MHT-CET 2021 Question Paper

25th September 2021

1. Which from the following is NOT a primary 9. What is the contribution of each particle at
amine? corner in unit cell of cubic system?
(A) Diphenyl amine (B) Benzyl amine 1 1
(C) p - Toluidine (D) Allyl amine (A) (B)
2 8
2. Which among the following has the lowest 1 1
(C) (D)
boiling point? 4 6
(A) CH3 – O – CH2 – CH3
(B) CH3 – CH2 – CH2 – OH 10. The enthalpy of formation of ammonia gas is
(C) CH3 – CH2 – CH2 – CH3 –46 kJ mol–1. Find the enthalpy of following
(D) CH3 – COOH reaction.
2N2(g) + 6H2(g) 
 4NH3(g)
3. Which of the following equations represents
(A) –184 kJ (B) –130 kJ
relation between t 1 and rate constant for a first
2 (C) –38 kJ (D) –92 kJ
order reactions?
11. What is the value of dextrorotation of glucose
2  303
(A) k (B) t 1  0  693 and sucrose respectively?
t1 k
2
2
(A) + 66.5 and + 52.7
k (B) + 52.7 and + 92.4
(C) t1  (D) t 1  2  303 k
2 0  693 2 (C) + 52.7 and + 66.5
(D) + 92.4 and +57.7
4. Which polymer is formed from hexamethylene
diammonium adipate monomer? 12. One mole maltose on hydrolysis forms
(A) Buna - S _______.
(B) Nylon 6,6 (A) one mole glucose and one mole galactose
(C) Nylon 6 (B) two moles glucose
(D) Polyacrylonitrile
(C) one mole glucose and one mole fructose
5. Calculate molar mass of solute if 5 g of it in (D) two moles galactose
100 g of solvent has the depression in freezing
point 2 15 K. (Kf for solvent = 14  7 K kg mol–1). 13. If ‘a’ is edge length of a simple cubic unit cell
(A) 180 g mol–1 (B) 78 g mol–1 then atomic radius is given as _______.
–1
(C) 60 g mol (D) 342 g mol–1 (A) 0.1 a (B) 0.5 a
(C) a (D) 1.5 a
6. Which among the following has the highest
boiling point? 14. Identify optically inactive compound from the
(A) Propan-1-ol (B) Ethanoic acid following.
(C) Propanone (D) Propanal
(A) 2-Bromopentane
7. Which of the following formulae is used to (B) 2-Bromo-3-methylbutane
calculate angular momentum of an electron in
given stationary orbit? (C) 3-Bromohexane
(D) 2-Bromo-2-methylbutane
(A) mvr = n  h  (B) mvr = n  2  
2    h 
15. Fraction of the total number of moles of an
mv  h  n electrolyte dissociated when equilibrium is
(C)  r  (D) mvr =
n  2  h attained is known as _______.
8. Identify the catalyst used in following reaction. (A) van’t Hoff factor
Vegetable oil + H2 Catalyst
vegetable ghee (B) degree of dissociation
(A) Ni(s) (B) Mo(s) (C) degree of hydrolysis
(C) Pb(s) (D) Fe(s) (D) percentage dissociation
1
  MHT- CET 25th Sept. 2021
QUESTION PAPER
16. Which among the following compounds is NOT 25. RCl +AgF   RF + AgCl 
a phenol? This reaction is an example of _______.
OH
OH (B) (A) Sandmeyer’s reaction
(A)
(B) Swartz reaction
(C) Finkelstein reaction
NO2 Br (D) Wurtz–Fitting reaction
(C) OH (D)
26. Identify the pair of compounds from the
OH following that exhibits chain isomerism.
(A) Ethanol and methoxymethane
17. If Q is charge of one mole of electron equal to (B) n-Butane and 2-methylpropane
96500 coulombs, then the number of moles of (C) Ethoxyethane and n-butyl alcohol
electrons actually passed during electrolysis is (D) Keto form and enol form of carbonyl
given as _______. compounds
96500 96500 27. What is the value of Henry’s law constant for
(A) (B)
Q 2Q CH3Br if its solubility is 0.08 mol L–1 at 0.5 bar?
Q (A) 0.50 mol L–1 bar–1
(C) 96500  Q (D) (B) 0.40 mol L–1 bar–1
96500
(C) 0.16 mol L–1 bar–1
18. Identify neutral complex from the following. (D) 0.08 mol L–1 bar–1
(A) [Fe(CN)6]4– (B) [Fe(CO)5] 28. Identify the magnetic behavior and structure of
(C) [Cu(NH3)4]2+ (D) [Ni(CN)4]2– [Ni(CN)4]2– complex from the following.
19. Which of the following polymer is used in the (A) Paramagnetic and pyramidal
manufacture of drinking straws? (B) Diamagnetic and tetrahedral
(A) Polypropylene (B) PET (C) Diamagnetic and square planar
(C) LDPE (D) Polystyrene (D) Paramagnetic and square planar
20. Aromatization reaction involves _______. 29. Calculate number of moles of nitrogen gas filled in
(A) dehydration and oxidation a container of volume 3  05 dm3 at 32 °C and at
(B) dehydrogenation and cyclization 4  7 atm pressure. (R = 0  0821 dm3 atm K–1 mol–1)
(C) dehydrogenation and oxidation (A) 2.30 (B) 1.65
(D) hydrogenation and cyclization (C) 1.14 (D) 0.57

21. Which of the following oxoacids of sulphur is 30. Which of the following compounds on reactions
called as pyrosulphuric acid? with Grignard’s reagent followed by hydrolysis
(A) H2S2O3 (B) H2SO5 forms tertiary alcohol?
(C) H2S2O7 (D) H2S2O8 (A) Propanone (B) Ethanal
(C) Methanal (D) Propanal
22. Find out the difference between ΔH and ΔU at
300 K for the following reaction. 31. Which among the following has the lowest pKa
value?
C(graphite) + CO2(g) 
 2CO(g)
(A) Monochloroacetic acid
(A) 2.5 kJ (B) 5.0 kJ (B) Acetic acid
(C) 3.6 kJ (D) 7.5 kJ (C) Trichloroacetic acid
(D) Dichloracetic acid
23. What is the relation between solubility and
32. The reaction in which –C≡N group is converted
solubility product for lead iodide?
into –CH2NH2 group is called ______.
(A) Ksp = 8S3 (B) Ksp = 4S3
2 (A) Hofmann alkylation
(C) Ksp = S (D) Ksp = 27S4 (B) Hofmann degradation
24. Which among the following reactions is used to (C) Mendius reaction
prepare oleum? (D) Hofmann elimination
(A) SO3 + H2SO4   33. What is the value of density of an element
(B) 2NaOH + SO2   having bcc structure with edge length 5 Ao ?
(Atomic mass = 70 g mol–1)
(C) I2 + SO2 + 2H2O  
(A) 4.35 g cm–3 (B) 3.72 g cm–3
(D) Na2SO3 + H2O + SO2   (C) 5.35 g cm –3
(D) 1.86 g cm–3
22
  MHT- CET 25th Sept. 2021
QUESTION PAPER
34. Which of the following factors does NOT affect 43. Which among the following groups causes +I
heat of reaction? effect?
(A) The path by which final products are formed (A) Cyano (B) Carboxy
(B) Temperature (C) Ethyl (D) Ester
(C) Physical states of reactants
44. How many coulombs of electricity is required to
(D) Physical states of products
deposit 0.5 g of calcium metal (Molar mass
35. Which of the following molecules has the = 40.0 g mol–1) from calcium ions?
highest bond order? (A) 2412.5 C (B) 3612.5 C
(A) Cl2 (B) O2 (C) 2214.0 C (D) 3302.0 C
(C) H2 (D) N2
45. Which polymer from the following is used to
36. A weak monobasic acid is 0.1 % dissociated in manufacture toys?
0.04 M solution. Calculate dissociation constant (A) Rayon (B) HDP
of acid. (C) LDP (D) Glyptal
(A) 4.5  10–6 (B) 2.8 10–6
–8 46. “A given compound always contains exactly the
(C) 4.0 10 (D) 2.5 10–8
same proportion of elements by weight” is a
37. In carbinol system, sec-butyl alcohol is named statement of _______.
as _______. (A) Law of combining volumes of gases
(A) sec-butyl carbinol (B) Law of conservation of mass
(B) ethyl methyl carbinol (C) Law of multiple proportion
(C) diethyl carbinol (D) Law of definite proportion
(D) isopropyl carbinol
47. What is the relation between boiling point
38. Which of the following metals when heated elevation and molality of solution?
with hydrogen does NOT form hydride? 1 m
(A) Kb = (B) Kb =
(A) Mg (B) Ca Tb  m Tb
(C) Si (D) Be Tb
(C) Kb = (D) Kb = ΔTb  m
39. What is the molar conductivity of 0.20 M KCl m
solution if its conductivity is 0.0242 S cm–1 at
48. Which among the following lanthanoid
298 K?
hydroxides is the strongest base?
(A) 148  4 S cm2 mol–1
(A) La(OH)3 (B) Lu(OH)3
(B) 82  6 S cm2 mol–1 (C) Sm(OH)3 (D) Ho(OH)3
(C) 121 0 S cm2 mol–1
(D) 484  0 S cm2 mol–1 49. Identify the number of electrons lost by H2O2
when it is oxidised to O2 according to following
40. Which of the following compounds forms reaction.
1-Bromo-1-methylcyclohexane when treated H 2O2 aq   ClO4 aq  
 ClO2 aq   O2 g 
with HBr?
CH3CH3 (A) 2 electrons
(B) 1 electron
(A) (B) (C) No loss of electron
CH3 (D) 4 electrons
CH3
(C) (D) 50. For the reaction 2NO  Cl2 
2NOCl ,
d  Cl2 
what is the relation between and
41. Which among the following statements about dt
common properties of d-block elements is NOT d  NOCl
true? ?
dt
(A) These are bad conductors of heat and
1 d  NOCl d  Cl2 
electricity. (A)  2
(B) These have high tensile strength. 2 dt dt
(C) These are electropositive metals. d  NOCl d  Cl2 
(B) 
(D) These are lustrous and shining. dt dt
d  NOCl 1 d  Cl2 
42. A first order reaction takes 40 min for 50% (C) 
decomposition; calculate its half life time. dt 2 dt
(A) 20 min (B) 4 min d  NOCl d  Cl2 
(D)  2
(C) 2 min (D) 40 min dt dt