5 Environmental hazards: No
14.6 Special precautions for user
Physico-Chemical properties: see section 9
14.7 Transport in bulk according Non-applicable
to Annex II of Marpol and
the IBC Code:

SECTION 15: REGULATORY INFORMATION

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture:
Regulation (EC) No 528/2012: contains a preservative to protect the initial properties of the treated article. Contains
Didecyldimethylammonium chloride.
Candidate substances for authorisation under the Regulation (EC) No 1907/2006 (REACH): Non-applicable
Substances included in Annex XIV of REACH ("Authorisation List") and sunset date: Non-applicable
Regulation (EC) No 1005/2009, about substances that deplete the ozone layer: Non-applicable
Article 95, REGULATION (EU) No 528/2012: Didecyldimethylammonium chloride (Product-type 1, 2, 3, 4, 6, 8, 10, 11, 12)
REGULATION (EU) No 649/2012, in relation to the import and export of hazardous chemical products: Contains
Didecyldimethylammonium chloride
Regulation (EC) No 648/2004 on detergents:
In accordance with this regulation the product complies with the following:
The tensoactives contained in this mixture comply with the biodegradibility criteria stipulated in Regulation (EC) nº648/2004 on
detergents. The information to prove this is available to the relevant authorities of the Member States and will be shown to them
by direct request or the request of a detergent manufacturer.
Relevant instructions for use:
DESCRIÇÃO:
The product is a quick-acting disinfectant that eliminates bacteria, fungi and viruses.
O Produto SANI PROTECT é um desinfetante de ação rápida que elimina todos os
It can be used on different types of surfaces, including hands.
tipos de bactérias, fungos e vírus.
Pode ser utilizado em todos os tipos de superfícies, tais como mãos, portas, etc.
Instructions for use
Não contém componentes perigosos. Não é inflamável e é biodegradável.
Apply on the surface to be treated.
UTILIZAÇÃO:
Warnings and
Pulverize na storagea ser tratada.
superfície
No hazardous components. Nonflammable. Biodegradable. Keep out of the reach of children. Do not apply on hot
MANUSEAMENTO
surfaces. Causes Eserious
ARMAZENAMENTO:
eye irritation.
Manter guardado e afastado das crianças. Siga as instruções na ficha de dados de
segurança para um manuseamento seguro do produto. Não aplique o produto em
superfícies quentes.
Labelling for contents:
Component Concentration interval
Non-ionic surfactants % (w/w) < 5

Preservation agents: Didecyldimethylammonium chloride (DIDECYLDIMONIUM CHLORIDE).

Seveso III:
Non-applicable
Limitations to commercialisation and the use of certain dangerous substances and mixtures (Annex XVII REACH,
etc ….):
Non-applicable
Specific provisions in terms of protecting people or the environment:

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 Safety data sheet
According to 1907/2006/EC (REACH), 2015/830/EU

HYDRU Disinfectant

SECTION 15: REGULATORY INFORMATION (continued)

It is recommended to use the information included in this safety data sheet as a basis for conducting workplace-specific risk
assessments in order to establish the necessary risk prevention measures for the handling, use, storage and disposal of this
product.
Other legislation:
The product could be affected by sectorial legislation
- Regulation (EC) No 1223/2009 of the European Parliament and of the Council of 30 November 2009 on cosmetic products
- Regulation (EC) No 648/2004 of the European Parliament and of the Council of 31 March 2004 on detergents
- Commission Regulation (EC) No 907/2006 of 20 June 2006 amending Regulation (EC) No 648/2004 of the European Parliament
and of the Council on detergents, in order to adapt Annexes III and VII
- Commission Regulation (EC) No 551/2009 of 25 June 2009 amending Regulation (EC) No 648/2004 of the European Parliament
and of the Council on detergents, in order to adapt Annexes V and VI thereto (surfactant derogation)
15.2 Chemical safety assessment:
The supplier has not carried out evaluation of chemical safety.

SECTION 16: OTHER INFORMATION

Legislation related to safety data sheets:
This safety data sheet has been designed in accordance with ANNEX II-Guide to the compilation of safety data sheets of
Regulation (EC) No 1907/2006 (Regulation (EC) No 2015/830)
Modifications related to the previous Safety Data Sheet which concerns the ways of managing risks.:
COMPOSITION/INFORMATION ON INGREDIENTS (SECTION 3, SECTION 11, SECTION 12):
· New declared substances
Didecyldimethylammonium chloride (7173-51-5)
Texts of the legislative phrases mentioned in section 3:
The phrases indicated do not refer to the product itself; they are present merely for informative purposes and refer to the
individual components which appear in section 3
CLP Regulation (EC) No 1272/2008:
Acute Tox. 4: H302 - Harmful if swallowed
Skin Corr. 1B: H314 - Causes severe skin burns and eye damage
Classification procedure:
Non-applicable
Advice related to training:
Minimal training is recommended in order to prevent industrial risks for staff using this product and to facilitate their
comprehension and interpretation of this safety data sheet, as well as the label on the product.
Principal bibliographical sources:
http://echa.europa.eu
http://eur-lex.europa.eu
Abbreviations and acronyms:
ADR: European agreement concerning the international carriage of dangerous goods by road
IMDG: International maritime dangerous goods code
IATA: International Air Transport Association
ICAO: International Civil Aviation Organisation
COD: Chemical Oxygen Demand
BOD5: 5-day biochemical oxygen demand
BCF: Bioconcentration factor
LD50: Lethal Dose 50
LC50: Lethal Concentration 50
EC50: Effective concentration 50
Log-POW: Octanol-water partition coefficient
Koc: Partition coefficient of organic carbon

The information contained in this safety data sheet is based on sources, technical knowledge and current legislation at European and state level, without being able to guarantee its accuracy. This
information cannot be considered a guarantee of the properties of the product, it is simply a description of the security requirements. The occupational methodology and conditions for users of
this product are not within our awareness or control, and it is ultimately the responsibility of the user to take the necessary measures to obtain the legal requirements concerning the
manipulation, storage, use and disposal of chemical products. The information on this safety data sheet only refers to this product, which should not be used for needs other than those specified.

- END OF SAFETY DATA SHEET -

Date of compilation: 06/03/2020 Revised: 07/04/2020 Version: 2 (Replaced 1)

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